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Depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 335-345页

作者： Feng Zhang Chenyang Zhang Linlin Wu Wei Sun Hongliang Zhang Jianhua Chen yong Pei Songjiang Li Engineering Research Center of Ministry of Education for Carbon Emission Reduction in Metal Resource Exploitation and Utilization Hunan International Joint Research Center for Efficient and Clean Utilization of Critical Metal Mineral ResourcesSchool of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining&MetallurgyBeijing 100160China Hunan Provincial Key Laboratory of Micro&Nano Materials Interfaces Science College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China Department of Chemistry Xiangtan UniversityXiangtan 411105China China Railway Resource Group Co.Ltd Beijing 102300China

The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth ***,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)*** X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption ***,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and ***,sulfite ions were chelated with lead ions to form PbSO_(3)in *** hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than *** interaction between sulfite ions and lead ions could effectively inhibit the activation of *** addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of ***,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some *** study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.

关键词： sphalerite galena sulfite ion density functional theory depression mechanism

基于PLUS模型的典型农牧交错带土地利用驱动力分析与多情景模拟

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水土保持研究 2025年第1期32卷 368-378页

作者：张启扬刘仁志栾朝旭北京师范大学环境学院水环境模拟国家重点实验室

[目的]实现农牧交错带地区破碎化土地利用变化的精准预测，为农牧交错带土地利用预测与结构调整提供重要工具。[方法]研究针对性构建了农牧交错带土地利用模拟方法(APE-PLUS),引入土地扩张分析策略(LEAS)、基于多类型随机斑块种子的CA模... 详细信息

[目的]实现农牧交错带地区破碎化土地利用变化的精准预测，为农牧交错带土地利用预测与结构调整提供重要工具。[方法]研究针对性构建了农牧交错带土地利用模拟方法(APE-PLUS),引入土地扩张分析策略(LEAS)、基于多类型随机斑块种子的CA模型(CARS)、Markov模型和土地利用情景设计，解决农牧交错带土地利用模拟中斑块零散、景观破碎、变化机制复杂的问题。采用二调、三调土地利用数据，分析了2014—2020年土地利用变化及其驱动力，模拟了2032年科左后旗自然增长、生态优先、耕地保护和可持续发展情景下的土地利用格局。[结果](1)农牧交错带土地利用模拟方法(APE-PLUS)精度较高，Kappa系数为0.87,总体精度达到0.92;(2)科左后旗2014—2020年土地利用变化显著，全旗47.85%的土地类型发生改变，14.65%的土地由耕地转变为草地，DEM和水资源是这一时期土地利用变化的主要驱动力；(3) 2032年多情景预测中，可持续发展情景耕地面积增长1.31%,林地和草地分别减少了0.77%和1.72%,其他用地面积减小28.4%,相比于其他3种情景，土地利用数量结构与空间格局更合理。此情景有助于减缓耕地扩张趋势和草地缩减趋势，有效控制水土流失、土壤沙化问题，提高生态保护与经济发展的协调程度。[结论]农牧交错带土地利用模拟方法(APE-PLUS)对科左后旗的土地利用具有较高的模拟精度，可以对农牧交错带斑块级的土地利用变化进行高精度的预测。

关键词：土地利用变化农牧交错带 PLUS模型科尔沁左翼后旗驱动因子

Vibration-assisted vat photopolymerization for pixelated-aliasing-free surface fabrication

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International Journal of Extreme Manufacturing 2024年第3期6卷 440-456页

作者： Han Xu renzhi Hu Shuai Chen Junhong Zhu Chi Zhou yong Chen Center for Advanced Manufacturing University of Southern CaliforniaLos AngelesCA 90007United States of America Daniel J.Epstein Department of Industrial and Systems Engineering University of Southern CaliforniaLos AngelesCA 90089United States of America Department of Aerospace and Mechanical Engineering University of Southern CaliforniaLos AngelesCA 90089United States of America Department of Industrial and Systems Engineering University of BuffaloBuffaloNY 14260United States of America

