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Journal of Materials Science & Technology 2019年第8期35卷 1767-1778页

作者： Rita Maurya Abdul Rahim Siddiqui prvan kumar katiyar Kantesh Balani Materials Science and Engineering Indian Institute of Technology Kanpur Kanpur 208016 India Centre for Material Science & Engineering National Institute of Technology Hamirpur Hamirpur 177005 India China-Canada Institute for Advanced Surface & Interface Science and Engineering Jiangsu University of Technology Changzhou 213001 China

The mechanical,tribological and corrosion protection offered to Mg-9Li-7Al-1Sn and Mg-9Li-5Al-3Sn-1Zn alloys by the epoxy coating containing polyaniline/graphene(PANI/Gr)pigments is undertaken in the current ***/Gr containing coatings were observed to be strongly adherent with a higher scratch hardness(Hs)and plowing hardness(Hp),*** 0.43 GPa,and Hpof 0.61 GPa,respectively when compared to that of neat epoxy coating(Hsof 0.17 GPa,and Hpof 0.40 GPa,respectively).Due to their higher Hsand Hpvalues,PANI/Gr based coatings displayed an enhanced wear resistance(Wear volume,Wv=4.53×10^-3 m^3)than that of neat epoxy coating(Wv=5.15×10^-3 m^3).The corrosion protection efficiency in corrosive environment of 3.5 wt%NaCl solution was obtained to be>99% for PANI/Gr containing coatings when compared to that of neat epoxy *** charge-transfer resistance(R(ct))of the PANI/Gr containing coatings were estimated to be>10^6 cm^2,which indicates their highly protective nature when compared to that of neat epoxy coating(R(ct)10^5 Ω cm^2).Hence,PANI/Gr containing coatings can be potentially used for wear resistance and corrosion protection applications in marine environments.

关键词： Mg-Li alloys Scratch hardness Plowing hardness Wear resistance Corrosion protection efficiency Charge transfer resistance

Recent progress and perspective on batteries made from nuclear waste

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Nuclear Science and Techniques 2023年第3期34卷 1-8页

作者： Nirmal kumar katiyar Saurav Goel School of Engineering London South Bank UniversityLondonSE10 AAUK University of Petroleum and Energy Studies Dehradun248007India

Sustainable energy sources are an immediate need to cope with the imminent issue of climate change the world is facing *** particular,the long-lasting miniatured power sources that can supply energy continually to power handheld gadgets,sensors,electronic devices,unmanned airborne vehicles in space and extreme mining are some of the examples where this is an acute *** is known from basic physics that radioactive materials decay over few years and some nuclear materials have their half-life until thousands of *** past five decades of research have been spent harnessing the decay energy of the radioactive materials to develop batteries that can last until the radioactive reaction ***,an emergent opportunity of industrial symbiosis to make use of nuclear waste by using radioactive waste as raw material to develop bat-teries with long shelf life presents a great opportunity for sustainable energy resource ***,the current canon of research on this topic is *** perspective draws fresh discussions on the topic while highlighting future directions in this wealthy arena of *** abstract A long-lasting miniaturised nuclear battery utilising 14C radioactive isotope as fuel.

关键词： Sustainable energy Nuclear waste battery Nano-diamond

Influence of alumina/MWCNT hybrid nanoparticle additives on tribological properties of lubricants in turning operations

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Friction 2019年第2期7卷 153-168页

作者： Anuj kumar SHARMA Jitendra kumar katiyar Shubrajit BHAUMIK Sandipan ROY Tribology and Surface Interaction Research Lab Department of Mechanical EngineeringSRM Institute of Science and Technology Kattankulathur

