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Tailoring S-scheme-based carbon nanotubes(CNTs)mediated Ag-CuBi_(2)O_(4)/Bi_(2)S_(3)nanomaterials for photocatalytic dyes degradation in the aqueous system

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Journal of Materials Science & Technology 2023年第31期162卷 11-24页

作者： Vishal Dutta Anita Sudhaik Sonu Pankaj Raizada Archana Singh Tansir Ahamad Sourbh Thakur quyet van le van-Huy Nguyen Pardeep Singh School of Advanced Chemical Sciences Shoolini UniversitySolanHimachal Pradesh173212India Department of Chemistry University Centre for Research and DevelopmentChandigarh UniversityGharuanMohaliPunjabIndia Advanced Materials and Processes Research Institute Hoshangabad RoadBhopal462026MPIndia Department of Chemistry College of ScienceKing Saud UniversityRiyadhSaudi Arabia Department of Organic Chemistry Bioorganic Chemistry and BiotechnologySilesian University of TechnologyB.Krzywoustego 444-100 GliwicePoland Department of Materials Science and Engineering Institute of Green Manufacturing TechnologyKorea University145Anam-ro Seongbuk-guSeoul02841Republic of Korea Faculty of Allied Health Sciences Chettinad Hospital and Research InstituteChettinad Academy of Research and EducationKelambakkam603103Tamil NaduIndia

In this study,S-scheme-based hydrothermal synthesis of Ag-CuBi_(2)O_(4)/CNTs/Bi_(2)S_(3)layered composites has been successfully reported.The photo-degradation of toxic dyes,viz.methyl orange(MO),and methylene blue(MB),has been used to examine nanocomposites with varying weight percent of Bi_(2)S_(3)for photocat-alytic activity in the visible range.Among candidates,Ag-CuBi_(2)O_(4)/CNTs/Bi_(2)S_(3)with a 10%loading of Bi_(2)S_(3)outperformed both pure and hybrid composites in photocatalytic activity.For MO degradation,the hybrid composite with 10%Bi_(2)S_(3)loading degrades 7.04 times higher than pristine CuBi_(2)O_(4)and Bi_(2)S_(3)samples,and for MB degradation,it degrades 4.96 times higher than pristine samples.High surface area,less re-combination rate of photogenerated charge carriers,photogenerated carriers faster separation,and high redox ability of Ag-CuBi_(2)O_(4)/CNTs/Bi_(2)S_(3)(10%)are all attributed to the improving photocatalytic perfor-mance.Even after ten cycles,the hybrid composite is chemically stable and reusable.Carbon nanotubes(CNTs)are a transfer bridge in layered structure for electrons because of their coordinated Fermi level between Ag-CuBi_(2)O_(4)and Bi_(2)S_(3).In addition,the scavenger and electron spin resonance(ESR)experiments verified that·O_(2)^(−),·OH,and h+were the important reactive species that successfully facilitated the pho-tocatalytic degradation process to degrade dyes.This study presents a straightforward and economical approach for obtaining a stable semiconductor-based photocatalytic system and a potential technique for future applications.

关键词： Ag-CuBi_(2)O_(4) Bi_(2)S_(3) Carbon nanotubes(CNTs) S-scheme charge transfer Dye degradation

Sulphur vacancy defects engineered metal sulfides for amended photo(electro)catalytic water splitting: A review

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Journal of Materials Science & Technology 2023年第21期152卷 50-64页

作者： Kusum Sharma Abhinandan Kumar Tansir Ahamad quyet van le Pankaj Raizada Archana Singh Lan Huong Nguyen Sourbh Thakur van-Huy Nguyen Pardeep Singh School of Advanced Chemical Sciences Shoolini UniversitySolanHimachal Pradesh 173212India Department of Chemistry College of ScienceKing Saud UniversitySaudi Arabia Department of Materials Science and Engineering Korea University145AnamroSeongbuk-guSeoul 02841Republic of Korea Advanced Materials and Processes Research Institute Hoshangabad RoadBhopalMP 462026India Faculty of Biology and Environment Ho Chi Minh City University of Food Industry(HUFI)140 Le Trong Tan StreetTay Thanh WardTan Phu DistrictHo Chi Minh CityVietnam Department of Organic Chemistry Bioorganic Chemistry and BiotechnologySilesian University of TechnologyB.Krzywoustego 444-100 GliwicePoland Faculty of Allied Health Sciences Chettinad Hospital and Research InstituteChettinad Academy of Research and EducationKelambakkam-603103Tamil NaduIndia

