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Study of ZnO nanoparticle-supported clay minerals for electrochemical sensors,photocatalysis,and antioxidant applications

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ChemPhysMater

ChemPhysMater 2024年第1期3卷 83-93页

作者： Mylarappa M N.raghavendra N.R.Bhumika C.H.Chaithra B.N.Nagalaxmi K.N.Shravana Kumara Department of Chemistry Sri Jagadguru Renukacharya College of ScienceArts&CommerceBengaluru 560009India Department of Chemistry East West Institute of TechnologyBengaluru 560091India Department of Chemistry Maharani Lakshmi Ammanni College for WomenBengaluru 560012India

In view of the current study’s demonstration of the synthesis of clay-doped ZnO composites,we present a low-cost method for producing clay-metal oxide(clay/ZnO).Utilizing the solution combustion technique,a composite of clay/ZnO was produced utilizing citric acid as both a fuel and a complexing agent.The hexagonal unit cell structure of the created clay/ZnO may be seen using XRD patterns.The ZnO-infused clay was visible in FE-SEM micrographs as homogenous,sphere-shaped ZnO.The possible involvement of clay/ZnO photocatalytic activity in the UV-induced photodegradation of malachite green dye was investigated.The 90%degradation rate shows the composite’s outstanding photocatalytic degradation capacity.The resulting substance was electrochemically analyzed using a constructed electrode in 0.1 M KOH electrolyte.It increased its sensor capabilities,which now include chemical and biomolecule sensors,and it excelled in cyclic voltammetry-based redox potential studies.To efficiently evaluate chemically synthesized NPs for electrochemical,sensing,and photocatalytic applications,this study intends to create a solution combustion procedure for the synthesis of clay/ZnO nanocomposite using urea as fuel.

关键词： Clay Clay/ZnO Photocatalytic Electrochemical sensors

Kiran Nandivada’s Stuck Blade in a Grinder Jar Degenerative Cascade by LSTV at L5-S1

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Open Journal of Orthopedics 2024年第1期14卷 12-21页

作者： Venkata Satya Kumar Kiran Nandivada Nadavinamani Shivanand raghavendra Nandivada Nikhil Bharadwaja Moola Sohith Mahadeva Reddy Ahmed Usama Rizvi Nandivada Ortho Spine Surgeon & Rheumatologist Abu Dhabi United Arab Emirates Senior Orthopedic Surgeon & Rheumatologist Abu Dhabi United Arab Emirates General Practitioner Visakhapatnam India Department of Medicine Kamineni Institute of Medical Sciences Telangana India Department of Medicine Tbilisi State Medical University Tbilisi Georgia

Background: Mario Bertolotti, (1917) described LSTV-Lumbar spinal transitional vertebra as Bertolotti Syndrome a century ago and associated low back pain with it. Yet, it needs to be given significance in general orthopaedic practice even now, and radiologists underreport it. LSTV is a congenital anatomical anomaly that Castellvi classified into four varying types. Purpose: I titled this phenomenon “Kiran Nandivada’s stuck blade in a grinder jar degenerative cascade by LSTV at L5-S1” to clearly explain how an abnormal mega-transverse apophysis with its various variations affects the weight-bearing mechanics as the L5-S1 which is a vital junction where the maximum body weight is directed into both the sacroiliac joints and if a transitional vertebra occurs it becomes detrimental and abnormally redirects the load-bearing forces and leads to a progressive degenerative cascade both proximally and distally. As the L5 vertebral rotations and other movements of flexion, extensions, lateral flexion are stuck like a bent grinder blade, the other areas of the region are damaged progressively as the pelvis, just like the grinder motor tries to move it, resulting in overheating and maybe even a burnout results in the form of facet arthritis, disc degeneration in the normal disc above, the transitional disc at L5-S1, foraminal osteophytes causing radiculopathy, sacroiliac joint arthritis. Material and Methods: Around 200 X-rays of children and adults with this congenital anomaly have been studied between 2020 and 2023. This is a retrospective study. Results: 1) Our study showed an Increased incidence of LSTV at 15%. 2) Patients ranged from asymptomatic, atypical lumbago to classical lumbago with sciatica and claudication. Findings supported facet and sacroiliac joint arthritis and the pain, relieved with physiotherapy, posture corrections, weight reduction, and lifestyle precautions, negating the need for local steroid injections, radiofrequency ablation or surgical excision as per our experience. Conclusion: Other dysplastic

关键词： LSTV Bertolotti Syndrome Transitional Vertebra Facet Tropism Congenital Dysplasia

Routing with Cooperative Nodes Using Improved Learning Approaches

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Intelligent Automation & Soft Computing 2023年第3期35卷 2857-2874页

作者： R.Raja N.Satheesh J.Britto Dennis C.raghavendra Department of CSIT CVR College of EngineeringTelanganaIndia Department of Computer Science and Engineering St.Martin’s Engineering CollegeSecunderabadTelanganaIndia Department of Computer Science and Engineering Dhanalakshmi Srinivasan UniversityTrichyTamilnaduIndia CSIT Department CVR College of EngineeringHyderabadIndia

