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Advanced Oxidation Process for DNAN Using UV/H2O2

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Engineering 2019年第5期5卷 849-854页

作者： Hailei Su Christos Christodoulatos Benjamin Smolinski per arienti Greg O’Connor Xiaoguang meng Center for Environmental Systems Stevens Institute of TechnologyHobokenNJ 07030USA US Army RDECOm-ARDEC PicatinnyNJ 07806USA

2,4-Dinitroanisole(DNAN)is an important component of insensitive munitions that is anticipated to replace 2,4,6-trinitrotoluene(TNT)in munitions *** hydrogen peroxide(H2O2)oxidation experiments and chemical analyses were conducted to study the effect of initial pH and H2O2 dosage on the kinetics of DNAN decomposition and the reaction *** results show that DNAN degradation followed zero-order kinetics when a 250 ppm DNAN solution was treated with ultraviolet(UV)light and 1500–4500 ppm H2O2 in an initial pH range of 4–***,when the H2O2 concentration was 750 ppm,DNAN degradation followed pseudo-first-order *** results indicate that DNAN can easily be oxidized by UV/H2O2 *** the H2O2 dosage was 1500 ppm and the initial pH was 7,DNAN was reduced from 250 ppm to less than 1 ppm in 3 ***,the total organic carbon(TOC)and total carbon(TC)concentrations were reduced slowly from 100 to less than 70 ppm carbon(C)in 3 h,and decreased to about 5 ppm after 9 h of treatment,suggesting the formation of other organic *** reaction intermediates were oxidized to carbon dioxide(CO2)at a slower rate than the oxidation of ***2 was emitted from the solution because the solution pH decreased rapidly to about 3 during the UV/H2O2 *** of the nitrogen in DNAN was converted to nitrate by UV/H2O2 oxidation after 9 h of *** research results indicate that UV/H2O2 oxidation is a promising technique for the treatment of DNAN in wastewater.

关键词： 2,4-Dinitroanisole Advanced oxidation processes Wastewater treatment Photocatalysis

Classifying moisture sources associated with snowfall in the mountains of Lesotho

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Journal of mountain Science 2024年第6期21卷 1941-1953页

作者： Alexi m.mARINAKI Jennifer m.FITCHETT School of Geography Archaeology and Environmental StudiesUniversity of the WitwatersrandPrivate Bag X3Wits 2050South Africa

An average of eight snowfall events occur each year in the eastern Lesotho *** snowfall events are typically associated with cut-off low(CoLs)systems and mid-latitude ***,the moisture sources of the snowfall are unclassified and *** Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)model,an air mass back trajectory model,has been used to evaluate moisture source waters locally in southern Africa and internationally in China and *** study uses HYSPLIT to determine the source moisture of snow in Lesotho.A list of all 82 snowfall events in Lesotho spanning 2017 to 2022 was compiled using the Snow Report SA Instagram page,including the date and location of snowfall.A 72-hour back trajectory for each snowfall event was initiated for both Afriski and the whole of *** amounts to models of moisture source trajectories for 28 and 82 snowfall days,*** air mass pathways are classified according to their frequency per snowfall event,per month in the snow season,per year and for the full *** this,associated moisture source regions and dominant air mass trajectories were *** study reports that the air mass trajectories associated with Afriski and Lesotho as a whole are very *** most common pathway of air mass trajectories transporting snow-bearing moisture to Lesotho was an inland trajectory from the northern regions of southern *** pathway makes up 16.6%of all trajectories reported and is associated with the Angola Low,the Congo Air Boundary and the *** High Pressure.

