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Energy and Built Environment 2024年第1期5卷 58-69页

作者： Jie Li Yuan Zhang Ziyang Zhu Jiangtian Zhu Jing luo Fen peng Xiaoqin Sun School of Energy and Power Engineering Changsha University of Science and TechnologyChangshaHunan 410114PR China

Trombe wall and phase change materials(PCMs)are two effective ways to regulate indoor thermal ***,Trombe wall surfers from overheating in summer and PCMs suffer from low heat transfer rate caused by the limited thermal *** compensate the shortcomings of the two methods,this paper proposed a Trombe wall system integrated with *** on a light-weight building envelope in Changsha,China,the thermal comfort of 10 kinds of Trombe wall systems with PCMs with a melting temperature of 18-28℃ were *** the integrated indoor discomfort duration(I_(D)),integrated indoor discomfort degree-hour(I_(DH)),indoor air temperature(T_(in)),PCM liquid fraction(γ)and heat flux across wall(q)as evaluation indexes,the indoor thermal comfort was assessed in hot summer and cold winter *** show that the Trombe wall helped PCMs complete the phase change process *** wall with PCM25 next to the wall inner surface possessed the lowest annual I_(D) and I_(DH),as 2877 h and 12,974℃·h,*** with the values in a traditional building,the I_(D) and I_(DH) were reduced by 7.01% and 14.14%.In order to give full play to the heat storage and heat release of the Trombe wall with PCMs,PCMs with phase change temperature 7℃ lower than the peak ambient temperature in summer or 8℃ higher than the winter night temperature was recommended according to regional climate conditions.

关键词： Trombe wall Phase change materials Integrated indoor discomfort duration Integrated discomfort degree-hour Liquid fraction

Stereodivergent Benzylic Substitution of Racemic Secondary Benzyl Esters Enabled by Pd/Cu Dual Catalysis

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CCS Chemistry 2024年第10期6卷 2452-2464页

作者： Youbin peng Guanlin Li Chongyu Han Yicong luo Xiaohong Huo Wanbin Zhang Shanghai Key Laboratory of Molecular Engineering of Chiral Drugs Frontiers Science Center for Transformative MoleculesSchool of Chemistry and Chemical EngineeringShanghai Jiao Tong UniversityShanghai 200240

Transition-metal-catalyzed asymmetric benzylic substitution of racemic benzyl esters is an efficient and straightforward route towards the construction of benzylic stereocenters but remains a challenge,due to the difficulty encountered in the suppression ofβ–H elimination and asymmetric ***,we successfully developed a highly diastereo-and enantioselective benzylic substitution of racemic 1-(aryl)alkyl esters with aldimine esters enabled by Pd/Cu dual *** array of enantioenrichedα-benzyl substitutedα-amino acids containing vicinal stereocenters were prepared with high levels of diastereo-and enantioselectivities(up to>20:1 dr and>99%ee)and the practicability of the products was further illustrated via their diverse *** dynamic kinetic asymmetric transformation process of the racemic benzyl esters was investigated experimentally and by computational studies.

关键词： amino acids asymmetric catalysis benzylic substitution bimetallic catalysis stereodivergent synthesis

Lightweight,Strong and High Heat-Resistant Poly(lactide acid)Foams via Microcellular Injection Molding with Self-Assembly Nucleating Agent

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Chinese Journal of Polymer Science 2024年第6期42卷 739-750页

作者： Xiao-Hu Bing Wen-Yu Ma Ming-Hui Wu peng Gao Xiao Zhou Hai-Bin luo Long Wang Wen-Ge Zheng School of materials Science and Engineering Shanghai UniversityShanghai200444China Ningbo Key Lab of Polymer Materials Ningbo Institute of Material Technology and EngineeringChinese Academy of SciencesNingbo315201China University of Chinese Academy of Sciences Beijing100049China