Vacancy engineering in metal sulfides has garnered enormous attention from researchers because of their outstanding ability to modulate the optical and physiochemical properties of photocatalysts.Typically,in the case of sulfides,the catalytic activity is drastically hindered by the quick reassembly of excitons and the photocorrosion effect.Hence designing and generating S-vacancies in metal sulfides has emerged as a potential strategy for attaining adequate water splitting to generate H_(2) and O_(2) because of the simulta-neous improvement in the optoelectronic features.However,developing efficient catalysts that manifest optimal photo(electro)catalytic performance for large-scale applicability remains challenging.Therefore,it is of utmost interest to explore the insightful features of creating S-vacancy and study their impact on catalytic performance.This review article aims to comprehensively highlight the roles of S-vacancy in sulfides for amended overall water-splitting activity.The photocatalytic features of S-vacancies modulated metal sulfides are deliberated,followed by various advanced synthetic and characterization techniques for effectual generation and identification of vacancy defects.The specific aspects of S-vacancies in refin-ing the optical absorption range charge carrier dynamics,and photoinduced surface chemical reactions are critically examined for overall water splitting applications.Finally,the vouchsafing outlooks and op-portunities confronting the defect-engineered(S-vacancy)metal sulfides-based photocatalysts have been summarized.

关键词： S-vacancy Photo(electro)catalysis Metal sulfides Water splitting Engineering Identification of S-vacancies

Recent progress in emerging BiPO_(4)-based photocatalysts:Synthesis,properties,modification strategies,and photocatalytic applications

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Journal of Materials Science & Technology 2022年第13期108卷 208-225页

作者： Rohit Kumar Pankaj Raizada Aftab Aslam Parwaz Khan van-Huy Nguyen quyet van le Suresh Ghotekar Rangabhashiyam Selvasembian Vimal Gandhi Archana Singh Pardeep Singh School of Advanced Chemical Sciences Shoolini UniversitySolan(Himachal Pradesh)-173212India Center of Excellence for Advanced Materials Research King Abdulaziz UniversityP.O.Box 80203Jeddah 21589Saudi Arabia Chemistry Department Faculty of ScienceKing Abdulaziz UniversityP.O.Box 80203Jeddah 21589Saudi Arabia Faculty of Biotechnology Binh Duong UniversityThu Dau MotVietnam. Department of Materials Science and Engineering Korea University145Anam-ro Seongbuk-guSeoul 02841South Korea Department of Chemistry Smt.Devkiba Mohansinhji Chauhan College of Commerce and ScienceSilvassa 396230University of MumbaiDadra and Nagar Haveli(UT)India Department of Chemistry S.N.ArtsD.J.M.Commerce and B.N.S.Science CollegeSangamner 422605Savitribai Phule Pune UniversityMaharashtraIndia Department of Biotechnology School of Chemical and BiotechnologySASTRA Deemed UniversityThanjavur-613401TamilnaduIndia Department of Chemical Engineering Faculty of TechnologyDharmsinh Desai UniversityNadiad-387001GujaratIndia Advanced Materials and Processes Research Institute Hoshangabad RoadBhopal 462026India

In this perspective,we have highlighted the current literature and explained the synthesis,structure,morphology,modification strategies,and photocatalytic applications of emerging BiPO_(4)-based photocatalysts.Since BiPO_(4)is a large bandgap photocatalyst,it uses UV light for the excitation of electrons,and also,the recombination of charge carriers is an issue in BiPO_(4).Various novel modification strategies of BiPO_(4)photocatalysts viz.defect modifications,heterojunction formation,phase-junctions,surface plasmon resonance,Schottky junction have been successfully proposed and highlighted.These modifications enhance the light absorption and inhibit the recombination of charge carriers BiPO_(4)photocatalyst.Finally,future aspects for further research on BiPO_(4)-based photocatalysts are also explored.It expects that BiPO_(4)-based photocatalysts represent a promising strategy for developing practical photocatalysts for energy and environmental remediation applications.

