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Kinetic Studies of Electrochemical Oxidation of 1,3-Benzenedithiol

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Chemical Research in Chinese Universities 1993年第3期9卷 231-239页

作者： h.S.Lee X.q.yang j.McBreen T.A.Skotheim Brookhaven National Laboratory Upton NY 11973 U.S.A. Brookhaven National Laboratory Upton NY 11973 U.S.A. Brookhaven National Laboratory Upton NY 11973 U.S.A. Moltech Corporation Stony Brook NY 11790-3350 U.S.A.

The electrochemical oxidation of 1, 3-benzenedithiol was investigated in a 0. 100 mol/L tetrabutylammonium perchlorate/acetonitrile electrolyte. The electrochemical techniques used were potential sweep, bulk electrolysis, rotating disc and the potential step method. The combination of the techniques yielded the number of electrons transferred per molecule, the reaction order, the transfer coefficient, the diffusion coefficient and concentration of dithiol anions, the standard heterogeneous rate constant as well as the formal potential and equilibrium constant of the preceeding dissociation reaction. This paper also illustrates the methods for studying the electrode kinetics of reactions which (a) involve a chemical reaction preceeding the electron-transfer process, (b) have insoluble polymer products, and (c) are totally irreversible.

关键词： Electrochemical oxidation 1,3-Benzenedithiol Electrode kinetics Organ-ic disulfide

EFFECT OF OVERLAPPING TREATMENT ON MICROSTRUCTURE OF LASER-CLAD WC/Ni60A COMPOSITE COATING

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Acta Metallurgica Sinica(English Letters) 1999年第5期12卷 1014-1018页

作者： C.Z. Chen 1,2) , X.D. Liu 3) , S.j. Zhang 4) , D.W. Cui 1) , T.q. Lei 2) and j.h. Yu 1) 1) College of Material Science and Technology, Shandong University of Technology, jinan 250061, China 2) College of Material Science and T

The effect of overlapping treatment on microstructure of laser clad WC/Ni60A composite coating was studied with XRD, SEM, TEM and SAED etc. The results show that during the overlapping treatment the existence of the residual heat and edge angle effect on the substrate has changed the composition and microstructure of the coating by raising the fusion temperature and increasing the dilution degree of the coating.

关键词： laser cladding WC/Ni60A microstructure overlapping edge angle effect

Further investigation on the fusion of ^(6)Li with ^(209)Bi target at near-barrier energies

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Chinese Physics C 2024年第7期48卷 106-117页

作者：张高龙焦振威张广鑫 M.R.Cortes 胡世鹏钱建强 D.Mengoni 屈卫卫李聪博郑云张焕乔孙慧斌王楠张春雷 j.j.Valiente-Dobón D.Testov M.Mazzocco A.Gozzelino C.Parascandolo D.Pierroutsakou M.La Commara A.Goasduff D.Bazzacco D.R.Napoli F.Galtarossa F.Recchia A.Illana S.Bakes I.Zanon S.Aydin G.de Angelis M.Siciliano R.Menegazzo S.M.Lenzi j.L.Ferreira j.Rangel Serkan Akkoyun L.F.Canto j.Lubian School of Physics Beihang UniversityBeijing 100191China Sino-French Institute of Nuclear Engineering and Technology Sun Yat-Sen UniversityZhuhai 519082China Instituto de Física Universidade Federal Fluminense24210-340NiteróiRio de JaneiroBrazil Institute for Advanced Study in Nuclear Energy&Safety Shenzhen UniversityShenzhen 518060China Shenzhen Key Laboratory of Research and Manufacture of high Purity Germanium Materials and Fetectors Shenzhen UniversityShenzhen 518060China INFN Sezione di PadovaPadovaItaly Dipartimento di fisica Astronomia dell'Universita di padova PadovaItaly State Key Laboratory of Radiation Medicine and Protection School of Radiation Medicine and ProtectionSoochow UniversitySuzhou 215123China China Institute of Atomic Energy Beijing 102413China The Key Laboratory of Beam Technology and Material Modification of Ministry of Education College of Nuclear Science and TechnologyBeijing Normal UniversityBeijing 100875China INFN Laboratori Nazionali di LegnaroI-35020 LegnaroItaly INFN Sezione di NapoliI-80126 NapoliItaly Dipartimento di Farmacia Universitàdi Napoli"Federico II"I-80131 NapoliItaly Department of Natural and Mathematical Sciences Faculty of EngineeringTarsus University33480 MersinTurkiye Physics Division Argonne National LaboratoryLemont-ILUSA Departamento de Matemaética Física e Computaç˜ao Universidade do Estado do Rio de JaneiroFaculdade de Tecnologia27537-000ResendeRio de JaneiroBrazil Department of Physics Sivas Cumhuriyet UniversitySivasTurkey Instituto de Física Universidade Federal do Rio de JaneiroCP 6852821941-972Rio de JaneiroBrazil

