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Green synthesis of glycolic acid through the electrocatalytic reduction of oxalic acid over black TiO_(2): An experimental and theoretical study

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Journal of Energy Chemistry 2025年第1期100卷 544-556页

作者： Hugo Olvera-Vargas Oscar Andrés Jaramillo-quintero Luis Darío Alarcón León Orlando Castro-Ocampo Christian A.Celaya Marina E.Rincón Jesús muñiz Instituto de Energías Renovables Universidad Nacional Autónoma de México(IER-UNAM)Priv.Xochicalco s/nCol.CentroTemixcoMorelos.CP 62580Mexico Centro de nanociencias y nanotecnología Universidad Nacional Autónoma de México(UNAM)Km 107Carretera Tijuana-EnsenadaEnsenadaB.C.C.P.22800Mexico

Herein,we present the electrocatalytic four-electron hydrogenation of oxalic acid into glycolic acid using black TiO_(2)as an *** acid is an abundant compound found in several sources of organic *** results showed a high selectivity of black TiO_(2)toward glycolic acid,with the formation of glyoxylic acid being the rate-limiting step (glyoxylic acid is the two-electron intermediate).The highest Faradaic efficiency (FE) of 69.6%±8.3% was achieved at 10.2 mA cm^(-2)in 4 h of electrolysis using an H-type cell operated at room temperature,with 50.2%±3.8% of oxalic acid conversion (degradation kinetic constant k=0.0042±0.0001 min-1),58.8%±7.0%of reaction yield and 1.2±0.18 g L-1of glycolic acid production.A theoretical model of black TiO_(2)coming from anatase TiO_(2)was implemented by introducing Ti3+defects,which gave black TiO_(2)the theoretical capability to easily transform oxalic acid into glycolic acid as experimentally *** reaction mechanism was supported and described in detail by density functional theory calculations,which revealed that surface Ti^(3+)states were the main catalytic *** is the first time that a detailed step-by-step mechanism at the atomic level has been proposed for this electrocatalytic reaction,which represents a valuable contribution to the understanding of this process of high energy/environmental *** is also the first time that black TiO_(2)has been used as an electrocatalyst for this sustainable process.

关键词： Chemical energy storage Electrochemical hydrogenation Density functional theory Renewable energy Oxalic acid

Optimizing cooling approach of spiral coil for an electromagnetic steel teeming system of ladle in continuous casting production

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Journal of Iron and Steel Research International 2025年第1期32卷 85-94页

作者： Ming He qing-wei Wang Li-jia Zhao Wang-zhong mu Xing-an Liu qiang Wang College of Horticulture Shenyang Agricultural UniversityShenyang110866LiaoningChina Key Laboratory of Electromagnetic Processing of Materials(Ministry of Education) Northeastern UniversityShenyang110819LiaoningChina Key Laboratory of Protected Horticulture(Ministry of Education) Shenyang Agricultural UniversityShenyang110866LiaoningChina Department of Materials Science and Engineering KTH Royal Institute of TechnologyStockholm10044Sweden

To address the current issues with the conventional slide gate system utilized in the steel teeming process,a unique electromagnetic induction controlled automated steel teeming(EICAST)technology has been *** means of spiral coil in this technology is directly related to its service ***,heat transfer processes of air cooling and spray cooling were compared and ***,the impacts of water temperature,water flow rate and air flow rate were examined in order to maximize the spray cooling *** maintain coil temperature at a low value consistently throughout the entire thermal cycle process of the ladle,a combined cooling mode was finally *** simulation was applied to examine the coil temperature variation with different cooling systems and *** coil operation,spray cooling is said to be more *** controlling the water flow rate and air flow rate,the spray cooling effect is ***,water temperature has little or no impact when using spray *** cooling during the secondary refining process and spray cooling prior to coil operation are combined to further lower coil *** the direction of the spray cooling is from bottom to top,the coil temperature is lowered below 165℃.A practical induction coil cooling plan was provided for the EICAST technology’s production process.

