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Surface Passivation and Energetic Modification Suppress Nonradiative Recombination in Perovskite Solar Cells

Nano-Micro Letters 2022年第7期14卷 32-42页

作者： Wei Dong Wencheng Qiao Shaobing Xiong Jianming Yang Xuelu Wang Liming Ding Yefeng Yao qinye bao Shanghai Key Laboratory of Magnetic Resonance East China Normal UniversityShanghai 200241People’s Republic of China School of Physics and Electronic Science East China Normal UniversityShanghai 200241People’s Republic of China Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190People’s Republic of China Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006ShanxiPeople’s Republic of China

Surface passivation via post-treatment is an important strategy for improving power conversion efficiency and operational stability of perovskite solar cells.However,so far the interaction mechanisms between passivating additive and perovskite are not well understood.Here,we report the atomic-scale interaction of surface passivating additive 2,2-difluoroethylammonium bromine(2FEABr)on the MAPbI_(3).It is found that the bulky 2FEA+cations tend to distribute at film surface,while the Br−anions diffuse from surface into bulk.A combination of 19F,207Pb,and 2H solid-state NMR further reveal the Br−anions’partial substitution for the I−sites,the restricted motion of partial MA+cations,and the firmed perovskite lattices,which would improve charge transport and stability of the perovskite films.Optical spectroscopy and ultraviolet photoelectron spectroscopy demonstrate that the 2FEABr induced surface passivation and energetic modification suppress the nonradiative recombination loss.These findings enable the efficiency of the p-i-n structured PSC significantly increasing from 19.44 to 21.06%,accompanied by excellent stability.Our work further establishes more knowledge link between passivating additive and PSC performance.

关键词： Passivation Solid-state NMR Charge transport Perovskite solar cell

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Organic Semiconductor Interfaces and Their Effects in Organic Solar Cells

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Chinese Journal of Chemistry 2023年第24期41卷 3792-3805页

作者： Chuanfei Wang Weidong Li Qi Zeng Xianjie Liu Mats Fahlman qinye bao School of Materials Science and Engineering Ocean University of ChinaQingdaoShandong266100 China School of Materials Science and Engineering Shanghai University of Engineering ScienceShanghai201620 China Laboratory of Organic Electronics ITNLinköping UniversityNorrköping60174 Sweden School of Physics and Electronic Science East China Normal UniversityShanghai200241 China Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and Perception Institute of OptoelectronicsFudan UniversityShanghai200433 China

Energy levels and energy level alignment at interfaces play a decisive role in designing efficient and stable organic solar cells(OSCs).In this review two usually used technologies in organic photovoltaic communities for measuring energy levels of organic semiconductors,photoelectron spectroscopy and electrochemical methods,are introduced,and the relationships between the values obtained from the corresponding techniques are compared.The energy level and energy level alignment across the interfaces involved in solution processed organic photovoltaics are described,and the corresponding integer charge transfer model for predicting and explaining energy level alignment is presented.The effects of the interface properties in designing efficient binary and ternary OSCs were discussed.The effects of environmental factors mainly including water vapor,oxygen gas and thermal annealing on energy levels and energy level alignment involved in photoactive layers,and the subsequent effects on the corresponding OSC properties are given.

关键词： Organic solar cells Interfaces Donor-acceptor systems Electron transfer Electronic Structures Efficiency

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4‑Terminal Inorganic Perovskite/Organic Tandem Solar Cells Offer 22%Efficiency

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Nano-Micro Letters 2023年第2期15卷 172-181页

