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Enhanced hydrogen production activity over BiOX–TiO2 under solar irradiation:Improved charge transfer through bismuth oxide clusters

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Journal of Energy Chemistry 2017年第3期26卷 390-397页

作者： police anil kumar reddy Chennaiahgari Manvitha Pullagurala Venkata Laxma reddy Ki-Hyun Kim Valluri Durga kumari Department of Civil&Environmental Engineering Hanyang University222WangsimniRoSeoul 133-791Republic of Korea Inorganic and Physical Chemistry Division Indian Institute of Chemical TechnologyHyderabad 500 607India Sarojini Naidu Vanitha Mahavidyala Osmania UniversityHyderabad 500 001India Program in Environmental Science and Engineering University of Texas El PasoEl PasoTexas 799038USA

A series of titania nanoparticles and nanotubes deposited with various quantities of bismuth（Bi） were prepared via sol-gel and hydrothermal methods, respectively. They were then characterized using X-ray diffraction spectroscopy（XRD）, X-ray photo electron spectroscopy（XPS）, UV–Vis diffused reflectance spectra（DRS）, photoluminescence spectra（PLS）, transmission electron microscopy（TEM）, energy dispersive analysis of X-rays（EDAX）, and BET surface analysis. These catalysts were employed for the photocatalytic production of hydrogen from a mixture of pure water and glycerol under solar light irradiation. The presence of the Bispecies was found to play a vital role in enhancing activity while minimizing electron hole recombination（relative to bare TiO）. The nanotubes exhibited better activity than the nanoparticles of Bi-deposited TiO, showing the significance of the morphology; however, photocatalytic activity is predominantly dependent on the deposition of bismuth. The activity increased by approximately an order of magnitude at the optimum concentration of Bi deposited over TiO（2 wt%）. The presence of the Bispecies played a vital role in minimizing electron hole recombination, resulting in higher activity compared to bare TiO.

关键词： Bismuth TiO2 nanotubes Visible photocatalysis Water splitting Hydrogen

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Photocatalytic Degradation of Isoproturon Pesticide on C, N and S Doped TiO2

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Journal of Water Resource and Protection 2010年第3期2卷 235-244页

作者： police anil kumar reddy Pulagurla Venkata Laxma reddy Vutukuri Maitrey Sharma Basavaraju Srinivas Valluri Durga kumari Machiraju Subrahmanyam 不详

TiO2 doped with C, N and S (TCNS photocatalyst) was prepared by hydrolysis process using titanium iso-propoxide and thiourea. The prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photo electron spectroscopy (XPS), BET surface area, FTIR and diffuse reflectance spectra (DRS). The results showed that the prepared catalysts are anatase type and nanosized par-ticles. The catalysts exhibited stronger absorption in the visible light region with a red shift in the adsorption edge. The photocatalytic activity of TCNS photocatalysts was evaluated by the photocatalytic degradation of isoproturon pesticide in aqueous solution. In the present study the maximum activity was achieved for TCNS5 catalyst at neutral pH with 1 g L-1 catalyst amount and at 1.14 x 10-4 M concentration of the pesticide solution. The TCNS photocatalysts showed higher phtocatalytic activity under solar light irradiation. This is attributed to the synergetic effects of red shift in the absorption edge, higher surface area and the inhibition of charge carrier recombination process.

关键词： Isoproturon Pesticide Degradation C N and S Doped TiO2 Visible Light Active Catalysts

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Bismuth Modified Porous Silica Preparation,Characterization and Photocatalytic Activity Evaluation for Degradation of Isoproturon

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Journal of Materials Science & Technology 2013年第7期29卷 639-646页

作者： anil kumar reddy police Srinivas Basavaraju Durga kumari Valluri Subrahmanyam Machiraju Inorganic and Physical Chemistry Division Indian Institute of Chemical TechnologyHyderabad 500607India

Porous silica prepared by using an acrylic emulsion has been impregnated with bismuth ion resulting in Bi2Si05 species containing surface. The as-prepared materials have been characterized by X-ray diffraction spectroscopy （XRD）, X-ray photoelectron spectroscopy （XPS）, UV-Vis diffuse reflectance spectroscopy （UV-Vis DRS）, scanning electron microscopy （SEM）, energy dispersive analysis of X-ray （EDAX）, transmission electron microscopy （TEM）, Fourier transform infrared spectroscopy （FTIR） and N2 adsorption/desorption techniques. EDAX analysis confirms the penetration of bismuth ions into the framework of silica to form Bi2SiO5, which is substantiated by XRD. The UV-Vis DRS shows that the catalysts are optically active and XPS confirms the inclusion of bismuth into the framework of silica. FTIR spectra illustrate the formation of Bi-O-Si linkages in the porous silica framework. SEM and TEM show the spherical morphology, whereas N2 adsorption/desorption study confirms the porosity of the prepared materials. The photocatalytic activity of the material is evaluated for the degradation of isoproturon herbicide and it is found that the material is active as compared to the commercial P-25 Degussa TiO2.

关键词： Acrylic emulsion Emulsion polymerization technique Porous silica Bi2SiO5 Photocatalyfic degradation lsoproturon

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