Mask image projection-based vat photopolymerization(MIP-VPP)offers advantages like low cost,high resolution,and a wide material range,making it popular in industry and ***,MIP-VPP employing liquid crystal displays(LCDs)has gained traction,increasingly replacing digital micromirror devices,particularly among hobbyists and in educational settings,and is now beginning to be used in industrial ***,LCD-based MIP-VPPsuffers from pronounced pixelated aliasing arising from LCD’s discrete image pixels and itsdirect-contact configuration in MIP-VPP machines,leading to rough surfaces on the 3D-printed ***,we propose a vibration-assisted MIP-VPP method that utilizes a microscalevibration to uniformize the light intensity distribution of the LCD-based mask image on VPP’s building *** maintaining the same fabrication speed,our technique generates asmoother,non-pixelated mask image,reducing the roughness on flat surfaces and boundary segments of 3D-printed *** light intensity modeling and simulation,we derived an optimal vibration pattern for LCD mask images,subsequently validated by *** assessed the surface texture,boundary integrity,and dimensional accuracy of componentsproduced using the vibration-assisted *** notably smoother surfaces and improved boundary roughness enhance the printing quality of MIP-VPP,enabling its promisingapplications in sectors like the production of 3D-printed optical devices and others.

关键词： additive manufacturing vat photopolymerization piezo vibration sub-pixel resolution aliasing

Overall Evaluation of the Effect of Residual Stress Induced by Shot Peening in the Improvement of Fatigue Fracture Resistance for Metallic Materials

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Chinese Journal of Mechanical Engineering 2015年第2期28卷 416-421页

作者： WANG renzhi RU Jilai Metal Physics Laboratory Beijing Institute of Aeronautical Materials Metal & Chemistry Institute China Academy of Railway Science

Before 1980s,the circular suspension spring in automobile subjected to torsion fatigue load,under the cyclic normal tensile stresses,the majority of fatigue fracture occurred was in normal tensile fracture mode（NTFM）and the fracture surface was under 45°*** there exists the interaction between the residual stresses induced by shot peening and the applied cyclic normal tensile stresses in NTFM,which represents as＂stress strengthening mechanism＂,shot peening technology could be used for improving the fatigue fracture resistance（FFR）of ***,since 1990s up to date,in addition to regular NTFM,the fatigue fractures occurred of peened springs from time to time are in longitudinal shear fracture mode（LSFM）or transverse shear fracture mode（TSFM）with the increase of applied cyclic shear stresses,which leads to a remarkable decrease of ***,LSFM/TSFM can be avoided effectively by means of shot peening treatment again on the peened *** phenomena have been rarely happened *** present there are few literatures concerning this *** upon the results of force analysis of a spring,there is no interaction between the residual stresses by shot peening and the applied cyclic shear stresses in shear ***;means that the effect of＂stress strengthening mechanism＂for improving the FFR of LSFM/TSFM is disappeared *** shot peening,however,both of residual stress and cyclic plastic deformed microstructure are induced synchronously like＂twins＂in the surface layer of a *** has been found for the first time by means of force analysis and experimental results that the modified microstructure in the＂twins＂as a＂structure strengthening mechanism＂can improve the FFR of LSFM/*** the same time,it is;also shown that the optimum technology of shot peening strengthening must have both＂stress strengthening mechanism＂and＂structure strengthening mechanism＂simultaneously so that the FFR of both NTFM and LSFM/TSFM can be improv

关键词： shot peening strengthening principle fatigue fracture resistance strengthening mechanisms of fatigue fracture classification on fatigue fracture mode

Review of Ultraviolet Non-Line-of-Sight Communication

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China Communications 2016年第6期13卷 63-75页

作者： renzhi Yuan Jianshe Ma Shenzhen Graduate School of Tsinghua University Shenzhen 518055China

With rapid advances of solar blind ultraviolet LED and ultraviolet detecting technology in recent years, ultraviolet communication gradually becomes a research hotspot due to its inherent advantages: low solar background noise, non-line-of-sight(NLOS) and good secrecy. The strong scattering characteristics in atmospheric render ultraviolet waveband the ideal choice for achieving NLOS optical communication. This paper reviews the research history and status of ultraviolet communication both in China and abroad, and especially introduces three main issues of ultraviolet communication: channel model, system analysis and design, light sources and detectors. For each aspect, current open issues and prospective research directions are analyzed.