作者： Ling Liu Hanrui Xiao Ke Jin Zuo Xiao Xiaoyan Du Keyou Yan Feng Hao qinye bao Chenyi Yi Fangyang Liu Wentao Wang Chuantian Zuo Liming Ding Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190People’s Republic of China School of Metallurgy and Environment Central South UniversityChangsha 410083People’s Republic of China School of Physics State Key Laboratory of Crystal MaterialsShandong UniversityJinan 250100People’s Republic of China School of Environment and Energy South China University of TechnologyGuangzhou 510000People’s Republic of China School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 610054People’s Republic of China School of Physics and Electronic Science East China Normal UniversityShanghai 200241People’s Republic of China State Key Laboratory of Power System Department of Electrical EngineeringTsinghua UniversityBeijing 100084People’s Republic of China School of Materials Science and Engineering Zhejiang Sci-Tech UniversityHangzhou 310018People’s Republic of China Key Laboratory of Semiconductor Materials Science Beijing Key Laboratory of Low Dimensional Semiconductor Materials and DevicesInstitute of SemiconductorsChinese Academy of SciencesBeijing 100083People’s Republic of China

After fast developing of single-junction perovskite solar cells and organic solar cells in the past 10 years,it is becoming harder and harder to improve their power conversion efficiencies.Tandem solar cells are receiving more and more attention because they have much higher theoretical efficiency than single-junction solar cells.Good device performance has been achieved for perovskite/silicon and perovskite/perovskite tandem solar cells,including 2-terminal and 4-terminal structures.However,very few studies have been done about 4-terminal inorganic perovskite/organic tandem solar cells.In this work,semi-transparent inorganic perovskite solar cells and organic solar cells are used to fabricate 4-terminal inorganic perovskite/organic tandem solar cells,achieving a power conversion efficiency of 21.25%for the tandem cells with spin-coated perovskite layer.By using drop-coating instead of spin-coating to make the inorganic perovskite films,4-terminal tandem cells with an efficiency of 22.34%are made.The efficiency is higher than the reported 2-terminal and 4-terminal inorganic perovskite/organic tandem solar cells.In addition,equivalent 2-terminal tandem solar cells were fabricated by connecting the sub-cells in series.The stability of organic solar cells under continuous illumination is improved by using semi-transparent perovskite solar cells as filter.

关键词： 4-Terminal tandem solar cells Inorganic perovskite solar cells Organic solar cells Semitransparent Drop-coating

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Multifunctional anchoring of O-ligands for high-performance and stable inverted perovskite solar cells

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InfoMat 2023年第2期5卷 34-44页

作者： Lisha Xie Xuhong Zhao Jianwei Wang Jun Li Chang Liu Shurong Wang qinye bao Mengjin Yang Xiaobin Niu Feng Hao Ziyi Ge Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingboPeople's Republic of China School of Materials and Energy University of Electronic Science and Technology of ChinaChengduPeople's Republic of China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijingPeople's Republic of China School of Physics and Electronic Science East China Normal UniversityShanghaiPeople's Republic of China

Functional additives have recently been regarded as emerging candidates to improve the performance and stability of perovskite solar cells(PSCs).Herein,nicotinamide(N),2-chloronicotinamide(2Cl),and 6-chloronicotinamide(6Cl)were employed as O-ligands to facilitate the deposition of MAPbI_(3)(MA=methylammonium)and MA-free FA_(0.88)Cs_(0.12)PbI_(2.64)Br_(0.36)(FA=formamidinium)perovskite films by multifunctional anchoring.By density functional theory(DFT)calculations and ultraviolet photoelectron spectroscopy(UPS)measurements,it is identified that the highest occupied molecular orbital(HOMO)level for additive modified MAPbI_(3)perovskite could reduce the voltage deficit for hole extraction.Moreover,due to the most favorable charge distribution and significant improvements in charge mobility and defect passivation,the power conversion efficiency(PCE)of 2Cl-MAPbI_(3)PSCs was significantly improved from 19.32%to 21.12%.More importantly,the two-dimensional grazing-incidence wide-angle X-ray scattering(GIWAXS)analysis showed that PbI_(2) defects were effectively suppressed and femtosecond transient absorption(TA)spectroscopy demonstrated that the trap-assisted recombination at grain boundaries was effectively inhibited in the 2Cl-MA-free film.As a result,the thermally stable 2Cl-MA-free PSCs achieved a remarkable PCE of 23.13%with an open-circuit voltage(V_(oc))of 1.164 V and an ultrahigh fill factor(FF)of 85.7%.Our work offers a practical strategy for further commercializing stable and efficient PSCs.

