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Fluoro-functionalized plant biomass adsorbent:Preparation and application in extraction of trace perfluorinated compounds from environmental water samples

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Journal of Environmental Sciences 2024年第3期137卷 703-715页

作者： Xi Tan Yan Shi Chun-Feng Ma quan chi Yu-Hang Yang Wen-Xiang Zhang Hua-Ming Xiao Xian Wang Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission School of Chemistry and Materials ScienceSouth-Central Minzu UniversityWuhan 430074China School of Pharmaceutical Sciences South-Central Minzu UniversityWuhan 430074China Key Laboratory of Oilseeds Processing of Ministry of Agriculture Hubei Key Laboratory of Lipid Chemistry and NutritionOil Crops Research Institute of the Chinese Academy of Agricultural SciencesWuhan 430062China

Perfuorinated compounds(PFCs)are toxic and widely present in the environment,and therefore effective adsorbents are required to remove PFCs from environmental *** the present study,a new type of fuorinated biomass materials was synthesized via an ingenious fuorosilanization *** adsorbents were applied for the adsorption of 13typical PFCs,including perfuorocarboxylic acids(PFCAs)and perfuorosulfonic acids(PFSAs).By comparing their adsorption performance,Fluorinated cedar slag(FCS)was discovered to have the best absorption efficiency and enabled highly efficient enrichment of *** adsorption recovery of FCS with the investigated PFCs is greater than 90%under the optimal adsorption *** to the high affinity of F-F sorbent-sorbate interaction,FCS had good adsorption capacities of PFCs from aqueous solution,with the maximum adsorption capacity of 15.80 mg/g for PFOS and 10.71 mg/g for PFOA,***,the adsorption time could be achieved in a short time(8 min).Using the FCS absorbent,an innovative FCS-solid phase extraction assisted with high performance liquid chromatography-electrospray-tandem mass spectrometry(FCS-SPE-HPLC-ESI-MS/MS)method was first developed to sensitively detect PFCs in the environmental water *** intra-day and inter-day recovery rates of the 13 compounds ranged from 90.7%-104.3%,with the RSD of 2.1%-4.7%(intra-day)and 2.5%-8.5%(inter-day),*** research demonstrates the potential of the newly fuoro-functionalized plant biomass to adsorb PFCs from environmental water,with the advantages of high adsorption efficiencies,high antiinterference,easy operation and low economic cost.

关键词： Fluoro-functionalized biomass Perfuorinated compounds(PFCs) Adsorption efficiency Mass spectrometry(MS) Fluorinated cedar slag(FCS)

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Recent Progress in Mass Spectrometry-based Metabolomics for Colorectal Cancer

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Chemical Research in chinese Universities 2022年第4期38卷 886-893页

作者： XIAO Chulei chi quan WANG Xian Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission School of Chemistry and Materials ScienceSouth-Central Minzu UniversityWuhan430074P.R.China

Metabolomics,one of the latest omics technologies,is employed to reveal overall metabolic trajectories,identify disease causative mechanisms and provide information for preventive diagnosis and drug *** is a disease known to alter cellular metabolism and so metabolomics can play an important role in the early diagnosis of cancer and in the evaluation of medical interventions and treatments for *** metabolomics studies rely on high-sensitive and high-throughput mass spectrometry *** recent years,various mass spectrometry(MS)methodologies have been developed and enriched the scope of metabolite detection,contributing to disease studies,such as diabetes,cancer,and *** cancer is the third most diagnosed cancer worldwide and its incidence ranked third in *** review focuses on the mass spectrometry technologies in metabolomics and summarizes the progress of metabolomics research in colorectal cancer.