关键词： ultraviolet communication non-line-of-sight scattering model

Synthesis and Structural Characterization of a Salt {[Co(Phen)_3][Mo_2S_2(μ-S)_2(edt)_2]}_2·(DMSO)_2·(Et_2O)(Phen = 1,10-Phenanthroline, edt=Ethane-1,2-dithiolate)

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Chinese Journal of Structural Chemistry 2005年第7期24卷 773-778,736页

作者： ZHANGWen-Hua renzhi-Gang ZHANGyong SchoolofChemistryandChemicalEngineering SuzhouUniversit） Suzhou215006 China

Reaction of [Et4N]2[Mo2S2(μ-S)2(edt)2] with CoCl2?6H2O and Phen in MeCN followed by recrystallization in DMSO/Et2O gave rise to dark-red block crystals of {[Co(Phen)3]- [Mo2S2(μ-S)2(edt)2]}2?(DMSO)2?(Et2O) 1 (C88H86Co2Mo4N12O3S18). 1 crystallizes in the monoclinic system, space group P21/c with a = 24.631(4), b = 16.117(3), c = 24.791(4) ?, β = 92.835o, V = 9829.3(3) ?3, Z = 4, Mr = 2438.57, Dc = 1.648 g/cm3, F(000) = 4928, μ = 12.61 cm-1, R = 0.0936 and wR = 0.1682 for 12998 observed reflections with I > 2.0σ(I). In the structure of 1, the Co atom of the [Co(Phen)3]2+ dication is octahedrally coordinated by three Phen ligands. The Mo atom of the [Mo2S2(μ-S)2(edt)2]2- dianion is coordinated by two μ-S, one terminal S and two S atoms from edt, forming a distorted square pyramidal geometry. The mean Co–N and Mo…Mo bond distances are 2.139 and 2.872 ?, respectively.

关键词： molybdenum cluster sulfur cobalt crystal structure synthesis

Viscosity and structure relationship with equimolar substitution of CaO with MgO in the CaO–MgO–Al_(2)O_(3)–SiO_(2)slag melts

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 70-79页

作者： yong Hou Shuo Zhang Jie Dang Jia Guo Hanghang Zhou Xuewei Lü College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials Chongqing UniversityChongqing 400044China

Currently,the Al_(2)O_(3)content in the high-alumina slag systems within blast furnaces is generally limited to 16wt%–18.5wt%,making it challenging to overcome this *** most studies that concentrated on managing the MgO/Al_(2)O_(3)ratio or basicity,this paper explored the effect of equimolar substitution of MgO for CaO on the viscosity and structure of a high-alumina CaO-MgO-Al_(2)O_(3)-SiO_(2)slag system,providing theoretical guidance and data to facilitate the application of high-alumina *** results revealed that the viscosity first decreased and then increased with higher MgO substitution,reaching a minimum at 15mol%MgO *** transform infrared spectroscopy(FTIR)results found that the depths of the troughs representing[SiO_(4)]tetrahedra,[AlO_(4)]tetrahedra,and Si-O-Al bending became progressively deeper with increased MgO *** of the Raman spectra showed that the average number of bridging oxygens per Si atom and the X_(Q^(3))/X_(Q^(2))(X_(Q^(i))is the molar fraction of Q^(i) unit,and i is the number of bridging oxygens in a[SiO_(4)]tetrahedral unit)ratio increased from 2.30 and 1.02 to 2.52 and 2.14,respectively,indicating a progressive polymerization of the silicate structure.X-ray photoelectron spectroscopy(XPS)results highlighted that non-bridging oxygen content decreased from 77.97mol% to 63.41mol% with increasing MgO concentration,whereas bridging oxygen and free oxygen contents *** analysis demonstrated a gradual increase in the polymerization degree of the tetrahedral structure with the increase in MgO ***,bond strength is another important factor affecting the slag *** occurrence of a viscosity minimum can be attributed to the complex evolution of bond strengths of non-bridging oxygens generated during depolymerization of the[SiO_(4)]and[AlO_(4)]tetrahedral structures by CaO and MgO.

