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Porous carbon catalysis in sustainable synthesis of functional heterocycles:An overview

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chinese chemical Letters 2024年第8期35卷 170-186页

作者： Uttam Pandurang patil Department of chemistry ACS CollegeShivaji UniversityPalus 416310MSIndia

Heterogeneous porous carbon(Pc)materials have gained unique importance in the catalysis community due to their captivating properties,including high specific surface area,tunable porosity,and *** can play a prominent role in the sustainable synthesis of functional heterocycles,as they are a low-cost alternative while being an efficient and user-friendly *** review examines the prepa-ration and applicability of these carbonaceous materials used as catalysts or support for biologically active heterocycles synthesis,including hydrogenation,oxidation,oxidative dehydrogenation,cross-coupling,and other organic ***,the challenges,potential future development directions,and opportuni-ties in the synthesis of potent bioactive heterocycles over Pc materials have been *** review will inspire further research to explore novel Pc materials and their implications in heterocyclization.

关键词： Sustainable chemistry Heterogeneous catalysts Porous carbons Heterocycles synthesis

水分胁迫情况下甘蔗叶片脯氨酸累积和活体内硝酸还原酶活性的遗传

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福建甘蔗 2004年第2期 42-44页

作者： r．M．Naik B．S．Kadam r．A．Pandhare S．M．Pawar r.c.patil P.G．Bhoi 陈玉水中央甘蔗研究站，Padegaon 不详

评价了以甘蔗品种co740和co671作为父本或母本杂交选育的几个甘蔗品系在水分胁迫下叶片渗透保护剂脯氨酸和叶片体内硝酸还原酶活性的遗传。结果表明，在水分胁迫下，抗旱耐盐甘蔗品种co740的叶片脯氨酸含量比co671高，叶片硝酸还原酶活... 详细信息

评价了以甘蔗品种co740和co671作为父本或母本杂交选育的几个甘蔗品系在水分胁迫下叶片渗透保护剂脯氨酸和叶片体内硝酸还原酶活性的遗传。结果表明，在水分胁迫下，抗旱耐盐甘蔗品种co740的叶片脯氨酸含量比co671高，叶片硝酸还原酶活性比co671低，而且，以co740作为母本的甘蔗杂种的叶片脯氨酸含量也比较高，叶片硝酸还原酶活性也比较低。从同样都以co671作为父本的甘蔗杂种co86032与co94014之间抗旱性的不同或许可以认为所用母本的抗旱性具有天然遗传潜力。

关键词：水分胁迫甘蔗叶片脯氨酸硝酸还原酶遗传品系

characterization of early maturing elite genotypes based on MTSI and MGIDI indexes:an illustration in upland cotton(Gossypium hirsutum L.)

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Journal of cotton research 2024年第3期7卷 253-265页

作者： D S rAJ Supritha patil rajesh S. patil Bhuvaneshwara r. NAYAK Spurthi N. PAWAr Kasu N. Department of Genetics and Plant Breeding College of AgricultureUniversity of Agricultural SciencesDharwad 580005India Agricultural research Station Dharwad 580005India Department of Biotechnology College of AgricultureUniversity of Agricultural SciencesDharwad 580005India Department of crop Physiology College of AgricultureUniversity of Agricultural SciencesDharwad 580005India

Background Globally,the cultivation of cotton is constrained by its tendency for extended periods of *** maturity plays a potential role in rainfed-based multiple cropping system especially in the current era of climate *** the current study,a set of 20 diverse Gossypium hirsutum genotypes were evaluated in two crop seasons with three planting densities and assessed for 11 morphological traits related to early *** study aimed to identify genotype(s)that mature rapidly and accomplish well under diverse environmental conditions based on the two robust multivariate techniques called multi-trait stability index(MTSI)and multi-trait genotype-ideotype distance index(MGIDI).results MTSI analysis revealed that out of the 20 genotypes,three genotypes,viz.,NNDc-30,A-2,and S-32 accomplished well in terms of early maturity traits in two ***,three genotypes were selected using MGIDI method for each planting densities with a selection intensity of 15%.The strengths and weaknesses of the genotypes selected based on MGIDI method highlighted that the breeders could focus on developing early-maturing genotypes with specific traits such as days to first flower and boll *** selected genotypes exhibited positive genetic gains for traits related to earliness and a successful harvest during the first and second ***,there were negative gains for traits related to flowering and boll *** The study identified three genotypes exhibiting early maturity and accomplished well under different planting *** multivariate methods(MTSI and MGIDI)serve as novel approaches for selecting desired genotypes in plant breeding programs,especially across various growing *** methods offer exclusive benefits and can easily construe and minimize multicollinearity issues.