关键词： additive engineering carrier non-radiative recombination defects passivation formamidinecesium inverted perovskite solar cells

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Perovskite films with gradient bandgap for self-powered multiband photodetectors and spectrometers

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Nano Research 2023年第7期16卷 10256-10262页

作者： Chuantian Zuo Lixiu Zhang Xiyan Pan He Tian Keyou Yan Yuanhang Cheng Zhiwen Jin Chenyi Yi Xiaoliang Zhang Wu-Qiang Wu qinye bao Liyuan Han Liming Ding Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190China School of Physics and Electronic Science East China Normal UniversityShanghai 200241China School of Integrated Circuits Tsinghua UniversityBeijing 100084China School of Environment and Energy South China University of TechnologyGuangzhou 510000China School of New Energy Nanjing University of Science and TechnologyJiangyin 214443China School of Physical Science and Technology Lanzhou UniversityLanzhou 730000China State Key Laboratory of Power System Department of Electrical EngineeringTsinghua UniversityBeijing 100084China School of Materials Science and Engineering Beihang UniversityBeijing 100191China School of Chemistry Sun Yat-sen UniversityGuangzhou 510006China State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong UniversityShanghai 200240China Key Laboratory of Semiconductor Materials Science Beijing Key Laboratory of Low Dimensional Semiconductor Materials and DevicesInstitute of SemiconductorsChinese Academy of SciencesBeijing 100083China

Bandgap-graded materials present varying spectral responses at different positions,making them possible to be used as an alternative to photoactive materials array in multi-spectral responsive devices,thus miniaturizing the apparatus.However,the preparation of bandgap-graded materials usually requires complicated deposition process.Here we report a facile lowtemperature solution process to make films with lateral bandgap gradients,which form spontaneously via self-spreading and interdiffusion of solutions.We show lead halide perovskite films with MAPbCl_(3)-MAPbBr_(3)and MAPbBr_(3)-MAPbI_(3)gradients,which exhibit light absorption onsets ranging from 410 to 781 nm.The bandgap-graded films were used to make self-powered multiband photodetectors,which show different spectral responses at different positions without applying bias voltage.Furthermore,self-powered spectrometers were made by using the multiband photodetectors.

关键词： self-spreading interdiffusion bandgap-graded perovskite multiband photodetectors self-powered spectrometers

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Defect passivation by nontoxic biomaterial yields 21% efficiency perovskite solar cells

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Journal of Energy Chemistry 2021年第4期30卷 265-271页

作者： Shaobing Xiong Tianyu Hao Yuyun Sun Jianming Yang Ruru Ma Jiulong Wang Shijing Gong Xianjie Liu Liming Ding Mats Fahlman qinye bao Key Laboratory of Polar Materials and Devices Department of Electronic ScienceSchool of Physics and Electronic ScienceEast China Normal UniversityShanghai 200241China School of Chemistry and Chemical Engineering Shanghai Jiao Tong UniversityShanghai 200025China Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006ShanxiChina Laboratory of Organic Electronics ITNLinköping UniversitySE-60174 NorrköpingSweden Wallenberg Wood Science Center Linköping UniversitySE-60174 NorrköpingSweden Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190China

Defect passivation is one of the most important strategies to boost both the efficiency and stability of perovskite solar cells(PSCs).Here,nontoxic and sustainable forest-based biomaterial,betulin,is first introduced into perovskites.The experiments and calculations reveal that betulin can effectively passivate the uncoordinated lead ions in perovskites via sharing the lone pair electrons of hydroxyl group,promoting charge transport.As a result,the power conversion efficiencies of the p-i-n planar PSCs remarkably increase from 19.14%to 21.15%,with the improvement of other parameters.The hydrogen bonds of betulin lock methylamine and halogen ions along the grain boundaries and on the film surface and thus suppress ion migration,further stabilizing perovskite crystal structures.These positive effects enable the PSCs to maintain 90%of the initial efficiency after 30 days in ambient air with 60%±5%relative humidity,75%after 300 h aging at 85℃,and 55%after 250 h light soaking,respectively.This work opens a new pathway for using nontoxic and low-cost biomaterials from forest to make highly efficient and stable PSCs.

