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Covalent triazine frameworks modified by ultrafine Pt nanoparticles for efficient photocatalytic hydrogen production

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Nano Research 2024年第6期17卷 4908-4915页

作者： Xu Han Xueying Ge Wen-Wen He wangwang Shen Tao Zhou Jian-Sen wang Rong-Lin Zhong Abdullah MAl-Enizi Ayman Nafady Shengqian Ma School of Chemistry and Life Science Advanced Institute of Materials ScienceChangchun University of TechnologyChangchun 130012China Laboratory of Theoretical and Computational Chemistry Institute of Theoretical ChemistryCollege of ChemistryJilin UniversityChangchun 130021China Department of Chemistry University of North Texas1508 W.Mulberry St.DentonTX 76201USA Department of Chemistry College of ScienceKing Saud UniversityRiyadh 11451Saudi Arabia

Pt nanoparticles(PtNPs)as active species have always been considered as one of the best semiconductor materials for photocatalytic hydrogen *** this study,a Schottky heterojunction has been successfully constructed by evenly loading ultrafine PtNPs onto a triazine-based covalent organic frameworks(COFs).This strategy maintained the high activity of these ultra-small PtNPs while maximizing the utilization of the Pt active *** fabricated PtNPs@covalent triazine-based framework-1(CTF-1)composite accomplished a significantly high rate of hydrogen evolution(20.0 mmol·g^(−1)·h^(−1),apparent quantum efficiency(AqE)=7.6%,atλ=450 nm)with 0.40 wt.%Pt loading,giving rise to a 44-fold-increase in the efficiency of the photocatalytic hydrogen production compared to the pristine *** calculations revealed that the strong electron transfer(q(Pt)=−0.726 qe,in the analysis of bader charge,q(Pt)is the charge quantity transferred from Pt cluster to CTF-1,and qe is the unit of charge transfer quantity)between PtNPs and CTF-1 triggers a strong interaction,which makes PtNPs being firmly attached to the structure of CTF-1,thereby enabling high stability and excellent hydrogen production ***,the hydrogen binding free energy(ΔGH*)of PtNPs@CTF-1 is much lower than that of the unmodified CTF-1,leading to a much lower intermediate state and hence a significant improvement in photocatalytic *** overall findings of this work provide a new platform to incorporate metallic NPs into COFs for the design and fabrication of highly efficient photocatalysts.

关键词： Pt nanoparticles covalent triazine-based framework-1(CTF-1) photocatalysts hydrogen evolution reaction

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Tensile Elastic behavior of a Zr-Cu-Ag-Al bulk Metallic Glass

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Journal of Materials Science & Technology 2014年第6期30卷 595-598页

作者： q.P.Cao J.b.Jin q.Yu X.D.wang D.X.Zhang Y.Jiang J.Z.Jiang International Center for New-Structured Materials (ICNSM) State Key Laboratory of Silicon MaterialsDepartment of Materials Science and Engineering Zhejiang University Department of Mechanical Engineering University of Nevada Reno NV 89557 USA State Key Laboratory of Modern Optical Instrumentation Zhejiang University

Tensile elastic behavior of bulk Zr46（Cu4.5/5.5Ag1/5.5）46Al8 metallic glass was experimentally investigated. It exhibited linear and non-linear time-independent elastic deformation with a demarcative stress of approximately 500 MPa within the timescale in the present work, and repeated loading-unloading before yielding did not alter stress-strain relationship. The pure linear elastic strain limit is 0.6%, significantly lower than 2% as generally reported, but still much higher than 0.1% observed for typical crystalline alloys. Deviation from linear elastic behavior at stresses higher than 500 MPa is explained here as a macroscopic manifestation of local fluctuations in elastic strain, which becomes pronounced at stresses higher than the critical value. The occurrence of non-linear elasticity is possibly also related to the sinusoidal relationship between shear stress and atomic displacement.

