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Enhancement of solar-driven photocatalytic activity of oxygen vacancy-rich Bi/BiOBr/Sr_(2)LaF_(7)∶Yb^(3+),Er^(3+)composites through synergetic strategy of upconversion function and plasmonic effect

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Journal of Environmental Sciences 2022年第5期34卷 76-87页

作者： yongjin Li Yingying Zhang Jiajing Wang Youzhun Fan Taizhong Xiao Zhaoyi Yin Tianhui Wang Jianbei qiu Zhiguo Song School of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China

For better use of solar energy,the development of efficient broadband photocatalyst has attracted extraordinary attention.In this study,a ternary composite consisting of Sr_(2)LaF_(7)∶Yb^(3+),Er^(3+)upconversion(UC)nanocrystals and Bi nanoparticles loaded BiOBr nanosheets with oxygen vacancies(OVs,SLFBB)was designed and synthesized by multi-step solvent-thermal method.Mechanisms of in-situ formation of Bi nanoparticles and OVs in BiOBr/Sr_(2)LaF_(7)∶Yb^(3+),Er^(3+)composites(SFLB)are clarified.The Bi metal and OVs enhanced the light-harvesting capacity in the region of visible-near-infrared(Vis-NIR),and promoted the separation of electron-hole(e-/h+)pairs.Furthermore,the surface plasmon resonance(SPR)effect of Bi metal can improve the energy transfer from Sr_(2)LaF_(7)∶Yb^(3+),Er^(3+)to BiOBr via nonradiative energy transfer process,resulting in enhancing the light utilization from up-converting NIR into Vis light.Due to the synergistic effects of UC function,SPR and OVs,the SFLBB exhibited obviously enhanced photocatalytic ability for the degradation of BPA with a rate of 8.9×10^(-3) min^(-1),which is about 2.78 times higher than 3.2×10^(-3) min^(-1) of BiOBr(BOB)under UV-Vis-NIR light irradiation.This work provides a novel strategy for the project of high-efficiency Bismuth-based broadband photocatalysts,which is helpful to fur-ther understand the mechanism of enhanced photocatalysis by UC function and plasmonic effect.

关键词： BiOBr/Sr_(2)LaF_(7)∶Yb^(3+),Er^(3+)composites In-situ generation Bi metal Oxygen vacancies Broadband photocatalysis

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A Study of Diagnosis METHOD for Turbocharger Abnormal Noise

A Study of Diagnosis METHOD for Turbocharger Abnormal Noise

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2019中国汽车工程学会年会

作者： Qiu Yongjin Wang Fangyu Ren Dong Dongfeng Motor Corporation Technical Center Xiangyang Technician College

Basedon the problem of abnormal noise of a turbocharger model in acceleration condition,the study starts from the spectrum characteristics of the abnormal noise.Combined with subjective evaluation and analysis of transmission paths and noise and vibration frequency of various components of engine compartment,this paper elaborates on the excitation characteristics of the turbocharger.According to the generation mechanism of abnormal noise,considering factors such as spatial layout,performance matching and cost constraints,a pneumatic buffer has been set reasonably to eliminate or reduce the influence of turbocharger abnormal noise on riding comfort during acceleration.By integrating principle,analysis and improvement,a set of diagnosis methods for abnormal noise of turbocharger is developed.After being improved and verified,the proposed methods have been applied.

关键词： turbocharger abnormal noise diagnosis method pneumatic buffer acceleration

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N-doped CoAl oxides from hydrotalcites with enhanced oxygen vacancies for excellent low-temperature propane oxidation

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Journal of Environmental Sciences 2022年第6期34卷 79-89页

作者： Enhui Wu Daifeng Lin Yinye Chen Xiaoshan Feng Kui Niu yongjin Luo Baoquan Huang Jianbin qiu Qingrong Qian Qinghua Chen Fujian Key Laboratory of Pollution Control&Resource Reuse Fujian Normal UniversityFuzhou 350007China College of Environmental Science and Engineering Fujian Normal UniversityFuzhou 350007China

