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Continental hydrothermal sedimentary siliceous rock andgenesis of superlarge germanium(Ge)deposit hosted incoal:A study from the Lincang Ge deposit,Yunnan,china

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Science china Earth sciences 2004年第11期47卷 973-984页

作者： qi huawen1,2.hu ruizhong1,su wenchao1,qi liang1 & feng jiayi1 1.key laboratory of ore deposit geochemistry,chinese academy of sciences,guiyang 550002.china 2.Department of Earth sciences,Nanjing University,Nanjing 210093,china Correspondence should be addressed to qi huawen(email: qihuawen@***) key laboratory of ore deposit geochemistry Chinese Academy of Sciences Guiyang China Department of Earth sciences Nanjing University Nanjing China

There are abundant hydrothermal sedimentary structures and plant fragment fossils in the siliceous rocks from the Lincang Ge deposit. The major element compositions of these siliceous rocks are characterized by high content SiO2, low TiO2 and Al2O3concentrations, and low Al/(Al+Fe+Mn) ratios (0.010 on average). The siliceous rocks are distinctly enriched in Ge, Sb, As, W, and secondly enriched in Cs, U, Mo and Tl. Their total REE content are generally less than 1μg/g, LREE relatively concentrated, and the values of Eu anomaly and Ce anomaly vary from 0.452 to 5.141 and 0.997 to 1.174, respectively. Their NAS-normalized REE patterns are plain or left-inclined. The Oxygen isotope compositions of these siliceous rocks are similar to those of the hydrothermal siliceous sinter. The above characteristics, as well as the geological setting of the deposit, indicate these siliceous rocks formed in continental hydrothermal envi- ronment. As the interlayer or cliff of the Ge-rich coal seams, siliceous rocks tightly contacted with ore-body, and the contents of Ge in siliceous rocks vary from 5.6 to 360 μg/g (78 μg/g on aver- age). The Ge content increased in coal which close to the siliceous rocks. With the increase of Ge content, the typical trace element ratios (i.e., Ge/Ga, Nb/Ta and U/Th) and REE patterns of Ge-rich coal are more close to those of the siliceous rocks. The Ge concentrated in coal seams of the Lincang Ge deposit might be transported by the hydrothermal water, which demonstrated by the siliceous rocks, during the coal-forming processes.

关键词： siliceous rock, continental hydrothermal sedimentation, superlarge Ge deposit, Lincang.

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