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Impacts of proppant distribution on development of tight oil reservoirs with threshold pressure gradient

Petroleum Science 2024年第1期21卷 445-457页

作者： Ming Yue Wei-Yao Zhu Fei-Fei Gou Tian-Ru Song Yu-Chun You qi-tao zhang State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing102206China School of Civil and Resource Engineering University of Science and Technology BeijingBeijing100083China

Field evidence indicates that proppant distribution and threshold pressure gradient have great impacts on well *** at the development of unconventional oil reservoirs in Triassic Chang-7 Unit,Ordos Basin of China,we presented an integrated workflow to investigate how(1)proppant placement in induced fracture and(2)non-linear flow in reservoir matrix would affect well productivity and fluid flow in the *** with our research before(Yue et al.,2020),here we extended this study into the development of multi-stage fractured horizontal wells(MFHWs)with large-scale complicated fracture *** integrated workflow is based on the finite element method and consists of simulation models for proppant-laden fluid flow,fracture flow,and non-linear seepage flow,*** results indicate that the distribution of proppant inside the induced cracks significantly affects the productivity of the *** we assign an idealized proppant distribution instead of the real distribution,there will be an overestimation of 44.98%in daily oil rate and 30.63%in cumulative oil production after continuous development of 1000 ***,threshold pressure gradient(TPG)also significantly affects the well performance in tight oil *** we simply apply linear Darcy’s law to the reservoir matrix,the overall cumulative oil production can be overrated by 77%after 1000 days of *** general,this research provides new insights into the development of tight oil reservoirs with TPG and meanwhile reveals the significance of proppant distribution and non-linear fluid flow in the production scenario design.

关键词： Proppant distribution Tight oil reservoir Multi-stage fractured horizontal well Threshold pressure gradient Moving boundary

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Improved photocatalytic performance of acetaldehyde degradation via crystal plane regulation on truncated octahedral CeO_(2)

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Rare Metals 2024年第5期43卷 2026-2038页

作者： Bin Xu Lu Jia Hui Yang Yue Wang Si-Yu Fan Sai-Sai Yuan qi-taozhang Ming zhang Teruhisa Ohno School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhou 225002China College of Environmental Science and Engineering Yangzhou UniversityYangzhou225127China Department of Applied Chemistry Faculty of EngineeringKyushu Institute of TechnologyKitakyushu804-8550Japan School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212000China National&Local Joint Engineering Research Center for Mineral Salt Deep Utilization Huaiyin Institute of TechnologyHuaian 223003China School of Materials Science and Engineering Henan University of Science and TechnologyLuoyang 471000China International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060China

In this study,the truncated octahedral CeO_(2)(CeO_(2)-to)with special morphology was prepared by the solvothermal method with oleic acid(OA)and oleamine(OM)as the morphology-directing ***-resolution transmission electron microscopy(HRTEM)results show that CeO_(2)-to exposes composite{100}and{111}facets,while CeO_(2)cubic(CeO_(2)-c)and CeO_(2)octahedral(CeO_(2)-o)only expose single crystal facets of{100}plane and{111}plane,***,this CeO_(2)-to photocatalyst exhibits remarkable photooxidation performance of gaseous acetaldehyde(CH_(3)CHO)degradation,in which CO_(2)generation value reaches 1.78 and 7.97-times greater than that of CeO_(2)-c and CeO_(2)-o,*** addition,the active species trapping experiment signifies that superoxide(·O_(2)^(-))and holes(h^(+))are the main reactive substances during the CH_(3)CHO degradation process,and the electron paramagnetic resonance(EPR)spectra indicates that the former is the major ***,the electron transfer mechanism between CeO_(2)-to{100}and{111}facets and the surface oxygen adsorption ability are revealed via density functional theory(DFT)*** is also confirmed that{100}facets are more conducive to the absorption of acetaldehyde than{111}***,a reasonable mechanism for improved photocatalytic CH_(3)CHO degradation on CeO_(2)-to is proposed based on relevant experiments and DFT *** study demonstrates that the systematic development of surface homojunction structured photocatalysts can efficiently increase the degradation activity for volatile organic compounds(VOCs).It also offers additional direction for optimizing the photocatalytic activity of other ceriumbased photocatalysts.

