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Failure mechanism and control countermeasures of surrounding rock at deep large section chamber intersection in the Wanfu Coal mine

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Journal of Mountain Science 2023年第7期20卷 2058-2075页

作者： SUN Xiao-ming qi zhen-min ZHANG Yong MIAO Cheng-yu ZHAO Cheng-wei HE Man-chao State Key Laboratory for GeoMechanics and Deep Underground Engineering China University of Mining&Technology BeijingBeijing 100083China School of Mechanics and Civil Engineering China University of Mining&Technology-BeijingBeijing 100083China Institute of Rock and Soil Mechanics Chinese Academy of SciencesWuhan 430060China

In order to solve the problem of large deformation at the intersection of deep large section soft rock roadway,this paper takes the intersection of kilometer-deep roadway in the Wanfu Coal mine as an engineering example and applies Negative Poisson’s Ratio(NPR)steel anchor cable in roadway support for the first *** combining numerical simulation indoor test,theoretical analysis and field test,the deformation mechanism of surrounding rock at the intersection of deep-buried roadway was analyzed,and the control strategy with micro NPR steel anchor cable as the core was put *** numerical simulation,the numerical analysis model of roadway intersection with different intersection angles and excavation sequence was constructed,and the impact of two key variables of rake angle and excavation sequence on the stability of surrounding rock at roadway intersection was *** optimal dip angle is 90°and the optimal excavation sequence was determined as pump house-pump house *** mechanical properties of the micro-NPR steel anchor cable were studied through the static tensile test in the *** results showed that the micro-NPR steel anchor cable showed high constant resistance,uniform tensile,no yield platform,and no obvious necking phenomenon during *** theoretical derivation,it was calculated that the vertical stress of roadway intersection is 45 MPa,and the bearing capacity of superposed arch composed of micro NPR steel anchor cable is 1257 kN,which is enough to guarantee the overall stability of *** application test and monitoring were carried out on site,and it was verified that the combined support strategy of short and long micro NPR steel anchor cable has a good control effect on large deformation of surrounding rock at intersection,which provides a new support material and support means for the safety and stabilization control of surrounding rock at intersection.

关键词： Mountain tunnel Composite lining Surrounding rock grade Force variation Primary support Secondary lining

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强采动巷道断顶卸压稳定性控制机理及应用

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科学技术与工程 2024年第17期24卷 7090-7098页

作者：刘光饶齐振敏杨位良刘建荣翟军存何晓青王慧孙延辉内蒙古上海庙矿业有限责任公司新上海一号煤矿鄂尔多斯016299 中国矿业大学(北京)力学与建筑工程学院北京100083 中国矿业大学(北京)深部岩土力学与地下工程国家重点实验室北京100083

为解决强采动条件下巷道大变形难题,以新上海一号矿1806N工作面辅运顺槽为工程背景,采用实地勘探、理论分析、数值模拟的方法分析强采动巷道变形破坏原因及围岩大变形机理,提出相应的控制对策进行现场工业性试验。研究发现:1806N工作面... 详细信息

为解决强采动条件下巷道大变形难题,以新上海一号矿1806N工作面辅运顺槽为工程背景,采用实地勘探、理论分析、数值模拟的方法分析强采动巷道变形破坏原因及围岩大变形机理,提出相应的控制对策进行现场工业性试验。研究发现:1806N工作面辅运顺槽大变形主要影响因素为岩石强度低、节理裂隙发育、完整性差、顶板富水严重、围岩遇水泥化,强采动高集中应力。基于围岩大变形断顶控制机理,形成辅运顺槽深部爆破定向预裂断顶结合补强加固的设计方案。借助数值模拟对断顶及未断顶巷道应力变化规律进行对比分析,断顶巷道端头最大垂直应力14.6 MPa,断顶后巷道端头最大垂直应力12.5 MPa,断顶后端头处垂直应力减小14%,断顶具有一定切断应力传递及减小巷道收缩的效果。开展现场工业性试验,断顶后端头顶底板位移减小37%,两帮变形减小19%,底臌发育长度减小92%,结果表明断顶可有效减少端头巷道变形以及超前底臌发育长度和高度,可为相似工程地质条件巷道建设提供参考。

