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Low-cost and fluoride-free synthesis of MFI zeolite nanosheets with enhanced stability for benzene alkylation with ethanol

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Journal of Energy Chemistry 2025年第1期100卷 458-468页

作者： Peng Zhu Cun liu Yiren Yu Guoshu Gao Yumeng Zhao Xiongfu Zhang Guodong liu Guohui Yang State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

Zeolite nanosheets with a short b-axis thickness are highly desirable in lots of catalytic reactions due to their reduced diffusion resistance. Nevertheless, conventional synthesis methods usually require expensive structure-directing agents(SDAs), pricey raw materials, and eco-unfriendly fluorine-containing additives. Here, we contributed a cost-effective and fluoride-free synthesis method for synthesizing high-quality MFI zeolite nanosheets through a Silicalite-1(Sil-1) seed suspension and urea cooperative strategy, only with inexpensive colloidal silica as the Si source. Our approach was effective for synthesizing both Sil-1 and aluminum-containing ZSM-5 nanosheets. By optimizing key synthesis parameters,including seed aging time, seed quantity, and urea concentration, we achieved precise control over the crystal face aspect ratio and b-axis thickness. We also revealed a non-classical oriented nanosheet growth mechanism, where Sil-1 seeds induced the formation of quasi-ordered precursor particles, and the(010)crystal planes of these particles facilitated urea adsorption, thereby promoting c-axis-oriented *** obtained ZSM-5 nanosheets exhibited exceptional catalytic performance in the benzene alkylation with ethanol, maintaining stability for over 500 h, which is 5 times longer than traditional ZSM-5 catalysts. Furthermore, large-scale production of ZSM-5 nanosheets was successfully carried out in a 3 L highpressure autoclave, yielding samples consistent with those from laboratory-scale synthesis. This work marks a significant step forward in the sustainable and efficient production of MFI nanosheets using inexpensive and environmentally friendly raw materials, offering the broad applicability in catalysis.

关键词： MFI zeolite ZSM-5 Nanosheets Scale-up synthesis Aromatic alkylation

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Efficient photocatalytic properties of a dinuclear iron complex with bis[2-hydroxybenzaldehyde]hydrazonate ligand

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Chinese Chemical Letters 2013年第5期24卷 373-375页

作者： Jing-wen Ran Shao-wen liu Peng Wu Jun pei Chemical Engineering College Huanggang Normal University Education Science and Technology College Huanggang Normal University

A novel photooxidative system for degrading toxic organic pollutants is reported.A new complex of Fe_2L_3（L = bis[2-hydroxybenzaldehyde]hydrazone） synthesized can efficiently activate hydrogen peroxide （H_2O_2） to oxidize and mineralize the target complexes rhodamine B（RhB） and methyl orange（MO） in aqueous media under ambient temperature and normal pressure and with visible light irradiation.

关键词： Synthesis Catalysis Degradation Mechanism

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智慧医疗情境下四方主体隐私行为的交互机理及演化趋势研究

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现代情报 2025年第1期45卷 135-149页

作者：朱光吴晗逸刘雯南京信息工程大学风险治理与应急决策研究院江苏南京210044 南京信息工程大学管理工程学院江苏南京210044

[目的/意义]本文针对智慧医疗情境下隐私行为研究在博弈主体、模型参数等方面的不足,探寻患者、医疗机构、智慧医疗平台和政府四方主体之间的隐私行为交互机理与演化趋势。[方法/过程]基于演化博弈理论,构建患者、医疗机构、智慧医疗平... 详细信息

[目的/意义]本文针对智慧医疗情境下隐私行为研究在博弈主体、模型参数等方面的不足,探寻患者、医疗机构、智慧医疗平台和政府四方主体之间的隐私行为交互机理与演化趋势。[方法/过程]基于演化博弈理论,构建患者、医疗机构、智慧医疗平台和政府四方博弈模型。根据不同参数调节下各方行为策略的收益、成本、损失等计算收益矩阵,求解主体的演化稳定策略,并考虑不同因素对主体行为策略及系统稳定状态的影响。[结果/结论]患者的隐私披露行为与披露隐私后获得的服务收益密切相关,医疗机构的隐私保护投入成本和隐私泄露概率对其隐私保护行为有显著影响,智慧医疗平台的政府奖惩、罚款收益和投入成本是影响其严格管理行为的关键因素,政府的监管行为与奖惩机制等因素密切相关。通过应用本文模型和方法,可以动态调整隐私保护机制,明确各方职责,推动智慧医疗可持续健康发展。

