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Single-atomic-site iron on N-doped carbon for chemoselective reduction of nitroarenes

Nano Research 2022年第1期15卷 603-611页

作者： Guoping Lu Kangkang Sun Yamei Lin qixuan du Jiawei Zhang Kui Wang Pengcheng Wang School of Chemical Engineering Nanjing University of Science&TechnologyNanjing 210094China Institute of Chemical Industry of Forest Products Chinese Academy of ForestryNational Engineering Laboratory for Biomass Chemical UtilizationNanjing 210042China School of Food Science and Pharmaceutical Engineering Nanjing Normal UniversityNanjing 210032China College of Materials Science and Engineering Hunan UniversityChangsha 410082China

A facile,gram-scale and sustainable approach has been established for the synthesis of single-atomic-site iron on N-doped carbon(Fe_(SA)@NC-20A)via the pyrolysis of aniline modified FeZn-ZIFs,in which the synthesis of zeolitic imidazolate frameworks(ZIFs)can be accomplished in water at room temperature,and no acid etching is *** as-synthesized catalyst exhibits better performance on the chemoselective hydrogenation of nitroarenes with a broad substrate scope(turnover frequency(TOF)up to 1,727 h^(-1),23 examples)than most of previously reported *** on high-angle annular dark field scanning transmission microscopy(HAADF-STEM)images in combination with X-ray photoelectron spectroscopy(XPS),X-ray absorption spectroscopy(XAS),electron spin resonance(ESR),and Mossbauer spectroscopy,Fe is dispersed as single atoms via forming FeNx(x=4-6).This work not only determines the active sites of FesA@NC-20A for hydrogenation(FeN4),but also proposes tentative pathways for both N-H activation of hydrazine and the reduction of nitroarene on FeN4 site,both of which are the key steps for the hydrogenation of *** addition,this catalyst shows excellent stability,and no significant activity degradation is observed when recycling for 10 times or restoring in air for 2 months.

关键词： single-atom-site iron zeolitic imidazolate framework the hydrogenation of nitroarene N-doped carbon drug synthesis

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Dealuminated Hβ zeolite for selective conversion of fructose to furfural and formic acid

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Green Energy & Environment 2024年第2期9卷 311-320页

作者： Rui Li qixuan Lin Junli Ren Xiaobao Yang Yingxiong Wang Lingzhao Kong State Key Laboratory of Pulp and Paper Engineering School of Light Industry and EngineeringSouth China University of TechnologyGuangzhou510640China Institute of Coal Chemistry Chinese Academy of Sciences27 South Taoyuan RoadTaiyuan030001China CAS Key Laboratory of Low-Carbon Conversion Science and Engineering Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai201210China School of Environmental Science and Technology Suzhou University of Science and Technology Suzhou Jiangsu215009China

The fructose-to-furfural transformation is facing major challenges in the selectivity and high efficiency. Herein, we have developed a simple and effective approach for the selective conversion of fructose to furfural using Hβ zeolite modified by organic acids for dealuminization to regulate its textural and acidic properties. It was found that citric acid-dealuminized Hβ zeolite possessed high specific surface areas, wide channels and high Brønsted acid amount, which facilitated the selective conversion of fructose to furfural with a maximum yield of 76.2% at433 K for 1 h in the γ-butyrolactone(GBL)-H_(2)O system, as well as the concomitant formation of 83.0% formic acid. The^(13)C-isotope labelling experiments and the mechanism revealed that the selective cleavage of C1–C2 or C5–C6 bond on fructose was firstly occurred to form pentose or C5 intermediate by weak Brønsted acid, which was then dehydrated to furfural by strong Brønsted acid. Also this dealuminized Hβ catalyst showed the great recycling performance and was active for the conversion of glucose and mannose.

