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Synthetic and biological studies on a cyclopolypeptide of plant origin

Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2008年第5期9卷 391-400页

作者： Rajiv dahiya Akhilesh KUMAR Department of Pharmaceutical Chemistry Rajiv Academy for Pharmacy

Objective:A natural cyclic peptide previously isolated from Citrus medica was synthesized by coupling of tetrapep-tide units Boc-Leu-Pro-Trp-Leu-OMe and Boc-Ile-Ala-Ala-Gly-OMe after proper deprotection at carboxyl and amino terminals followed by cyclization of linear octapeptide segment. Methods:Solution phase technique was adopted for the synthesis of cyclooctapeptide-sarcodactylamide. Required tetrapeptide units were prepared by coupling of Boc-protected dipeptides viz. Boc-Leu-Pro-OH and Boc-Ile-Ala-OH with respective dipeptide methyl esters Trp-Leu-OMe and Ala-Gly-OMe. Cyclization of linear octapeptide unit was done by p-nitrophenyl ester method. The structure of synthesized cyclopolypeptide was elucidated by FTIR,1H NMR,13C NMR,FABMS spectral data and elemental analysis. The newly synthesized peptide was evaluated for dif-ferent pharmacological activities including antimicrobial,anthelmintic and cytotoxic activities. Results:Synthesis of sarcodac-tylamide was accomplished with >78% yield utilizing dicyclohexylcarbodiimide(DCC) as coupling agent. Newly synthesized peptide possessed potent cytotoxic activity against Dalton's lymphoma ascites(DLA) and Ehrlich's ascites carcinoma(EAC) cell lines,in addition to moderate anthelmintic activity against earthworms Megascoplex konkanensis,Pontoscotex corethruses and Eudrilus sp. Moreover,cyclopolypeptide displayed good antimicrobial activity against pathogenic fungi Candida albicans and Gram-negative bacteria Pseudomonas aeruginosa,in comparison to standard drugs griseofulvin and ciprofloxacin. Conclusion:Solution phase technique employing DCC and triethylamine(TEA) as base proved to be effective for the synthesis of natural cyclooctapeptide. N-methyl morpholine(NMM) was found to be a better base for the cyclization of linear octapeptide unit in comparison to TEA and pyridine.

关键词： Cyclic octapeptide Citrus medica var. sarcodactylis Sarcodactylamide Peptide synthesis Anthelmintic activity Antimicrobial activity Cytotoxicity

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Magnetic moments of octet baryons in hot and dense nuclear matter

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Chinese Physics C 2017年第9期41卷 108-122页

作者： Harpreet Singh Arvind Kumar Harleen dahiya Department of Physics Dr. B R Ambedkar National Institute of Technology Jalandhar Jalandhar- 144011 Punjab India

We have calculated the in-medium magnetic moments of octet baryons in the presence of hot and dense symmetric nuclear matter. Effective magnetic moments of baryons have been derived from medium modified quark masses within the chiral SU（3） quark mean field model. Further, for better insight into the medium modification of baryonic magnetic moments, we have considered the explicit contributions from the valence quarks, sea quarks and the sea orbital angular momentum of sea quarks. These effects have been successful in giving the description of baryonic magnetic moments in vacuum. The magnetic moments of baryons are found to vary significantly as a function of density of nuclear medium.

关键词： nuclear matter magnetic moments heavy ion collisions

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Direct roll transfer printed silicon nanoribbon arrays based high-performance flexible electronics

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npj Flexible Electronics 2021年第1期5卷 159-168页

作者： Ayoub Zumeit Abhishek Singh dahiya Adamos Christou Dhayalan Shakthivel Ravinder dahiya Bendable Electronics and Sensing Technologies(BEST)Group James Watt School of EngineeringUniversity of GlasgowGlasgowUK

Transfer printing of high mobility inorganic nanostructures,using an elastomeric transfer stamp,is a potential route for highperformance printed *** this method to transfer nanostructures with high yield,uniformity and excellent registration over large area remain a ***,we present the‘direct roll transfer’as a single-step process,i.e.,without using any elastomeric stamp,to print nanoribbons(NRs)on different substrates with excellent registration(retaining spacing,orientation,etc.)and transfer yield(∼95%).The silicon NR based field-effect transistors printed using direct roll transfer consistently show high performance i.e.,high on-state current(Ion)>1 mA,high mobility(μ_(eff))>600 cm^(2)/Vs,high on/off ratio(I_(on)/_(off))of around 10^(6),and low hysteresis(<0.4 V).The developed versatile and transformative method can also print nanostructures based on other materials such as GaAs and thus could pave the way for direct printing of high-performance electronics on large-area flexible substrates.