关键词： bulk metallic glass Tension test Elastic-plastic deformation

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Analysis of local crystallographic orientation in an annealed Ti60 billet

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Journal of Materials Science & Technology 2019年第4期35卷 591-595页

作者： Z.b.Zhao Z.Liu q.J.wang J.R.Liu R.Yang Institute of Metal Research Chinese Academy of Sciences School of Materials Science and Engineering University of Science and Technology of China

A heterogeneous microstructure in terms of local orientation distribution is often found in near-α titanium alloys. The presence of large regions with similar crystallographic orientation, called ‘macrozones',could drastically decrease the fatigue performance of titanium alloys. The present work reports on the crystallographic orientation of a near-α titanium alloy, Ti60, billet after annealing in an α+β phase *** texture was found to be weak, and no obvious macrozone was found in our measured zone where the variant selection is suppressed. Meanwhile, in-depth electron backscattered diffraction(EbSD) analysis was applied to evaluate the final microstructure, and the mechanisms by which they formed were analyzed.

关键词： Titanium alloys Microstructure Texture Heat treatment EbSD

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共享社会经济路径(SSP1~5)中国及分省经济预估数据集_v2

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气候变化研究进展 2024年第4期20卷 498-503页

作者：杨聿铭翟建青苏布达景丞姜彤郭欢欢南京信息工程大学地理科学学院/灾害风险管理研究院南京210044 南京信息工程大学气候与环境治理研究院南京210044 中国气象局国家气候中心北京100081 中国科学院新疆生态与地理研究所荒漠与绿洲生态国家重点实验室乌鲁木齐830011 江苏第二师范学院地理科学学院南京210013

随着全球经济快速增长,特别是基于传统工业化模式的增长,增加了化石燃料的使用,造成气候变暖和极端天气事件增加[1]。在追求短期经济利益的压力下,一些政府可能忽视或延迟实施必要的环境保护和气候治理措施。加之快速城市化和工业化导... 详细信息

随着全球经济快速增长,特别是基于传统工业化模式的增长,增加了化石燃料的使用,造成气候变暖和极端天气事件增加[1]。在追求短期经济利益的压力下,一些政府可能忽视或延迟实施必要的环境保护和气候治理措施。加之快速城市化和工业化导致对煤炭、石油等化石能源的需求激增,温室气体大量排放,气候进一步恶化,气候治理的难度加大。快速经济增长常常伴随着对自然资源的消耗,包括水资源、森林、矿产等,这不仅直接破坏了自然环境,还会降低这些生态系统对气候变化的适应能力和减缓作用。气候风险研究在应对气候变化方面发挥着关键作用,它包括对未来气候条件的预估,评估气候变化对环境、经济和社会的潜在影响,以及制定适应和减缓气候变化的策略。

关键词：工业化模式未来气候极端天气事件气候变化化石燃料气候治理环境保护快速城市化

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Distinct dendritic α phase emerging on the surface of primary α phase in a compressed near-α titanium alloy

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Journal of Materials Science & Technology 2018年第4期34卷 666-669页

作者： Z.Liu Z.b.Zhao J.R.Liu q.J.wang R.Yang Institute of Metal Research Chinese Academy of Sciences School of Materials Science and Engineering University of Science and Technology of China

The characteristic of the surface morphology of primary α phase was studied in a deformed near-α tita- nium alloy. Dendritic α phase emerged on the surfaces of primary α phase when the alloy was air-cooled in α ＋β phase field after deformation. The dendritic α grain has the same orientation with its original primary α grain. The formation of the dendritic α phase could be explained by interface instability in epi- taxial growth process of the primary α phase. The dislocations induced by deformation could facilitate the formation of dendritic α phase leading to the dendritic α phase and more obvious with the increase of strain. The growth of dendritic α phase was finally limited by the nucleation of second α phase with cooling.

关键词： Epitaxial growth Dendritic α phase Microstructure Interface instability Hot deformation

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High-Speed Friction Stir Welding of T6-Treated b4Cp/6061Al Composite

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Acta Metallurgica Sinica(English Letters) 2020年第1期33卷 67-74页

作者： Y.Z.Li Y.N.Zan q.Z.wang b.L.Xiao Z.Y.Ma Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of Sciences72 Wenhua RoadShenyang 110016China Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of Sciences72 Wenhua RoadShenyang 110016China University of Science and Technology of China Shenyang 110016China