A series of nitrogen-doped CoAlO(N-CoAlO)were constructed by a hydrothermal route combined with a controllable NH_(3) treatment strategy.The effects of NH_(3) treatment on the physico-chemical properties and oxidation activities of N-Co AlO catalysts were investigated.In comparison to CoAlO,a smallest content decrease in surface Co^(3+)(serving as active sites)while a largest increased amount of surface Co^(2+)(contributing to oxygen species)are obtained over N-Co AlO/4h among the N-CoAlO catalysts.Meanwhile,a maximum N doping is found over N-CoAlO/4h.As a result,N-CoAlO/4h(under NH_(3) treatment at 400℃ for 4 hr)with rich oxygen vacancies shows optimal catalytic activity,with a T90(the temperature required to reach a 90% conversion of propane)at 266℃.The more oxygen vacancies are caused by the co-operative effects of N doping and suitable reduction of Co^(3+) for NCoAlO/4h,leading to an enhanced oxygen mobility,which in turn promotes C_(3)H_(8) total oxidation activity dominated by Langmuir-Hinshelwood mechanism.Moreover,in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTs)analysis shows that N doping facilities the decomposition of intermediate species(propylene and formate)into CO_(2)over the catalyst surface of N-CoAlO/4h more easily.Our reported design in this work will provide a promising way to develop abundant oxygen vacancies of Co-based catalysts derived from hydrotalcites by a simple NH_(3) treatment.

关键词： Hydrotalcite derived oxides Propane oxidation N doping Co species Oxygen vacancies

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Color tunable and white light emitting via energy transfer in single-phase BiOCl:Er^(3+),Sm^(3+) phosphors for WLEDs

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Journal of Rare Earths 2018年第3期36卷 231-237页

作者： Xiangzhou Zhang yongjin Li Rui Hu Zuyuan Xu Jianbei qiu Zhengwen Yang Zhiguo Song School of Materials Science and Engineering Kunming University of Science and Technology School of Materials Science and Engineering Sun Yat-sen University

BiOCl crystal shows potential as efficient optical host due to its special layered structure. Here,the luminescence properties of the Er^3＋/Sm^3＋ co-doped BiOCl phosphors as single-phase phosphors were reported. Upon near ultraviolet excitation（NUV, 380 nm corresponding the ^4 I15/2→ ^4 G11/2 transition of Er^3＋ ions）, the phosphors exhibit the efficient characteristic emissions of Er^3＋ and Sm^3＋ ions simultaneously. The energy transfer（ET） from Er^3＋ to Sm^3＋ ions in the layered crystals has been validated by the variation of emission intensities and decay lifetimes respectively, which is ascribed to be a dipoledipole interaction. By virtue of the ET behavior and increasing Sm^3＋ ion concentration, the enhancing emission intensity of Sm^3＋ and the tunability of emission color from yellowish-green（0.318, 0.420） to white（0.343, 0.347） are realized. The results of our work indicate that the Er^3＋/Sm^3＋ co-doped BiOCI phosphor has a promising application serving as single component white emitting phosphors for NUV excited WLEDs.

关键词： BiOCl Er^3＋ Sm^3＋ Color tunable Photoluminescence Energy transfer

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Spacing graphene and Ni-Co layered double hydroxides with polypyrrole for high-performance supercapacitors

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Journal of Materials Science & Technology 2020年第20期52卷 190-197页

作者： Jing Liang Cuili Xiang yongjin Zou Xuebu Hu Hailiang Chu Shujun qiu Fen Xu Lixian Sun Guangxi Key Laboratory of Information Materials Guilin University of Electronic TechnologyGuilin 541004China Chongqing University of Technology College of Chemistry&Chemical EngineeringChongqing 400054China

The urgent need of high-performance of energy storage devices triggers us to design newly class of materials.Generally,the materials feature with high conductivity,abundant pore s and excellent stability.Here,a sandwiched hybrid composite containing reduced graphene oxide,polypyrrole and Ni-Co layered double hydroxides(RGO/PPy/NiCo-LDH) was prepared in a facile way.The polypyrrole was incorporated in the two dimensional(2D) nanosheets,which not only serve as the spacer to increase the surface area,but also enhance the conductivity of the nanocomposite.The obtained architecture was employed as an advanced electrode in a supercapacitor.The electrode shows an ultrahigh specific capacitance(2534 F g^-1 at 1 A g^-1) and good cycling efficiency(78 % after 5000 cycles).Moreover,an asymmetric cell based RGO/PPy/NiCo-LDH composite demonstrates excellent electrochemical properties and good prospect of practical use.

