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Journal of Analysis and Testing 2024年第2期8卷 228-236页

作者： Wenjing Song Yingyi Guo Pengyu liu Xiucong pei School of Public Health Shenyang Medical CollegeShenyang110034China Shenyang Institute for Food and Drug Control Shenyang110021China Key Laboratory of Food Pollutant Inspection and Risk Assessment in Liaoning Province Shenyang110021China

There is a strong correlation between bisphenol A(BPA)and the risks of endocrine disruption in ***,the mechanism behind this correlation is still unknown due to the challenge of accurately assessing BPA levels in biological ***,we demonstrate a molecularly imprinted polymer(MIP)modified impedimetric sensor treated with bovine serum albumin(BSA)not only reduces the impact of protein interference but also maintains both specificity and sensitivity for the precise analysis of *** platinum disc electrode was coated with MIP via electrochemical polymerization of o-phenylenediamine(o-PD)in the presence of BPA as a template,and free sites were then blocked with 1%*** impedance spectroscopy(EIS)was utilized for the detection of *** linear range for detection was between 1.0 pg/L and 10.0 ng/L,with a detection limit(LOD)of 0.28 pg/*** sensor presented a good selectivity over structurally similar steroid hormones and BPA *** validate the performance of the proposed sensor in the presence of possible interfering proteins,it was used to quantify BPA in real samples without any prior *** findings indicate that such an impedimetric sensor can be used to measure BPA in complex matrices.

关键词： Bisphenol A Molecularly imprinted polymers Impedimetric sensor Bovine serum albumin Biological matrices

In situ generation of oxyanions-decorated cobalt(nickel)oxyhydroxide catalyst with high corrosion resistance for stable and efficient seawater oxidation

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Journal of Energy Chemistry 2024年第7期94卷 508-516页

作者： Fengting Luo pei yu Jueting Xiang Junjie Jiang Shijian Chen Chongqing Key Laboratory of Interface Physics in Energy Conversion College of PhysicsChongqing UniversityChongqing 401331China Center of Modern Physics Institute for Smart City of Chongqing University in LiyangLiyang 213300JiangsuChina

The development of efficient and robust anode materials for stable alkaline seawater electrolysis is severely limited by chlorine evolution reaction and chloride ***,the sulfur-doped cobalt-nickel bimetallic phosphides(CoNiPS)are specifically designed as a pre-catalyst for navigating a surface reconstruction to fabricate the anions(PO^(3-)_(4) and SO^(2-)_(4))-decorated Co(Ni)OOH catalyst(R-CoNiPS)with exceptional durability and high activity for stable alkaline seawater oxidation(ASO).Various experiment techniques together with theoretical simulations both demonstrate that the in situ-generated PO^(3-)_(4) and SO^(2-)_(4) anions on catalyst surface can improve the oxygen evolution reaction(OER)activity,regulating and stabilizing the catalytic active species Co(Ni)OOH,as well as make a critical role in inhibiting the adsorp-tion of chloride ions and extending the service life of ***,this R-CoNiPS electrode exhi-bits superb OER activity toward AsO and stands out among the non-precious ASO electrocatalysts reported recently,requiring low overpotentials of 420 and 440 mV to attain large current densities of 500 and 1000 mA cm^(-2) in an alkaline natural seawater electrolyte,***,the catalyst displays a negligible chloride corrosion at room temperature during ASO operation(>200 h)at 500 mA cm^(-2).This work opens up a new viewpoint for designing high-activity and durable electrocata-lystsforseawaterelectrolysis.