关键词： Metabolomics Mass spectrometry Colorectal cancer Biomarker

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Ru(II)-Catalyzed ortho C-H Allylation of N-Aryl-7-azaindoles with 2-Methylidene Cyclic Carbonate

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chinese Journal of Chemistry 2024年第9期42卷 985-989页

作者： Jing Zhang quan-Jian Luo Han-chi Wang Jin-Heng Li Bo Sun State Key Laboratory Base of Eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and Technology QingdaoShandong266042China State key Laboratory of Applied Organic Chemistry Lanzhou University LanzhouGansu 7300ooChina School of Chemistry and Chemical Engineering Henan Normal UniversityXinxiangHenan 453007China

A Ru(II)-catalyzed ortho allylation reaction of N-aryl-7-azaindole with readily available 2-methylidene cyclic carbonate has been *** reaction is an effective pathway for synthesizing 7-azaindole derivatives with a wide scope of substrates and high *** addition,the method can be extended to the allylation of other heterocyclic compounds and several cyclic carbonates,highlighting the practicality of this strategy for synthesis.

关键词： Ru(II) Allylation N-Aryl-7-azaindoles Cyclic carbonates Heterocyclic compounds C-H activation

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Analysis of mechanical strengths of extreme line casing joint considering geometric, material, and contact nonlinearities

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Petroleum Science 2024年第3期21卷 1992-2004页

作者： Ji-Yun Zhang chi Peng Jian-Hong Fu quan Cao Yu Su Jian-Yun Pang Zi-Qiang Yu Petroleum Engineering School Southwest Petroleum University Engineering Technology Research Institute of CNPC Southwest Oil and Gas Field Company

To address the challenges associated with difficult casing running, limited annular space, and poor cementing quality in the completion of ultra-deep wells, the extreme line casing offers an effective solution over conventional casings. However, due to its smaller size, the joint strength of extreme line casing is reduced, which may cause failure when running in the hole. To address this issue, this study focuses on the CST-ZT Φ139.7 mm × 7.72 mm extreme line casing and employs the elastic-plastic mechanics to establish a comprehensive analysis of the casing joint, taking into account the influence of geometric and material nonlinearities. A finite element model is developed to analyze the forces and deformations of the extreme line casing joint under axial tension and external collapse load. The model investigates the stress distribution of each thread tooth subjected to various tensile forces and external pressures. Additionally, the tensile strength and crushing strength of the extreme line casing joint are determined through both analytical and experimental approaches. The findings reveal that, under axial tensile load, the bearing surface of each thread tooth experiences uneven stress, with relatively high equivalent stress at the root of each thread tooth. The end thread teeth are valuable spots for failure. It is observed that the critical fracture axial load of thread decreases linearly with the increase of thread tooth sequence. Under external pressure, the circumferential stress is highest at the small end of the external thread, leading to yield deformation. The tensile strength of the joint obtained from the finite element model exhibits a relative error of less than 7% compared to the analytical and experimental values,proving the reliability of the finite element model. The tensile strength of the joint is 3091.9 k ***, in terms of anti-collapse capability, the joints demonstrate higher resistance to collapse compared to the casing body, which i

关键词： Extreme line casing Elastic-plastic mechanics Finite element analysis Tensile strength Collapse strength

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Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-co-butylene 1,4-cyclohexanedicarboxylate)Copolymers

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chinese Journal of Polymer Science 2018年第6期36卷 756-764页

作者： Fei Liu De-quan chi Hai-Ning Na Jin Zhu Ningbo Key Laboratory of Polymer Materials Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China

In this study, the isothermal crystallization kinetics and crystalline morphology of poly（butylene adipate-co-butylene 1,4-cyclohexanedicarboxylate）（PBAC）, which refers to a copolyester containing a non-planar ring structure, were investigated by differential scanning calorimetry and polarized optical microscopy, and compared with those of neat poly（butylene 1,4-cyclohexanedicarboxylate）（PBC）. The results indicate that the introduction of butylene adipate（BA） unit into PBAC did not change the intrinsical crystallization mechanism. But, the crystallization rate and ability, and equilibrium melting temperature of PBAC copolymers were reduced. All PBC and PBAC copolymers could only form high density of nucleation from melt at given supercooling, while no Maltese cross or ring-banded spherulites could be observed. PBAC copolymers with a high amount of BA unit became amorphous after quenching with liquid nitrogen from melt, while PBC and PBAC copolymers with a low amount of BA unit could still form a large amount of nuclei under the same treatment.