T6-treated 20 wt% b4 Cp/6061 Al sheets were joined under welding speeds of 400–1200 mm/min by friction stir welding(FSW) with a threaded cermet pin. The macro-defect-free FSW joints could be achieved at high welding speeds up to 1200 mm/min, but larger plunge depth was required at the welding speeds of 800 and 1200 mm/min to eliminate the tunnel defect. In the nugget zone(NZ) of the joints, the b4 C particles were broken up and uniformly redistributed. The NZ exhibited lower hardness than the base metal(bM), and the hardness value almost did not change with increasing welding speed, attributable to the dissolution of precipitates. Compared with the bM, the joints showed lower tensile strength. As the welding speed increased from 400 to 800 mm/min, the joint efficiencies were nearly the same and up to ~ 73%. When the welding speed increased up to 1200 mm/min, the tensile strength significantly decreased, due to the occurrence of kissing bond defect at the bottom of the NZ. With increasing welding speed, the fracture location of the joints transferred gradually from the heat-affected zone to the NZ due to the kissing bond defects.

关键词： Metal-matrix composites Microstructures Mechanical properties Friction stir welding High-speed welding

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Enhanced oxidation resistance of Ce by addition of Ga and nanocrystallization

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Journal of Materials Science & Technology 2023年第16期147卷 26-36页

作者： T.S.Liang Y.F.Jiang H.Y.Li W.wang q.Zhang b.Zhang Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China The 404 Company Limited China National Nuclear CorporationLanzhou 732850China State Key Laboratory of Material Processing and Die&Mould Technology School of Material Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

Ce is prone to catastrophic oxidation at room temperature and its oxidation resistance is difficult to be improved by ***,we found that the oxidation resistance of active metal Ce can be significantly improved by the addition of 20 at.%*** ion beam lift-out technique and scanning transmission electron microscopy analysis disclosed that a discontinuous Ga-rich layer was generated beneath the oxide layer in the coarse-grained Ce-Ga *** Ga-rich layer formed by selective oxidation of Ce acts as a diffusion barrier for Ce outward diffusion and ceases the O/M interfacial reaction when a critical concentration of Ga(75 at.%)is *** nanocrystallization,uniform distribution of Ga was *** oxidation,a relatively continuous Ga-rich layer was formed which further enhanced the oxidation *** introduction of noble elements combining with nanocrystallization may provide a novel strategy for the protection of metals with high activity and poor oxidation resistance.

关键词： Ce-Ga alloy Oxidation resistance Diffusion barrier Nanocrystallization

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Ground-state mass of ^(22)Al and test of state-of-the-art ab initio calculations

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Chinese Physics C 2024年第3期48卷 72-78页

作者：孙铭泽于越王新鹏王猛李健国张玉虎 K.blaum 陈祖毅陈瑞九邓涵宇付超义葛文文黄文嘉焦红扬李红蕙李宏福罗胤芳廖挺 YuALitvinov 司敏帅鹏史金阳王茜邢元明徐星徐瑚珊许甫荣袁琪 T.Yamaguchi 颜鑫亮杨建成原有进周小红周旭张敏曾奇 CAS Key Laboratory of High Precision Nuclear Spectroscopy Institute of Modern PhysicsChinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China Max-Planck-Institut für Kernphysik Saupfercheckweg 169117 HeidelbergGermany GSI Helmholtzzentrum für Schwerionenforschung Planckstraße 164291 DarmstadtGermany Advanced Energy Science and Technology Guangdong Laboratory Huizhou516007China State Key Laboratory of Nuclear Physics and Technology School of PhysicsPeking UniversityBeijing 100871China Department of Physics Saitama UniversitySaitama 338-8570Japan School of Nuclear Science and Engineering East China University of TechnologyNanchang 330013China

The ground-state mass excess of the T_(z)=−2 drip-line nucleus ^(22)Al is measured for the first time as 18103(10)keV using the newly-developed bρ-defined isochronous mass spectrometry method at the cooler storage ring in *** new mass excess value allowed us to determine the excitation energies of the two low-lying 1+states in ^(22)Al with significantly reduced uncertainties of 51 *** compared to the analogue states in its mirror nucleus ^(22)F,the mirror energy differences of the two 1^(+)states in the ^(22)Al-^(22)F mirror pair are determined to be−625(51)keV and−330(51)*** excitation energies and mirror energy differences are used to test the state-of-the-art ab initio valence-space in-medium similarity renormalization group calculations with four sets of interactions derived from the chiral effective field *** mechanism leading to the large mirror energy differences is investigated and attributed to the occupation of theπs_(1/2) orbital.