The complete and incomplete fusion cross sections for ^(6)Li+^(209)Bi were measured using the in-beamγ-ray method around the Coulomb *** cross sections of(deuteron captured)incomplete fusion(ICF)products were re-quantified experimentally for this reaction *** results reveal that the ICF cross section is equivalent to that of complete fusion(CF)above the Coulomb barrier and dominant near or below the Coulomb barrier.A theoretical calculation based on the continuum discretized coupled channel(CDCC)method was performed for the aforementioned CF and ICF cross sections;the result is consistent with the *** universal fusion function(UFF)was also compared with the measured CF cross section for different barrier parameters,demonstrating that the CF suppression factor is significantly influenced by the choice of potential,which can reflect both dynamic and static effects of breakup on the fusion process.

关键词： cross section incomplete fusion suppression factor weakly bound nuclei

Design and optimization of the composition and mechanical properties for non-equiatomic CoCrNi medium-entropy alloys

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journal of Materials Science & Technology 2023年第8期139卷 232-244页

作者： j.X.Yan Z.j.Zhang P.Zhang j.h.Liu h.Yu q.M.hu j.B.yang Z.F.Zhang Shi-changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering Chongqing Jiaotong UniversityChongqing 400074China chool of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China School of Materials Science and Engineering Northeastern UniversityShenyang 110819China School of Information Science and Engineering Shenyang University of TechnologyShenyang 111003China

The development of multi-principal element alloys(MPEAs,also called as high-or medium-entropy al-loys,hEAs/MEAs)provides tremendous possibilities for materials ***,designing MPEAs with desirable mechanical properties confronts great challenges due to their vast composition *** this work,we provide an essential criterion to efficiently screen the CoCrNi MEAs with outstanding strength-ductility *** negative Gibbs free energy difference△E_(FCC-BCC)between the face-centered cubic(FCC)and body-centered cubic(BCC)phases,the enhancement of shear modulus G and the decline of stacking fault energy(SFE)γ_(isf)are combined as three requisites to improve the FCC phase stability,yield strength,deformation mechanisms,work-hardening ability and ductility in the *** effects of chemical composition on△E_(FCC-BCC),G andγisf were investigated with the first principles calculations for Co_(x)Cr_(33)Ni_(67-x),Co_(33)Cr_(y)Ni_(67-y)and Co_(z)Cr_(66-z)Ni_(34)(0≤x,y≤67 and 0≤z≤66)*** on the essential criterion and the calculation results,the composition space that displays the neg-ative Gibbs free energy difference△E_(FCC-BCC),highest shear modulus G and lowest SFEγ_(isf)was screened with the target on the combination of high strength and excellent *** this context,the optimal composition space of Co-Cr-Ni alloys was predicted as 60 at.%-67 at.%Co,30 at.%-35 at.%Cr and 0 at.%-6 at.%Ni,which coincides well with the previous experimental evidence for Co_(55)Cr_(40)Ni_(5)*** valid-ity of essential criterion is further proved after systematic comparison with numerous experimental data,which demonstrates that the essential criterion can provide significant guidance for the quick exploitation of strong and ductile MEAs and promote the development and application of MPEAs.