关键词： Electromagnetic induction controlled automated steel teeming technology Spiral coil Spray cooling Heat transfer Continuous casting

Differential response of injured and healthy retinas to syngeneic and allogeneic transplantation of a clonal cell line of immortalized olfactory ensheathing glia:a double-edged sword

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neural Regeneration Research 2025年第8期20卷 2395-2407页

作者： María norte-muñoz María Portela-Lomba Paloma Sobrado-Calvo Diana Simón Johnny Di Pierdomenico Alejandro Gallego-Ortega Mar Pérez JoséMCabrera-Maqueda Javier Sierra Manuel Vidal-Sanz María Teresa Moreno-Flores Marta Agudo-Barriuso Grupo de Investigación Oftalmología Experimental Departamento de OftalmologíaOptometríaOtorrinolaringología y Anatomía PatológicaFacultad de MedicinaUniversidad de MurciaInstituto Murciano de Investigación Biosanitaria(IMIB)Campus de Ciencias de la SaludMurciaSpain Experimental Sciences Faculty Universidad Francisco de VitoriaPozuelo de AlarcónMadridSpain Anatomy Histology and Neuroscience DepartmentMedicine FacultyUniversidad Autónoma de MadridMadridSpain Center of neuroimmunology Service of NeurologyLaboratory of Advanced Imaging in Neuroimmunological DiseasesHospital Clínic of BarcelonaInstitut d’Investigacions Biomèdiques August Pi i Sunyer(IDIBAPS)and Universitat de BarcelonaBarcelonaSpain Medicine Faculty Universidad Francisco de VitoriaPozuelo de AlarcónMadridSpain

Olfactory ensheathing glia promote axonal regeneration in the mammalian central nervous system,including retinal ganglion cell axonal growth through the injured optic ***,it is unknown whether olfactory ensheathing glia also have neuroprotective *** ensheathing glia express brain-derived neurotrophic factor,one of the best neuroprotectants for axotomized retinal ganglion ***,we aimed to investigate the neuroprotective capacity of olfactory ensheating glia after optic nerve *** ensheathing glia cells from an established rat immortalized clonal cell line,TEG3,were intravitreally injected in intact and axotomized retinas in syngeneic and allogeneic mode with or without microglial inhibition or immunosuppressive *** and gene expression analyses were *** bulb-derived primary olfactory ensheathing glia and TEG3 express major histocompatibility complex classⅡ*** and syngenically transplanted TEG3 cells survived in the vitreous for up to 21 days,forming an *** axotomized retinas,only the allogeneic TEG3 transplant rescued retinal ganglion cells at 7 days but not at 21 *** these retinas,microglial anatomical activation was higher than after optic nerve crush *** intact retinas,both transplants activated microglial cells and caused retinal ganglion cell death at 21 days,a loss that was higher after allotransplantation,triggered by pyroptosis and partially rescued by microglial inhibition or ***,neuroprotection of axotomized retinal ganglion cells did not improve with these *** different neuroprotective properties,different toxic effects,and different responses to microglial inhibitory treatments of olfactory ensheathing glia in the retina depending on the type of transplant highlight the importance of thorough preclinical studies to explore these variables.

关键词： cell therapy immune recognition major histocompatibility complex class II(MHCII) neuroprotection olfactory ensheathing glia retinal ganglion cells

A　nEW　DITERPEnOID　FROM　COLEUS　SCUTELLARIOIDES

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Chinese Chemical Letters 1996年第5期7卷 441-442页

作者： mu, q Zhang, HJ Li, CM Sun, HD ACAD SInICA KUNMING INST BOTLAB PHYTOCHEMKUNMING 650204PEOPLES R CHINA

Abstract: From the herbs of Coleus sculellarioides, a new diterpenoid was isolated and identified as 2-(2'ξ-methoxypropy)-3-hydroxy-5,7,8-trimethylphenanthrene-1,4--dione,named as scutequinone(1).

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Prognostic model for esophagogastric variceal rebleeding after endoscopic treatment in liver cirrhosis: A Chinese multicenter study

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World Journal of Gastroenterology 2025年第2期31卷 85-101页

作者： Jun-Yi Zhan Jie Chen Jin-Zhong Yu Fei-Peng Xu Fei-Fei Xing De-Xin Wang Ming-Yan Yang Feng Xing Jian Wang Yong-Ping mu Cell Biology Laboratory Shuguang Hospital Affiliated to Shanghai University of Traditional Chinese MedicineShanghai 201203China Institute of Liver Diseases Shanghai Academy of Chinese MedicineShanghai 201203China Clinical Key Laboratory of Traditional Chinese Medicine of Shanghai Shuguang Hospital Affiliated to Shanghai University of Traditional Chinese MedicineShanghai 201203China Key Laboratory of Liver and Kidney Disease of the Ministry of Education Shanghai University of Traditional Chinese MedicineShanghai 201203China Department of Gastroenterology and Hepatology Zhongshan Hospital Affiliated to Fudan UniversityShanghai 200032China Shanghai Institute of Liver Disease Fudan UniversityShanghai 200032China Evidence-Based Medicine Center Fudan UniversityShanghai 200032China Department of Gastrointestinal Endoscopy Shuguang Hospital Affiliated to Shanghai University of Traditional Chinese MedicineShanghai 201203China Department of Hepatology Shuguang Hospital Affiliated to Shanghai University of Traditional Chinese MedicineShanghai 201203China