关键词： Photocatalysis Modification strategies Environmental remediation BiPO_(4)photocatalyst

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Novel Z-Scheme ZnIn_(2)S_(4)-based photocatalysts for solar-driven environmental and energy applications: Progress and perspectives

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Journal of Materials Science & Technology 2021年第28期87卷 234-257页

作者： Yogesh Kumar Rohit Kumar Pankaj Raizada Aftab Aslam Parwaz Khan quyet van le Pardeep Singh van-Huy Nguyen School of Advanced Chemical Sciences Shoolini UniversitySolanHP173229India Department of Chemistry Government Degree CollegeSolanHP173212India Chemistry Department Faculty of ScienceKing Abdulaziz UniversityP.O.Box 80203Jeddah21589Saudi Arabia Institute of Research and Development Duy Tan UniversityDa Nang550000Vietnam Department for Management of Science and Technology Development Ton Duc Thang UniversityHo Chi Minh CityVietnam Faculty of Applied Sciences Ton Duc Thang UniversityHo Chi Minh CityVietnam

Benefiting from strong redox ability,improved charge transport,and enhanced charge separation,Zscheme heterostructures of ZnIn_(2)S_(4) based photocatalysts have received considerable interest to tackle energy needs and environmental issues.The present review highlights the properties of ZnIn_(2)S_(4),which make it a promising photocatalyst,and a suitable combination with oxidation photocatalyst to form Zscheme,leading to improve their photocatalytic properties dramatically.As the central part of this review,various types of Z-scheme heterojunction developed recently based on ZnIn_(2)S_(4) and their application in pollutant degradation,water splitting,CO_(2) reduction,and toxic metals remediation.Some analytical techniques to detect or trap the active radical and study the charge separation and lifetime of charge carriers in these Z-schemes are highlighted.This review offers its readers a broad optical window for the structural architecture of ZnIn_(2)S_(4)-based Z-schemes,photocatalytic activity,stability,and their technological applications.Finally,we discuss the challenges and opportunities for further development on Z-Scheme ZnIn_(2)S_(4)-based photocatalysts toward energy and environmental applications based on the recent progress.

关键词： ZnIn_(2)S_(4) Z-scheme photocatalyst Charge transfer mechanism Pollutant degradation Environmental remediation

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A TEM study on the microstructure of spark plasma sintered ZrB2-based composite with nano-sized SiC dopant

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Progress in Natural Science:Materials International 2021年第1期31卷 47-54页

作者： Mehdi Shahedi Asl Abbas Sabahi Namini Seyed Ali Delbari quyet van le Mohammadreza Shokouhimehr Mohsen Mohammadi Marine Additive Manufacturing Centre of Excellence (MAMCE) University of New Brunswick Department of Engineering Sciences Faculty of Advanced Technologies University of Mohaghegh Ardabili Department of Engineering Sciences Faculty of Advanced Technologies Sabalan University of Advanced Technologies (SUAT) Department of Materials Science and Engineering Research Institute of Advanced Materials Seoul National University Institute of Research and Development Duy Tan University

Sintering behavior of ZrB2ceramic with nano-sized SiC dopant was studied. ZrB2-25 vol% nano-sized SiC was selected as the starting mixture to fabricate the composite. The manufacturing process was accomplished at 1800℃ for 5 min under 25 MPa via spark plasma sintering(SPS). The as-sintered sample reached a relative density of 99%. Besides the initial phases, namely ZrB2and SiC, the high-resolution X-ray diffraction(HRXRD) was used to study the formation of an in-situ ZrC phase. The possible chemical interactions during the ZrC phase formation were scrutinized. The microstructure of the composite was studied by the field emission scanning electron microscopy(FESEM) and transmission electron microscopy(TEM). Elemental analysis through FESEM evaluations revealed the formation of amorphous phases, rich in Zr, C, Si, B, and O elements, which was in harmony with the thermodynamical assessments. TEM studies endorsed the formation of such phases, containing a glassy bed of Si–B–O with ZrC and C islands dispersed therein.

关键词： Spark plasma sintering ZrB 2 Nano-sized SiC Glassy phases

Graphene-based catalysts for electrochemical carbon dioxide reduction

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Carbon Energy 2020年第2期2卷 158-175页

作者： Amirhossein Hasani Mahider Asmare Teklagne Ha Huu Do Sung Hyun Hong quyet van le Sang Hyun Ahn Soo Young Kim School of Chemical Engineering and Materials Science Integrative Research Center for Two-Dimensional Functional MaterialsInstitute of Interdisciplinary Convergence ResearchChung-Ang UniversitySeoulRepublic of Korea Department of Materials Science and Engineering Korea UniversitySeoulRepublic of Korea Institute of Research and Development Duy Tan UniversityDa NangVietnam

Electrochemical carbon dioxide(CO2)reduction is considered to be an efficient strategy to produce usable fuels and overcome the concerns regarding global warming.For this purpose,an efficient,earth abundant,and a low cost catalyst has to be designed.It has been found that graphene-based materials could be promising candidates for CO2 conversion because of their unique physical,mechanical,and electronic properties.In addition,the surface of graphenebased materials can be modified by using different strategies,including doping,defect engineering,producing composite structures,and wrapping shapes.In this review,the fundamentals of electrochemical CO2 reduction and recent progress of graphene-based catalysts are investigated.Furthermore,recent studies on graphene-based materials for CO2 reduction are summarized.