关键词： Fructose Dealuminated-Hb zeolite Selective conversion Furfural

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Coaxial Wet Spinning of Boron Nitride Nanosheet‑Based Composite Fibers with Enhanced Thermal Conductivity and Mechanical Strength

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Nano-Micro Letters 2024年第2期16卷 126-138页

作者： Wenjiang Lu qixuan Deng Minsu Liu Baofu Ding Zhiyuan Xiong Ling Qiu Tsinghua Shenzhen International Graduate School(TSIGS) Tsinghua UniversityShenzhen 518055People’s Republic of China Monash Suzhou Research Institute(MSRI) Monash UniversitySuzhou 215000People’s Republic of China Faculty of Materials Science and Engineering/Institute of Technology for Carbon Neutrality Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055People’s Republic of China Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality Shenzhen 518055People’s Republic of China School of Light Industry and Engineering South China University of TechnologyGuangzhou 510614People’s Republic of China

Hexagonal boron nitride nanosheets(BNNSs)exhibit remarkable thermal and dielectric ***,their self-assembly and alignment in macroscopic forms remain challenging due to the chemical inertness of boron nitride,thereby limiting their performance in applications such as thermal *** this study,we present a coaxial wet spinning approach for the fabrication of BNNSs/polymer composite fibers with high nanosheet *** composite fibers were prepared using a superacid-based solvent system and showed a layered structure comprising an aramid core and an aramid/BNNSs ***,the coaxial fibers exhibited significantly higher BNNSs alignment compared to uniaxial aramid/BNNSs fibers,primarily due to the additional compressive forces exerted at the core-sheath interface during the hot drawing *** a BNNSs loading of 60 wt%,the resulting coaxial fibers showed exceptional properties,including an ultrahigh Herman orientation parameter of 0.81,thermal conductivity of 17.2 W m^(-1)K^(-1),and tensile strength of 192.5 *** results surpassed those of uniaxial fibers and previously reported BNNSs composite fibers,making them highly suitable for applications such as wearable thermal management *** findings present a promising strategy for fabricating high-performance composite fibers based on BNNSs.

关键词： Boron nitride nanosheets Coaxial fiber Interfacial compression Nanosheet aligning Wearable thermal management

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Pathology of pain and its implications for therapeutic interventions

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Signal Transduction and Targeted Therapy 2024年第7期9卷 2851-2899页

作者： Bo Cao qixuan Xu Yajiao Shi Ruiyang Zhao Hanghang Li Jie Zheng Fengyu Liu You Wan Bo Wei Department of General Surgery First Medical CenterChinese PLA General HospitalBeijing 100853China Medical School of Chinese PLA Beijing 100853China Neuroscience Research Institute and Department of Neurobiology School of Basic Medical SciencesKey Laboratory for NeuroscienceMinistry of Education/National Health CommissionPeking UniversityBeijing 100191China

Pain is estimated to affect more than 20%of the global population,imposing incalculable health and economic *** pain management is crucial for individuals suffering from ***,the current methods for pain assessment and treatment fall short of clinical *** from advances in neuroscience and biotechnology,the neuronal circuits and molecular mechanisms critically involved in pain modulation have been *** research achievements have incited progress in identifying new diagnostic and therapeutic *** this review,we first introduce fundamental knowledge about pain,setting the stage for the subsequent *** review next delves into the molecular mechanisms underlying pain disorders,including gene mutation,epigenetic modification,posttranslational modification,inflammasome,signaling pathways and *** better present a comprehensive view of pain research,two prominent issues,sexual dimorphism and pain comorbidities,are discussed in detail based on current *** status quo of pain evaluation and manipulation is summarized.A series of improved and innovative pain management strategies,such as gene therapy,monoclonal antibody,brain-computer interface and microbial intervention,are making strides towards clinical *** highlight existing limitations and future directions for enhancing the quality of preclinical and clinical *** to decipher the complexities of pain pathology will be instrumental in translating scientific discoveries into clinical practice,thereby improving pain management from bench to bedside.