关键词：强采动断顶卸压巷道支护软岩

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Th17/Treg balance and macrophage polarization ratio in lower extremity arteriosclerosis obliterans

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Asian Pacific Journal of Tropical Biomedicine 2024年第3期14卷 127-136,I0006-I0009页

作者： zhen-zhen Li min Liu Xiong-Hui He zhen-Dong Liu Zhan-Xiang Xiao Hao qian You-Fei qi Cun-Chuan Wang Department of Metabolic and Bariatric Surgery The First Affiliated Hospital of Jinan UniversityGuangzhouGuangdong Province510632China Department of Vascular Surgery Hainan General HospitalHainan Affiliated Hospital of Hainan Medical UniversityHaikouHainan Province570311China Department of Physical Examination Hainan General HospitalHainan Affiliated Hospital of Hainan Medical UniversityHaikouHainan Province570311China Department of Gastrointestinal Surgery Hainan General HospitalHainan Affiliated Hospital of Hainan Medical UniversityHaikouHainan Province570311China

Objective:To explore the balance of peripheral blood T helper 17 cells/regulatory T cell(Th17/Treg)ratio and the polarization ratio of M1 and M2 macrophages in lower extremity arteriosclerosis obliterans(ASO).Methods:A rat model of lower extremity ASO was established,and blood samples from patients with lower extremity ASO before and after surgery were *** was used to detect interleukin 6(IL-6),IL-10,and ***-time RCR and Western blot analyses were used to detect Foxp3,IL-6,IL-10,and IL-17 ***,flow cytometry was applied to detect the Th17/Treg ratio and M1/M2 ***:Compared with the control group,the iliac artery wall of ASO rats showed significant hyperplasia,and the concentrations of cholesterol and triglyceride were significantly increased(Pminal angioplasty and arterial stenting),all these changes were significantly improved(P<0.05).Conclusions:The Th17/Treg and M1/M2 ratios were significantly increased in ASO,and surgery can effectively improve the balance of Th17/Treg,and reduce the ratio of M1/M2,and the expression of inflammatory factors.

关键词： Lower extremity arteriosclerosis Regulatory T cells Regulatory B cells Inflammatory factors M1 macrophages M2 macrophages

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A systematic COSMO-RS study on mutual solubility of ionic liquids and C6-hydrocarbons

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Green Chemical Engineering 2024年第1期5卷 97-107页

作者： Chuxin qi zhen Song Hongye Cheng Lifang Chen Zhiwen qi State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast China University of Science and Technology130 Meilong RoadShanghai200237China

When considering the usage of ionic liquids(ILs)for reactions and separations involving non-polar or weak-polar hydrocarbons,the knowledge of the mutual solubility behaviors of ILs and hydrocarbons is of the utmost *** this work,taking four typical C6-hydrocarbons namely benzene,cyclohexene,cyclohexane,and hexane as representatives,the mutual solubility of ILs and non-polar or weak-polar hydrocarbons are systematically studied based on the COSMO-RS *** reliability of COSMO-RS for these systems is first evaluated by comparing experimental and predicted hydrocarbon-in-IL activity coefficient at infinite dilution and binary/ternary liquid-liquid equilibria of related ***,the mutual solubility of the four hydrocarbons and13,650 ILs(composed by 210 cations and 65 anions)are *** effect of different IL structural characteristics including alkyl chain length,cation family/symmetry/functional group,and anion on the IL-hydrocarbon mutual solubility behaviors are further analyzed by the analyses of interaction energy and screen charge *** mutual solubility databases and the structural effects identified thereon could provide useful guidance for IL selection in related applications.