关键词： Medium-entropy alloys First-principles calculations Phase stability Stacking-fault energy Strength Ductility

Effect and mechanism of coking residual ammonia water treating by flue gas

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journal of Environmental Sciences 2001年第2期13卷 237-246页

作者： Z j Cheng G j Yin L q yang W Wang D D Cheng Environmental Protection Research Institute Central Research Institute of Building and Construction Ministry of Metallurgical Industry Beijing 100088 China.

The treatment of coking residual ammonia water has been a big difficult problem at home and abroad, and there is no breakthrough research achievement in the past. The invention patent "The method of treating all coking wastewater or treating coking residual ammonia water by flue gas" has been successfully used in huaian Steel Works for high concentration and organic industry wastewater treatment. Not only can it realize the wastewater zero discharge, but also the wastewater treatment has an effect of de-sulfur and de-nitrogen for flue gas. So that the flue gas exhaust can meet the requirement of emission standard. The mass transfer and heat transfer, fly ash absorption and coagulation, acid and alkali neutralization reaction, catalysis oxidation and reduction reaction in flue gas would be the major factors.

关键词： Effect and mechanism of coking residual ammonia water

ATOMIC STATES AND BRITTLENESS OF hcp Ti_3Al-ORDERED-TYPE ALLOYS

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Acta Metallurgica Sinica(English Letters) 2007年第4期20卷 270-276页

作者： h.j. Peng Y.q. Xie College of Chemistry and Chemical Engineering Central South University Changsha 410083 China College of Materials Science and Engineering Central South University Changsha 410083 China

On the basis of the framework of systematic science of alloys （SSA）, the basic information such as states, volumes, and potential energies of characteristic atoms in hcp Ti-Al system have been determined. The average atomic state of the hcp Ti3Al compound consisting of ψ4^Ti and ψ0^Al atoms is 0.75[Ar] （3dn）^0.573 （3dc）^2.1685 （4sc）^0.972 （4sf）^0.3093 ＋ 0.25[Ne] （3sc）^1.32 （3pc）^1.19 （3sf ＋ 3pf）^0.49. The brittleness of the ordered hcp Ti3Al compound has been discussed considering the fundamental factors, which are atomic states, bond networks, potential energy wave planes, and the ratio xTi/xAl. The existence of more pc and more dc directional electrons in the hcp Ti3Al compound lead to considerable brittleness; From bond networks and potential energy wave planes, the hcp Ti3Al compound has poorer ductility than the pure hcp Ti metal and the pure fcc Al metal; The Al-rich hcp Ti3Al ordered type alloys have poorer ductility than the Ti-rich hcp Ti3Al ordered type alloys.

关键词： Ti3Al alloy atomic state brittleness

Experimental Study and Numerical Simulation of the Casting-Forging Complex Near Net Forming of Alternator Claw-pole

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上海交通大学学报 2004年第Z2期38卷 79-82页

作者： j.L.Song D.j.hu q.C.Wang h.q.Chen h.G.Guo School of Mechanical and Power Engineering Shanghai Jiaotong University Shanghai200030 China Scool of Materials Science and Engineering Taiyuan Heavy Machinery Institute Taiyuan030024 China School of Mechanical and Power Engineering Shanghai Jiaotong University Shanghai200030 China Scool of Materials Science and Engineering Taiyuan Heavy Machinery Institute Taiyuan030024 China Scool of Materials Science and Engineering Taiyuan Heavy Machinery Institute Taiyuan030024 China Scool of Materials Science and Engineering Taiyuan Heavy Machinery Institute Taiyuan030024 China

As a newly developed precision technology, casting-forging complex near net forming process is utilized to produce complex components with a short lead time, low cost and high precision, thus to accelerate the response speed of the market and enhance the competitive power of products. In this paper, the casting-forging complex near net forming process of alternator claw pole was developed and investigated with a combination of experimental and numerical simulation method. qualified near net workpiece was manufactured, mechanical parameter and relative field information during the forming process was also obtained. While the alternator claw-pole is processed with this technology, the forming force is small, the process is short and the quality of forgings is perfect. Therefore, the complex casting-forging near net forming process of claw-pole is an energy and material saving technology, which will have a vast developing and application prospect in the future.