关键词： Seawater electrolysis Anions Oxygen evolution reaction Chloride corrosion

Establishing Modular Cell-Free Expression System for the Biosynthesis of Bicyclomycin from a Chemically Synthesized Cyclodipeptide

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Chinese Journal of Chemistry 2024年第4期42卷 384-390页

作者： Yi-pei liu yu-Heng Zhao Wen-Qi Zhang Lian Wu Linjuan Huang Gong-Li Tang Jun-Bin He Shaanxi Natural Carbohydrate Resource Engineering Research Center College of Food Science and TechnologyNorthwest UniversityXi'anShaanxi710069 China State Key Laboratory of Chemical Biology Shanghai Institute of Organic ChemistryUniversity of Chinese Academy of Sciences(CAS)CASShanghai200032 China School of Chemistry and Materials Science Hangzhou Institute for Advanced StudyUniversity of CAS1 Sub-lane XiangshanHangzhouZhejiang310024 China

Cell-free expression systems have emerged as a versatile and powerful platform for metabolic engineering,biosynthesis and synthetic biology ***,successful examples of the synthesis of complex natural products using this system are still ***,a structurally unique and complex diketopiperazine alkaloid,is a clinically promising antibiotic that selectively inhibits the transcription termination factor ***,we established a modular cell-free expression system with cascade catalysis for the biosynthesis of bicyclomycin from a chemically synthesized *** six cell-free expressed biosynthetic enzymes,including five iron-andα-ketoglutarate-dependent dioxygenases and one cytochrome P450 monooxygenase,were active in converting their substrates to the corresponding *** co-expressed enzymes in the cell-free module were able to complete the related partial *** vitro biosynthesis of bicyclomycin was also achieved by reconstituting the entire biosynthetic pathways(i.e.,six enzymes)using the modular cell-free expression *** study demonstrates that the modular cell-free expression system can be used as a robust and promising platformforthe biosynthesis of complex antibiotics.

关键词： Natural products Bicyclomycin Biosynthesis Iron-andα-ketoglutarate-dependent dioxygenases Cytochrome P450 monooxygenase Cell-freeprotein synthesis Enzyme catalysis

Relation Between the Eventual Continuity and the E-property for Markov-Feller Semigroups

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Acta Mathematicae Applicatae Sinica 2024年第1期40卷 1-16页

作者： Yong liu Zi-yu liu LMAM School of Mathematical SciencePeking UniversityBeijing100871China

We investigate some relations between two kinds of semigroup regularities, namely the e-property and the eventual continuity, both of which contribute to the ergodicity for Markov processes on Polish *** precisely, we prove that for Markov-Feller semigroup in discrete time and stochastically continuous MarkovFeller semigroup in continuous time, if there exists an ergodic measure whose support has a nonempty interior,then the e-property is satisfied on the interior of the support. In particular, it implies that, restricted on the support of each ergodic measure, the e-property and the eventual continuity are equivalent for the discrete-time and the stochastically continuous continuous-time Markov-Feller semigroups.

关键词： Markov-Feller semigroup ergodicity e-property eventual continuity

Light-controlled switchable underwater adhesive

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SmartMat 2024年第2期5卷 115-123页

作者： Song Yang Yanfei Ma Chenxi Qin Zhizhi Zhang Jianqing yu Xiaowei pei Bo yu Wenbo Sheng Feng Zhou Weimin liu Northwestern Polytechnical University Center of Advanced Lubrication and Seal MaterialsSchool of Materials Science and EngineeringXi'anChina State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhouChina Shandong Laboratory of Yantai Advanced Materials and Green Manufacture Yantai Zhongke Research Institute of Advanced Materials and Green Chemical EngineeringYantaiChina

Despite extensive efforts in designing and preparing switchable underwater adhesives,it is not easy to regulate the underwater adhesion strength locally and ***,we design and synthesize photoreversible copolymer of poly[dopamine methacrylamide-co-methoxyethyl-acrylate-co-7-(2-methacryloyloxyethoxy)-4-methylcoumarin].Due to the dynamic formation and breaking of chemical crosslinking networks within the smart adhesives,the material shows widely tunable adhesion strength from∼150 to∼450 kPa and long-range reversible maneuverability under orthogonal 254 and 365 nm ultraviolet light stimulation via the coumarin dimerization and ***,the adhesive exhibits good circulation performance and stability in an acid–base *** also demonstrated that the bolt can be coated with the smart adhesive material for on-demand *** design principle opens the door to the development of remotely controllable high-performance smart underwater adhesives.