关键词：智慧医疗演化博弈隐私行为患者医疗机构智慧医疗平台政府

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Numerical investigation of edge configurations on piston-modal resonance in a moonpool induced by heaving excitations

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Journal of Hydrodynamics 2019年第4期31卷 682-699页

作者： Sheng-chao Jiang pei-wen Cong Lei Sun Chang-feng liu School of Naval Architecture State Key Laboratory of Structural Analysis for Industrial Equipment Dalian University of T/echnology Dalian 116024 China State Key Laboratory of Coastal and Offshore Engineering Dalian University of Technology Dalian 116024 China Department of Civil and Environmental Engineering National University of Singapore Singapore College of Ocean and Civil Engineering Dalian Ocean University Dalian 116023 China

The renormalization group (RNG) turbulent model is used to investigate the fluid resonance in a moonpool formed by two identical rectangular hulls under synchronous heaving excitation (e.g., a catamaran or dual pontoon). The numerical model is validated against the available experimental data, and accurate numerical solutions are obtained. The present study focuses on the amplitude of the moving hulls and the edge configuration of the moonpool entrance, as well as their influences on the piston-modal resonant wave in the moonpool. The dependence of the resonant wave amplitude in the moonpool on the heaving amplitude, the characteristic moonpool dimensions and the local velocity magnitude is derived based on a theoretical analysis, and the results are in good agreement with the RNG turbulent solutions. Five different edge profiles are considered, including two convex edges, two concave edges (both with various dimensions), and a sharp edge. Numerical examinations show that the edge configuration has a significant influence on the piston-modal resonant responses, a larger opening size leading to a higher resonant frequency and a larger resonant wave amplitude in the moonpool. Various flow patterns of the piston-modal resonance in the vicinity of the moonpool entrance are also identified, mainly depending on the edge profile. More intensive turbulent and vortical flows give rise to more significant dissipation, accounting for the smaller relative wave amplitude in the moonpool. With the increase of the heaving amplitude, the relative piston-modal resonant amplitude is decreased in an approximate power function. Within the scope of this work, the numerical investigations show that the piston-modal resonant frequency is hardly affected by the heaving amplitude.

关键词： Moonpool wave resonance comer shape renormalization group (RNG) turbulent model heaving motion

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Data processing of the Kuiyang-ST2000 deep-towed high-resolution multichannel seismic system and application to South China Sea data

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Journal of Oceanology and Limnology 2023年第2期41卷 644-659页

作者： Yanliang pei Mingming wen Zhengrong WEI Baohua liu Kai liu Guangming KAN Key Laboratory of Marine Geology and Metallogeny First Institute of OceanographyMinistry of Natural ResourcesQingdao 266061China Guangzhou Marine Geological Survey China Geological SurveyMinistry of Natural ResourcesGuangzhou 511458China College of Ocean Science and Engineering Shandong University of Science and TechnologyQingdao 266590China Laoshan Laboratory Qingdao 266237Chin

The Kuiyang-ST2000 deep-towed high-resolution multichannel seismic system was designed by the First Institute of Oceanography,Ministry of Natural Resources(FIO,MNR).The system is mainly composed of a plasma spark source(source level:216 dB,main frequency:750 Hz,frequency bandwidth:150-1200 Hz)and a towed hydrophone streamer with 48 *** the source and the towed hydrophone streamer are constantly moving according to the towing configuration,the accurate positioning of the towing hydrophone array and the moveout correction of deep-towed multichannel seismic data processing before imaging are ***,according to the characteristics of the system and the towing streamer shape in deep water,travel-time positioning method was used to construct the hydrophone streamer shape,and the results were corrected by using the polynomial curve fitting ***,a new data-processing workflow for Kuiyang-ST2000 system data was introduced,mainly including float datum setting,residual static correction,phase-based moveout correction,which allows the imaging algorithms of conventional marine seismic data processing to extend to deep-towed seismic *** successfully applied the Kuiyang-ST2000 system and methodology of data processing to a gas hydrate survey of the Qiongdongnan and Shenhu areas in the South China Sea,and the results show that the profile has very high vertical and lateral resolutions(0.5 m and 8 m,respectively),which can provide full and accurate details of gas hydrate-related and geohazard sedimentary and structural features in the South China Sea.