Poly(lactide acid)(PLA)foams have shown considerable promise as eco-friendly alternatives to nondegradable plastic foams,such as polystyrene(PS)***,PLA foam typically suffers from low heat-resistance and poor cellular structure stemming from its inherent slow crystallization rate and low melt *** this study,a high-performance PLA foam with well-defined cell morphology,exceptional strength and enhanced heat-resistance was successfully fabricated via a core-back microcellular injection molding(MIM)*** scanning calorimetry(DSC)results revealed that the added hydrazine-based nucleating agent(HNA)significantly increased the crystallization temperature and accelerated the crystallization process of ***,the addition of a 1.5 wt%of HNA led to a significant reduction in PLA’s cell size,from 43.5µm to 2.87µm,and a remarkable increase in cell density,from 1.08×10^(7)cells/cm^(3)to 2.15×10^(10)cells/cm^(3).This enhancement resulted in a final crystallinity of approximately 55.7%for the PLA blend foam,a marked improvement compared to the pure PLA ***,at 1.5 wt%HNA concentration,the tensile strength and tensile toughness of PLA blend foams demonstrated remarkable improvements of 136%and 463%,***,the Vicat softening temperature of PLA blend foam increased significantly to 134.8°C,whereas the pure PLA foam exhibited only about 59.7℃.These findings underscore the potential for the preparation of lightweight injection-molded PLA foam with enhanced toughness and heat-resistance,which offers a viable approach for the production of high-performance PLA foams suitable for large-scale applications.

关键词： Poly(lactide acid) Nucleating agent Microcellular injection molding Heat-resistance Toughness

Multi-stimuli-responsive aggregation-induced emission copper iodide cluster

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Science China Chemistry 2024年第4期67卷 1193-1197页

作者： Bo Li Yuan-Yuan Liu peng luo Ye-Ru Liu Ying-Jun Chen Kai Li Shuang-Quan Zang College of Chemistry and Pharmacy Engineering Nanyang Normal UniversityNanyang 473061China Green Catalysis Center and College of Chemistry Zhengzhou UniversityZhengzhou 450001China

Stimuli-responsive luminescent materials have attracted significant attention in the development of smart photoactive materials for both fundamental research and technological *** this work,a new copper iodide cluster(1)with aggregationinduced emission(AIE)characteristic,was obtained combining Cu_(4)I_(4) core with rhodamine B derivative ligand.1 has reversible and distinct multi-stimuli-responsive luminescence for external temperature,volatile organic compound,and mechanical ***,1 exhibited unusual large blue shift(84 nm)after being ground,which originated from the change of intermolecular ***,1 exhibits high oxygen quenching efficiency for 82.2% at 1 *** studies showed that the multi-stimuli-responsive luminescence properties of 1 can be attributed to the regulation of cluster-centered luminescence process,metal-to-ligand charge transfer process,halide-to-metal charge transfer luminescence process and aggregationinduced barrier to oxygen *** work not only reports an AIE copper iodide cluster,but also provides a new strategy to develop multi-stimuli-responsive luminescence materials.

关键词： copper iodide cluster aggregation-induced emission multi-stimuli-response

Flotation separation of feldspar from quartz using sodium fluosilicate as a selective depressant

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Rare Metals 2024年第3期43卷 1288-1300页

作者： Xin Hu Xian-Ping luo Zi-Shuai Liu Yong-Bing Zhang He-peng Zhou Zhi-Zhao Yang Xue-Kun Tang Faculty of Resource and Environmental Engineering Jiangxi University of Science and TechnologyGanzhou341000China Yichun Lithium New Energy Industry Research Institute Jiangxi University of Science and TechnologyYichun336000China

The physical and chemical properties of feldspar and quartz are highly similar,thus they cannot be easily separated *** this work,the flotation separation of feldspar from quartz using sodium fluosilicate(Na_(2)SiF_(6);SF)as a selective depressant was ***,the influence mechanism of SF on the selective flotation separation of feldspar and quartz was investigated via flotation tests,chemical analysis of flotation solution,Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS)and contact angle *** results of the flotation tests show that feld spar and quartz without SF treatment have good *** SF treatment,feldspar still has good floatability,whereas quartz has significantly reduced *** solution chemical analysis shows that the functional group plays an important role in depressing the quartz is[SiF_(6)]^(2-).FTIR,XPS and contact angle analysis results show that[SiF_(6)]^(2-)is adsorbed only on the surface of ***,a thin hydrophilic SiOF layer is generated on the surface,which interferes with the adsorption of the collector on the surface of the *** phenomenon leads to a significant reduction in quartz's ***,SF has a good ability to separate feldspar from quartz by flotation.

