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Mechanism investigation of A-site doping on modulating electronic band structure and photocatalytic performance towards CO_(2) reduction of LaFeO_(3) perovskite

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Nano Research 2024年第5期17卷 3733-3744页

作者： Chi Cao Jinshuo Li yang hu Lin Zhang Wensheng yang State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of ChemistryJilin UniversityChangchun 130012China Engineering Research Center for Nanomaterials Henan UniversityKaifeng 475004China

Three kinds of metal atoms with different valence electronic configurations,Bi(6s^(2)6p^(3)),Y(4d^(1)5s^(2)),and Ce(4f^(1)5d^(1)6s^(2)),were selected to investigate the effect of A-site(La^(3+))doping on electronic band structure,photoelectric properties,and photocatalytic performance of LaFeO_(3) *** was identified that the Bi doped LaFeO_(3) presented significantly improved photocatalytic activity towards the reduction of CO_(2),while the Y or Ce doped LaFeO_(3) displayed decreased photocatalytic activity compared to the pristine LaFeO_(3).It was revealed that doping of all the three metal atoms resulted in narrowed band gap and thus extended light absorption of LaFeO_(3) by lowering its conduction band minimum(CBM).The recombination rate and mobility of the charge carriers were represented by the relative effective mass(D)between holes and electrons for pristine and A-site doped LaFeO_(3).The doping of Bi resulted in increased D value,attributed to the Bi 6s electron states at the valence band maximum(VBM),and thus promoted separation and transfer of the charge carriers and improved photocatalytic activity of LaFeO_(3).In contrast,the doping of Ce resulted in significantly decreased D value,induced by the highly localized Ce 4f hole states at the CBM,and thus higher recombination rate of the charge carriers and decreased photocatalytic activity of LaFeO_(3).Furthermore,the Y doped LaFeO_(3) with a slightly decreased D value presented slightly increased recombination rate of the charge carriers and thus decreased photocatalytic *** a work provides new insights into the A-site doping in LaFeO_(3) perovskite,which should be helpful for optimizing the electronic band structure and activity of perovskite-type photocatalysts at atomic level.

关键词： A-site doping electronic band structure charge carrier behavior photocatalytic CO_(2)reduction perovskite-type photocatalytsts

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Design,preparation,and characterization of a novel ZnO/CuO/Al energetic diode with dual functionality:Logic and destruction

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Defence Technology（防务技术） 2024年第4期34卷 57-68页

作者： Jialu yang Jiaheng hu Yinghua Ye Jianbing Xu Yan hu Ruiqi Shen School of Chemistry and Chemical Engineering Nanjing University of Science and TechnologyNanjing 210094China Micro-Nano Energetic Devices Key Laboratory of MIIT Nanjing 210094China Institute of Space Propulsion Nanjing University of Science and TechnologyNanjing 210094China

Self-destructing chips have promising applications for securing *** paper proposes a new concept of energetic diodes for the first time,which can be used for self-destructive chips.A simple two-step electrochemical deposition method is used to prepare ZnO/CuO/Al energetic diode,in which N-type ZnO and P-type CuO are constricted to a PN *** paper comprehensively discusses the material properties,morphology,semiconductor characteristics,and exploding performances of the energetic *** results show that the energetic diode has typical rectification with a turn-on voltage of about 1.78 V and a reverse leakage current of about 3×10^(-4)*** a constant voltage of 70 V loads to the energetic diode in the forward direction for about 0.14 s or 55 V loads in the reverse direction for about 0.17 s,the loaded power can excite the energetic diode exploding and the current rises to about100 *** to the unique performance of the energetic diode,it has a double function of rectification and *** energetic diode can be used as a logic element in the normal chip to complete the regular operation,and it can release energy to destroy the chip accurately.