关键词： transfer performance high

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The stronger venue for flexible electronics

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npj Flexible Electronics 2023年第1期7卷 46-47页

作者： Ravinder dahiya Bendable Electronics&Sustainable Technologies(BEST)gp. Department of Electrical and Computer EngineeringNortheastern UniversityBostonMA 02115USA

I am deeply honoured and delighted to write this editorial as the new Editor-in-Chief of npj Flexible Electronics.I feel a strong sense of connection to the journal as some of the early papers by my group were published here.I would like to begin by thanking the outgoing Editor-in-Chief,*** Bradley for passing on this strong and healthy *** journal has had a lot of success under his and ***’s excellent stewardship and incredible *** is evident from the large number of downloads(about 425,000 so far)of the papers published in npj Flexible Electronics and the altimetric mentions(925,as per 2022 usage metric).

关键词： journal passing thank

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Fault Tolerance in the Joint EDF-RMS Algorithm: A Comparative Simulation Study

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Computers, Materials & Continua 2022年第9期72卷 5197-5213页

作者： Rashmi Sharma Nitin Nitin Deepak dahiya University of Petroleum&Energy Studies(UPES) School of Computer ScienceEnergy Acres BuildingBidholiDehradun248007UttarakhandIndia Department of Electrical Engineering and Computer Science College of Engineering and Applied ScienceUniversity of Cincinnati2600 Clifton AveCincinnatiOH 45221United States College of Computer and Information Sciences(CCIS) Majmaah UniversityMajmaah11952Kingdom of Saudi Arabia

Failure is a systemic error that affects overall system performance and may eventually crash across the entire *** Real-Time Systems(RTS),deadline is the key to successful completion of the *** tasks effectively meet the deadline,it means the system is working in pristine ***,missing the deadline means a systemic fault due to which the system can crash(hard RTS)or degrade inclusive performance(soft RTS).To fine-tune the RTS,tolerance is the critical issue and must be handled with extreme *** article explains the context of fault tolerance with improvised Joint EDF-RMS algorithm in *** backup method has been derived to prevent the system from being recursively migrating the same *** any task migrates three times,this migrated task will get shifted to the backup *** backup queue assigns the task to a backup processor and is destined for final *** performance evaluation purposes,a relative graph between fault and failure rates,failure and total processor utilization along with other averages have been ***,these archived results are compared with fault-tolerant Earliest Deadline First(EDF)and Rate Monotonic Scheduling(RMS)algorithms independently in relatively similar *** comparisons show better performance against overloading conditions.

关键词： Fault tolerance joint edf-rms algorithm real-time systems(RTS) distributed systems migration

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Generalized Bleustein-Gulyaev type waves in layered porous piezoceramic structure

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Applied Mathematics and Mechanics(English Edition) 2015年第9期36卷 1223-1242页

作者： A.K.VASHISHTH A.dahiya V.GUPTA Department of Mathematics Kurukshetra University

The propagation of a Bleustein-Gulyaev （B-G） type wave in a structure consisting of multiple layers and a half-space of porous piezoelectric materials is theoreti- cally studied. The solutions of the problem in terms of the mechanical displacements and electric potential functions are obtained for each layer and the half-space. The dispersion equation is obtained for electrically open and shorted boundary conditions by use of the transfer matrix method. A peculiar kind of B-G waves is investigated, which can propagate only in the layer over the half-space. The relationship between the piezoelectric constants and the dielectric constants is found for the existence of a peculiar kind of propagation modes. The numerical results in terms of the phase velocity and the electromechanical coupling factor with different thicknesses of the layer stack are presented.

关键词： Bleustein-Gulyaev (B-G) type wave electro-mechanical coupling porouspiezoceramic transfer matrix

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Channel estimation and channel tracking for correlated block-fading channels in massive MIMO systems

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Digital Communications and Networks 2018年第2期4卷 138-147页

作者： Suresh dahiya Arun Kumar Singh Department of Electrical Engineering Indian Institute of Technology Jodhpur Rajasthan 342011 India

This paper presents a channel estimation and tracking method for correlated block-fading channels in massive MIMO wireless cellular systems. In order to conserve resources, the proposed algorithm requires the uplink pilot signal only once, at the start of communication. By utilizing the temporal correlation between consecutive Resource Blocks （RBs） and the error correction capability of turbo codes, the channel matrix in subsequent RBs is estimated at the Base Station （BS） itself using the uplink data of current the RB and the estimated channel matrix of previous the RB. Compared to existing blind estimation methods, the proposed method places fewer limitations on the system settings such as the number of BS antennas, the number of users, and the number of coherent channel usage compared to existing blind estimation methods. Simulation results show that the proposed algorithm provides better performance for a moderate RB size, a high-order of QAM scheme, and a smaller ratio of the number of BS antennas and mobile terminals （N/K）. For a reasonably small N/K （order of 10）, the proposed scheme achieves a lower symbol error probability than the conventional pilot-based estimation approach.