关键词： Perovskite solar cells Defect passivation Nontoxic biomaterial Efficiency

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Recent progress in organic solar cells(PartⅠmaterial science)

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Science China Chemistry 2022年第2期65卷 224-268页

作者： Yahui Liu Bowen Liu Chang-Qi Ma Fei Huang Guitao Feng Hongzheng Chen Jianhui Hou Lingpeng Yan Qingya Wei Qun Luo qinye bao Wei Ma Wei Liu Weiwei Li Xiangjian Wan Xiaotian Hu Yanchun Han Yaowen Li Yinhua Zhou Yingping Zou Yiwang Chen Yongfang Li Yongsheng Chen Zheng Tang Zhicheng Hu Zhi-Guo Zhang Zhishan Bo College of Textiles&Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao 266071China Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of SciencesSuzhou 215123China Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510640China Beijing Advanced Innovation Center for Soft Matter Science and Engineering&State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical TechnologyBeijing 100029China State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China Beijing National Laboratory for Molecular Sciences Institute of ChemistryChinese Academy of SciencesBeijing 100190China State Key Laboratory of Powder Metallurgy College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of Physics and Electronic Science East China Normal UniversityShanghai 200241China State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049China State Key Laboratory and Institute of Elemento-Organic Chemistry Key Laboratory of Functional Polymer MaterialsCollege of ChemistryNankai UniversityTianjin 300071China College of Chemistry/Institute of Polymers and Energy Chemistry(IPEC) Nanchang UniversityNanchang 330031China State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China Laboratory of Advanced Optoelectronic Materials College of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China Center for Advanced Low-Dimension Materials State Key Laboratory for Modification of Chemical Fibers and Polymer Material

During past several years,the photovoltaic performances of organic solar cells(OSCs)have achieved rapid progress with power conversion efficiencies(PCEs)over 18%,demonstrating a great practical application prospect.The development of material science including conjugated polymer donors,oligomer-like organic molecule donors,fused and nonfused ring acceptors,polymer acceptors,single-component organic solar cells and water/alcohol soluble interface materials are the key research topics in OSC field.Herein,the recent progress of these aspects is systematically summarized.Meanwhile,the current problems and future development are also discussed.

关键词： organic solar cells power conversion efficiency photovoltaic materials polymer solar cells

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A chlorinated copolymer donor demonstrates a 18.13% power conversion efficiency

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Journal of Semiconductors 2021年第1期42卷 11-15,16-23页

作者： Jianqiang Qin Lixiu Zhang Chuantian Zuo Zuo Xiao Yongbo Yuan Shangfeng Yang Feng Hao Ming Cheng Kuan Sun qinye bao Zhengyang Bin Zhiwen Jin and Liming Ding Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190China Key Laboratory of Low-grade Energy Utilization Technologies and Systems(MOE) School of Energy and Power EngineeringChongqing UniversityChongqing 400044China Hunan Key Laboratory of Super Microstructure and Ultrafast Process School of Physics and ElectronicsCentral South UniversityChangsha 410083China Department of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731China Institute for Energy Research Jiangsu UniversityZhenjiang 212013China Key Laboratory of Polar Materials and Devices(MoE) School of Physics and Electronic ScienceEast China Normal UniversityShanghai 200241China College of Chemistry Sichuan UniversityChengdu 610064China School of Physical Science and Technology Lanzhou UniversityLanzhou 730000China

The rapid development of low-bandgap(LBG)nonfullerene acceptors and wide-bandgap(WBG)copolymer donors in recent years has boosted the power conversion efficiency(PCE)of organic solar cells(OSCs)to the 18%level[1−21].The commercialization of OSCs is highly expected.However,critical issues like the cost and the stability also determine whether OSCs can enter the market or not[22].