关键词： Eastern Lesotho Highlands Afriski Snow Cut-off Lows HYSPLIT Synoptic Climatology

The Triple Helix of innovation as a double game involving domestic and foreign actors

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Journal of Data and Information Science 2024年第1期9卷 82-100页

作者： Eustache mêgnigbêto University of Antwerp Antwerpen 2000Belgium

Purpose:The collaboration relationships between innovation actors at a geographic level may be considered as grouping two separate layers,the domestic and the *** the level of each layer,the relationships and the actors involved constitute a Triple Helix *** paper distinguished three levels of analysis:the global grouping together all actors,the domestic grouping together domestic actors,and the foreign related to only actors from partner ***/methodology/approach:Bibliographic records data from the Web of Science for South Korea and West Africa breakdown per innovation actors and distinguishing domestic and international collaboration are analyzed with game *** core,the Shapley value,and the nucleolus are computed at the three levels to measure the synergy between ***:The synergy operates more in South Korea than in West Africa;the government is more present in West Africa than in South Korea;domestic actors create more synergy in South Korea,but foreign more in West Africa;South Korea can consume all the foreign synergy,which is not the case of West *** limitations:Research data are limited to publication records;techniques and methods used may be extended to other research *** implications:West African governments should increase their investment in science,technology,and innovation to benefit more from the synergy their innovation actors contributed at the foreign ***,the results of the current study may not be sufficient to prove that greater investment will yield benefits from foreign ***/value:This paper uses game theory to assess innovation systems by computing the contribution of foreign actors to knowledge production at an area *** proposes an indicator to this end.

关键词： Triple Helix Game theory Core Shapley value Nucleolus South Korea West Africa

This year's Nobel Prize to gastroenterology:Robin Warren and Barry marshall awarded for their discovery of Helicobacter pylori as pathogen in the gastrointestinal tract

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World Journal of Gastroenterology 2006年第19期12卷 3126-3127页

作者： per m Hellstr(o|¨)m Department of medicine Unit of Gastroenterology and Hepatology Karolinska University HospitalSolnaStockholmSweden

TO THE EDITORPeptic ulcer disease is a major health care concern in the society today, in view of personal suffering as well as economical health care costs.

关键词： Helicobacter pylori Nobel Prize Gastroenterology Helicobacter Infections History, 21st Century Humans Inflammation Peptic Ulcer Stomach Neoplasms

BOUNDARY PROCEDURES FOR THE TImE-DEPENDENT BURGERS' EQUATION UNDER UNCERTAINTY

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Acta mathematica Scientia 2010年第2期30卷 539-550页

作者： per Pettersson Jan Nordstrm Gianluca Iaccarino mechanical Engineering and Institute for Computational mathematical Engineering Stanford University Division of Scientific Computing Department of Information TechnologyUppsala University School of mechanical Industrial and Aeronautical EngineeringUniversity of the Witvatersrand Department of Aeronautics and Systems Integration FOIThe Swedish Defense Research Agency

The Burgers＇ equation with uncertain initial and boundary conditions is approximated using a Polynomial Chaos Expansion （PCE） approach where the solution is represented as a series of stochastic, orthogonal polynomials. The resulting truncated PCE system is solved using a novel numerical discretization method based on spatial derivative operators satisfying the summation by parts property and weak boundary conditions to ensure stability. The resulting PCE solution yields an accurate quantitative description of the stochastic evolution of the system, provided that appropriate boundary conditions are available. The specification of the boundary data is shown to influence the solution; we will discuss the problematic implications of the lack of precisely characterized boundary data and possible ways of imposing stable and accurate boundary conditions.

关键词： stochastic Burgers' equation uncertainty quantification polynomial chaos

Complexed amino acid minerals ***-glycinate chelated minerals:Impact on the performance of old laying hens

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Animal Nutrition 2024年第1期16卷 395-408页

作者： marcos J.B.Santos maria C.m.m.Ludke Leandro m.Silva Carlos B.V.Rabello mércia R.Barros Fabiano S.Costa Clariana S.Santos Jamille S.S.Wanderley Department of Animal Science Rural Federal University of PernambucoRecifePEBrazil Department of Veterinary Science Rural Federal University of PernambucoRecifePEBrazil