关键词： Truncated octahedral CeO_(2)(CeO_(2)-to) Composite crystal faces Surface energy level Efficient electrontransfer

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Double network self-healing hydrogel based on hydrophobic association and ionic bond for formation plugging

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Petroleum Science 2022年第5期19卷 2150-2164页

作者： Ying-Rui Bai qi-tao zhang Jin-Sheng Sun Guan-Cheng Jiang Kai-He Lv School of Petroleum Engineering China University of Petroleum(East China)Qingdao266580ShandongChina CNPC Engineering Technology R&D Company Limited Beijing102206China College of Petroleum Engineering China University of Petroleum(Beijing)Beijing102249China

Self-healing hydrogels have attracted tremendous attention in the field of oil and gas drilling and production engineering because of their excellent self-healing performance after physical *** this study,a series of double network self-healing(DN_(SA))hydrogels based on hydrophobic association and ionic bond were prepared for plugging pores and fractures in formations in oil and gas drilling and production *** mechanical,rheological,and self-healing properties of the DN_(SA)hydrogels were *** revealed that the DN_(SA)hydrogels exhibited excellent mechanical properties with a tensile stress of 0.67 MPa and toughness of 7069 kJ/cm^(3) owing to the synergistic effect of the double *** addition,the DN_(SA)hydrogels exhibited excellent compression resistance,notch insensitivity,and self-healing *** DN_(SA)-2 hydrogel was granulated and made into gel particles with different particle sizes and used as a plugging *** self-healing mechanism of DN_(SA)-2 hydrogel particles in fractures was explored,and it’s plugging effect on fractures of different widths and porous media of different permeabilities were *** results revealed that the plugging capacity of the DN_(SA)-2 hydrogel particles for a fracture with width of 5 mm and a porous medium with a permeability of 30μm^(2) was 3.45 and 4.21 MPa,respectively,which is significantly higher than those of commonly used plugging agents in the *** DN_(SA)hydrogels with excellent mechanical and self-healing properties prepared in this study will provide a new approach for applying hydrogels in oil and gas drilling and production engineering.

关键词： Self-healing hydrogel Hydrophobic association Ionic bond Mechanical property Rheological property Formation plugging

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Cobalt(Ⅲ)hydride HAT mediated enantioselective intramolecular hydroamination access to chiral pyrrolidines

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Science China Chemistry 2024年第6期67卷 2002-2008页

作者： qi Meng tao qin Huanran Miao Ge zhang qian zhang Jilin Province Key Laboratory of Organic Functional Molecular Design&Synthesis Department of ChemistryNortheast Normal UniversityChangchun130024China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai200032China

Enantioenriched pyrrolidines and derivatives are ubiquitous substructures in compounds of importance to medicinal and biological ***,we report an efficient cobalt-catalyzed intramolecular asymmetric hydroamination reaction that produces chiral pyrrolidines with good to excellent yield and *** with previously reported radicalinvolved methodologies for enantioenriched pyrrolidines,these conditions feature two elegant versatilities,enabling(1)the use of cobalt-catalyzed hydrogen atom transfer(HAT)to generate organocobalt intermediates that bring radical reaction to organometallic chemistry,and(2)enantioselective intramolecular C-N bond forging through an S_(N)2-like displacement involving dynamic kinetic resolution(DKR).This approach provides a new alternative and efficient methodology for enantioselective radical-involved C-N bond construction that can be used in the synthesis of both chiral pyrrolidines and homologous nitrogen heterocycles.

关键词： asymmetric catalysis radical hydroamination cobalt catalysis hydrogen atom transfer

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Electrochemical filtration for drinking water purification:A review on membrane materials,mechanisms and roles

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Journal of Environmental Sciences 2024年第7期141卷 102-128页

作者： Yuying qi Donghao Li Shixuan zhang Fengxiang Li tao Hua College of Environmental Science and Engineering Nankai UniversityTianjin 300350China Key Laboratory of Pollution Process and Environmental Criteria Ministry of EducationTianjin 300350China Tianjin Engineering Center of Environmental Diagnosis and Contamination Remediation Tianjin 300350China

Electrochemical filtration can not only enrich low concentrations of pollutants but also produce reactive oxygen species to interact with toxic pollutants with the assistance of a power supply,making it an effective strategy for drinking water *** addition,the application of electrochemical filtration facilitates the reduction of pretreatment procedures and the use of chemicals,which has outstanding potential for maximizing process simplicity and reducing operating costs,enabling the production of safe drinking water in smaller *** recent years,the research on electrochemical filtration has gradually increased,but there has been a lack of attention on its application in the removal of low concentrations of pollutants from low conductivity *** this review,membrane substrates and electrocatalysts used to improve the performance of electrochemical membranes are briefly ***,the application prospects of emerging single-atom catalysts in electrochemical filtration are also ***,several electrochemical advanced oxidation processes coupled with membrane filtration are described,and the related working mechanisms and their advantages and shortcomings used in drinking water purification are ***,the roles of electrochemical filtration in drinking water purification are presented,and the main problems and future perspectives of electrochemical filtration in the removal of low concentration pollutants are discussed.

