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Calculating Models of Mass Action Concentrations for Ni-Mn and Co-Mn Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 2000年第4期14卷 246-250页

作者： Jian Zhang (Metallurgy school, university of science and technology beijing, beijing 100083, china) Metallurgy school University of Science and Technology Beijing Beijing 100083 China

According to phase diagrams, measured activities as well as the coexistence theory of motallic melts structure involving compound formation, the calculating models of mass action concentrations for Ni-Mn and Co-Mn melts are formulated and their thermodynamic parameters are optimized. As a result, the calculated mass action concentrations agree well with the corresponding measured activities, showing that these models can reflect the structural characteristics of both Ni-Mn and Co-Mn melts.

关键词： activity metallic melts coexistence theory mass action concentration

Laser-field-induced magnon amplification in a magnetic semiconductor quantum well under an external magnetic field

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Journal of university of science and technology beijing 2003年第5期10卷 69-72页

作者： peng FengPhysics Department, university of science and technology beijing, beijing 100083, china Phys. Dept. Univ. of Sci. and Technol. Beijing Beijing 100083 China

The laser-field induced magnon amplification in a magnetic semiconductorquantum well under an external magnetic field was discussed, it is shown that when the laserfrequency is near to the electron cyclotron frequency, no matter how weaker the laser field is, themagnon amplification always occurs. In case of fixed laser frequency, the optical absorption ofmagnons obeys the definite selection rule to the laser field strength. The rate of change of magnonoccupation is calculated, and the amplification condition is given.

关键词： magnon amplification magnetic semiconductor quantum well laser field

A Back Look on the Binary Phase Diagrams of Metals from the Mass Action Law and the Coexistence Theory of Metallic Melts

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Journal of university of science and technology beijing 2001年第1期8卷 15-19页

作者： Jian Zhang Metallurgy school, university of science and technology beijing, beijing 100083, china Univ Sci & Technol beijing Met Sch Beijing 100083 Peoples R China

According to the mass action law and the coexistence theory of metallic melts, the mass action concentrations of Cu-Mg, Bi-Tl and Ni-Al melts involving compound formation have been calculated. The calculated results show that, except the ultimate case of pure element, when two elements are present in the melts, all structural units (atoms and molecules) without exception will be present in the melts, i.e., their concentrations may change from great to small, but they will not vanish into nothing, and only under such conditions, the calculated results both agree with practice and obey the law of mass action. In view of that over considerable wide composition range, the activities of both elements of the three solid binary alloys mentioned above have been measured, this seems in contradiction with the present relevant phase diagrams, in which the structural units are determined by composition range, so the latter needs further investigation and consideration.

关键词： activity phase diagram the mass action law the coexistence theory

Calculating Models of Mass Action Concentrations for Fe-P and Cr-P Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 1999年第3期13卷 174-177页

作者： Jian Zhang(Metallurgy school, university of science and technology beijing, beijing 100083, china) Metallurgy school University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagrams, reliable reference experimental data and the coexistence theory of metallic melts structure involving compound formation, calculating models of mass action concentrations for Fe-P and Cr-P melts have been formulated. At the same time, some of their thermodynamic parameters have been optimized. The calculated results not only agree well with the measuredvalues, but also obey the mass action law rigorously, this in turn shows that these models can reflect the structural characteristics of corresponding melts.

关键词： activity phase diagram coexistence theory mass action concentration

Nonclassical Plane-crystallographic Groups and Their Applications IV

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International Journal of Minerals,Metallurgy and Materials 1998年第4期12卷 228-232页

作者： Lequan Min Xaodan zhang(Applied science school, school,university of science and technology beijing, beijing 100083,china) Applied science school University of Science and Technology Beijing Beijing 100083 China

Eight kinds of nonclasslcal periodic lattices with locally 8-fold rotational symmetries are *** can be described via nonclassical Planc-crystallographic groups. The periodic lattices may be interpreted bythe projections on the plane of the corresponding unit cells consisting of embedding polyhedrons, respectively. TheFourier-transform patterns of the Periodic lattices have striking approximate'8-fold rotational symmetries', some ofwhich are similar to those displaying in the electrton-diffraction patterns of so-called quasicrystals.