关键词： dynamic covalent bonds photoresponsive reversible adhesion switchable adhesion underwater adhesion

New Hybrid CHP System Integrating Solar Energy and Exhaust Heat Thermochemical Synergistic Conversion with Dual-Source Energy Storage

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Journal of Thermal Science 2024年第3期33卷 970-984页

作者： QIN yuanlong liu Taixiu LI peijing ZHAO Kai JIAO Fan pei Gang liu Qibin Department of Thermal Science and Energy Engineering University of Science and Technology of ChinaHefei230027China Institute of Engineering Thermophysics Chinese Academy of SciencesBeijing100190China University of Chinese Academy of Sciences Beijing100049China School of Energy Power and Mechanical EngineeringNorth China Electric Power UniversityBeijing102206China

For the efficient use of solar and fuels and to improve the supply-demand matching performance in combined heat and power(CHP)systems,this paper proposes a hybrid solar/methanol energy system integrating solar/exhaust thermochemical and thermal energy *** proposed system includes parabolic trough solar collectors(PTSC),a thermochemical reactor,an internal combustion engine(ICE),and hybrid storage of thermal and chemical energy,which uses solar energy and methanol fuel as input and outputs power and *** methanol thermochemical decomposition reaction,mid-and-low temperature solar heat and exhaust heat are upgraded to chemical energy for efficient power *** thermal energy storage(TES)stores surplus thermal energy,acting as a backup source to produce heat without emitting CO_(2).Due to the energy storage,time-varying solar energy can be used steadily and efficiently;considerable supply-demand mismatches can be avoided,and the operational flexibility is *** the design condition,the overall energy efficiency,exergy efficiency,and net solar-to-electric efficiency achieve 72.09%,37.65%,and 24.63%,*** fuel saving rate(FSR)and the CO_(2) emission reduction(ER_(CO_(2)))achieve 32.97%and 25.33%,*** research findings provide a promising approach for the efficient and flexible use of solar energy and fuels for combined heat and power.

关键词： hybrid energy system solar thermochemical exhaust heat energy storage operational flexibility

Recent Advances in the Synthesis of Zeolites from Solid Wastes

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Chemical Research in Chinese Universities 2024年第4期40卷 646-656页

作者： liu pei WU Qinming CHEN Zhenghai XIAO Feng-Shou Key Laboratory of Biomass Chemical Engineering of Ministry of Education and College of Chemical and Biological Engineering Zhejiang UniversityHangzhou310028P.R.China Zhejiang Provincial Innovation Center of Green Petrochemical Technology Ningbo315048P.R.China Kente Catalysts Inc. Xianju317300P.R.China

With the rapid development of industrialization,it is inevitable to produce solid wastes in the fields of energy petrochemical ***,the storage and utilization of these solid wastes have become a considerable *** to the main element composition of these solid wastes including silicon and aluminum,it has attracted extensive attention for synthesizing *** review summarized the properties of major solid wastes including coal fly ash,coal gangue,spent fluid catalytic cracking(FCC)catalyst,lithium slag,bauxite residue,and waste ***,the preparation of LTA,FAU,ZSM-5,SSZ-13,Beta,and MOR zeolites from these solid wastes were ***,the current challenges and perspectives were discussed.

关键词： Solid waste Zeolite Utilization Sustainable route Application

Molecular Dynamics Simulation Studies on the Micromorphology and Proton Transport of Nafion/Ti_(3)C_(2)T_(x) Composite Membrane

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Chinese Journal of Polymer Science 2024年第3期42卷 373-387,I0009页

作者： Zhi-yue Han Su-Peng pei Chun-Yang yu Yong-Feng Zhou School of Chemical and Environmental Engineering Shanghai Institute of TechnologyShanghai 201418China School of Chemistry&Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Key Laboratory of Electrical Insulation and Thermal AgingShanghai Jiao Tong UniversityShanghai 200240China Key Laboratory of Green and High-end Utilization of Salt Lake Resources Chinese Academy of SciencesXining 810008China