In IoT,routing among the cooperative nodes plays an incredible role in fulﬁlling the network requirements and enhancing system performance.The eva-luation of optimal routing and related routing parameters over the deployed net-work environment is challenging.This research concentrates on modelling a memory-based routing model with Stacked Long Short Term Memory(s-LSTM)and Bi-directional Long Short Term Memory(b-LSTM).It is used to hold the routing information and random routing to attain superior performance.The pro-posed model is trained based on the searching and detection mechanisms to com-pute the packet delivery ratio(PDR),end-to-end(E2E)delay,throughput,etc.The anticipated s-LSTM and b-LSTM model intends to ensure Quality of Service(QoS)even in changing network topology.The performance of the proposed b-LSTM and s-LSTM is measured by comparing the signiﬁcance of the model with various prevailing approaches.Sometimes,the performance is measured with Mean Absolute Error(MAE)and Root Mean Square Error(RMSE)for mea-suring the error rate of the model.The prediction of error rate is made with Learn-ing-based Stochastic Gradient Descent(L-SGD).This gradual gradient descent intends to predict the maximal or minimal error through successive iterations.The simulation is performed in a MATLAB 2020a environment,and the model performance is evaluated with diverse approaches.The anticipated model intends to give superior performance in contrast to prevailing approaches.

关键词： Internet of Things(IoT) stacked long short term memory bi-directional long short term memory error rate stochastic gradient descent

Patient interest in video recording of colonoscopy:A survey

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World Journal of Gastroenterology 2010年第4期16卷 458-461页

作者： Meghana raghavendra Douglas K Rex Division of Gastroenterology/Hepatology Indiana University Medical CenterIndianapolisIN 46202United States

AIM:To find if patients are interested in obtaining a video recording of their colonoscopy procedure.METHODS:We conducted a survey of outpatients presenting for colonoscopy regarding their interest in obtaining a video recording of their colonoscopy.RESULTS:Two hundred and forty-eight patients(mean age 57.9 years;57% male) were surveyed.Two hundred and one patients(81%) were interested in obtaining a video recording.No significant predictors of patients' interest in the video recording were identified.After reading a brief educational paragraph explaining missed lesions during colonoscopy,135 patients(54%) were more interested in having a video recording,and none were less interested.One hundred and fifty-six patients(63%) were willing to pay for a video recording.In multivariable analyses,younger age was predictive of willingness to pay for a video recording.Prior history of colorectal cancer and a family history of colorectal cancer were predictive of willingness to pay a greater amount.CONCLUSION:Patients undergoing colonoscopy expressed substantial interest in obtaining a videorecording of their procedure.Awareness of missing lesions during colonoscopy increased interest in having a videorecording.

关键词： Colonoscopy Video recording Survey

An interacting two-fluid scenario for dark energy in a Bianchi type-I cosmological model

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Research in Astronomy and Astrophysics 2012年第5期12卷 473-484页

作者： Triloki Singh raghavendra Chaubey Department of Applied Mathematics Institute of Technology Banaras Hindu University DST-Centre for Interdisciplinary Mathematical Sciences Faculty of Science Banaras Hindu University

We study the evolution of the dark energy parameter within a Bianchi type-I cosmological model filled with barotropic fluid and dark energy. The solutions have been obtained for power law and exponential forms of the expansion parameter （they correspond to a constant deceleration parameter in general relativity）. After a long time, the models tend to be isotropic under certain conditions.

关键词： cosmological model -- dark energy parameter -- barotropic fluid

Lepton and quark mixing patterns with generalized CP transformations

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Chinese Physics C 2022年第10期46卷 25-42页

作者： Joy Ganguly raghavendra Srikanth Hundi Department of Physics Indian Institute of Technology HyderabadKandi-502284India

In this study,we modify a scenario,originally proposed by Grimus and Lavoura,in order to obtain maximal values for the atmospheric mixing angle and CP,violating the Dirac phase of the lepton sector.To achieve this,we employ CP and some discrete symmetries in a type Ⅱ seesaw model.To make predictions about the neutrino mass ordering and smallness of the reactor angle,we establish some conditions on the elements of the neutrino mass matrix of our model.Finally,we study the quark masses and mixing pattern within the framework of our model.