关键词： cotton MTSI MGIDI Genotype environment interaction Early maturity Multi-trait Multi-environment

Trigonelline mitigates bleomycin-induced idiopathic pulmonary fibrosis in mice

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Asian Pacific Journal of Tropical Biomedicine 2024年第9期14卷 391-400,I0008-I0291页

作者： Swapnil Gavhane chandrakant Gawli Sachin Kumar Biswajit Das Gayatri Marathe Vishal S.patil Harun M.Patel Basavaraj Bommanahalli chanakya Nath Kundu chandragouda r.patil r.c.Patel Institute of Pharmaceutical Education and research Karwand NakaShirpurMaharashtra 425405India Department of Pharmacology Delhi Pharmaceutical Sciences and Research UniversityNew Delhi 110017India School of Biotechnology Kalinga Institute of Industrial TechnologyBhubaneshwar 751024India Gadag Institute of Medical Sciences GadagKarnataka 582103India

Objective:To evaluate the effect of trigonelline on bleomycin-induced idiopathic pulmonary fibrosis(IPF)and to explore its underlying mechanisms using network ***:IPF was induced in c57BL/6 mice by a single intratracheal instillation of bleomycin(5 mg/kg).Trigonelline was administered at doses of 25,50,and 100 mg/kg/day orally from the 2nd day post-bleomycin induction up to the 14th *** IPF-induced mice,lung coefficient,immune cell infiltration in bronchoalveolar lavage fluid,and oxidative stress were *** alterations in lung tissues were also ***,network pharmacology approach was conducted to reveal molecular interactions of bleomycin and trigonelline with targets of ***:Trigonelline treatment reduced bleomycin-induced oxidative stress and immune cell infiltration,and mitigated physiological changes in the lung tissues of ***,trigonelline alleviated bleomycin-induced histological alterations in lung *** pharmacology analysis showed that bleomycin and trigonelline interacted with IPF targets,such as NFKB1,HDAc2,HIF1A,and ***:The interaction of trigonelline with key IPF targets and its ameliorative effects on lung damage and oxidative stress highlight its potential in treating *** may be considered an antifibrotic agent for further clinical development.

关键词： Trigonelline Idiopathic pulmonary fibrosis Antifibrotic Bleomycin Network pharmacology

Experimental and numerical investigation to elucidate the fluid flow through packed beds with structured particle packings

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Particuology 2024年第6期89卷 218-237页

作者： Shirin patil christian Gorges Joel Lòpez Bonilla Moritz Stelter Frank Beyrau Berend van Wachem Laboratory of Technical Thermodynamics Otto-von-Guericke-Universität MagdeburgUniversitätsplatz 239106 MagdeburgGermany chair of Mechanical Process Engineering Otto-von-Guericke-Universität MagdeburgUniversitätsplatz 239106 MagdeburgGermany

The present paper presents an experimental and numerical investigation of the dispersion of the gaseous jet flow and co-flow for the simple unit cell(SUc)and body-centred cubic(Bcc)configuration of particles in packed *** experimental setup is built in such a way that suitable and simplified boundary conditions are imposed for the corresponding numerical framework,so the simulations can be done under very similar conditions as the ***,a porous plate is used for the co-flow to achieve the uniform velocity and the fully developed flow is ensured for the jet *** SUc and Bcc particle beds consist of 3D-printed spheres,and the non-isotropy near the walls is mostly eliminated by placing half-spheres at the channel *** flow velocities are analysed directly at the exit of the particle bed for both beds over 36 pores for the SUc configuration and 60 pores for the Bcc configuration,for particle reynolds numbers of 200,300,and *** particle image velocimetry is experimentally arranged in such a way that the velocities over the entire region at the exit of the packed bed are obtained *** numerical method consists of a state-of-the-art immersed boundary method with adaptive mesh *** paper presents the pore jet structure and velocity field exiting from each pore for the SUc and Bcc packed particle *** numerical and experimental studies show a good agreement for the SUc configuration for all flow *** the Bcc configuration,some differences can be observed in the pore jet flow structure between the simulations and the experiments,but the general flow velocity distribution shows a good overall *** axial velocity is generally higher for the pores located near the centre of the packed bed than for the pores near the *** addition,the axial velocities are observed to increase near the peripheral pores of the packed *** behaviour is predominant for the Bcc configuration as compared to t