BACKGROUnD Rebleeding after recovery from esophagogastric variceal bleeding(EGVB)is a severe complication that is associated with high rates of both incidence and *** its clinical importance,recognized prognostic models that can effectively predict esophagogastric variceal rebleeding in patients with liver cirrhosis are *** To construct and externally validate a reliable prognostic model for predicting the occurrence of esophagogastric variceal *** This study included 477 EGVB patients across 2 cohorts:The derivation cohort(n=322)and the validation cohort(n=155).The primary outcome was rebleeding events within 1 *** least absolute shrinkage and selection operator was applied for predictor selection,and multivariate Cox regression analysis was used to construct the prognostic *** validation was performed with bootstrap *** assessed the discrimination,calibration and accuracy of the model,and performed patient risk *** Six predictors,including albumin and aspartate aminotransferase concentrations,white blood cell count,and the presence of ascites,portal vein thrombosis,and bleeding signs,were selected for the rebleeding event prediction following endoscopic treatment(REPET)*** predicting rebleeding within 1 year,the REPET model ex-hibited a concordance index of 0.775 and a Brier score of 0.143 in the derivation cohort,alongside 0.862 and 0.127 in the validation ***,the REPET model revealed a significant difference in rebleeding rates(Pn low-risk patients and intermediate-to high-risk patients in both *** We constructed and validated a new prognostic model for variceal rebleeding with excellent predictive per-formance,which will improve the clinical management of rebleeding in EGVB patients.

关键词： Esophagogastric variceal bleeding Variceal rebleeding Liver cirrhosis Prognostic model Risk stratification Secondary prophylaxis

Acute and chronic excitotoxicity in ischemic stroke and late-onset Alzheimer's disease

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neural Regeneration Research 2025年第7期20卷 1981-1988页

作者： Shan Ping Yu Emily Choi Michael qJiang Ling Wei Department of Anesthesiology Emory University School of MedicineAtlantaGAUSA Center for Visual and neurocognitive Rehabilitation Atlanta Veterans Affairs Medical CenterDecaturGAUSA

Stroke and Alzheimer's disease are common neurological disorders and often occur in the same *** comorbidity of the two neurological disorders represents a grave health threat to older *** review presents a brief background of the development of novel concepts and their clinical *** activity of glutamatergic n-methyl-D-aspartate receptors and n-methyl-D-aspartate receptor-mediated Ca^(2+)influx is critical for neuronal *** ischemic insult induces prompt and excessive glutamate release and drastic increases of intracellular Ca^(2+)mainly via n-methyl-D-aspartate receptors,particularly of those at the extrasynaptic *** Ca^(2+)-evoked neuronal cell death in the ischemic core is dominated by necrosis within a few hours and days known as acute ***,mild but sustained Ca^(2+)increases under neurodegenerative conditions such as in the distant penumbra of the ischemic brain and early stages of Alzheimer's disease are not immediately toxic,but gradually set off deteriorating Ca^(2+)-dependent signals and neuronal cell loss mostly because of activation of programmed cell death *** on the Ca^(2+)hypothesis of Alzheimer's disease and recent advances,this Ca^(2+)-activated“silent”degenerative excitotoxicity evolves from years to decades and is recognized as a unique slow and chronic *** n-methyl-D-aspartate receptor subunit Glun3A,primarily at the extrasynaptic site,serves as a gatekeeper for the n-methyl-D-aspartate receptor activity and is neuroprotective against both acute and chronic *** stroke and Alzheimer's disease,therefore,share an n-methyl-D-aspartate receptor-and Ca^(2+)-mediated mechanism,although with much different time *** is thus proposed that early interventions to control Ca^(2+)homeostasis at the preclinical stage are pivotal for individuals who are susceptible to sporadic late-onset Alzheimer's disease and Alzheimer's disease-related

关键词： Ca^(2+)hypothesis cognitive deficits hyperactivity late-onset Alzheimer's disease neurodegeneration n-methyl-D-aspartate receptors n-methyl-D-aspartate receptor subunits pathogenesis preventive treatment