关键词： catalyst CO2 reduction electrochemical graphene

Evaluation of Weathering Performance of Rosin-Copper Based Treated Wood

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Journal of Renewable Materials 2022年第11期10卷 2765-2780页

作者： Thi Thanh Hien Nguyen Nho quyet Tran Thi Minh Nguyet Nguyen Hien Mai Trinh Xuan Phuong le Trong Kien Nguyen College of Wood Industry and Interior Design Vietnam National University of ForestryHa NoiViet Nam College of Economics and Management Northeast Forestry UniversityHarbinChina

This study aimed to evaluate the effect of natural weathering on some surface characteristics and mechanical properties of Styrax wood treated with mixtures of 1.0%,2.0%,or 4.0%rosin sizing agent and 3%copper sulfate.Wood samples after treatment were exposed to outdoor conditions for one year and changes in color,glossiness,weight loss,compression strength parallel to grain(CSPG),modulus of rupture(MOR),and modulus of elasticity(MOE)were investigated after 6 and 12-month of natural weathering.The results showed that rosin-copper treatment could improve color stability and gloss of samples after weathering.Mass losses of all rosin-copper treated samples after 12 months of exposure were negligible compared with the untreated control samples.In addition,rosin-copper treatment enhanced the CSPG compared to untreated controls,but slightly decreased the MOR and MOE of Styrax wood before weathering.Natural weathering factors induced a reduction for all strength properties,however,the decrease rate for strength properties of rosin-copper treated samples was negligible compared with the untreated control samples after 12-month natural weathering exposure.The FTIR and SEM-EDX confirmed that the use of the rosin-copper formulations to impregnate wood could decrease the hazard of the copper preservative leaching into the environment,while also enhancing more resistance against weathering factors and other biotic factors.

关键词： Rosin-copper weathering color stability CSPG MOR MOE

Optimizing Bidders Selection of Multi-Round Procurement Problem in Software Project Management Using Parallel Max-Min Ant System Algorithm

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Computers, Materials & Continua 2021年第1期66卷 993-1010页

作者： Dac-Nhuong le Gia Nhu Nguyen arish Garg quyet-Thang Huynh Trinh Ngoc Bao Nguyen Ngoc Tuan Institute of Research and Development Duy Tan UniversityDa Nang550000Vietnam Faculty of Information Technology Duy Tan UniversityDa Nang550000Vietnam Faculty of Information Technology Haiphong UniversityHaiphong180000Vietnam Graduate School Duy Tan UniversityDa Nang550000Vietnam School of Mathematics Thapar Institute of Engineering and TechnologyPatiala147004India Hanoi University of Science and Technology Hanoi100000Vietnam Hanoi University Hanoi100000Vietnam Department of ICT Ministry of Education and TrainingHanoi100000Vietnam

This paper presents a Game-theoretic optimization via Parallel Min-Max Ant System(PMMAS)algorithm is used in practice to determine the Nash equilibrium value to resolve the confusion in choosing appropriate bidders of multi-round procurement problem in software project management.To this end,we introduce an approach that proposes:(i)A Game-theoretic model of multiround procurement problem(ii)A Nash equilibrium strategy corresponds to multi-round strategy bid(iii)An application of PSO for the determination of global Nash equilibrium.The balance point in Nash Equilibrium can help to maintain a sustainable structure not only in terms of project management but also in terms of future cooperation.As an alternative of procuring entities subjectively,a methodology to support decision making has been studied using Nash equilibrium to create a balance point on benefit in procurement where buyers and suppliers need multiple rounds of bidding.Our goal focus on the balance point in Nash Equilibrium to optimizing bidder selection in multi-round procurement which is the most beneficial for both investors and selected tenderers.Our PMMAS algorithm is implemented based on MPI(message passing interface)to find the approximate optimal solution for the question of how to choose bidders and ensure a path for a win-win relationship of all participants in the procurement process.We also evaluate the speedup ratio and parallel efficiency between our algorithm and other proposed algorithms.As the experiment results,the high feasibility and effectiveness of the PMMAS algorithm are verified.