关键词： pain thereby summarized

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Review on piezoelectric actuators:materials,classifications,applications,and recent trends

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Frontiers of Mechanical Engineering 2024年第1期19卷 5-33页

作者： Xuyang ZHOU Shuang WU Xiaoxu WANG Zhenshan WANG qixuan ZHU Jinshuai SUN Panfeng HUANG Xuewen WANG Wei HUANG Qianbo LU Institute of Flexible Electronics(IFE) Northwestern Polytechnical UniversityXi’an 710072China School of Automation Northwestern Polytechnical UniversityXi’an 710072China Key Laboratory of Flexible Electronics of Zhejiang Province Ningbo Institute of Northwestern Polytechnical UniversityNingbo 315103China

Piezoelectric actuators are a class of actuators that precisely transfer input electric energy into displacement,force,or movement outputs efficiently via inverse piezoelectric effect-based electromechanical *** types of piezoelectric actuators have sprung up and gained widespread use in various applications in terms of compelling attributes,such as high precision,flexibility of stoke,immunity to electromagnetic interference,and structural *** paper systematically reviews the piezoelectric materials,operating principles,representative schemes,characteristics,and potential applications of each mainstream type of piezoelectric ***,we intend to provide a more scientific and nuanced perspective to classify piezoelectric actuators into direct and indirect categories with several *** addition,this review outlines the pros and cons and the future development trends for all kinds of piezoelectric actuators by exploring the relations and mechanisms behind *** rich content and detailed comparison can help build an in-depth and holistic understanding of piezoelectric actuators and pave the way for future research and the selection of practical applications.

关键词： piezoelectric actuator piezoelectric effect amplified piezoelectric actuator ultrasonic actuator stepping actuator piezoelectric polymer

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冲击式水轮机水斗设计方法及性能优化

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清华大学学报（自然科学版） 2024年第5期64卷 852-859页

作者：孙启轩谭磊清华大学能源与动力工程系水圈科学与水利工程全国重点实验室北京100084

雅鲁藏布江下游蕴藏着丰富的水电资源,具有高水头、大容量等特点,冲击式水轮机是优选机型。转轮是冲击式水轮机的核心过流部件和做功部件,水斗形状对转轮性能至关重要。该文将水斗三维几何形状的构造线划分为轮廓线、过流剖面线和引导线... 详细信息

雅鲁藏布江下游蕴藏着丰富的水电资源,具有高水头、大容量等特点,冲击式水轮机是优选机型。转轮是冲击式水轮机的核心过流部件和做功部件,水斗形状对转轮性能至关重要。该文将水斗三维几何形状的构造线划分为轮廓线、过流剖面线和引导线3类,给定若干特征参数,提出了一种可控参数的冲击式水轮机水斗三维设计方法。选择水斗深度、宽度增量、出水边角度、分水刃角度和缺口圆直径等参数对冲击式水轮机水斗开展正交优化。由极差分析可知,宽度增量对转轮效率的影响最大,对出水边角度、缺口圆直径和水斗深度的影响较小,对分水刃角度的影响最小。优化后,冲击式水轮机的水力效率增加了6.71%。相比于原型水斗,优化水斗的总扭矩更大,在扭矩减少至0的过程中平缓过渡,有利于提高机组的水力效率和运行稳定性。

关键词：冲击式水轮机水斗设计方法正交优化数值模拟

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大国制造业兴衰与国际经济秩序变迁

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学术前沿 2024年第9期 73-90页

作者：黄琪轩上海交通大学国际与公共事务学院上海交通大学政治经济研究院上海市创新政策评估研究中心

从国际经济秩序演进历程看,秩序调整与世界政治领导国国内制造业兴衰紧密相关。制造业兴衰影响大国在世界政治中的结构性权力,进而影响其在不同国际秩序中的利益。在制造业成长阶段,英美两国均试图建立重商主义的国内或国际秩序,以促成... 详细信息

从国际经济秩序演进历程看,秩序调整与世界政治领导国国内制造业兴衰紧密相关。制造业兴衰影响大国在世界政治中的结构性权力,进而影响其在不同国际秩序中的利益。在制造业成长阶段,英美两国均试图建立重商主义的国内或国际秩序,以促成本土制造业发展;在制造业成熟阶段,两国积极推进贸易自由化的国际秩序构建;在制造业衰落阶段,两国面临日益增大的保护主义压力,同时积极推进以金融自由化为重点的秩序构建。依托制造业优势地位,以贸易自由化为重点,中国逐渐成为维护国际经济秩序的建设性力量。

关键词：大国制造业贸易自由化金融自由化国际经济秩序

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上海大都市圈创新网络的演化特征及其对创新产出的影响——基于“蜂鸣—管道”视角