The perfluorosulfonic acid(PFSA) membrane doped with two-dimensional conductive filler Ti_(3)C_(2)T_(x) is a fuel cell proton exchange membrane with high application potential. Experimental studies showed that the proton conductivity of Nafion/Ti_(3)C_(2)T_(x) composite membrane is improved significantly compared with that in pure Nafion. However, the microscopic mechanism of doping on the enhancement of membrane performance is remain unclear now. In this work, molecular dynamics simulation was used to investigate the microscopic morphology and proton transport behaviors of Nafion/Ti_(3)C_(2)T_(x) composite membrane at the molecular level. The results shown that there were significant differences about the diffusion kinetics of water molecules and hydroxium ions in Nafion/Ti_(3)C_(2)T_(x) at low and high hydration levels in the nanoscale *** the increase of water content, Ti_(3)C_(2)T_(x) in membrane was gradually surrounded by ambient water molecules to form a hydration layer, and forming a relatively continuous proton transport channel between Nafion polymer and Ti_(3)C_(2)T_(x) monomer. The continuous proton transport channel could increase the number of binding sites of proton and thus achieving high proton conductivity and high mobility of water molecules at higher hydration level. The current work can provide a theoretical guidance for designing new type of Nafion composite membranes.

关键词： Nafion/Ti_(3)C_(2)T_(x)composite membrane Proton transport Molecular dynamics simulation

Accurate Source-Receiver Positioning Method for a High-Resolution Deep-Towed Multichannel Seismic Exploration System

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Journal of Ocean University of China 2024年第2期23卷 415-426页

作者： LI Jing liu Kai WEI Zhengrong ZHANG Liancheng liu Yangting pei Yanliang liu Chenguang liu Baohua Key Laboratory of Marine Geology and Metallogeny First Institute of OceanographyMNRQingdao 266061China Laboratory for Marine Geology Laoshan LaboratoryQingdao 266061China College of Ocean Science and Engineering Shandong University of Science and TechnologyQingdao 266590China Key Laboratory of Fluid Transmission Technology of Zhejiang Province Zhejiang Sci-Tech UniversityHangzhou 310018China

The near-seabed multichannel seismic exploration systems have yielded remarkable successes in marine geological disaster assessment,marine gas hydrate investigation,and deep-sea mineral exploration owing to their high vertical and horizontal ***,the quality of deep-towed seismic imaging hinges on accurate source-receiver positioning *** light of existing technical problems,we propose a novel array geometry inversion method tailored for high-resolution deep-towed multichannel seismic exploration *** method is independent of the attitude and depth sensors along a deep-towed seismic streamer,accounting for variations in seawater velocity and seabed slope *** approach decomposes the towed line array into multiline segments and characterizes its geometric shape using the line segment distance and pitch *** optimization parameters for seawater velocity and seabed slope angle,we establish an objective function based on the model,yielding results that align with objective *** the particle swarm optimization algorithm enables synchronous acquisition of optimized inversion results for array geometry and seawater *** validation using theoretical models and practical data verifies that our approach effectively enhances source and receiver positioning inversion *** algorithm exhibits robust stability and reliability,addressing uncertainties in seismic traveltime picking and complex seabed topography conditions.

关键词： high-resolution deep-towed multichannel seismic exploration source-receiver positioning array geometry inversion seawater heterogeneity seabed slope angle

Graph Signal Reconstruction from Low-Resolution Multi-Bit Observations

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Chinese Journal of Electronics 2024年第1期33卷 153-160页

作者： Zhaoting liu Chen yu Yafeng WANG Shuchen liu School of Communication Engineering Hangzhou Dianzi University

Low hardware cost and power consumption in information transmission, processing and storage is an urgent demand for many big data problems, in which the high-dimensional data often be modelled as graph *** paper considers the problem of recovering a smooth graph signal by using its low-resolution multi-bit quantized observations. The underlying problem is formulated as a regularized maximum-likelihood optimization and is solved via an expectation maximization scheme. With this scheme, the multi-bit graph signal recovery(MB-GSR) is efficiently implemented by using the quantized observations collected from random subsets of graph nodes. The simulation results show that increasing the sampling resolution to 2 or 3 bits per sample leads to a considerable performance improvement, while the energy consumption and implementation costs remain much lower compared to the implementation of high resolution sampling.

关键词： Quantization (signal) Costs Power demand Simulation Energy resolution Signal sampling Signal reconstruction