关键词： Parallel min-max ant system multi-objective multi-round procurement software project management project conflicts Nash equilibrium game theory MPI

Mitogenomic phylogeny of the Asian colobine genus Trachypithecus with special focus on Trachypithecus phayrei(Blyth, 1847) and description of a new species

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Zoological Research 2020年第6期41卷 656-669页

作者： Christian Roos Kristofer MHelgen Roberto Portela Miguez Naw May Lay Thant Ngwe Lwin Aung Ko Lin Aung Lin Khin Mar Yi Paing Soe Zin Mar Hein Margaret Nyein Nyein Myint Tanvir Ahmed Dilip Chetry Melina Urh EGrace Veatch Neil Duncan Pepijn Kamminga Marcus AHChua Lu Yao Christian Matauschek Dirk Meyer Zhi-Jin Liu Ming Li Tilo Nadler Peng-Fei Fan le Khac quyet Michael Hofreiter Dietmar Zinner Frank Momberg Primate Genetics Laboratory German Primate CenterLeibniz Institute for Primate ResearchGoettingen 37077Germany Gene Bank of Primates German Primate CenterLeibniz Institute for Primate ResearchGoettingen 37077Germany Chances for Nature(CfN) Goettingen 37073Germany Australian Museum Research Institute Australian MuseumSydneyNew South Wales 2010Australia Natural History Museum London SW7 BDUK Wildlife Conservation Society(WCS)-Myanmar Program Yangon 11041Myanmar Fauna&Flora International(FFI)-Myanmar Programme Yangon 11201Myanmar Popa Mountain Park Nature and Wildlife Conservation DivisionForest DepartmentPopa 05242Myanmar World Wide Fund for Nature(WWF)-Myanmar Yangon 11191Myanmar Department of Zoology Jagannath UniversityDhaka 1100Bangladesh Primate Research and Conservation Division AaranyakGuwahatiAssam 781028India Department of Anthropology Emory UniversityAtlantaGA 30322USA Department of Anthropology Yale UniversityNew HavenCT 06511USA Department of Mammalogy American Museum of Natural HistoryNew YorkNY 10024USA Naturalis Biodiversity Center Leiden 2333 CRThe Netherlands lee Kong Chian Natural History Museum National University of SingaporeSingapore 117377Singapore Department of Environmental Science and Policy George Mason UniversityFairfaxVA 22030USA Key Laboratory of Animal Ecology and Conservation Biology Institute of ZoologyChinese Academy of SciencesBeijing 100101China Center for Excellence in Animal Evolution and Genetics Chinese Academy of SciencesKunmingYunnan 650223China Cuc Phuong Commune Nho Quan DistrictNinh Binh ProvinceVietnam School of Life Sciences Sun Yat-Sen UniversityGuangzhouGuangdong 510275China Center for Biodiversity Conservation and Endangered Species Ho-Chi-Minh CityVietnam Institute for Biochemistry and Biology University of PotsdamPotsdam 14476Germany Cognitive Ethology Laboratory German Primate CenterLeibniz Institute for Primate ResearchGoettingen 37077Germany leibniz Science Campus Primate Cognition Goettingen 37077Germany De

Trachypithecus,which currently contains 20 species divided into four groups,is the most speciose and geographically dispersed genus among Asian colobines.Despite several morphological and molecular studies,however,its evolutionary history and phylogeography remain poorly understood.Phayre’s langur(Trachypithecus phayrei) is one of the most widespread members of the genus,but details on its actual distribution and intraspecific taxonomy are limited and controversial.Thus,to elucidate the evolutionary history of Trachypithecus and to clarify the intraspecific taxonomy and distribution of T.phayrei,we sequenced 41 mitochondrial genomes from georeferenced fecal samples and museum specimens,including two holotypes.Phylogenetic analyses revealed a robustly supported phylogeny of Trachypithecus,suggesting that the T.pileatus group branched first,followed by the T.francoisi group,and the T.cristatus and T.obscurus groups most recently.The four species groups diverged from each other 4.5-3.1 million years ago(Ma),while speciation events within these groups occurred much more recently(1.6-0.3 Ma).Within T.phayrei,we found three clades that diverged 1.0-0.9 Ma,indicating the existence of three rather than two taxa.Following the phylogenetic species concept and based on genetic,morphological,and ecological differences,we elevate the T.phayrei subspecies to species level,describe a new species from central Myanmar,and refine the distribution of the three taxa.Overall,our study highlights the importance of museum specimens and provides new insights not only into the evolutionary history of T.phayrei but the entire Trachypithecus genus as well.

关键词： Colobinae Integrative zoology Mitochondrial genome Museum specimens New species

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