关键词： Electrochemical filtration Drinking water Conductive membrane Low concentration Electrocatalyst

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Alternative splicing and related RNA binding proteins in human health and disease

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Signal Transduction and Targeted Therapy 2024年第3期9卷 839-871页

作者： Yining tao qi zhang Haoyu Wang Xiyu Yang Haoran Mu Department of Orthopedics Shanghai General HospitalShanghai Jiao Tong University School of Medicine200000 ShanghaiChina Shanghai Bone Tumor Institution 200000 ShanghaiChina Department of Biochemistry and Molecular Cell Biology Shanghai Key Laboratory for Tumor Microenvironment and InflammationShanghai Jiao Tong University School of Medicine200000 ShanghaiChina

Alternative splicing(AS)serves as a pivotal mechanism in transcriptional regulation,engendering transcript diversity,and modifications in protein structure and *** varying tissues,developmental stages,or under specific conditions,AS gives rise to distinct splice *** implies that these isoforms possess unique temporal and spatial roles,thereby associating AS with standard biological activities and *** these,AS-related RNA-binding proteins(RBPs)play an instrumental role in regulating alternative splicing *** physiological conditions,the diversity of proteins mediated by AS influences the structure,function,interaction,and localization of proteins,thereby participating in the differentiation and development of an array of tissues and *** pathological conditions,alterations in AS are linked with various diseases,particularly *** changes can lead to modifications in gene splicing patterns,culminating in changes or loss of protein *** instance,in cancer,abnormalities in AS and RBPs may result in aberrant expression of cancer-associated genes,thereby promoting the onset and progression of *** and RBPs are also associated with numerous neurodegenerative diseases and autoimmune ***,the study of AS across different tissues holds significant *** review provides a detailed account of the recent advancements in the study of alternative splicing and AS-related RNA-binding proteins in tissue development and diseases,which aids in deepening the understanding of gene expression complexity and offers new insights and methodologies for precision medicine.

关键词： organs alterations thereby

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A Two-Layer Encoding Learning Swarm Optimizer Based on Frequent Itemsets for Sparse Large-Scale Multi-Objective Optimization

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IEEE/CAA Journal of Automatica Sinica 2024年第6期11卷 1342-1357页

作者： Sheng qi Rui Wang tao zhang Xu Yang Ruiqing Sun Ling Wang College of Systems Engineering National University of Defense TechnologyChangsha 410073China Xiangjiang Laboratory Changsha 410205China College of Computer National University of Defense TechnologyChangsha 410073China Department of Automation Tsinghua UniversityBeijing 100084China IEEE

Traditional large-scale multi-objective optimization algorithms(LSMOEAs)encounter difficulties when dealing with sparse large-scale multi-objective optimization problems(SLM-OPs)where most decision variables are *** a result,many algorithms use a two-layer encoding approach to optimize binary variable Mask and real variable Dec ***,existing optimizers often focus on locating non-zero variable posi-tions to optimize the binary variables ***,approxi-mating the sparse distribution of real Pareto optimal solutions does not necessarily mean that the objective function is *** data mining,it is common to mine frequent itemsets appear-ing together in a dataset to reveal the correlation between *** by this,we propose a novel two-layer encoding learning swarm optimizer based on frequent itemsets(TELSO)to address these *** mined the frequent terms of multiple particles with better target values to find mask combinations that can obtain better objective values for fast ***-mental results on five real-world problems and eight benchmark sets demonstrate that TELSO outperforms existing state-of-the-art sparse large-scale multi-objective evolutionary algorithms(SLMOEAs)in terms of performance and convergence speed.

关键词： Evolutionary algorithms learning swarm optimiza-tion sparse large-scale optimization sparse large-scale multi-objec-tive problems two-layer encoding.