关键词： Poly(butylene adipate-co-butylene 1 4-cyclohexanedicarboxylate) Isothermal crystallization kinetics Crystalline morphology

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Study on the Structural Effect of Maltoligosaccharides on Cytochrome c Complexes Stabilities by Native Mass Spectrometry

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Natural Products and Bioprospecting 2018年第1期8卷 57-61页

作者： quan chi Ying-Zhi Liu Xian Wang Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission College of Chemistry and Materials ScienceSouth-Central University for NationalitiesWuhanHubei 430074People’s Republic of China

Noncovalent interactions between ligands and targeting proteins are essential for understanding molecular mechanisms of *** this work,we investigated the interaction of Cytochrome c(Cyt c)with maltoligosaccharides,namely maltose(Mal Ⅱ),maltotriose(Mal Ⅲ),maltotetraose(Mal Ⅳ),maltopentaose(Mal Ⅴ),maltohexaose(Mal Ⅵ)and maltoheptaose(Mal Ⅶ).Using electrospray ionization mass spetrometry(ESI-MS)assay,the 1:1 and 1:2 complexes formed by Cyt c with maltoligosaccharide ligand were *** corresponding association constants were calculated according to the deconvoluted *** order of the relative binding affinities of the selected oligosaccharides with Cyt c were as MalⅢ>MalⅣ>MalⅡ>MalⅤ>MalⅥ>MalⅦ.The results indicated that the stability of noncovalent protein complexes was intimately correlated to the molecular structure of bound *** relevant functional groups that could form H-bonds,electrostatic or hydrophobic forces with protein’s amino residues played an important role for the stability of protein *** addition,the steric structure of ligand was also critical for an appropriate interaction with the binding pocket of proteins.

关键词： Electrospray ionization mass spectrometry Maltoligosaccharides Cytochrome c complexes Structure-binding relationship

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Growth and Cd Accumulation of Orychophragmus violaceus as Affected by Inoculation of Cd-Tolerant Bacterial Strains

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Pedosphere 2014年第3期24卷 322-329页

作者： LIANG Xia HE chi-quan NI Gang TANG Gui-E CHEN Xue-Ping LEI Yan-Ru School of Environmental and Chemical Engineering Shanghai University

Beneficial interactions between microorganisms and plants, particularly in the rhizosphere, are a research area of global interest. Four cadmium(Cd)-tolerant bacterial strains were isolated from heavy metal-contaminated sludge and their effects on Cd mobility in soil and the root elongation and Cd accumulation of Orychophragmus violaceus were explored to identify the capability of metalresistant rhizobacteria for promoting the growth of O. violaceus roots on Cd-contaminated soils. The isolated strains, namely, Bacillus subtilis, B. cereus, B. megaterium, and Pseudomonas aeruginosa, significantly enhanced the plant Cd accumulation. The Cd concentrations in the roots and shoots were increased by up to 2.29- and 2.86-fold, respectively, by inoculation of B. megaterium, as compared with the uninoculated control. The bacterial strains displayed different effects on the shoot biomass. Compared with the uninoculated plants, the shoot biomass of the inoculated plants was slightly increased by B. megaterium and significantly decreased by the other strains. B. megaterium was identified as the best candidate for enhancing Cd accumulation in O. violaceus. Thus, this study provides novel insight into the development of plant-microbe systems for phytoremediation.