关键词： Energetic diode ZnO—CuO—Al thermite ZnO/CuO PN junction Electrical explosion performance Self-destructing chips

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Trauma care construction under the guidance of county-level trauma centers

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Chinese Journal of Traumatology 2018年第5期21卷 256-260页

作者： pei-yang hu Xin-Yi Chen Xiong-huan Chen Yi-Min Chen Trauma Center Tiantai People's Hospital of Zhejiang Province Taizhou 317200 Zhejiang Province China

Severe trauma has the characteristics of complicated condition, multiple organs involved, limitq auxiliary examinations, and difficulty in treatment. Most of the trauma patients were sent to prima hospitals to receive treatments. But the traditional mode of separate discipline management can easi lead to delayed treatment, missed or wrong diagnosis and high disability, which causes a high mc tality in severe trauma patients. Therefore, if the primary hospitals, especially county-level hospit~ （usually the top general hospital within the administrative region of a county）, can establish a sc entific and comprehensive trauma care system, the success rate of trauma rescue in this region can ] greatly improved. On March 1st, 2013, Tiantai People＇s Hospital of Zhejiang Province, China set up trauma care center, which integrated the pre-hospital and in-hospital trauma treatment procedur~ and has achieved good economic and social benefits. Till March 1st, 2017, 1265 severe trauma patier （injury severity score 〉16） have been treated in this trauma center. The rescue success rate reach~ 95~ and the delayed and]or missed diagnosis rate was less than 5%. Totally 86 severe cases of peK fractures with unstable hemodynamics were treated, and the success rate was 92%. The in-hospil emergency rescue response time is less than 3 min, and the time from definite diagnosis to surge is within 35 min.

关键词： Severe trauma Integrated emergency management system County-level hospital

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High-stability temperature control and frequency-domain analysis of sandwich-like insulation design based on phase change materials for satellite thermal management

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Science China(Technological Sciences) 2024年第8期67卷 2387-2404页

作者： WANG ZiHan HE ChenBo hu yang TANG Guihua Key Laboratory of Thermo-Fluid Science and Engineering Ministry of EducationSchool of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China

High-stability thermal management is critical for the measurements of high sensitivity for temperature, but also challenging because any small thermal disturbances could lead to unacceptable temperature fluctuations. The present work delivers a design for passive temperature control, customized for a component in the satellites for gravitational wave detection. A novel sandwichlike structure is proposed with the configurations of proper materials, consisting of a layer of insulation material and two layers of nanocomposite phase change materials, bringing an integration of heat insulation and absorption/storage. Its performance is examined using an improved thermal network model and the revised transfer function method(TFM). The basic results of the two methods are validated by present COMSOL simulations and available numerical and experimental data in the literature. An effective reduction of temperature fluctuation is achieved to the scale of 0.1 K, even under two thermal disturbances from different directions: a radiative heat flux of 20 W m~(-2)(inside) and a temperature fluctuation of about 20 K(outside). Moreover,the TFM is employed to analyze the effects of the frequency of thermal disturbance: excellent damping performance is obtained for over 3.2 mHz and the underlying mechanism is discussed. Overall, the present design is expected to be combined with active temperature control to explore more possible ways for temperature control with higher stability.

关键词： temperature control sandwich insulation structure phase change material thermal network model transfer function method

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Cationic starch microparticles with integrated antibacterial and hemostatic performance

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Science China Technological Sciences 2024年第10期67卷 3235-3246页

作者： SU yang NIU MengXin XU KaiDong XU Chen yang peiLang hu yang XU Fu-Jian Key Lab of Biomedical Materials of Natural Macromolecules (Beijing University of Chemical Technology Ministry of Education)Beijing Laboratory of Biomedical MaterialCollege of Materials Science and EngineeringBeijing University of Chemical Technology Department of Burn Ruijin Hospital Affiliated to Shanghai Jiao Tong University School of Medicine