A hybrid lubricant with improved thermal and tribological properties was developed by blending multiwalled carbon nanotubes(MWCNTs) with alumina-based nanoparticles into cutting fluid at fixed volumetric proportions(10:90). The hybrid cutting fluid was prepared in different volumetric concentrations(0.25, 0.75, and 1.25 vol%), and the tribological properties and contact angles were measured using pin-on-disc tribometry and goniometry, respectively. The study showed a reduction in wear and friction coefficient with increasing nanoparticle concentration. The cutting fluid performance was investigated using minimum quantity lubrication(MQL) in the turning of AISI 304 stainless steel. Regression models were developed for measuring the temperature and tool flank wear in terms of cutting speed, feed, depth of the cut, and nanoparticle concentration using response surface methodology. The developed hybrid nanolubricants significantly reduced the tool flank wear and nodal temperature by 11% and 27.36%, respectively, as compared to alumina-based lubricants.

关键词： hybrids nanolubricants MQL MWCNT tool wear friction coefficient

Titanium nanoparticles attenuates arsenic toxicity by up-regulating expressions of defensive genes in Vigna radiata L

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Journal of Environmental Sciences 2020年第6期32卷 18-27页

作者： Priya katiyar Bhumika Yadu Jyoti Korram Manmohan L.Satnami Meetul kumar S.Keshavkant School of Studies in Biotechnology Pt.Ravishankar Shukla UniversityRaipur 492010India School of Studies in Chemistry Pt.Ravishankar Shukla UniversityRaipur 492010India Directorate of International Cooperation Defence Research and Development OrganizationNew Delhi 110001India

Arsenic(As)-toxicity is recognized as one of the major environmental problems,affecting productivity of crops worldwide,thereby threatening sustainable agriculture and food *** in nanotechnology and its impacts have brought up concerns about the application of engineered nanoparticles(NPs)in various sectors of the economy,including the field of *** various NPs,there has been a rising amount of interest regarding the effects of titanium NPs(TiNPs)on plants growth and development,and their fate of abiotic stress ***,the present study was aimed to assess the ameliorative potentialities of chemically and biologically/green synthesized TiNPs to alleviate As-induced toxic responses in Vigna radiata *** results revealed that exposure to As hindered the growth indices(radicle length and biomass)and membrane integrity,while were improved with the application of chemical and green synthesized *** addition,treatment of As provoked the accretion of reactive oxygen species(superoxide and hydrogen peroxide)and malondialdehyde(a lipid per oxidized product),but were diminished by the supplementation of chemical and green manufactured *** experimental data also signified that exogenous application of chemical and green synthesized TiNPs conferred tolerance to As-induced oxidative injuries via perking-up the expressions of antioxidant genes and enzyme systems viz;superoxide dismutase and ***,the present study inferred that chemically and green synthesized TiNPs,particularly green manufactured,effectively mitigated the adverse impacts of As by augmenting antioxidant machinery,thereby proving its potentiality in the alleviation of As-toxicity,at least in Vignaradiata L.

关键词： Antioxidants Arsenic Gene expression Titanium nanoparticles(TiNPs) Reactive oxygen species(ROS) Vigna radiata L

Low-cost high entropy alloy(HEA)for high-efficiency oxygen evolution reaction(OER)

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Nano Research 2022年第6期15卷 4799-4806页

作者： Lalita Sharma Nirmal kumar katiyar Arko Parui Rakesh Das Ritesh kumar Chandra Sekhar Tiwary Abhisek K.Singh Aditi Halder Krishanu Biswas School of Basic Sciences Advanced Materials Research Centre(AMRC)Indian Institute of Technology Mandi(H.P)KamandMandi 175005India Department of Materials Science and Engineering Indian Institute of Technology KanpurKanpur 208016India School of Engineering London South Bank UniversityLondonSE10 AAUK Materials Research Centre Indian Institute of ScienceBangalore 560012India Metallurgical and Materials Engineering Indian Institute of Technology KharagpurKharagpur 382355India