关键词： Kuiyang-ST2000 system deep-towed system seismic data process plasma spark source high resolution gas hydrate South China Sea

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Deciphering fungal metabolon coupling tandem inverse-electrondemand Diels-Alder reaction and semipinacol rearrangement for the biosynthesis of spiro polycyclic alkaloids

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Science China Chemistry 2025年第01期 288-296页

作者： Shuai liu wen-Qiang Xu Ying-Tong Di Man-Cheng Tang Ding-Kang Chen Ming-Ming Cao Yao-wen Chang Hong-Yu Tang Chun-Mao Yuan Jun-Bo Yang Zhi-Li Zuo Han Guo Zi-Fei Xu Ying Zeng Yun-Dong Wu Xiao-Jiang Hao Key Laboratory of Phytochemistry and Natural Medicines (Chinese Academy of Sciences) Kunming Institute of Botany Chinese Academy of Sciences University of Chinese Academy of Sciences Lab of Computational Chemistry and Drug Design State Key Laboratory of Chemical Oncogenomics Peking University Shenzhen Graduate School Shenzhen Bay Laboratory State Key Laboratory of Microbial Metabolism School of Life Sciences & Biotechnology Shanghai Jiao Tong University State Key Laboratory of Functions and Applications of Medicinal Plants Guizhou Medical University Molecular Biology Experimental Center Germplasm Bank of Wild Species in Southwest China Kunming Institute of Botany Chinese Academy of Sciences Yunnan Key Laboratory for Wild Plant Resources Kunming Institute of Botany Chinese Academy of Sciences Research Unit of Chemical Biology of Natural Anti-Virus Products Chinese Academy of Medical Sciences

In the intricate process of natural product biosynthesis, a metabolon can enhance metabolic flux by associating sequential enzymes. A fungal metabolon, comprising of flavin-dependent monooxygenase Spe F and P450 monooxygenase Spe G, is identified in the biosynthesis of spiro polycyclic alkaloids(+)-notoamide B and its diastereomer(+)-versicolamide B. Using notoamide E as a substance, Spe F/Spe G metabolon can control the stereoselectivity of its 2,3-epoxidation, followed by hydrogen atom ion at C-17 to generate reactive epoxide tau-m A with dienyl iminium unit. Subsequently,(+)-notoamide B and(+)-versicolamide B are produced via tandem nonenzymatic inverse-electron-demand Diels-Alder reaction and semipinacol rearrangement. This provides the first example of metabolon in the biosynthesis of spiro-prenylated indole alkaloids.

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Online Monitoring Method for Insulator Self-explosion Based on Edge Computing and Deep Learning

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CSEE Journal of Power and Energy Systems 2022年第6期8卷 1684-1696页

作者： Baoquan Wei Zhongxin Xie Yande liu Kaiyun wen Fangming Deng pei Zhang State Key Laboratory of Performance Monitoring and Protecting of Rail Transit Infrastructure East China Jiaotong UniversityNanchang 330013China School of Mechatronics and Vehicle Engineering East China Jiaotong UniversityNanchang 330013China School of Electrical Engineering Beijing Jiaotong UniversityBeijing 10091China

Aiming at the problems of traditional centralized cloud computing which occupies large computing resources and creates high latency,this paper proposes a fault detection scheme for insulator self-explosion based on edge computing and DL(deep learning).In order to solve the high amount of computation brought by the deep neural network and meet the limited computing resources at the edge,a lightweight SSD(Single Shot MultiBox Detector)target recognition network is designed at the edge,which adopts the MobileNets network to replace VGG16 network in the original model to reduce redundant *** the cloud,three detection algorithms(Faster-RCNN,Retinanet,YOLOv3)with obvious differences in detection performance are selected to obtain the coordinates and confidence of the insulator self-explosion area,and then the self-explosion fault detection of the overhead transmission line is realized by a novel multimodel fusion *** experimental results show that the proposed scheme can effectively reduce the amount of uploaded data,and the average recognition accuracy of the cloud is 95.75%.In addition,it only increases the power consumption of edge devices by about 25.6W/h in their working *** with the existing online monitoring technology of insulator selfexplosion at home and abroad,the proposed scheme has the advantages of low transmission delay,low communication cost and high diagnostic accuracy,which provides a new idea for online monitoring research of power internet of things equipment.