It is urgently demanded to develop biomaterials with balanced hemostatic/antibacterial ability and facile preparation methods. In this work, cationic starch microparticles(MSQP), prepared by the facile grafting of microporous starch particles(MS) with tunable quaternized polyethyleneimine, were readily constructed as promising hemostatic materials for integrated antibacterial and hemostatic performance. The cationic grafts not only endowed MSQP with good antibacterial ability, but also benefited from biocompatible MS to achieve favorable biocompatibility. Moreover, in vitro results confirmed the superior hemostatic property of MSQP2(with the medium content of cationic grafts) among three MSQP and pristine MS. After investigating the bloodmaterial interactions of MSQP/MS, the procoagulant mechanism of MSQP2 was revealed that the optimal amount of cationic grafts achieves highly balanced plasma-protein adhesion, platelet adhesion and blood coagulation system. In vivo artery-injury model further demonstrated the superior hemostatic performance of MSQP2 for potential severe hemorrhage. This work sheds light on the design of cationic polymer-based biomaterials for balanced antibacterial and hemostatic functions.

关键词： hemostasis antibacterial cationic polymer microparticles

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Ship recognition based on HRRP via multi-scale sparse preserving method

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Journal of Systems Engineering and Electronics 2024年第3期35卷 599-608页

作者： yang Xueling ZHANG Gong SONG hu College of Electronic and Information Engineering Nanjing University of Aeronautics and AstronauticsNanjing 210016China Key Lab of Radar Imaging and Microwave Photonics Ministry of EducationNanjing 210016China Nanjing Marine Radar Institute Nanjing 210016China

In order to extract the richer feature information of ship targets from sea clutter, and address the high dimensional data problem, a method termed as multi-scale fusion kernel sparse preserving projection(MSFKSPP) based on the maximum margin criterion(MMC) is proposed for recognizing the class of ship targets utilizing the high-resolution range profile(HRRP). Multi-scale fusion is introduced to capture the local and detailed information in small-scale features, and the global and contour information in large-scale features, offering help to extract the edge information from sea clutter and further improving the target recognition accuracy. The proposed method can maximally preserve the multi-scale fusion sparse of data and maximize the class separability in the reduced dimensionality by reproducing kernel Hilbert space. Experimental results on the measured radar data show that the proposed method can effectively extract the features of ship target from sea clutter, further reduce the feature dimensionality, and improve target recognition performance.

关键词： ship target recognition high-resolution range profile(HRRP) multi-scale fusion kernel sparse preserving projection(MSFKSPP) feature extraction dimensionality reduction

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Observations on spontaneous chiral symmetry breaking and the mass gap of QCD in finite volume

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Communications in Theoretical Physics 2024年第9期76卷 42-47页

作者： Xiaolan Meng Bolun hu Yi-Bo yang University of Chinese Academy of Sciences School of Physical SciencesBeijing 100049China CAS Key Laboratory of Theoretical Physics Institute of Theoretical PhysicsChinese Academy of SciencesBeijing 100190China School of Fundamental Physics and Mathematical Sciences Hangzhou Institute for Advanced StudyUCASHangzhou 310024China International Centre for Theoretical Physics Asia-Pacific Beijing/HangzhouChina

We present a lattice quantum chromodynamics(QCD)simulation with 2+1+1 flavor full QCD ensembles using near-physical quark masses and different spatial sizes L,at a~0.055 *** results show that the scalar and pesudoscalar 2-point correlator with a valence pion mass of approximately 230 MeV become degenerated at L≤1.0 fm,and such an observation suggests that the spontaneous chiral symmetry breaking disappears effectively at this *** the same time,the mass gap between the nucleon and pion masses remains larger thanΛQCDin the entire L∈[0.2,0.7]fm range.