关键词： C6-hydrocarbons Ionic liquids Mutual solubility COSMO-RS Structural effect analysis

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Amino acids TORC(talk)to anabolism through uncharged tRNA

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Science China(Life Sciences) 2024年第8期67卷 1775-1776页

作者： zhen-zhen Ma Shi-min Zhao The Obstetrics&Gynecology Hospital of Fudan University State Key Laboratory of Genetic EngineeringShanghai Key Laboratory of Metabolic Remodelling and HealthFudan UniversityShanghai 200090China

Anabolism is essential for proliferation as well as to replenish dysfunctional macromolecules in *** to that both substantial building blocks and energy are required for anabolism,cells must double check whether these prerequisites are met before deciding to start *** acids are building blocks of protein synthesis,their sufficiency in cells is closely monitored by several mechanisms,which all are linked to protein synthesis.

关键词： synthesis. synthesis deciding

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One-step pore diffusion mechanism of Li^(+) in solid electrolyte interphase for fast-charging lithium-ion battery

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Rare Metals 2024年第7期43卷 3438-3440页

作者： Shan Wang Shu-Yuan Liu Alireza Khataee Ke-zhen qi College of Pharmacy Dali UniversityDali 671000China Research Laboratory of Advanced Water and Wastewater Treatment Processes Department of Applied ChemistryFaculty of ChemistryUniversity of TabrizTabriz 51666-16471Iran Peoples'Friendship University of Russia(RUDN University) Moscow117198Russian Federation

Li^(+) transport in solid electrolyte interphase is recognized as important factor,which has become a research ***,an one-step pore diffusion mechanism for Li^(+) transport through solid electrolyte interphase was proposed,which was different from previous two-step *** one-step pore diffusion process could effectively eliminate the dynamic limitations of Li^(+) transport in solid electrolyte interphase (SEI) for rapid charging *** work will contribute to the development of rapid charging lithium-ion batteries.

关键词： battery mechanism electrolyte

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Revisiting the island of hexadecapoledeformation nuclei in the A≈150 mass region:focusing on the model application to nuclear shapes and masses

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Communications in Theoretical Physics 2024年第2期76卷 74-88页

作者： Xiao-Yang Wei Hua-Lei Wang zhen-zhen Zhang min-Liang Liu School of Physics and Microelectronics Zhengzhou UniversityZhengzhou 450001China Key Laboratory of High Precision Nuclear Spectroscopy Institute of Modern PhysicsChinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China

Based on the potential-energy-surface calculation,the impact of different deformation degrees of freedom on a single-particle structure and binding energies in nuclei around^(152)Nd,located on one of the hexadecapole-deformation islands,is analyzed in a multi-dimensional deformation *** energy maps,curves and tables are presented to indicate nuclear *** calculated equilibrium deformations and binding energies with different potential parameters are compared with experimental data and other *** is found that the inclusion of the hexadecapole deformations,especially the axial one,can improve the theoretical description of both nuclear shapes and *** addition,our calculated potential-energy curve shows that a critical deformation-point,β_(2)≈0.4,exists—the triaxial(hexadecapole)deformation effect can be neglectable but the hexadecapole(triaxial)one plays an important role before(after)such a critical point.

关键词： hexadecapole deformation binding energy potential-energy-surface calculation nuclear property

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Direct ink writing of multifunctional gratings with gel-like MXene/norepinephrine ink for dynamic electromagnetic interference shielding and patterned Joule heating

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Nano Research 2024年第3期17卷 1585-1594页

作者： Pei-Zhu Jiang Zhiming Deng Peng min Lvxuan Ye Cheng-Zhang qi Hao-Yu Zhao Ji Liu Hao-Bin Zhang Zhong-zhen Yu Beijing Key Laboratory of Advanced Functional Polymer Composites Beijing University of Chemical TechnologyBeijing 100029China State Key Laboratory of Organic-Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China School of Chemistry CRANN and AMBERTrinity College DublinDublin D02PN40Ireland