关键词： Uniform particle packing Packed bed reactor Stereo particle image velocimetry Immersed boundary method

Deep learning-based prediction of 3-dimensional silver contact shapes enabling improved quality control in solar cell metallization

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Energy and AI 2024年第3期17卷 513-524页

作者： Marius Singler Akshay patil Linda Ney Andreas Lorenz Sebastian Tepner Florian clement Fraunhofer Institute for Solar Energy Systems(ISE) Heidenhofstr.279110 FreiburgGermany EKrA Automatisierungstechnik GmbH Zeppelinstraße 1674357 BonnigheimGermany

The industrial metallization of Si solar cells predominantly relies on screen printing,with silver as the preferred electrode ***,the design of commercial screens often leads to suboptimal silver usage and increased electrical resistance due to print-related inhomogeneities like mesh marks,constrictions and ***-time monitoring of quality parameters during production has thus become increasingly *** inline optical quality control systems usually only include 2D visualizations of the printed layout,which limits their effectiveness in quality *** that allow 3D measurements are usually slow,expensive,and therefore not worth considering in most *** research focuses on the development of a model that can estimate the three-dimensional shape of printed contact fingers from a single 2D image without the need of additional hardware using deep ***,a workflow for the generation of training data,which involves the creation of image pairs from a 2D microscope and a 3D confocal laser scanning microscope(cLSM)to accurately represent solar cell fingers,is *** model training,the predicted height maps are compared with the ground truth height maps,and the robustness of the model with respect to a paste variation and screen parameter variation is *** results confirm the feasibility and reliability of deep learning-based 3D shape estimation,extending its applicability to new,previously unseen data from screen-printed contact *** a structural similarity index(SSIM)score of 0.76,a strong correlation between the estimated and ground truth height maps is *** summary,our deep learning-based approach for height map estimation offers an effective and reliable solution for fast inline detection and analysis of the cross-sectional area of the printed contact fingers.

关键词： Deep Learning Front-side metallization Image2Heigth Solar cell Screen-printing

Long-term outcomes of urethral balloon dilation for anterior urethral stricture: A prospective cohort study

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Asian Journal of Urology 2024年第3期11卷 480-485页

作者： Ahmed M.Abdel Gawad Abhijit patil Abhishek Singh Arvind P.Ganpule ravindra B.Sabnis Mahesh r.Desai Department of Urology Muljibhai Patel Urological HospitalNadiadIndia Department of Urology Faculty of MedicineAl-Azhar UniversityDamiettaEgypt

Objective:To prospectively follow up a cohort of anterior urethral stricture disease patients managed with balloon dilation(BD)for 3 years to evaluate the long-term outcomes and to study factors that contribute to ***:This study included men who had urethral BD for significant anterior urethral stricture disease between January 2017 and March *** about the patient age,stricture characteristics,and recurrence date were recorded,along with information on postoperative indwelling catheter use and operative ***,information about the self-calibration procedure was collected and where available,free flow(FF)measurements during the follow-up period were recorded and *** was defined as a lack of symptoms and acceptable FF rates(maximum flow rate>12 mL/s).results:The final analysis was conducted on 187 *** mean follow-up period was 37 *** long-term overall success rate at the end of our study was 66.8%.Our recurrence rate was 7.4%at 12 months,24.7%at 24 months,and reached 33.2%at the end of our *** time to recurrence ranged from 91 days to 1635 days,with a mean of 670 *** stricture-free survival was significantly shorter with lengthy peno-bulbar(p=0.031)and multiple strictures(p=0.015),and in the group of patients who were not committed to self-calibration protocol(pr,post-procedural self-calibration was the most important factor that may have decreased the incidence of recurrence(odds ratioZ5.85).Adjuvant self-calibration after BD not only reduced the recurrence rate from 85.4%in the non-self-calibration group to 15.1%in the self-calibration one(proved the overall stricture-free survival and FF parameters.