The present study was to evaluate the effect of trace minerals(Zn,mn,and Cu)from complexed amino acid minerals(ZmCAA)and bis-glycinate chelated minerals(ZmCGly)in laying hen diets on performance,internal and external egg quality,yolk mineral deposition,intestinal morphometry,and bone *** 78 to 98 weeks of age,400 White LSL-Lite strain laying hens were distributed in a randomized design with 4 treatments with 10 replicates per *** were distributed in a 2×2 factorial arrangement using either Zn,mn,and Cu of ZmCAA or ZmCGly source at 2 levels:low(20,20,and 3.5 mg/kg of Zn,mn,and Cu,respectively)or high(40,40,and 7 mg/kg of Zn,mn,and Cu,respectively).The analysis of variance was performed,and in cases where differences were observed,the means were compared using Tukey?s test(Pmineral supplementation had a significant impact on the performance of laying *** fed ZmCAA had higher egg production(P=0.01),egg weight(P=0.02),egg mass(P=0.01),and lower feed conversion ratio(P=0.05)compared to those fed *** ZmCAA supplementation showed higher albumen height(P=0.01),albumen weight(P=0.01),and eggshell thickness(Pmn(Pmetry(PmCAA *** the small intestine,ZmCAA resulted in longer villi(P=0.02)and shorter crypt depth(P=0.01)in the *** and ileum measurements were influenced by the level and source of trace minerals(PmCAA exhibited superior performance,egg quality,deposition of trace minerals in the egg yolk,and bone density compared to hens fed *** this study,older laying hens supplemented with ZmCAA at lower levels demonstrated adequate levels of supplementation.

关键词： Bis-glycinates metal-amino acids Radiodensity Trace minerals

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Laparoscopic distal pancreatectomy for adenocarcinoma of the pancreas

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World Journal of Gastroenterology 2014年第37期20卷 13402-13411页

作者： Bergthor Bjrnsson per Sandstrm Department of Surgery County Council of stergtland and Department of Clinical and Experimental MedicineFaculty of Health SciencesLinkping University

Since the first report on laparoscopic distal pancreatectomy (LDP) appeared in the 1990s, the procedure has been performed increasingly frequently to treat both benign and malignant lesions of the pancreas. many earlier publications have shown LDP to be a good alternative to open distal pancreatectomy for benign lesions, although this has never been studied in a prospective, randomized manner. The evidence for the use of LDP to treat adenocarcinoma of the pancreas is not as well established. The purpose of this review is to evaluate the current evidence for LDP in cases of pancreatic adenocarcinoma. We conducted a review of English language publications reporting LDP results between 1990 and 2013. All studies reporting results in patients with histologically proven pancreatic adenocarcinoma were included. Thirty-nine publications were found and included in the results for a total of 309 cases of pancreatic adenocarcinoma (potential double publications were not eliminated). most LDP procedures are performed in selected cases and generally involve smaller tumors than open distal pancreatectomy (ODP) procedures. Some of the papers report unselected cases and include procedures on larger tumors. The number of lymph nodes harvested using LDP is comparable to the number obtained with ODP, as is the frequency of R0 resections. Current data suggest that similar short term oncological results can be obtained using LDP as those obtained using ODP.

关键词： Adenocarcinoma of the pancreas Laparoscopy Distal pancreatectomy Surgical margins Pancreatic resection

Oxidized organic molecules in the tropical free troposphere over Amazonia

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National Science Review 2024年第1期11卷 174-184页

作者： Qiaozhi Zha Diego Aliaga Radovan Krejci Victoria A.Sinclair Cheng Wu Giancarlo Ciarelli Wiebke Scholz Liine Heikkinen Eva Partoll Yvette Gramlich Wei Huang markus Leiminger Joonas Enroth Otso per?kyl? Runlong Cai Xuemeng Chen Alkuin maximilian Koenig Fernando Velarde Isabel moreno Tuukka Pet?j? Paulo Artaxo Paolo Laj Armin Hansel Samara Carbone markku Kulmala marcos Andrade Douglas Worsnop Claudia mohr Federico Bianchi Institute for Atmospheric and Earth System Research/Physics University of Helsinki Joint International Research Laboratory of Atmospheric and Earth System Sciences Nanjing University Department of Environmental Science & Bolin Centre for Climate Research Stockholm University Department of Chemistry and molecular Biology University of Gothenburg Institute for Ion and Applied Physics University of Innsbruck Ionicon Analytik GmbH Laboratory for Atmospheric Physics Institute for Physics Research Universidad Mayor de San Andrés Institute of Physics University of Sao Paulo Institute for Geosciences and Environmental Research (IGE) University of Grenoble Alpes Agrarian Sciences Institute Federal University of Uberl?ndia Beijing Advanced Innovation Center for Soft matter Science and Engineering Beijing University of Chemical Technology Department of Atmospheric and Oceanic Sciences University of Maryland Aerodyne Research Inc. Department of Environmental System Science ETH Zürich Switzerland and Laboratory of Atmospheric Chemistry Paul Scherrer Institute