关键词： copolymer donor stability

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Hollow Bio-derived Polymer Nanospheres with Ordered Mesopores for Sodium-Ion Battery

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Nano-Micro Letters 2020年第3期12卷 1-11页

作者： Yan Ai Yuxiu You Facai Wei Xiaolin Jiang Zhuolei Han Jing Cui Hao Luo Yucen Li Zhixin Xu Shunqi Xu Jun Yang qinye bao Chengbin Jing Jianwei Fu Jiangong Cheng Shaohua Liu State Key Laboratory of Precision Spectroscopy and Department of Materials School of Physics and Electronic ScienceEast China Normal UniversityShanghai 200241People’s Republic of China Department of Physics and Astronomy Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China School of Chemistry and Chemical Engineering Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Center for Advancing Electronics Dresden(cfaed)and Department of Chemistry and Food Chemistry Technische Universität Dresden01062 DresdenGermany School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450052People’s Republic of China State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghai 200050People’s Republic of China

Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in materials with limited diversity and complexity in architecture as well as microstructure.Here,we develop a novel coordination polymerization-driven hierarchical assembly of micelle strategy,using phytic acid-based natural compounds as an example,for the spatially controlled fabrication of metal coordination bio-derived polymers.The resultant ferric phytate polymer nanospheres feature hollow architecture,ordered meso-channels of^12 nm,high surface area of 401 m2 g−1,and large pore volume of 0.53 cm3 g−1.As an advanced anode material,this bio-derivative polymer delivers a remarkable reversible capacity of 540 mAh g−1 at 50 mA g−1,good rate capability,and cycling stability for sodium-ion batteries.This study holds great potential of the design of new complex bio-materials with supramolecular chemistry.

关键词： Self-assembly Biomimetic synthesis Mesoporous polymer Ferric phytate Sodium-ion battery

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Low-Temperature Aging Provides 22% E cient Bromine-Free and Passivation Layer-Free Planar Perovskite Solar Cells

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Nano-Micro Letters 2020年第7期12卷 29-42页

作者： Xin Wang Luyao Wang Tong Shan Shibing Leng Hongliang Zhong qinye bao Zheng-Hong Lu Lin-Long Deng Chun-Chao Chen School of Material Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China School of Chemistry and Chemical Engineering Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Key Laboratory of Solar Materials and Devices Department of Electronic ScienceSchool of Physics and Electronic ScienceEast China Normal UniversityShanghai 200240People’s Republic of China Department of Materials Science and Engineering University of Toronto184 College StreetTorontoON M5S 3E4Canada Pen-Tung Sah Institute of Micro-Nano Science and Technology Xiamen UniversityXiamen 361005People’s Republic of China

Previous reports of formamidinium/methylamine(FAMA)-mixed halide perovskite solar cells have focused mainly on controlling the morphology of the perovskite film and its interface—for example,through the inclusion of bromine and surface passivation.In this paper,we describe a new processing pathway for the growth of a high-quality bromine-free FAMAPbI3 halide perovskites via the control of intermediate phase.Through low-temperature aging growth(LTAG)of a freshly deposited perovskite film,α-phase perovskites can be seeded in the intermediate phase and,at the same time,prevent beta-phase perovskite to nucleate.After postannealing,large grain-size perovskites with significantly reduced PbI2 presence on the surface can be obtained,thereby eliminating the need of additional surface passivation step.Our pristine LTAG-treated solar cells could provide PCEs of greater than 22%without elaborate use of bromine or an additional passivation layer.More importantly,when using this LTAG process,the growth of the pure alpha-phase FAMAPbI3 was highly reproducible.

关键词： Aging growth Bromine-free Passivation layer Lead iodide Perovskite solar cells

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