关键词： Deep learning edge computing insulator self-explosion online monitoring power inspection

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Application Analysis of Multiple Neurons Connected with Fast Inhibitory Synapses

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Journal of Bionic Engineering 2024年第4期21卷 1905-1918页

作者： wen Duan Weihai Chen Jianhua Wang Zhongcai pei Jingmeng liu Jianer Chen School of Automation Science and Electrical Engineering Beihang UniversityXueyuan RoadBeijing100191China Hangzhou Innovation Institute Beihang UniversityChuanghui StreetHangzhou310051ZhejiangChina School of Electrical Engineering and Automation Anhui UniversityAnhui230601ZhejiangChina Zhejiang Rehabilitation Medical Center Binsheng RoadHangzhou310052ZhejiangChina

Almost all living organisms exhibit autonomic oscillatory activities,which are primarily generated by the rhythmic activities of their neural *** nonlinear oscillator models have been proposed to elucidate these neural behaviors and subsequently applied to the domain of robot ***,the oscillation patterns generated by these models are often unpredictable and need to be obtained through parameter *** study introduces a mathematical model that can be used to analyze multiple neurons connected through fast inhibitory *** characteristic of this oscillator is that its stationary point is stable,but the location of the stationary point changes with the system *** through reasonable topology and threshold parameter selection can the oscillation be *** study analyzed the conditions for stable oscillation in two-neuron networks and three-neuron networks,and obtained the basic rules of the phase relationship of the oscillator network established by this *** addition,this study also introduces synchronization mechanisms into the model to enable it to be synchronized with the sensing ***,this study used these theories to establish a robot single leg joint angle generation *** experimental results showed that the simulated robot could achieve synchronization with human motion,and had better control effects compared to traditional oscillators.

关键词： Oscillator Phase trajectory Synaptic threshold Synchronization Motion generation

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Engineering atomic Rb-N configurations to tune radical pathways for highly selective photocatalytic H2O2 synthesis coupled with biomass valorization

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Journal of Energy Chemistry 2025年第1期100卷 215-225页

作者： Jiaye Li Shuang Pan Yihuang Chen Qiong liu College of Chemistry and Materials Engineering Wenzhou University Guangdong Provincial Key Laboratory of Chemical Measurement and Emergency Test Technology (China) Institute of Analysis Guangdong Academy of Sciences (China National Analytical CenterGuangzhou)

Photocatalytic oxygen reduction for hydrogen peroxide （H2O2） synthesis presents a green and costeffective production ***,achieving highly selective H2O2synthesis remains challenging,necessitating precise control over free radical reaction pathways and minimizing undesirable oxidative ***,we report for the visible light-driven simultaneous co-photocatalytic reduction of O2to H2O2and oxidation of biomass using the atomic rubidium-nitride modified carbon nitride（CNRb）.The optimized CNRb catalyst demonstrates a record photoreduction rate of 8.01 mM h-1for H2O2generation and photooxidation rate of 3.75 mM h-1for furfuryl alcohol to furoic acid,achieving a remarkable solar-to-chemical conversion （SCC） efficiency of up to 2.27%.Experimental characterizations and DFT calculation disclosed that the introducing atomic Rb–N configurations allows for the high-selective generation of superoxide radicals while suppressing hydroxyl free radical *** is because the Rb–N serves as the new alternative site to perceive a stronger connection position for O2adsorption and reinforce the capability to extract protons,thereby triggering a high selective redox product *** study holds great potential in precisely regulating reactive radical processes at the atomic level,thereby paving the way for efficient synthesis of H2O2coupled with biomass valorization.

关键词： Atomic economy Radical pathway regulation Rubidium atom coordination Biomass valorization

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大白菜地方种质种内遗传关系的RAPD分析

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山东农业大学学报（自然科学版） 2002年第2期33卷 154-157页

作者：黄宝勇曲士松孙晋斌张杰徐培文刘恒英山东省农业科学院蔬菜研究所济南250100

对大白菜亚种内 11个地方种质材料 ,用改进的CTAB法提取DNA后进行RAPD(RandomAmplifiedPolymorphicDNA)分析。聚类结果表明 :当遗传距离为 0 .18时 ,11份材料可分为二个生态类群 ,第一类群属于直筒类型 (交叉性气候生态型 ) ,另一类群在... 详细信息

对大白菜亚种内 11个地方种质材料 ,用改进的CTAB法提取DNA后进行RAPD(RandomAmplifiedPolymorphicDNA)分析。聚类结果表明 :当遗传距离为 0 .18时 ,11份材料可分为二个生态类群 ,第一类群属于直筒类型 (交叉性气候生态型 ) ,另一类群在 0 .15时 ,又分为二个类群 ,矮桩类型 (海洋性气候生态型 )和直筒与矮桩的过渡类型。同时表明 ,应用RAPD选择特定引物在同一亚种内不同品种间进行遗传多样性、亲缘关系及品种鉴定等研究是可行的。

关键词：大白菜地方种质种内遗传 RAPD 遗传关系聚类分析

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