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Electrodeposition of cobalt from aqueous sulphate solutions in the presence of tetra ethyl ammonium bromide

Transactions of Nonferrous Metals Society of China 2015年第6期25卷 2047-2053页

作者： pinak patnaik Subrat Kumar PADHY Bankim Chandra TRIPATHY Indra Narayan BHATTACHARYA Raja Kishore PARAMGURU CSIR-Institute of Minerals and Materials Technology Hydro and Electrometallurgy Department Academy of Scientific and Innovative Research Training and Development Complex School of Mechanical Engineering KIIT University

The effect of tetra ethyl ammonium bromide （TEAB） as an additive on the structural, morphological characteristics of the cobalt metal produced from aqueous sulphate solutions was investigated. The concentration of TEAB was varied in a range of 1-50 mg/L to evaluate its effect on current efficiency, energy consumption and quality of electrodeposited cobalt metal. Smooth and bright deposits of cobalt were obtained at low concentration of TEAB （10 mg/L） maintaining a current efficiency of 99.6%, with a low energy consumption of 2.38 kW＇h/kg. X-ray diffraction studies reveal that （100） plane is the most preferred plane of crystal growth during cobalt electrodeposition. Scanning electron micrographs indicate that smooth and uniform deposit of cobalt is obtained at 10 mg/L beyond which the deposit quality deteriorates. Cyclic voltammetric studies indicate that the presence of TEAB in the electrolytic bath polarizes the cathode and decreases the cathodic current considerably. XPS results confirm the electrodeposition of high pure cobalt with no sign of chemical bonding with TEAB as evident from the FTIR spectra.

关键词： cobalt tetra ethyl ammonium bromide (TEAB) electrodeposition polarisation study current efficiency deposit morphology

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Synthesis and characterization of fibrous nickel hydroxide obtained from spent nickel catalyst

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Transactions of Nonferrous Metals Society of China 2013年第10期23卷 2977-2983页

作者： pinak patnaik Avijit BISWAL Bankim Chandra TRIPATHY Sangitarani PRADHAN Barsha DASH Ramasamy SAKTHIVEL T.SUBBAIAH CSIR-Institute of Minerals and Materials Technology Academy of Scientific and Innovative Research (AcSIR)

The recovery of nickel from spent nickel catalyst for the preparation of nickel hydroxide was studied. Nickel was extracted from the spent catalyst by acid leaching with 1 mol/L sulfuric acid at 90 ℃. Purified nickel solution was used in the preparation of nickel hydroxide. Three different methods, namely urea hydrolysis, conventional, and hydrothermal methods, of precipitation using NaOH were employed to get various nickel hydroxides samples named as Ni（OH）E-U, Ni（OH）2-C, and Ni（OH）E-H, respectively. Hydrothermal treatment induced better crystallinity in the Ni（OH）2 compared with conventional method. Both Ni（OH）2-C and Ni（OH）E-H samples have mixed phases of fl-Ni（OH）2 and a＊-Ni（OH）E.0.75H20 phases, whereas Ni（OH）2-U has only a＊-Ni（OH）2.0.75H20. TEM image of Ni（OH）E-U sample shows rod-like Ni（OH）2 structures. Among all, Ni（OH）2-U shows the best electrochemical activity.

关键词： spent nickel catalyst fibrous nickel hydroxide recovery

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