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Semiconductor based photocatalysts for detoxification of emerging pharmaceutical pollutants from aquatic systems: A critical review

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Nano Materials Science 2021年第1期3卷 25-46页

作者： prasenjit kar Komal Shukla Pratyush Jain Govindasamy Sathiyan Raju Kumar Gupta Department of Chemical Engineering Indian Institute of Technology KanpurKanpur208016Uttar PradeshIndia Center for Environmental Science and Engineering Indian Institute of Technology KanpurKanpur208016Uttar PradeshIndia

The presence of emerging pharmaceutical pollutants at low concentration levels in the surface and ground water has caused a potential threat to the marine and human *** emerging pharmaceutical pollutants generally include analgesics and anti-inflammatories,lipid-lowering drugs,antiepileptics,antibiotics,and β-blockers *** recent years,various processes have been developed and advanced oxidation process is the most effective for decontamination of emerging pharmaceutical pollutants till *** based photocatalysis technology has recently received a great interest for the removal of new emerging pharmaceutical *** review article highlights the removal of emerging pharmaceutical pollutants especially through photocatalysis as well as recent progress using different *** focus has been given over fundamental key dynamics processes of nanomaterials and degradation pathways of emerging pharmaceutical ***,this review concludes with the perspectives and outlook over future developments in photocatalysis technology for the degradation of emerging pharmaceutical pollutants leading to a solution for realworld in near future.

关键词： Emerging pharmaceutical pollutants Photocatalysis Nanomaterials Degradation mechanism

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In-Situ Hydrothermal Synthesis of Bi–Bi2O2CO3 Heterojunction Photocatalyst with Enhanced Visible Light Photocatalytic Activity

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Nano-Micro Letters 2017年第2期9卷 58-67页

作者： prasenjit kar Tuhin Kumar Maji Ramesh Nandi Peter Lemmens Samir Kumar Pal Department of Chemical Biological and Macromolecular Sciences S.N.Bose National Centre for Basic SciencesBlock JDSector ⅢSaltLakeKolkata 700106India Institute for Condensed Matter Physics TU BraunschweigMendelssohnstraße 338106 BrunswickGermany Laboratory for Emerging Nanometrology TU BraunschweigBrunswickGermany

Bismuth containing nanomaterials recently received increasing attention with respect to environmental applications because of their low cost, high stability and nontoxicity. In this work, Bi–Bi_2O_2CO_3 heterojunctions were fabricated by in-situ decoration of Bi nanoparticles on Bi_2O_2CO_3 nanosheets via a simple hydrothermal synthesis approach. X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM) and high-resolution TEM(HRTEM) were used to confirm the morphology of the nanosheet-like heterostructure of the Bi–Bi_2O_2CO_3 composite. Detailed ultrafast electronic spectroscopy reveals that the in-situ decoration of Bi nanoparticles on Bi_2O_2CO_3 nanosheets exhibit a dramatically enhanced electron-hole pair separation rate, which results in an extraordinarily high photocatalytic activity for the degradation of a model organic dye, methylene blue(MB) under visible light illumination. Cycling experiments revealed a good photochemical stability of the Bi–Bi_2O_2CO_3 heterojunction under repeated irradiation. Photocurrent measurements further indicated that the heterojunction incredibly enhanced the charge generation and suppressed the charge recombination of photogenerated electron-hole pairs.

关键词： Bi nanoparticles Bi–Bi2O2CO3 nanosheets Heterojunction Hydrothermal method Charge separation Visible light photocatalytic activity

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Semiconductor based photocatalysts for detoxification of emerging pharmaceutical pollutants from aquatic systems: A critical review

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纳米材料科学 2021年第1期

作者： prasenjit kar Komal Shukla Pratyush Jain Govindasamy Sathiyan Raju Kumar Gupta

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