关键词： Graphene Ni-Co layered double hydroxides Polypyrrole Supercapacitor Porous carbon

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Binary Co–Ni oxide nanoparticle-loaded hierarchical graphitic porous carbon for high-performance supercapacitors

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Journal of Materials Science & Technology 2020年第2期37卷 135-142页

作者： Yin Liu Cuili Xiang Hailiang Chu Shujun qiu Jennifer McLeod Zhe She Fen Xu Lixian Sun yongjin Zou Guangxi Key Laboratory of Information Materials Guilin University of Electronic TechnologyGuilin541004China Department of Chemistry Queen’s UniversityK7L 3N6Canada

Heteroatom doped graphitic porous carbon is highly desirable for electrochemical applications because of its excellent conductivity and high surface area.In this study,highly uniform Co-Ni oxide nanoparticleloaded B,N-doped hierarchical graphitic porous carbon was prepared through a dual pyrolysis process.Graphene dispersed chitosan hydrogel was first used as a precursor to fabricate the porous carbon(GCS–C)at 700℃.Co and Ni oxide nanoparticles were further anchored on the porous carbon through chemical reduction and calcined at high temperature.The structure of the porous carbon was optimized by the introduction of graphene to the chitosan hydrogel.The graphitic degree of the porous carbon was significantly improved by the Co and Ni species.The heteroatom B and N were found to be well doped in the composite.These features enable the composite to be an excellent candidate for supercapacitor electrodes.The composite demonstrates a high capacitance(1266.7 F g-1 at 1 A g-1)and excellent stability.

关键词： Graphitic carbon Graphene Metal oxides Supercapacitor Porous carbon

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Rambutan-like hierarchically porous carbon microsphere as electrodematerial for high-performance supercapacitors

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Carbon Energy 2021年第2期3卷 361-374页

作者： Chunfeng Shao Shujun qiu Guiming Wu Boyang Cui Hailiang Chu yongjin Zou Cuili Xiang Fen Xu Lixian Sun Guangxi Key Laboratory of Information Materials School of Materials Science and EngineeringGuangxi Collaborative Innovation Center of Structure and Property for New Energy and MaterialsGuilin University of Electronic TechnologyGuilinChina Key Laboratory of Fuel Cell Technology of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhouChina

Used as high-performance electrodes,both structural and compositional alterations of carbon materials play very important roles in energy conversion/storage devices.Especially in supercapacitors,hierarchical pores and heteroatom doping in carbon materials are indispensable.Here the rambutan-like hierarchically porous carbon microspheres(PCMs)have been constructed via a hydrothermal treatment,followed by carbonization/activation.The hierarchically porous microstructure is composed of three-dimensional porous carbon networks,which give rise to a large surface area.Moreover,N and O functional groups are introduced in the as-prepared samples,which could generate the extra pseudocapacitance.Benefitting from the interconnected hierarchical and open structure,PCM exhibits outstanding capacitive performance,for example,superior specific capacitance and rate capability(397 and 288 F g^(−1) at 0.5 and 20A g^(−1),respectively),as well as long cycling stability(about 95%capacitance retention after 10,000 cycles).These encouraging results may pave an efficient way to fabricate advanced supercapacitors in the future.

关键词： DTPA glucose hierarchically porous carbon rambutan-like microspheres supercapacitors

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Origin of Oils in“Subtle pools”in the Dongying Depression,Bohai Bay Basin, China

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Acta Geologica Sinica(English Edition) 2008年第1期82卷 184-196页

作者： LI Sumei JIANG Zhengxue LIU Keyu qiu Guiqiang GAO yongjin State key laboratory of petroleum resource andprospecting Beijing 102249 China Basin ＆ Reservoir Research Center University of Petroleum Beijing 102249 China CSIRO Petroleum P.O. Box 1130 Bentley WA 6102 Australia Shengli Oilfield Company Limited SINOPEC Dongying 257015 China

Subtle traps or oil pools have become an important exploration play in the Dongying Depression, Bohai Bay Basin, east China. Despite recent successes in exploration, the formation mechanisms of subtle traps are still not well understood. The majority of subtle oil pools in the Dongying Depression are developed in the middle interval of the Es3 Member of the Paleogene Shahejie Formation with the subtle traps being primarily of lenticular basin-floor turbidite sands encompassed in mudstones. Oil in the subtle traps was previously thought to have migrated directly from the surrounding source rocks of the same formation （Es3）. Detailed geochemical investigation of 41 oils and 41 rock samples from the depression now indicates that the oils from the subtle traps cannot be correlated well with the surrounding Es3 source rocks, which are characterized by high Pr/ Ph （〉1）, low Gammacerane/C30hopane, representing a freshwater lacustrine setting. In contrast the oils features low Pr/Ph （〈1） and relatively high Gammacerane content, showing a genetic affinity with the underlying Es4 source rocks, which also have the same qualities, indicating a brackish lacustrine setting. Oils in the Es3 subtle traps are probably derived from mixed sources with the contribution from the upper Es4 source rocks predominating. Therefore unconventional oil migration and accumulation mechanisms need to be invoked to explain the pooling of oils from the ES4 source rocks, which probably came through a thick low interval of the Es3 source rocks with no apparent structural or stratigraphic pathways. We suggest that the subtle oil migration pathway probably plays an important role here. This finding may have significant implications for future exploration and the remaining resource evaluation in the Dongying Depression.