关键词： nuclear mass bρ-defined IMS mirror energy difference ab initio VS-IMSRG calculations chiral interactions

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Superb Strengthening Effect of Net-Like Distributed Amorphous Al_(2)O_(3)on Creep Resistance of(b_(4)C+Al_(2)O_(3))/Al Neutron-Absorbing Materials

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Acta Metallurgica Sinica(English Letters) 2022年第12期35卷 2007-2013页

作者： Y.N.Zan X.Lei J.F.Zhang D.wang q.Z.wang b.L.Xiao Z.Y.Ma Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Shi-Changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Nuclear Equipment Division Beijing Institute of Nuclear EngineeringChina Nuclear Power Engineering Co.LtdBejing 100840China

b4C reinforced Al composites are widely used as neutron absorbing materials(NAMs)due to excellent neutron absorbing efficiency,however,such NAMs exhibit poor high-temperature *** meet the requirement for structure-function integration,NAMs with enhanced high-temperature mechanical properties are *** this work,a novel(b4 C+Al_(2)O_(3))/Al NAM with netlike distribution of Al_(2)O_(3)was fabricated by powder metallurgy method and subjected to high-temperature tensile creep *** was shown that the creep resistance was enhanced by several orders of magnitude via the addition of only2.1 vol.%netlike-distributed Al_(2)O_(3).(b_(4)C+Al_(2)O_(3))/Al exhibited high apparent stress exponents ranging from 16 to 25 and high apparent activation energy of 364 kJ/*** creep behaviour could be rationalized using the substructure-invariant model and its rupture behaviour could be described by the Dobes-Milicka equation.

关键词： Neutron absorber material Al matrix composite Tensile creep b_(4)C/Al

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Reduction effect of final-pass heavy reduction rolling on the texture development,tensile property and stretch formability of ZWK100 alloy plates

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Journal of Materials Science & Technology 2022年第16期111卷 211-223页

作者： b.q.Shi L.Y.Zhao X.L.Shang b.H.Nie D.C.Chen C.q.Li Y.q.Cheng School of Materials Science and Hydrogen Energy Foshan UniversityFoshan 528000China School of Materials and Energy Guangdong University of TechnologyGuangzhouGuangdong 510006China GD Midea Air-Conditioning Equipment Co. Ltd.Foshan 528311China Guangdong Key Laboratory of Hydrogen Energy Technology Foshan 528000China YunFu(Foshan)R&D Center of Hydrogen Energy Standardization Yunfu 527326China

Obviously planar anisotropy due to‘TD split’orthotropic texture(TD indicates Transverse direction)always exist in the Rare-earth(RE)or Ca containing Mg alloy sheets,which is likely caused by the lowreduction rolling(and annealing)as revealed in our previous *** this work,the as-cast billets of a ZWK100 alloy were subjected to final-pass heavy reduction rolling(FHRR)at 500°C with different reductions(30%-70%)after rough rolling,aiming to investigate the reduction effect on the microstructure and texture *** results show that FHRR with higher reductions above 50%is in favor of shear banding formation but has little effect on the as-deformed texture components,and the excellent formability with single-pass reduction up to 70%is mainly ascribed to the activation of prismatic *** with reduction above 50%and annealing can generate uniform grain structures of~10μm and symmetrical‘oblique-line split’texture in(0001)pole figures,with basal poles tilting by about 50°from ND(Normal direction)towards some oblique-line of TD and RD(Rolling direction)as well as uniform distribution of counter lines as an annular shape,resulting in excellent elongation to failure of~50%and ultra-low planar anisotropyΔr_of~0.1 and high stretch formability(Erichsen value:8.1).The formation‘oblique-line split’texture in(0001)pole figures is mainly correlated with the preferred growth tendency of grains with■//RD,which was suggested to relate to the high mobility of some special boundaries such as 40°-45°■.The influences of starting textures on the mechanical properties,planar anisotropy and related deformation modes,as well as their correlations with the stretch formability were comparatively investigated with the‘TD split’orthotropic texture as a counterpoint.

关键词： Magnesium alloys Texture Plane anisotropy Stretch formability Rolled sheets

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