Oxygen evolution reaction(OER)is the key step involved both in water splitting devices and rechargeable metal-air batteries,and hence,there is an urgent need for a stable and low-cost material for efficient *** the present investigation,Co-Fe-Ga-NiZn(CFGNZ)high entropy alloy(HEA)has been utilized as a low-cost electrocatalyst for ***,after cyclic voltammetry activation,CFGNZ-nanoparticles(NPs)are covered with oxidized surface and form high entropy(oxy)hydroxides(HEOs),exhibiting a low overpotential of 370 mV to achieve a current density of 10 mA/cm^(2)with a small Tafel slope of 71 mV/*** alloy has higher electrochemical stability in comparison to state-of-the art RuO2 electrocatalyst as no degradation has been observed up to 10 h of *** electron microscopy(TEM)studies after 10 h of long-term chronoamperometry test showed no change in the crystal structure,which confirmed the high stability of *** density functional theory(DFT)based calculations show that the closeness of d(p)-band centers to the Fermi level(EF)plays a major role in determining active *** work highlights the tremendous potential of CFGNZ HEA for OER,which is the primary reaction involved in water splitting.

关键词： high entropy alloy cyclic voltammetry activation oxygen evolution reaction electrocatalyst nanocrystalline catalyst

Thermo-mechanical and tribological properties of SU-8/h-BN composite with SN150/perfluoropolyether filler

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Friction 2020年第1期8卷 151-163页

作者： Anand Singh RATHAUR Jitendra Kkatiyar Vinay kumar PATEL Department of Mechanical Engineering Govind Ballabh Pant Institute of Engineering and Technology GhurdauriPauri GarhwalUttarakhand 246194India Department of Mechanical Engineering SRM Institute of Science and TechnologyKattankulathur CampusChennaiTamil Nadu 603203India

In this study, SU-8 and its composites are fabricated by blending 10 wt.% hexagonal boron nitride(h-BN) fillers with/without lubricants, such as 10 wt.% base oil(SN150) and 20 wt.% perfluoropolyether(PFPE). The thickness of SU-8 and its composites coating is fabricated in the range ~100–105 μm. Further, SU-8 and its composites are characterized by a 3D optical profilometer, atomic force microscopy, scanning electron microscopy, a thermal gravimetric analyzer, a goniometer, a hardness tester, and an optical microscope. Under a tribology test performed at different normal loads of 2, 4, and 6 N and at a constant sliding speed of 0.28 m/s, the reduction in the initial and steady-state coefficient of friction is obtained to be ~0.08 and ~0.098, respectively, in comparison to SU-8(~0.42 and ~0.75), and the wear resistance is enhanced by more than 103 times that of pure SU-8. Moreover, the thermal stability is improved by ~80–120 ℃, and the hardness and elastic modulus by ~3 and ~2 times that of pure SU-8, respectively. The SU-8 composite reinforced with 10 wt.% h-BN and 20 wt.% PFPE demonstrated the best thermo-mechanical and tribological properties with a nano-textured surface of high hydrophobicity.

关键词： SU‐8 boron nitride perfluoropolyether(PFPE) base oil(SN 150) in‐situ lubrication

Thin Film Encapsulation at Low Temperature Using Combination of Inorganic Dyad Layers and Spray Coated Organic Layer

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Journal of Encapsulation and Adsorption Sciences 2017年第4期7卷 140-148页

作者： Sandeep kumar Monica katiyar Department of Materials Science and Engineering Indian Institute of Technology Kanpur India National Centre for Flexible Electronics Indian Institute of Technology Kanpur India

Organic devices have many advantages such as low material consumption and low energy requirements, but they have serious issues regarding long term stability. Hence we need to develop a barrier film which solves this problem. Initially, the organic devices were fabricated on glass and were encapsulated using glass and epoxy (as sealant). Gradually there was a need to shift on to flexible substrates which required encapsulation to be flexible as well. Therefore, the motivation of the work is to develop thin film encapsulation that can be made flexible. The low temperature PECVD grown films of SiOx and SiNxwere used as the barrier film. Alternate inorganic layers (2-dyads) provided barrier of ~10-2 g/m2 day and increasing the number of dyads to five improved the water vapor transmission rate (WVTR) only by one order of magnitude. However, introducing organic layers in this structure resulted in WVTR value of order 10-5 g/m2 day. The organic layers were deposited by spray technique.