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经济地理 2024年第1期44卷 107-117页

作者：王启轩任婕曹湛同济大学建筑与城市规划学院上海200092 自然资源部国土空间智能规划技术重点实验室上海200092

创新网络的建构与完善对推动区域创新发展具有重要意义。文章采用2010—2019年专利合作数据,以上海大都市圈为对象,借鉴“蜂鸣—管道”模型,构建区县单元间与区县单元内的创新网络,并分析蜂鸣与管道对都市圈内创新产出不均衡的异质性影... 详细信息

创新网络的建构与完善对推动区域创新发展具有重要意义。文章采用2010—2019年专利合作数据,以上海大都市圈为对象,借鉴“蜂鸣—管道”模型,构建区县单元间与区县单元内的创新网络,并分析蜂鸣与管道对都市圈内创新产出不均衡的异质性影响。结果表明:(1)上海大都市圈的创新网络呈现出本地蜂鸣与区域管道相互交织的格局;根据蜂鸣与管道的组合特征,不同区县可分为“网络型”“外向型”“孤岛型”和“内向型”4类。(2)蜂鸣与管道总体上会促进区县单元的创新产出,但过于紧密的蜂鸣和管道则与区县单元创新产出间存在倒“U”型关系。(3)中国的都市圈创新发展要综合考虑不同创新合作模式对创新产出的差异化影响,充分发挥本地与区域创新网络的正外部性,并避免过强蜂鸣与管道带来的负外部性。

关键词：创新网络“ 蜂鸣—管道”模型演化特征专利合作上海大都市圈

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Survey and Analysis of Postoperative Quality of Life in Gynaecological Oncology Patients

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Journal of Advances in Medicine Science 2024年第1期7卷 7-14页

作者： Yujing Zhou Fengjuan Yuan Moyu Shang Xiaoyu Chang Haiyue Huang Shirui Wang Xuanxiang Bian qixuan Gao Yanan Dai Pingdingshan University PingdingshanHenan467000China

Goal:To investigate the current status of quality of life of postoperative patients with gynaecological tumours,and to analyse the relevant factors affecting the quality of life of postoperative patients with gynaecological ***:One hundred and fifty-three postoperative gynecological oncology patients who attended the gynaecology and oncology departments of three tertiary hospitals in Henan Province from June 2023 to March 2024 were investigated by convenience sampling *** patients’postoperative survival quality was investigated through the General Information Survey Scale and Quality of Life Score ***:The quality of life measurement scale score of postoperative gynaecological oncology patients in this study was(121.27±10.87),in which there was a difference in the quality of life of postoperative gynaecological oncology patients of different age,education level,marital status,and per capita monthly income of the family,pducation level,unstable marital status,and poor economic status,and provide personalised targeted interventions to improve their quality of life.

关键词： Gynaecological oncology Quality of life Current status survey

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铁路车站客流量波动规律与预测方法探讨

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铁道经济研究 2024年第4期 72-79页

作者：任琦璇中国铁路经济规划研究院有限公司运输研究所北京100038

铁路客运呈现出显著波动特性和复杂变化趋势,准确把握客流变化规律和趋势,实现客流的精准预测,对铁路网络规划、运营组织优化、服务质量提升具有重要意义。以铁路车站客流量2017—2019年历史数据为基础,对节假日和非节假日铁路车站客运... 详细信息

铁路客运呈现出显著波动特性和复杂变化趋势,准确把握客流变化规律和趋势,实现客流的精准预测,对铁路网络规划、运营组织优化、服务质量提升具有重要意义。以铁路车站客流量2017—2019年历史数据为基础,对节假日和非节假日铁路车站客运量波动规律进行分析,通过日期和节假日属性特征设计,应用提出融合注意力机制的长短时记忆网络(LSTM-AM)模型对铁路某车站日客流量进行预测。结果表明,LSTM-AM模型预测误差小且能够较好地反映出客流变化规律,可以为铁路相关部门提供数据支持。

关键词：铁路车站客流量预测节假日波动规律 LSTM-AM模型实证分析

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