关键词： nonclasslcal crystallographic groups locoally 8-fold symmetry Fourier-transform patterns, quasicrystals

Nonlinear Theory on Dynamic Controlling Interface Patterns DuringSolidification of a Dilute Binary Alloy

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International Journal of Minerals,Metallurgy and Materials 1999年第4期13卷 253-258页

作者： Zidong Wang Hanqi Hu(Material science and Engineering school, university of science and technology beijing, beijing 100083, china) Material science and Engineering school University of Science and Technology Beijing Beijing 100083 China

In non-equilibrium nonlinear region, the nonlinear equations of time dependence of perturbation amplitude at the solid/liquidinterface during solidification of a dilute binary alloy are established on the base of assuming that there is local equilibrium at the solid/liquid interface and considering that curvature, temperature and composition at the solid/liquid interface which are related to the perturbation amplitude are nonlinear. As a result, patterns at the solid/liquid interface during solidification process, which is from nonsteadystate to steady state can be controlled by these nonlinear equations.

关键词： nonlinearity solidification, dilute binary alloy, dynamic control

Recycling of Spent Nickel-Cadmium Batteries

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International Journal of Minerals,Metallurgy and Materials 2000年第2期14卷 126-131页

作者： Xanghua Kong Pingnan Wu(Metallurgy school, university of science and technology beijing, beijing 100083, china) Metallurgy school University of Science and Technology Beijing Beijing 100083 China

A technique for recycling spent nickel-cadmium batteries, which makes separaion of cadmium and nickel possible, is developed by laboratory-scale experiments. NH3-H2CO3 aqueous solution was used in this leaching technique. Since neutralization and/or solvent extraction were not required in the separation procedure of nickel and cadmium, the closed systemizaion of the process becomespossible. Experimental results show that, (1) if the NH3 concentraion of leaching solution is sufficiently high and the ratio of H2CO3 toNH3 is properly adjusted, both Ni(OH)2 and Cd(OH)2 react with NH, and quickly dissolve into leaching solution, and (2) Ni(OH)2 can beconverted into insoluble NiO by calcination at 500℃, and CdO from Cd(OH)2 by calcination maintains good solubility in NH3-H2CO3aqueous solution. As a conclusion, the recycling technique characterized by two step leaching can be developed based on such changesin dissolution behavior by calcination. Meanwhile, the yields of 99.8% for nickel and 97.6% for cadmium are obtained, and the puritiesof Recycling of Spent Nickel-Cadmium BatterieRecycling of Spent Nickel-Cadmium Batteries Recycling of Spent Nickel-Cadmium Batteriesrecovered nickel and cadmium are 99.9% and 98.6%, respectively.

关键词： nickel-cadmium batteries recycling, ammonia leaching closed system environmental protection

Theory for Constructing Generalized Synchronization and Applications

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International Journal of Minerals,Metallurgy and Materials 2000年第3期14卷 225-228页

作者： Xiaodan Zhang, Lequan Min (Applied science school, university of science and technology beijing, beijing 100083, china) Applied science school University of Science and Technology Beijing Beijing 100083 China

The approaches for constructing directionally coupled generalized synchronization (GS) systems are presented, which are available for the driving system and the respond system that are in GS via a given diffeomorphi... 详细信息

关键词： Chaos generalized synchronization predictability

Redistribution of Boron during Ferrite Reaction in Nb-B Microalloyed Steel

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International Journal of Minerals,Metallurgy and Materials 1998年第4期12卷 223-227页

作者： Shanwu Yang Xinlai He(Applied science school, university of science and technology beijing, beijing 100083, china) Applied science school University of Science and Technology Beijing Beijing 100083 China

By contrast of microstructure and boron distribution in the same area of samples, the behavior of boronduring ferrite reaction in Nb-B microalloyed steel was studied. Boron atoms have segregated to original austeniteboundaries betfore ferrite reaction starts during isothermal treatment. The concentration of boron in small Pieces offerrite foming along austenite boundaries may be remarkably higher than that in austenite matrix, but it will reducegradually when the ferrite continuously grows. There is no obvious boron segregation on interface of γ/α and α/α.These facts indicate that ferrite growth is not controlled by diffusion of boron in austenite.

关键词： boron segregation ferrite reaction microalloyed steel