New particle formation(NPF) in the tropical free troposphere(FT) is a globally important source of cloud condensation nuclei, affecting cloud properties and climate. Oxidized organic molecules(OOms)produced from biogenic volatile organic compounds are believed to contribute to aerosol formation in the tropical FT, but without direct chemical observations. We performed in situ molecular-level OOms measurements at the Bolivian station Chacaltaya at 5240 m above sea level, on the western edge of Amazonia. For the first time, we demonstrate the presence of OOms, mainly with 4–5 carbon atoms, in both gas-phase and particle-phase(in terms of mass contribution) measurements in tropical FT air from Amazonia. These observations, combined with air mass history analyses, indicate that the observed OOms are linked to isoprene emitted from the rainforests hundreds of kilometers away. Based on particle-phase measurements, we find that these compounds can contribute to NPF, at least the growth of newly formed nanoparticles, in the tropical FT on a continental scale. Thus, our study is a fundamental and significant step in understanding the aerosol formation process in the tropical FT.

关键词： oxidized organic molecules tropical aerosol formation Amazon free troposphere

Quantitative and Qualitative Responses of Hydroponic Tomato Production to Different Levels of Salinity

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Phyton-International Journal of Experimental Botany 2024年第6期93卷 1311-1323页

作者： Khalid A.Al-Gaadi Ahmed m.Zeyada ElKamil Tola Abdullah m.Alhamdan Khalid A.m.Ahmed Rangaswamy madugundu mohamed K.Edrris Department of Agricultural Engineering College of Food and Agriculture SciencesKing Saud UniversityRiyadh11451Saudi Arabia Precision Agriculture Research Chair Deanship of Scientific ResearchKing Saud UniversityRiyadh11451Saudi Arabia Chair of Dates Industry&Technology Deanship of Scientific ResearchKing Saud UniversityRiyadh11451Saudi Arabia Agricultural Research Centre Agricultural Engineering Research Institute(AEnRI)Giza12619Egypt

From economic and nutritional points of view,tomato is,historically,considered one of the most important *** signiﬁcant yield reduction,most commercial cultivars of tomato crops are sensitive to moderate levels of ***,high levels of salt stress can negatively affect the yield and quality of tomato ***,this study was conducted to evaluate the yield and fruit quality of three tomato cultivars(Forester,Ghandowra-F1,and Feisty-Red)cultivated hydroponically,under three different levels of nutrient solution *** of tomato fruits was performed based on quantity(number and weight of fruits,and total fruit yield),physical quality(color andﬁrmness),and chemical quality(refractometric index“Brix”,pH,EC,K^(+),Na^(+),and NO_(3)-).Experiments were conducted using three salinity levels of the nutrient solution with electrical conductivity values(dSm^(-1))of 2.5(control),6.0,and *** showed that the studied tomato cultivars were signiﬁcantly inﬂuenced by high salinity(9.5 dSm^(-1))in comparison to the low(2.5 dSm^(-1))and medium(6.0 dSm^(-1))levels of *** average,the highest fruit weight per plant of 1944.84 g and total fruit yield of 4.42 kgm^(-2) were observed at the low salinity level;however,no signiﬁcant differences were obtained in the two yield factors(single fruit weight and total fruit yield)for the low and medium salinity *** the other hand,a signiﬁcant reduction in tomato yield(31%)was associated with the high salinity level compared to the yield at low and medium salinity *** of physical quality parameters showed highly signiﬁcant differences among all salinity *** average,the maximum value of color change(1.72)was associated with the medium salinity level,and the maximum value ofﬁrmness(9.61 Ncm^(-1))was recorded at the high salinity *** levels and tomato cultivars introduced signiﬁcant differences in chemical quality parameters;however,no signiﬁcant differences in these

关键词： Quality cultivars yield color ﬁrmness brix