关键词： aluminosilicate viscosity structure spectroscopy

Prominent cycling reversibility and kinetics enabled by CaTiO3 protective layer on Zn metal for aqueous Zn-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 245-258页

作者： Gaeun Lee yong Nam Ahn Seongjoon So Chanwoo Park Jong-Seong Bae Taehyun Park Il Tae Kim Jaehyun Hur School of Chemical Biological and Battery Engineering Gachon University Seongnam Busan Center Korea Basic Science Institute

Aqueous Zn-ion batteries （AZIBs） have received considerable attention owing to their various advantages such as safety,low cost,simple battery assembly conditions,and high ionic ***,they still suffer from serious problems,including uncontrollable dendrite growth,corrosion,hydrogen evolution reaction （HER） from water decomposition,electrode passivation,and unexpected *** creation of a uniform artificial nanocrystal layer on the Zn anode surface is a promising strategy for resolving these ***,we propose the use of a perovskite CaTiO3（CTO） protective layer on Zn（CTO@Zn） as a promising approach for improving the performance of *** CTO artificial layer provides an efficient pathway for Zn ion diffusion towards the Zn metal because of the high dielectric constant （εr=180） and ferroelectric characteristics that enable the alignment of dipole moments and redistribute the Zn2+ions in the CTO *** avoiding the direct contact of the Zn anode with the electrolyte solution,the uneven dendrite growth,corrosion,parasitic side reactions,and HER are mitigated,while CTO retains its mechanical and chemical robustness during ***,CTO@Zn demonstrates an improved lifespan in a symmetric cell configuration compared with bare ***@Zn shows steady overpotential （～68 m V） for 1500 h at 1 mA cm-2/0.5 mA h cm-2,excelling bare ***,when paired with the V2O5-C cathode,the CTO@Zn//V2O5-C full battery delivers 148.4 mA h g-1（based on the mass of the cathode） after 300 *** study provides new insights into Zn metal anodes and the development of high-performance AZIBs.

关键词： Artificial layer Dielectric constant Zn metal anode Zinc aqueous battery

CD87-targeted BiTE and CAR-T cells potently inhibit invasive nonfunctional pituitary adenomas

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Science China(Life Sciences) 2024年第10期67卷 2169-2185页

作者： Yuan Ren Xinjie Bao Ming Feng Bing Xing Wei Lian yong Yao renzhi Wang Department of Neurosurgery Peking Union Medical College HospitalChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100730China

Recently,bispecific T-cell engagers(BiTEs)and chimeric antigen receptor-modified T cells(CAR-Ts)have been shown to have high therapeutic efficacy in hematological ***87 is highly expressed in solid tumors with an oncogenic *** assess their cytotoxic effects on invasive nonfunctioning pituitary adenomas(iNFPAs),we first examined CD87 expression and its effects on the metabolism of iNFPA *** generated CD87-specific BiTE and CAR/IL-12 T cells,and their cytotoxic effects on iNFPAs cells and in mouse models were ***87 had high expression in i NFPA tissue and cell samples but was undetected in noncancerous brain ***87×CD3 BiTE and CD87 CAR/IL-12 T-cells showed antigenic specificity and exerted satisfactory cytotoxic effects,decreasing tumor cell proliferation in vitro and reducing existing tumors in experimental ***,the above findings suggest that CD87 is a promising target for the immunotherapeutic management of iNFPAs using anti-CD87 BiTE and CD87-specific CAR/IL-12 T cells.

关键词： CD87 chimeric antigen receptor T cells invasive non-functional pituitary adenomas bispecific T cell engager Warburg effect