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Preparation of hydrophobic flat sheet membranes from PVDF-HFP copolymer for enhancing the oxygen permeance in nitrogen/oxygen gas mixture

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Chinese Journal of Chemical Engineering 2020年第6期28卷 1566-1581页

作者： Bahador Akbari Asghar Lashanizadegan parviz darvishi Abdolrasoul Pouranfard Department of Chemical Engineering School of EngineeringYasouj UniversityYasoujIran

In this study, poly(vinilydene fluoride-co-hexafluoropropylene)(PVDF-HFP) was used for preparation of hydrophobic membranes using non-solvent induced phase inversion(NIPS) technique. PVDF-HFP copolymer with concentrations of 10 wt% and 12 wt% was prepared to investigate the effect of polymer concentration on pore structure,morphology, hydrophobicity and performance of prepared membranes. Besides, the use of two coagulation baths with the effects of parameters such as coagulant time, polymer type and concentration, and the amount of nonsolvent were studied. The performance of prepared membranes was evaluated based on the permeability and selectivity of oxygen and nitrogen from a gas mixture of nitrogen/oxygen under operating conditions of feed flow rate(1–5 L·min-1), inlet pressure to membrane module(0.1–0.5 MPa) and temperatures between 25 and 45 °C. The results showed that the use of two coagulation baths with different compositions of distillated water and isopropanol,coagulant time, polymer type and concentration, and the amount of non-solvent additive have the most effect on pore structure, morphology, thickness, roughness and crystallinity of fabricated membranes. Porosity ranges for the three fabricated membranes were determined, where the maximum porosity was 73.889% and the minimum value was 56.837%. Also, the maximum and minimum average thicknesses of membrane were 320.85 μm and115 μm. Besides, the values of 4.7504 × 10-7 mol· m-2· s-1· Pa-1, 0.525 and 902.126 nm were achieved for maximum oxygen permeance, O2/N2 selectivity and roughness, respectively.

关键词： Oxygen-enriched air Hydrophobic flat sheet membrane PVDF-HFP copolymer Enhancing oxygen permeance Pore structure

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Investigating the structural effect of electrospun nano-fibrous polymeric films on water vapor transmission

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Chinese Journal of Chemical Engineering 2019年第1期27卷 100-109页

作者： Seyed Jalil Poormohammadian parviz darvishi Abdol Mohammad Ghalambor Dezfuli Chemical Engineering Department School of EngineeringYasouj University Physics Department Shahid Chamran University of Ahvaz

Electrospun polymers have many applications in the ***, the structure of these polymers has been less widely considered by *** this work, the structural effect of electrospun and casted films of polyacrylonitrile(PAN) and polyvinylidene fluoride(PVDF) polymers on water vapor transmission were *** of water vapor was measured at 35, 60 and 80 ℃ and different relative *** diffusion coefficients were calculated based on mass changes of the polymer *** water vapor transmission rate(WVTR) was also measured at 35 ℃ and 90% relative *** results indicated that electrospun nano-fibrous polymers(ESNPs) absorb much higher water vapor compared to non-porous casted *** interaction of water molecules with mentioned polymers was investigated based on Flory-Huggins *** Flory-Huggins interaction parameter of electrospun films was less than casted films, suggesting much better interaction of water molecules with electrospun *** was also found that electrospun films have anomalous kinetic behavior and do not obey the Fickian diffusion ***, it was revealed that ESNPs show less resistance to water vapor transmission and they are good candidates for the applications of water vapor separation using membranes.

关键词： Water vapor transmission Polymer structure Nanofiber Electrospinning Porous layer

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