关键词： lattice QCD chiral symmetry breaking confinement

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Bi@C nanosphere anode with Na^(+)-ether-solvent cointercalation behavior to achieve fast sodium storage under extreme low temperatures

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Carbon Energy 2024年第9期6卷 325-337页

作者： Lingli Liu Siqi Li Lei hu Xin Liang Wei yang Xulai yang Kunhong hu Chaofeng Hou Yongsheng Han Shulei Chou School of Energy Materials and Chemical EngineeringHefei UniversityHefeiChina LIB Technology Center of Anhui Province Hefei UniversityHefeiChina School of Advanced Manufacturing Engineering Hefei UniversityHefeiChina State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijingChina Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhouChina

The low ion transport is a major obstacle for low-temperature(LT)sodium-ion batteries(SIBs).Herein,a core-shell structure of bismuth(Bi)nanospheres coated with carbon(Bi@C)is constructed by utilizing a novel Bi-based complex(1,4,5,8-naphthalenetetracarboxylic dianhydride as the ligand)as the precursor,which provides an effective template to fabricate Bi-based ***-40℃,the Bi@C anode achieves a high capacity,which is equivalent to 96%of that at 25℃,benefitting from the core-shell nanostructured engineering and Na^(+)-ether-solvent cointercalation *** special Na+-diglyme cointercalation behavior may effectively reduce the activation energy and accelerate the Na+diffusion kinetics,enabling the excellent low-temperature performance of the Bi@C *** expected,the fabricated Na_(3)V_(2)(PO_(4))_(3)//Bi@C full-cell delivers impressive rechargeability in the ether-based electrolyte at-40℃.Density functional theory calculations and electrochemical tests also reveal the fast reaction kinetic mechanism at LT,thanks to a much lower diffusion energy barrier(167 meV)and a lower reaction activation energy(32.2 kJ mol^(-1))of Bi@C anode in comparison with that of bulk *** work provides a rational design of Bi-based electrodes for rechargeable SIBs under extreme conditions.

关键词： bismuth core-shell structure low-temperature conditions sodium-ion batteries

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Performance Analysis and Optimization of Energy Harvesting Modulation for Multi-User Integrated Data and Energy Transfer

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China Communications 2024年第1期21卷 148-162页

作者： Yizhe Zhao Yanliang Wu Jie hu Kun yang School of Information and Communication Engineering University of Electronic Science and Technology of ChinaChengdu 611731China

Integrated data and energy transfer(IDET)enables the electromagnetic waves to transmit wireless energy at the same time of data delivery for lowpower *** this paper,an energy harvesting modulation(EHM)assisted multi-user IDET system is studied,where all the received signals at the users are exploited for energy harvesting without the degradation of wireless data transfer(WDT)*** joint IDET performance is then analysed theoretically by conceiving a practical time-dependent wireless *** the aid of the AO based algorithm,the average effective data rate among users are maximized by ensuring the BER and the wireless energy transfer(WET)*** results validate and evaluate the IDET performance of the EHM assisted system,which also demonstrates that the optimal number of user clusters and IDET time slots should be allocated,in order to improve the WET and WDT performance.

关键词： energy harvesting modulation(EHM) integrated data and energy transfer(IDET) performance analysis wireless data transfer(WDT) wireless energy transfer(WET)

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Sequence design in terpolymerization ofε-caprolactone,CO_(2) and cyclohexane oxide:Random ester-carbonate distributions lead to large-span tunability

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Chinese Chemical Letters 2024年第5期35卷 259-264页

作者： Zhenjie yang Chenyang hu Xuan Pang Xuesi Chen Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China

It is of great interest to make a degradable material widely tailorable to replace petroleum-derived products among diverse ***,we report the construction of a new multi-purpose degradable material for the first time via a simple ternary copolymerization system comprisingε-caprolactone(ε-CL),cyclohexane oxide(CHO)and CO_(2).Under low pressure of 1 bar∼5 bar,the ring-opening polymerization(ROP)ofε-CL and ring-opening copolymerization(ROCOP)of CO_(2) and CHO can simultaneously *** carbonate units are randomly distributed on the polymer *** random terpolymers have controllable molar mass(10-106 kDa)and compositions(4-33 mol%CO_(2)).And the obtained materials show large-span tunability from tough plastic to elastomer and even adhesive.

关键词： Polyesters CO_(2)-derived copolymers Random copolymerization Elastomers Adhesives

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