关键词：诸葛菜属根际细菌镉积累接种菌株枯草芽胞杆菌巨大芽孢杆菌地上部生物量

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铁卟啉与活性氮的相互作用

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化学通报 2010年第1期73卷 18-23页

作者：池泉中南民族大学化学与材料科学学院武汉430074

在活性氮(RNS)与蛋白质的相互作用过程中,含铁卟啉蛋白/铁卟啉可以催化RNS转化为惰性的NO3-,阻止蛋白质的硝化;同时,含铁卟啉蛋白/铁卟啉也可通过高价铁氧化物及.NO2的产生来加速蛋白质的硝化。生理条件下,血红蛋白、肌红蛋白等含铁卟... 详细信息

在活性氮(RNS)与蛋白质的相互作用过程中,含铁卟啉蛋白/铁卟啉可以催化RNS转化为惰性的NO3-,阻止蛋白质的硝化;同时,含铁卟啉蛋白/铁卟啉也可通过高价铁氧化物及.NO2的产生来加速蛋白质的硝化。生理条件下,血红蛋白、肌红蛋白等含铁卟啉蛋白可清除多余的RNS;氧化应激条件下,过氧化物酶等含铁卟啉蛋白可以不同的方式催化加速RNS对蛋白质的硝化。

关键词：活性氮铁卟啉蛋白质硝化

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基于最小路由代价的巨型星座网络接入策略

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系统工程与电子技术 2024年第5期46卷 1792-1800页

作者：张驰陈全唐祖平魏蛟龙华中科技大学电子信息与通信学院湖北武汉430074 国防科技大学空天科学学院湖南长沙410073

针对低轨巨型星座网络星间路由复杂、网关卫星负载不均衡等问题,在星地接入策略中考虑星间路由代价,提出一种基于最小路由代价的接入策略。该策略分为3个阶段:在最短跳数估计阶段,根据用户终端和信关站位置估算用户终端至网关卫星的星... 详细信息

针对低轨巨型星座网络星间路由复杂、网关卫星负载不均衡等问题,在星地接入策略中考虑星间路由代价,提出一种基于最小路由代价的接入策略。该策略分为3个阶段:在最短跳数估计阶段,根据用户终端和信关站位置估算用户终端至网关卫星的星间路由跳数;在网关卫星分配阶段,基于估计跳数建立二分图模型,采用带权最小代价匹配算法确定网关卫星和接入卫星类型;在接入卫星选择阶段,以星间路由跳数和星地仰角加权构造接入准则,在确定类型的可视卫星中选择最优接入卫星。仿真结果表明,所提方法能够显著降低系统整体星间路由跳数,提高网关卫星负载均衡性和用户接入成功率。

关键词：巨型星座网络最小路由代价网关匹配接入策略负载均衡

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Comparison of physiological responses to oxidative and heavy metal stress in seedlings of rice paddy, Oryza sativa L.

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Journal of Environmental Sciences 2000年第4期12卷 458-462页

作者： YU Guo\|ying, WANG Guo\|ping, HE chi\|quan (Lab for Wetland Process and Environment, Changchun Institute of Geography, The chinese Academy of Sciences, Changchun 130021,china E\|mail: yuguoying@***) 中科院长春地理所湿地环境开放实验室吉林长春 1 3 0 0 2

Physiological responses on the bases of activities of antioxidant enzymes: peroxidase, catalase, superoxide dismutase and glutathione reductase as well as estimation of total protein, lipid peroxidation and thiols in the form of protein, non\|protein, glutathione and phytochelatin measured in growing seedlings of paddy, Oryza sativa L., from day 2 to 8 were compared following treatment of seeds for 5h with oxidative agents, paraquat 5 × 10 -5 , 10 -4 , 10 -3 mol/L, H 2O 2 10 -3 , 5×10 -3 , 10 -2 mol/L, and CdCl 2 10 -5 , 10 -4 , 5×10 -3 mol/L. A significant induction of all antioxidant enzymes along with an increase in the levels of protein, lipid peroxidation and glutathione was noted in response to oxidative stress, CdCl 2 induced significant peroxidase and catalase activities but not superoxide dismutase. In a marked contrast from oxidative stress, CdCl 2 decreased glutathione reductase activity as well as glutathione levels but increased phytochelatin level. The different physiological responses thus underlined the crucial involvement of glutathione and phytochelatin in the oxidative and heavy metal\|linduced adaptive responses respectively.

关键词： adaptive response oxidative stress heavy metal antioxidant enzymes glutathione phytochelatin

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