关键词： Flotation separation Depressants Sodium fluorosilicate Quartz Feldspar

Endovascular treatment of direct carotid cavernous fistula resulting from rupture of intracavernous carotid aneurysm: A case report

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World Journal of Clinical Cases 2024年第11期12卷 1940-1946页

作者： Guang Ouyang Kai-Li Zheng Kuan luo Mu Qiao Yuan Zhu De-rui Pan Department of Neurosurgery Puren Hospital Affiliated to Wuhan University of Science and TechnologyWuhan 430081Hubei ProvinceChina Department of Neurosurgery The Third Hospital of WuhanWuhan 430081Hubei ProvinceChina

BACKGROUND Direct carotid cavernous fistulas(CCFs)are typically the result of a severe traumatic brain ***-flow arteriovenous shunts secondary to rupture of an intracavernous aneurysm,resulting in direct CCFs,are *** use of a pipeline embolization device in conjunction with coils and Onyx glue for treatment of direct high-flow CCF resulting from ruptured cavernous carotid artery aneurysm in a clinical setting is not well *** SUMMARY A 58-year-old woman presented to our department with symptoms of blepharoptosis and intracranial bruits for 1 *** physical examination,there was right eye exophthalmos and ocular motor *** rest of the neurological examination was ***,the patient had no history of head *** patient was treated with a pipeline embolization device in the ipsilateral internal carotid artery across the *** and Onyx were placed through the femoral venous route,followed by placement of the pipeline embolization device with assistance from a balloon-coiling *** intraoperative or perioperative complications *** symptoms of bulbar hyperemia and bruits subsided immediately after the *** Pipeline embolization device in conjunction with coiling and Onyx may be a safe and effective approach for direct CCFs.

关键词： Intravascular therapy Carotid cavernous fistulas Intracavernous carotid aneurysms Case report

Polygon search algorithm for ultra-compact multifunctional integrated photonics design

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Photonics Research 2024年第7期12卷 1527-1541页

作者： TE DU ZHENG peng PEIXIN HUANG ZHAOJIAN ZHANG HANSI MA XINpeng JIANG JIE HUANG MINGYU luo HONGXIN ZOU JUNBO YANG Center of Material Science College of ScienceNational University of Defense TechnologyChangsha 410073China Institute for Quantum Science and Technology College of ScienceNational University of Defense TechnologyChangsha 410073China College of Computer National University of Defense TechnologyChangsha 410073China College of Systems Engineering National University of Defense TechnologyChangsha 410073China Defense Innovation Institute Academy of Military SciencesBeijing 100071China Photonics Research Institute Department of Electrical and Electronic EngineeringThe Hong Kong Polytechnic UniversityHong Kong 999077China Hunan Key Laboratory of Mechanism and Technology of Quantum Information Changsha 410073China

Ultra-compact multifunctional integrated photonic modules have great practical significance to photonic integrated circuits (PICs).However,the design effect and efficiency of the existing mainstream inverse design algorithms are incompetent when designing these *** analyze their shortcomings in this task,and propose a new,to our knowledge,inverse design algorithm named polygon search (PS) algorithm to address these *** utilize the PS algorithm to design an integrated dual-channel mode-conversion-crossing waveguide *** module integrates three functions:interconversion between TE_(0) and TE_(1),interconversion between TE_(0) and TE_(2),and channel crossing within only a 4μm×4μm footprint,and its performance is verified by experimental *** not only greatly reduces the total footprint of many PICs but also greatly improves their fabricating ***,we propose a PS-designed mode mixer and a PS-designed bending waveguide,and connect them with the integrated modules to form a four-channel crossing-mode-division-multiplexing *** system can provide multiple modes on the basis of channel crossing and transmit the output signal in the same direction in parallel within a single output waveguide,which significantly increases the communication bandwidth and decreases the footprint of *** last,we demonstrate the effect and efficiency advantages of the PS algorithm over several mainstream inverse design algorithms by a comprehensive contrast experiment and explain these advantages in theory from several perspectives.

关键词： waveguide mixer algorithm

Photocatalytic vinyl radical-mediated multicomponent 1,4-/1,8-carboimination across alkynes and olefins/(hetero)arenes

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Science China Chemistry 2024年第2期67卷 558-567页

作者： Shan-Shan Li Yu-Shi Jiang Xue-Ling luo Xuming Ran Yuqiang Li Dong Wu Cheng-Xue Pan peng-Ju Xia School of Chemistry and Pharmaceutical Sciences Guangxi Normal UniversityGuilin541004China Shanghai Artificial Intelligence Laboratory Shanghai200433China The Institute for Advanced Studies Wuhan UniversityWuhan430064China