关键词： alternator claw-pole casting-forging near net forming numerical simulation

Recent development of chemically complex metallic glasses: from accelerated compositional design, additive manufacturing to novel applications

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Materials Futures 2022年第1期1卷 9-31页

作者： j Y Zhang Z q Zhou Z B Zhang M h Park q Yu Z Li j Ma A D Wang h G huang M Song B S Guo q Wang Y yang Department of Mechanical Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China Shenzhen Key Laboratory of high Performance Nontraditional Manufacturing College of Mechatronics and Control EngineeringShenzhen UniversityShenzhenGuangdong 518060People’s Republic of China School of Materials Science and Engineering Dongguan University of TechnologyDongguanGuangdong 523808People’s Republic of China Institute of Materials China Academy of Engineering PhysicsJiangyouSichuan 621907People’s Republic of China State Key Laboratory of Powder Metallurgy Central South UniversityChangshaHunan 410083People’s Republic of China Institute of Advanced Wear&Corrosion Resistant and Functional Materials Jinan UniversityGuangzhouGuangdong 510632People’s Republic of China Institute of Materials Laboratory for MicrostructuresShanghai UniversityShanghai 200444People’s Republic of China Department of Materials Science and Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China Department of Advanced Design and System Engineering College of EngineeringCity University of Hong KongKowloon TongKowloonHong KongPeople’s Republic of China

Metallic glasses(MGs)or amorphous alloys are an important engineering material that has a history of research of about 80–90 *** different fast cooling methods were developed for multi-component MGs between 1960s and 1980s,1990s witnessed a surge of research interest in the development of bulk metallic glasses(BGMs).Since then,one central theme of research in the metallic-glass community has been compositional design that aims to search for MGs with a better glass forming ability,a larger size and/or more interesting properties,which can hence meet the demands from more important *** this review article,we focus on the recent development of chemically complex MGs,such as high entropy MGs,with new tools that were not available or mature yet until recently,such as the state-of-the-art additive manufacturing technologies,high throughput materials design techniques and the methods for big data analyses(*** learning and artificial intelligence).We also discuss the recent use of MGs in a variety of novel and important applications,from personal healthcare,electric energy transfer to nuclear energy that plays a pivotal role in the battle against global warming.

关键词： metallic glasses amorphous alloys alloy design additive manufacturing machine learning high throughput materials design

Continuous wave and active q-switched operation of Watt-level LED-pumped two-rod Nd,Ce:YAG laser

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Chinese Physics B 2024年第7期33卷 361-366页

作者：沈建平芦鹏徐少聪江容容陈阳陈亮邢凤阳 College of Electronic and Optical Engineering&College of Flexible Electronics Nanjing University of Posts and TelecommunicationsNanjing 210023China

A high-performance LED-side-pumped two-rod Nd,Ce:YAG laser with continuous-wave(CW) and acousto–optical(A-O) q-switched operation is demonstrated in this work. A symmetrically shaped flat–flat cavity with two identical LEDside-pumped laser modules is employed for power scalability. In the CW regime, the maximum output average power of laser at 1064 nm is 4.41 W, corresponding to a maximum optical conversion efficiency of 5.3% and a slope efficiency is 12.4%. In the active q-switched regime, the pulse energy of laser reaches as high as 0.89 m j at a repetition rate of 800 hz with a pulse width of 457.2 ns, the corresponding highest peak output power is 1.94 k W and the M~2 factor is measured to be about 8.8. To the best of the authors' knowledge, this is the first demonstration and the highest performance of a CW LED-side-pumped two-rod laser Nd,Ce:YAG with Watt-level output reported so far.

关键词： Watt-level LED-pumped CW Nd Ce:YAG actively q-switched operation