关键词： neutrino physics nuetrino mass and mixing model quark mass and mixing analysis of scalar potential

Magnesium alloys as extremely promising alternatives for temporary orthopedic implants-A review

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Journal of Magnesium and Alloys 2023年第8期11卷 2688-2718页

作者： C.A.Niranjan T.raghavendra Madhuri P.Rao C.Siddaraju M.Gupta Vikram Kumar S.Jain R.Aishwarya Department of Industrial Engineering and Management Ramaiah Institute of TechnologyBengaluru-54India Department of Mechanical Engineering National Institute of EngineeringMysuru-08India Department of Chemistry B.M.S.College of EngineeringBengaluru-19India Department of Mechanical Engineering Ramaiah Institute of TechnologyBengaluru-54India Department of Mechanical Engineering NUS Singapore-75Singapore Department of Metallurgical and Materials Engineering Indian Institute of TechnologyMadras-36India

Mg alloys are emerging as potential and very promising alternatives for replacing permanent metallic implant materials such as steels and titanium in applications where the implants need to be removed following healing through revision surgery.Use of Mg alloys for implant application is seen as a game changer and Mg alloys are almost perfect materials for the future in both engineering and biomedical applications.Present review therefore focuses on highlighting significance of Mg alloys in biomedical field and risks of using permanent metallic implants particularly when the implants are no longer required after the injury is healed.In this review,importance of orthopedic implants in present scenario,serious concern related to accidents that are causing permanent disabilities,demand in orthopedic implant market worldwide,potential applications of Mg based materials and their compatibility in biological environment is presented and discussed.In addition,degradation rate,major reactions associated with Mg based materials and effect of alloying elements on implant performance are also discussed based on in-vivo results.Recent advances in development of Mg alloys through various techniques and their performance in in-vitro conditions are also outlined.Possible ways to eliminate the limitations of Mg alloys include alloying,melt purification,surface alterations,surface modifications,chemical treatment,secondary processing etc.are discussed.Challenges and opportunities for Mg alloys to become ideal implant material is also addressed.

关键词： Accidents Fractures Burden of fracture Magnesium Ultimate alternative Degradation rate Alloying Melt purification Coating

The general class of Bianchi cosmological models with viscous fluid and particle creation in Brans-Dicke theory

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Research in Astronomy and Astrophysics 2014年第5期14卷 533-552页

作者： raghavendra Chaubey Anjani Kumar Shukla DST-Centre for Interdisciplinary Mathematical Sciences Faculty of Science Banaras Hindu University Varanasi India

This paper deals with the general class of Bianchi cosmological models with bulk viscosity and particle creation described by full causal thermodynamics in Brans-Dicke theory. We discuss three types of average scale-factor solutions for the general class of Bianchi cosmological models by using a special law for the deceler- ation parameter which is linear in time with a negative slope. The exact solutions to the corresponding field equations are obtained in quadrature form and solutions to the Einstein field equations are obtained for three different physically viable cosmologies. All the physical parameters are calculated and discussed in each model.

关键词： cosmology theory

Direct radiative forcing of urban aerosols over Pretoria(25.75°S, 28.28°E) using AERONET Sunphotometer data:First scientific results and environmental impact

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Journal of Environmental Sciences 2014年第12期26卷 2459-2474页

作者： Ayodele Joseph Adesina Kanike raghavendra Kumar Venkataraman Sivakumar Derek Griffith Discipline of Physics School of Chemistry and Physics College of Agriculture Engineering and Science Westville CampusUniversity of Kwa Zulu–Natal Durban 4000 South Africa Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration School of Atmospheric PhysicsNanjing University of Information Science and Technology Optronic Sensor Systems Council for Scientific and Industrial Research (CSIR)–DPSS Pretoria 0001 South Africa

The present study uses the data collected from Cimel Sunphotometer of Aerosol Robotic Network（AERONET） for the period from January to December, 2012 over an urban site,Pretoria（PTR; 25.75°S, 28.28°E, 1449 m above sea level）, South Africa. We found that monthly mean aerosol optical depth（AOD, τa） exhibits two maxima that occurred in summer（February） and winter（August） having values of 0.36 ± 0.19 and 0.25 ± 0.14,respectively, high-to-moderate values in spring and thereafter, decreases from autumn with a minima in early winter（June） 0.12 ± 0.07. The Angstrom exponents（α440–870） likewise,have its peak in summer（January） 1.70 ± 0.21 and lowest in early winter（June） 1.38 ± 0.26,while the columnar water vapor（CWV） followed AOD pattern with high values（summer） at the beginning of the year（February, 2.10 ± 0.37 cm） and low values（winter） in the middle of the year（July, 0.66 ± 0.21 cm）. The volume size distribution（VSD） in the fine-mode is higher in the summer and spring seasons, whereas in the coarse mode the VSD is higher in the winter and lower in the summer due to the hygroscopic growth of aerosol particles.The single scattering albedo（SSA） ranged from 0.85 to 0.96 at 440 nm over PTR for the entire study period. The averaged aerosol radiative forcing（ARF） computed using SBDART model at the top of the atmosphere（TOA） was- 8.78 ± 3.1 W/m2, while at the surface it was- 25.69 ± 8.1 W/m2 leading to an atmospheric forcing of ＋ 16.91 ± 6.8 W/m2, indicating significant heating of the atmosphere with a mean of 0.47 K/day.

关键词： Pretoria AERONET Aerosol optical depth Single scattering albedo Radiative forcing