关键词： Massive MIMO Channel estimation Resource block Turbo coding Mobile terminal

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Engineered chitosan for improved 3D tissue growth through Paxillin-FAK-ERK activation

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Regenerative Biomaterials 2020年第2期7卷 141-151页

作者： Md Abdul Kafi Khudishta Aktar Mitsugu Todo Ravinder dahiya BEST Group School of EngineeringUniversity of GlasgowGlasgow G128QQUK Department of Microbiology and Hygiene Bangladesh Agricultural UniversityMymensingh 2202Bangladesh Research Institute for Applied Mechanics Kyushu UniversityKasugaFukuokaJapan

Scaffold engineering has attracted significant attention for three-dimensional(3D)growth,prolifer-ation and differentiation of stem cells in *** available scaffolds suffer from issues such as poor ability for cell adhesion,migration and *** paper addresses these issues with 3D porous chitosan scaffold,fabricated and functionalized with cysteine-terminated Arg-Gly-Asp(Cys-RGD)tri-peptide on their *** study reveals that the compressive moduli of the scaffold is independent to RGD functionalization but shows dependence on the applied freezing temperature(TM)during the fabrication *** low freezing TM(-80℃)produces scaffold with high compressive moduli(14.64±1.38 kPa)and high TM(-30℃)produces scaffold with low compressive moduli(5.6±0.38 kPa).The Cys-RGD functionalized scaffolds lead to significant improvements in adhesion(150%)and proliferation(300%)of human mesenchymal stem cell(hMSC).The RGD-integrin coupling activates the focal adhesion signaling(Paxillin-FAK ERK)path-ways,as confirmed by the expression of p-Paxillin,p-FAK and p-ERK protein,and results in the observed improvement of cell adhesion and *** proliferation of hMSC on RGD func-tionalized surface was evaluated with scanning electron microscopy imaging and distribution though pore was confirmed by histochemistry of transversely sectioned *** hMSC adhe-sion and proliferation in scaffold with high compressive moduli showed a constant enhancement(with a slope value 9.97)of compressive strength throughout the experimental period of 28 *** improved cell adhesion and proliferation with RGD functionalized chitosan scaffold,together with their mechanical stability,will enable new interesting avenues for 3D cell growth and differen-tiation in numerous applications including regenerative tissue implants.

关键词： adhesion signaling chitosan hMSC porous scaffold proliferation Cys-RGD tssue engineering

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Energy autonomous electronic skin

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npj Flexible Electronics 2019年第1期3卷 1-24页

作者： Carlos García Núñez Libu Manjakkal Ravinder dahiya Bendable Electronics and Sensing Technologies(BEST)Group School of EngineeringUniversity of GlasgowG128QQ GlasgowUK Scottish Universities Physics Alliance(SUPA) Institute of Thin FilmsSensors&Imaging(TFSI)University of the West of ScotlandPaisley PA12BEUK

Energy autonomy is key to the next generation portable and wearable systems for several *** these,the electronic-skin or e-skin is currently a matter of intensive investigations due to its wider applicability in areas,ranging from robotics to digital health,fashion and internet of things(IoT).The high density of multiple types of electronic components(***,actuators,electronics,etc.)required in e-skin,and the need to power them without adding heavy batteries,have fuelled the development of compact flexible energy systems to realize self-powered or energy-autonomous *** compact and wearable energy systems consisting of energy harvesters,energy storage devices,low-power electronics and efficient/wireless power transfer-based technologies,are expected to revolutionize the market for wearable systems and in particular for *** paper reviews the development in the field of self-powered e-skin,particularly focussing on the available energy-harvesting technologies,high capacity energy storage devices,and high efficiency power transmission *** paper highlights the key challenges,critical design strategies,and most promising materials for the development of an energy-autonomous e-skin for robotics,prosthetics and wearable *** paper will complement other reviews on e-skin,which have focussed on the type of sensors and electronics components.

关键词： electronic autonomous harvesting

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Organic bulk heterojunction enabled with nanocapsules of hydrate vanadium pentaoxide layer for high responsivity self-powered photodetector

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Journal of Semiconductors 2022年第9期43卷 39-45页

作者： Hemraj dahiya Anupam Agrawal Ganesh D.Sharma Abhishek Kumar Singh The LNM Institute of Information Technology Department of PhysicsJaipurRajasthan 302031India Bhilai Institute of Technology DurgChhattisgarh491001India Rajiv Gandhi Institute of Petroleum Technology Department of Electronics EngineeringAmethiU.P.229304India

This article demonstrates the fabrication of organic-based devices using a low-cost solution-processable technique.A blended heterojunction of chlorine substituted 2D-conjugated polymer PBDB-T-2Cl,and PC71BM supported nanocapsules hy-drate vanadium penta oxides(HVO)as hole transport layer(HTL)based photodetector fabricated on an ITO coated glass sub-strate under ambient *** device forms an excellent organic junction diode with a good rectification ratio of~*** device has also shown excellent photodetection properties under photoconductive mode(at reverse bias)and zero bias for green light wavelength.A very high responsivity of~6500 mA/W and high external quantum efficiency(EQE)of 1400%have been reported in the *** proposed organic photodetector exhibits an excellent response and recovery time of~30 and~40 ms,respectively.

关键词： self-powered detector green light sensor HVO PBDB-T-2Cl detector processable solution sensor

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