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纵波在层状随机孔隙介质中的衰减

地球物理学报 2025年第1期68卷 375-383页

作者：穆常青宋永佳胡恒山哈尔滨工业大学航天科学与力学系哈尔滨150001

储层岩石常具有细密层状结构,研究弹性波在这种细密分层岩石中的衰减特性有助于更准确的获取储层信息.本文将细密分层岩石视为分层随机孔隙介质,并基于小扰动近似,在Biot理论框架下得到了纵波透射分层随机孔隙介质后有效波数的解析表达... 详细信息

储层岩石常具有细密层状结构,研究弹性波在这种细密分层岩石中的衰减特性有助于更准确的获取储层信息.本文将细密分层岩石视为分层随机孔隙介质,并基于小扰动近似,在Biot理论框架下得到了纵波透射分层随机孔隙介质后有效波数的解析表达式,利用有效波数可获得透射波的逆品质因子.本文对透射纵波的衰减特性进行了研究,分析了特征层厚、入射角、介质参数扰动变化以及介质渗透率变化对纵波衰减的影响.计算结果表明,衰减具有角度依赖性,各介质参数的扰动和渗透率变化影响纵波衰减.

关键词：层间流散射 Biot全局流衰减各向异性随机介质

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Hymenopteran-specific TRPA channel from the Texas leaf cutter ant (Atta texana) is heat and cold activated and expression correlates with environmental temperature

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InSECT SCIEnCE 2025年第1期32卷 301-320页

作者： York, Julia M. Taylor, Timothy n. LaPotin, Sarah Lu, Ying mueller, Ulrich Univ Illinois Dept Evolut Ecol & Behav Urbana IL USA Univ Texas Austin Dept Integrat Biol Austin TX USA Univ Texas Austin Inst Neurosci Austin TX USA Univ Utah Dept Human Genet Salt Lake City UT USA Univ Illinois Dept Evolut Ecol & Behav Urbana IL 61801 USA

Leaf cutting ants of the genus Atta cultivate fungal gardens, carefully modifying environmental conditions to maintain optimal temperature for fungal growth. Antennal nerves from Atta are highly temperature sensitive, but the underlying molecular sensor is unknown. Here, we utilize Atta texana (Texas leaf cutter ant) to investigate the molecular basis of ant temperature sensation and how it might have evolved as the range expanded northeast across Texas from ancestral populations in Mexico. We focus on transient receptor potential (TRP) channel genes, the best characterized temperature sensor proteins in animals. Atta texana antennae express 6 of 13 Hymenopteran TRP channel genes and sequences are under a mix of relaxed and intensified selection. In a behavioral assay, we find A. texana workers prefer 24 C-degrees (range 21-26 C-degrees) for fungal growth. There was no evidence of regulatory evolution across a temperature transect in Texas, but instead Hymenoptera-specific TRPA (HsTRPA) expression highly correlated with ambient temperature. When expressed in vitro, HsTRPA from A. texana is temperature activated with q10 values exceeding 100 on initial exposure to temperatures above 33 C-degrees. Surprisingly, HsTRPA also appears to be activated by cooling, and therefore to our knowledge, the first non-TRPA1 ortholog to be described with dual heat/cold activation and the first in any invertebrate.

关键词： electrophysiology evolution invertebrate leaf cutter ants temperature TRP channels

Comparison of adaptive structural damage identification techniques in nonlinear hysteretic vibration isolation systems

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Earthquake Engineering and Engineering Vibration 2013年第4期12卷 659-667页

作者： mu Tengfei Zhou Li Jann n.Yang State Key Laboratory of Mechanics and Control of Mechanical Structures Nanjing University of Aeronautics and Astronautics Department of Civil and Environmental Engineering University of California

Early structural damage identification to obtain an accurate condition assessment can assist in the reprioritization of structural retrofitting schedules in order to guarantee structural safety. nowadays, seismic isolation technology has been applied in a wide variety of infrastructure, such as buildings, bridges, etc., and the health conditions of these nonlinear hysteretic vibration isolation systems have received considerable attention. To effectively detect structural damage in vibration isolation systems based on vibration data, three time-domain analysis techniques, referred to as the adaptive extended Kalman filter （AEKF）, adaptive sequential nonlinear least-square estimation （ASnLSE） and adaptive quadratic sum-sqnares error （AqSSE）, have been investigated. In this research, these analysis techniques are compared in terms of accuracy, convergence and efficiency, for structural damage detection using experimental data obtained through a series of laboratory tests based on a base-isolated structural model subjected to E1 Centro and Kobe earthquake excitations. The capability of the AEKF, ASnLSE and AqSSE approaches in tracking structural damage is demonstrated and compared.

关键词： structural health monitoring parameter identification damage tracking nonlinear hysteretic system experimental verification