检索结果-南通市图书馆

PVA/PVP blend polymer matrix for hosting carriers in facilitated transport membranes: Synergistic enhancement of CO2 separation performance

引用

Green Energy & Environment 2020年第1期5卷 59-68页

作者： ragne marie lilleby helberg Zhongde Dai Luca Ansaloni Liyuan Deng Department of Chemical Engineering Norwegian University of Science and Technology

CO2 separation performance in facilitated transport membranes has been reported depended not only on the CO2 carrier properties but also to a great extent on the polymeric matrix regarding the capacity of retaining water and carriers as well as the processability for coating defect-free ultra-thin films. In this study, the blends of hydrophilic polymers polyvinyl pyrrolidone(PVP) and polyvinyl alcohol(PVA) were studied to find an optimal polymer matrix to host carriers in facilitated transport membranes for enhanced CO2 separation. It is found out that the optimized blend is 50/50 PVA/PVP by weight, which shows a significant increase in the water uptake(from 63 to 84%) at equilibrium state compared to the neat PVA. Polyethyleneimine(PEI) was employed to provide sample carriers to evaluate the synergistic effect of PVA and PVP on the CO2 separation performance. A thin film composite(TFC) membrane of the optimized blend(50/50 PVA/PVP with 50 wt% PEI) was fabricated on polysulfone(PSf) porous support. The fabrication of the TFC membranes is simple and low cost, and CO2 permeance of the optimized blend membrane is nearly doubled with the CO2/N2 selectivity remained unchanged, showing great potential for industrial applications of the resulted membranes.

关键词： TFC membrane Facilitated transport CO2 separation Polyvinyl alcohol Polyvinyl pyrrolidone

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Nanocomposite membranes with high-charge and size-screened phosphorylated nanocellulose fibrils for CO_(2)separation

引用

Green Energy & Environment 2021年第4期6卷 585-596页

作者： ragne marie lilleby helberg Jonathan Ø.Torstensen Zhongde Dai Saravanan Janakiram Gary Chinga-Carrasco Øyvind W.Gregersen Kristin Syverud Liyuan Deng Department of Chemical Engineering Norwegian University of Science and TechnologyTrondheim7491Norway RISE PFI Trondheim7491Norway

In this study,cellulose nanofibrils(CNF)of high charge(H-P-CNF)and screened size(H-P-CNF-S)were fabricated by increasing the charge of phosphorylated cellulose nanofibrils(P-CNFs)during the pre-treatment step of CNF *** show that the H-P-CNF have a significantly higher charge(3.41 mmol g^(-1))compared with P-CNF(1.86 mmol g^(-1)).Centrifugation of H-P-CNF gave a supernatant with higher charge(5.4 mmol g^(-1))and a reduced size(H-P-CNF-S).These tailored nanocelluloses were added to polyvinyl alcohol(PVA)solutions and the suspensions were successfully coated on porous polysulfone(PSf)supports to produce thin-film nanocomposite *** humid mixed gas permeation tests show that CO_(2)permeability increases for membranes with the addition of H-P-CNF-S by 52%and 160%,compared with the P-CNF/PVA membrane and neat PVA membrane,respectively.

关键词： CO_(2)separation Nanocellulose Phosphorylated CNF PVA Nanocomposite TFC membrane

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：