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Enhancing Evolutionary Algorithms With Pattern Mining for Sparse Large-Scale Multi-Objective Optimization Problems

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IEEE/CAA Journal of Automatica Sinica 2024年第8期11卷 1786-1801页

作者： Sheng qi Rui Wang tao zhang Weixiong Huang Fan Yu Ling Wang the College of Systems Engineering National University of Defense Technology IEEE the Xiangjiang Laboratory the College of Transportation and Engineering Central South University the Department of Automation Tsinghua University

Sparse large-scale multi-objective optimization problems(SLMOPs) are common in science and engineering. However, the large-scale problem represents the high dimensionality of the decision space, requiring algorithms to traverse vast expanse with limited computational resources. Furthermore, in the context of sparse, most variables in Pareto optimal solutions are zero, making it difficult for algorithms to identify non-zero variables efficiently. This paper is dedicated to addressing the challenges posed by SLMOPs. To start, we introduce innovative objective functions customized to mine maximum and minimum candidate sets. This substantial enhancement dramatically improves the efficacy of frequent pattern mining. In this way,selecting candidate sets is no longer based on the quantity of nonzero variables they contain but on a higher proportion of nonzero variables within specific dimensions. Additionally, we unveil a novel approach to association rule mining, which delves into the intricate relationships between non-zero variables. This novel methodology aids in identifying sparse distributions that can potentially expedite reductions in the objective function value. We extensively tested our algorithm across eight benchmark problems and four real-world SLMOPs. The results demonstrate that our approach achieves competitive solutions across various challenges.

关键词： Evolutionary computation Benchmark testing Pareto optimization Linear programming Association rule learning Object recognition Indexes

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Characterization of a smog chamber for studying formation of gas-phase products and secondary organic aerosol

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Journal of Environmental Sciences 2024年第2期136卷 570-582页

作者： qi Yuan Zhuozhi zhang Meng Wang Kin Fai Ho tao Wang Shuncheng Lee Department of Civil and Environmental Engineering The Hong Kong Polytechnic UniversityKowloonHong KongChina School of Public Health and Primary Care The Chinese University of Hong KongShatinHong KongChina

Smog chambers provide a potent approach to explore the secondary organic aerosol formation under varied *** study describes the construction and characterization of a new smog chamber facility for studying the formation mechanisms of gas-phase products and secondary organic aerosol from the photooxidation of volatile organic *** chamber is a 5.4 m^(3) Fluorinated Ethylene Propylene(FEP)Teflon reactor with the potential to perform photooxidation experiments at controlled temperature and relative *** characterizations were conducted for evaluation of stability of environmental parameters,mixing time,background contamination,light intensity,and wall losses of gases and *** photolysis rate of NO_(2)(J_(NO2))ranged from(1.02-3.32)×10^(-3)sec^(-1),comparable to the average J_(NO2)in ambient *** wall loss rates for NO,NO_(2),and O_(3)were 0.47×10^(-4),0.37×10^(-4),and 1.17×10^(-4)min^(-1),while wall loss of toluene was obsoletely found in a 6 hr *** particle number wall loss rates are(0.01-2.46)×10^(-3)min^(-1)for 40-350 nm with an average lifetime of more than one day.A series of toluene photooxidation experiments were carried out in absence of NO_xunder dry *** results of the simulation experiments demonstrated that the chamber is well designed to simulate photolysis progress in the atmosphere.

关键词： Smog chamber Gas-phase oxidation Chamber characterization Chemical mechanism

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Spatially charge-separated 2D homojunction for photocatalytic hydrogen production

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Rare Metals 2023年第12期42卷 3952-3959页

作者： Xi-Juan Wang Sai-Sai Yuan Lei Yang Ying Dong Yi-Ming Chen Wu-Xiang zhang Chuan-Xiang Chen qi-tao zhang Teruhisa Ohno School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212100China International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of EducationInstitute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060China Department of Applied Chemistry Faculty of EngineeringKyushu Institute of TechnologyKitakyushu 804-8550Japan

Suppression of photogenerated charge recombination is crucial for efficient photocatalytic hydrogen *** have garnered more attention than heterojunctions due to their superior crystal binding and band structure ***,most homojunctions suffer from redox interference caused by continuous oxidizing and reducing phases that impede the ability to improve photocatalytic ***,the preparation of homojunction photocatalysts with completely spatial separation of both in charge and redox phases remains ***,the preparation of a two-dimensional(2D)homojunction CeO_(2) with a back-to-back geometry and fully separated oxidizing and reducing phases is *** prepared CeO_(2) is composed of nanosheets with twocontrasting smooth and rough *** and theoretical results indicate that the rough surface contains more highly reducing CeO_(2){220}and strongly visiblelight-absorbing CeO_(2){200}facets than the smooth *** 2D homojunction CeO_(2) produces three-times more hydrogen than normal CeO_(2) nanosheets,and even more than that of CeO_(2) nanosheets loaded with gold *** work presents a new homojunction photocatalyst model with completely spatial separation of both in charge and redox phases that is expected to inspire further research into homojunction photocatalysts.

关键词： hydrogen charge separated

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