关键词： Balloon dilation Internal urethrotomy recurrence Self-calibration Urethral stricture

A systematic review of spatial disaggregation methods for climate action planning

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Energy and AI 2024年第3期17卷 458-469页

作者： Shruthi patil Noah Pflugradt Jann M.Weinand Detlef Stolten Jürgen Kropp Institute of Energy and climate research Techno-economic Systems Analysis(IEK-3)Forschungszentrum JülichWilhelm-Johnen-StraßeJülich52425NRWGermany University of Potsdam Institute for Environmental Science and GeographyKarl-Liebknecht-Str.24-25Potsdam-Golm14476BrandenburgGermany chair for Fuel cells RWTH Aachen Universityc/o IEK-3Forschungszentrum JülichJülich52425NRWGermany Potsdam Institute for climate Impact research(PIK) Member of the Leibniz AssociationP.O.Box 601203PotsdamD-14412BrandenburgGermany

National-level climate action plans are often formulated broadly. Spatially disaggregating these plans to individual municipalities can offer substantial benefits, such as enabling regional climate action strategies and for assessing the feasibility of national objectives. Numerous spatial disaggregation approaches can be found in the literature. This study reviews and categorizes these. The review is followed by a discussion of the relevant methods for the disaggregation of climate action plans. It is seen that methods employing proxy data, machine learning models, and geostatistical ones are the most relevant methods for the spatial disaggregation of national energy and climate plans. The analysis offers guidance for selecting appropriate methods based on factors such as data availability at the municipal level and the presence of spatial autocorrelation in the *** the urgency of addressing climate change escalates, understanding the spatial aspects of national energy and climate strategies becomes increasingly important. This review will serve as a valuable guide for researchers and practitioners applying spatial disaggregation in this crucial field.

关键词： Spatial downscaling Proxy data Mass-preserving climate action plans Spatial autocorrelation Machine learning Geostatistical models

Fish Gelatin-Based Film containing Maillard reaction Products:Properties and Its Use as Bag for Packing chicken Skin Oil

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Journal of renewable Materials 2024年第6期12卷 1125-1143页

作者： Krisana Nilsuwan Yolanda Victoria rajagukguk Umesh patil Thummanoon Prodpran Soottawat Benjakul International center of Excellence in Seafood Science and Innovation Faculty of Agro-IndustryPrince of Songkla UniversitySongkhla90110Thailand Department of Food Safety and Quality Management PoznańUniversity of Life SciencesPoznań60-637Poland center of Excellence in Bio-Based Materials and Packaging Innovation Faculty of Agro-IndustryPrince of Songkla UniversityHat YaiSongkhla90110Thailand Department of Food and Nutrition Kyung Hee UniversitySeoul02447Republic of Korea

Maillard reaction is a non-enzymatic browning reaction and its products(MrPs)have been proven to possess antioxidant *** research aimed to produce a fish gelatin-based packaging incorporated with MrPs to retard lipid oxidation in chicken skin oil(cSO)during storage at ambient temperature(28℃–30℃).MrPs produced from fish gelatin and fructose(1:1,90℃,pH 11)showed the highest antioxidant properties compared to those prepared under other *** glycerol/MrPs ratios(30:0,25:5,20:10,15:15,10:20,5:25,0:30)were incorporated into the film and resulting films were ***/MrPs at 10:20 ratio was chosen to add into the film prior to bag preparation via heat sealing *** packed in the bag was monitored for lipid hydrolysis and oxidation during 15 days of storage(30℃±0.5℃,rH 52%±5%).After 15 days,quality deterioration was lower in cSO packed in the prepared gelatin bag as evidenced by lower FFA,TBArS,and volatile compounds in comparison with cSO packed in LDPE *** gelatin film added with MrPs possessed an excellent water vapor barrier property(WV-BP).This finding indicated that MrPs could be used to substitute glycerol and simultaneously could serve as antioxidants for the developed active *** novel packaging can be a potential alternative packaging for retarding lipid oxidation of lipid or fatty foods.

关键词： Active film antioxidant shelf-life extension Maillard reaction products fish gelatin