关键词： Thin Film Encapsulation PECVD Organic Inorganic Silicon Oxide Silicon Nitride

Analysis of Mechanical Behavior of Red Blood Cell Membrane with Malaria Infection

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World Journal of Mechanics 2011年第3期1卷 100-108页

作者： Vinod kumar katiyar Demeke Fisseha 不详

Human red blood cells (RBCs) are responsible to transport oxygen and carbon dioxide for human bodies. The physiological functions of RBCs are greatly influenced by their mechanical properties. When RBC is infected by Malaria parasite called Plasmodium falciparum, it shows progressive changes in mechanical properties and loses its deformability. The infected red blood cells (IRBCs) develop properties of cytoadherence (stickiness) and rosetting (the binding of non-infected RBCs to parasitized RBCs). In this paper to analyze the mechanical properties and deformability of the IRBC, we applied stress-stretch ratio relation of its biomembrane .To express this constitutive relation, we proposed a mathematical model (Neo-Hookean model) based on membrane theory. On this model, we present continuous stress-stretch ratio curves for the relation derived from the model for different intracellular developmental stages of the parasite, to determine the mechanical properties of IRBC. The analytical results obtained from the mathematical model are more closed with the experimental data [1] which demonstrates the validity of the model. By restricting our attention to spherically symmetric deformation in the final schizont stage of parasite development, the pressure-extension ratio relation curve also adapted from the proposed strain energy function. The change in osmotic pressure versus volumetric ratio has been also considered for IRBC before hemolysis.

关键词： Cell Mechanics Malaria Infected Red Blood Cell Mathematical Model RBC Membrane Elasticity

Think Home: A Smart Home as Digital Ecosystem

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Circuits and Systems 2016年第8期7卷 1976-1991页

作者： Vijender kumar Solanki Venkatesan Muthusamy Somesh katiyar Anna University Chennai India KSRIET Nammakal India Chandigarh Group of College Punjab India

This work brings all new and advanced technology which is proposed for refinement and improvement in the existing electrification system at domestic as well as commercial levels including hotels, commercial complexes, apartments, rented floors and rooms. This advanced module will not only convey means of luxury but will also accomplish real-time energy monitoring and cost es-timation. This developed module will rule out entire re-wiring and will be fruitful at places where installation of a new meter was a problem. The new system after installation will offer means of comfort to the consumer, elderly as well as handicapped and disabled people in operating electric load with ease and comfort. Apart from this, it would also benefit the apartment/hotel owner’s and business personnel who have rented their property or portion of property and face problems in calculating energy bill.

关键词： Power & Cost Estimation Energy Consumption Calculator. Keywords— Home Automation

The Automated Vehicle Detection of Highway Traffic Images by Differential Morphological Profile

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Journal of Transportation Technologies 2014年第2期4卷 150-156页

作者： Bharti Sharma Vinod kumar katiyar Arvind kumar Gupta Akansha Singh Department of Earth quake Indian Institute of Technology Roorkee Roorkee India Department of Information Technology College of Engineering Roorkee Roorkee India Department of Mathematics Indian Institute of Technology Roorkee Roorkee India Department of Mathematics Indian Institute of Technology Ropa Ropar India

Vehicle detection has been the critical part of the traffic surveillance system for many years. However, vehicle detection method is still challenging. In this paper, differential morphology closing profile is used to extract the vehicle automatically from the traffic image. Along with closing profile, some addition operation has been applied as a part of the algorithm to get the high detection and quality rate. Result demonstrated that the novel method has an excellent detection and quality percentage. We also have compared our automated detection method with other traditional image processing based methods and the results indicate that our proposed method provides better results than traditional image processing based methods.

关键词： Average Filter Differential Morphology Closing Profile Structure Element Thresholding Vehicle Detection