关键词： lenticular oil pools biomarkers oil-source rock correlation hydrocarbon migration and accumulation subtle oil migration pathway

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Formation and Accumulation of Hydrocarbons in the Central Uplift,Dongying Depression

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Petroleum Science 2006年第3期3卷 12-22页

作者： Li Sumei qiu Guiqiang Gao yongjin Jiang Zhenxue Key Laboratory for Hydrocarbon Accumulation Ministry of Education China University of Petroleum Beijing 102249 China Basin and Reservoir Research Center China University of Petroleum Beijing 102249 China Shengli Oilfield Company SINOPEC Dongying Shandong 257015 China

A large number of crude oil and rock samples from various oil pools of the Central Uplift in Dongying Depression were investigated to reveal the origin and accumulation of hydrocarbons. The results showed that the composition and areal distribution of hydrocarbons vary with the location of the oil pools. An increasing trend of gammacerane/C30-hopane and steranes/hopanes but a decreasing trend of prystane/phytane （Pr/Ph） and 18（H）-/17（H）- trisnorhopane （Ts/Tm） ratios were observed from southwest to northeast. This indicates a variation of source rocks and hydrocarbon properties. An increasing trend of water salinity with much more input of algae-rich microorganisms in the deposition environment of the source rock was observed from southwest to northeast. However, the thermal maturity of the source rocks showed a decreasing trend in the same direction. Oil-to-oil and oil-to-source rock correlations showed that most oils were sourced from Es3 and Es4 members with a burial depth of more than 3,000-3,150 m and 2,700 m respectively. The oils in the Shinan and Ying 11 sand bodies, which were generally mixed with the Es4 sourced oils, came mostly from Es3 mudstones. It is quite significant that the Es4 derived oils migrated vertically for hundreds of meters and accumulated in an overlying lithologic pool of the Es3^m, i.e., Ying 11 synclinal lithologic pool, which suggests that the mechanisms of migration and accumulation for subtle oil pools in the Dongying Depression are more complex than that of the previously expected.

关键词： Dongying Depression Central Uplift source rock oil-gas genesis subtle oil pool

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Superior performance for lithium storage from an integrated composite anode consisting of SiO-based active material and current collector

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Frontiers of Materials Science 2020年第3期14卷 243-254页

作者： Junqiang Hua Hailiang Chu Ying Zhu Tingting Fang Shujun qiu yongjin Zou Cuili Xiang Kexiang Zhang Bin Li Huanzhi Zhang Fen Xu Lixian Sun Guangxi Key Laboratory of Information Materials Guangxi Collaborative Innovation Centre of Structure and Property for New Energy Materialsand School of Materials Science and EngineeringGuilin University of Electronic TechnologyGuilin541004China

Silicon-based material is considered to be one of the most promising anodes for the next-generation lithium-ion batteries(LIBs)due to its rich sources,nontoxicity,low cost and high theoretical specific capacity.However,it cannot maintain a stable electrode structure during repeated charge/discharge cycles,and therefore long cycling life is difficult to be achieved.To address this problem,herein a simple and efficient method is developed for the fabrication of an integrated composite anode consisting of SiO-based active material and current collector,which exhibits a core-shell structure with nitrogen-doped carbon coating on SiO/P micro-particles.Without binder and conductive agent,the volume expansion of SiO active material in the integrated composite anode is suppressed to prevent its pulverization.At a current density of 500 mA·g−1,this integrated composite anode exhibits a reversible specific capacity of 458 mA·h·g−1 after 200 cycles.Furthermore,superior rate performance and cycling stability are also achieved.This work illustrates a potential method for the fabrication of integrated composite anodes with superior electrochemical properties for high-performance LIBs.

关键词： lithium-ion battery silicon monoxide red phosphorus rate performance integrated composite anode

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