Intelligent electromagnetic interference(EMI)shielding modulators with a wide tuning range and cyclic stability are urgently needed but their fabrication remains challenging.A gel-like MXene/norepinephrine ink is developed and multifunctional MXene gratings with wide EMI shielding effectiveness(SE)tuning range,superior reversibility,and high mechanical flexibility are constructed by direct ink writing approach for dynamic EMI shielding and patterned Joule heating *** modulable MXene/norepinephrine grating with a high conductivity of 3510 S·cm-1 can conveniently realize the seamless modulation of the EMI SE by adjusting the angle between the MXene grating filaments and the electric field of the incident electromagnetic waves,offering highly reversible switching between shielding“On”(28.0 dB)and“Off”(0.5 dB)***,due to the optimized integration of the MXene ink and the rationally designed pattern,a superior specific EMI SE of 95,688.2 dB·cm^(2)·g^(-1) is achieved in the“On”***,the MXene/norepinephrine ink can be used to fabricate many complex patterned gratings with superior stability,instant responsibility,and superb mechanical flexibility,exhibiting a unique patterned Joule heating *** writing of multifunctional gratings paves a means for developing intelligent EMI shielding materials,wearable electronic devices,and advanced thermal management materials.

关键词： MXene ink direct ink writing electromagnetic interference shielding multifunctional gratings Joule heating

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Progress and challenges of electrolyte modulation in aqueous zinc-ion batteries

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Rare Metals 2024年第7期43卷 2940-2967页

作者： qi-Hang Yang Lu-Fei Wang Xiao-Yu Wang Meng-Meng zhen Tianjin Key Laboratory of Clean Energy and Pollution Control School of Energy and Environmental EngineeringHebei University of TechnologyTianjin 300071China

As a new type of green battery system,aqueous zinc-ion batteries(AZIBs)have gradually become a research hotspot due to their low cost,high safety,excellent stability,high theoretical capacity(820 mAh·g^(-1))of zinc anode,and low redox potential(-0.76 V *** hydrogen electrode(SHE)).AZIBs have been expected to be an alternative to lithium-ion batteries for large-scale commercial energy storage ***,they are facing thorny issues such as degradation of cycling performance,zinc dendrites,and side *** the same time,these problems cause short cycling life of batteries,thus severely limiting their commercial *** recent years,many more researches have been conducted on the modification of anode and cathode materials of AZIBs,but there is a lack of in-depth discussion on the characteristics and mechanism of electrolyte *** this review,we will make a systematic summary of the current problems with two electrodes in AZIBs,as well as the types and functions of electrolyte ***,we further systematically describe the modulation mechanism of electrolyte additives in the performance of the cathode and *** prospects and development directions of additive modulation strategies for AZIBs electrolytes are prospected.

关键词： Electrolyte additives Aqueous zinc-ion batteries Zinc anode protection Cathode chemistry

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Optimization on crystallization process of the magnetic core lysozyme

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Particuology 2024年第4期87卷 106-113页

作者： Lixia Hou Chunxiao Qu min Su Zhihan Liang qi Hao School of Chemical Engineering Hebei University of TechnologyTianjin300130China

The continuous growth of the biomedical market highlights the significance of improvement in the ef-ficiency of batch production for protein drug ***,we investigated the effect of polymer-modified Fe_(3)O_(4) nanoparticles on lysozyme(Lys)crystallization at different conditions,using function-alized Fe_(3)O_(4) magnetic nanoparticles(Polymer C@Fe_(3)O_(4))as nucleation *** study revealed that the surface charge density of Polymer C@Fe_(3)O_(4) was highest at a modification mass ratio of Fe_(3)O_(4) to Polymer C is 8∶*** ratio facilitates the augmentation of electrostatic interaction and the promotion of *** adding 15%of the PolymerC@Fe_(3)O_(4) prepared from Fe_(3)O_(4) with an average particle size of 150 nm,the magnetic core lysozyme(M-Lys)crystals with an average particle size of 11.08μm,narrow size distribution,and regular morphology were obtained in a yield of 82.42%within 60 min.

关键词： Protein Crystallization Magnetic particle Lysozyme

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