We developed a highly selective and efficient multicomponent transformation by utilizing alkynes and olefins/(hetero)arenes through photoinduced energy-transfer *** reaction involves the formation of three distinct chemical bonds,namely C(sp~3)–C(sp~2),C(sp~2)–C(sp~3),and C(sp~3)–N,in a single coordinated *** strategy used a vinyl radical-mediated radical relay approach under mild conditions,exhibiting a broad substrate scope(>70 examples),excellent functional-group tolerance,and remarkable regio-and *** the utilization of a combination of experimental techniques and density functional theory(DFT),we delved deeper into the mechanistic intricacies of this distinctive *** revealed that the selective radical addition to electron-deficient alkynes,rather than olefins,was governed by the inherent reactivity of alkyl *** discovery presented a highly effective approach for the synthesis of stereodefined multisubstituted alkenes.

关键词： alkyne-olefin coupling DFT studies regio-and anti-stereoselectivity multisubstituted alkenes

Advanced rare earth tantalate RETaO_(4)(RE=Dy,Gd and Sm) with excellent oxygen/thermal barrier performance

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Journal of Rare Earths 2024年第8期42卷 1595-1603,I0007页

作者： Jun Wang Jianyu Li Chunyu Jiang Jianbo Song Xing Yang Xiaolong Ma Kailiang luo peng Wu Xiaoyu Chong Jing Feng Faculty of Material Science and Engineering Kunming University of Science and TechnologyKunming650093China Shanxi Tianxuan Coating Technology Co. LtdXi'an710000China

Thermal barrier coatings(TBCs) materials with lowered the rmal and oxygen ion conductivity can provide thermal and oxidative protection for high te mperature hot-end components in aero nautical engines and gas turbines,The rare-earth tantalate RETaO_(4)(RE=Dy,Gd and Sm) ceramics with monoclinic(m) phase were successfully synthesized via spark plasma *** vacancies responsible for the thermal and oxygen ion conductivities of RETaO_(4) were demonstrated by atomic-resolution energy dispersive Xray and X-ray photoelectron *** the three samples,DyTaO_(4) has excellent oxygen/thermal barrier *** to the current service thermal barrier coating material ZrO_(2)-8 wt% Y_(2)O_(3)(8 YSZ),DyTaO_(4) has an ultra-low oxygen ion conductivity benefiting from low oxygen vacancy concentration and strong stretching force *** intrinsic thermal conductivity of DyTaO_(4)is 68.2% less than that of 8 ***,the thermal expansion rate curves indicate that the phase transformation does not happen from room te mperature to 1200℃.The above results demonstrate that high-growth rate the rmally grown oxide can be retarded by creating dense DyTaO_(4) coating with lowered thermal and oxygen ion conductivity.

关键词： Thermal barrier coatings Rare earths Oxygen vacancies Thermal conductivity Oxygen ion conductivity

Pollen-expressed RLCKs control pollen tube burst

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Plant Communications 2024年第8期5卷 147-156页

作者： Yin-Jiao Xu Ting luo peng-Min Zhou Wei-Qi Wang Wei-Cai Yang Hong-Ju Li Center for Developmental Biology Institute of Genetics and Developmental BiologyChinese Academy of SciencesBeijing 100101China Center for Molecular Agrobiology Institute of Genetics and Developmental BiologyChinese Academy of SciencesBeijingChina Key Laboratory of Seed Innovation Institute of Genetics and Developmental BiologyChinese Academy of SciencesBeijingChina

In angiosperms,the pollen tube enters the receptive synergid cell,where it ruptures to release its cytoplasm along with two sperm *** interaction is complex,and the exact signal transducers that trigger the bursting of pollen tubes are not well *** this study,we identify three homologous receptor-like cytoplasmic kinases(RLCKs)expressed in pollen tubes of Arabidopsis,Delayed Burst 1/2/3(DEB1/2/3),which play a crucial role in this *** genes produce proteins localized on the plasma membrane,and their knockout causes delayed pollen tube burst and entrance of additional pollen tubes into the embryo sac due to fertilization *** show that DEBs interact with the Ca^(2+)pump ACA9,influencing the dynamics of cytoplasmic Ca^(2+)in pollen tubes through *** results highlight the importance of DEBs as key signal transducers and the critical function of the DEB-ACA9 axis in timely pollen tube burst in synergids.

关键词： Pollen tube burst RLCKs Calcium signaling/transport Double fertilization