检索结果-南通市图书馆

Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene

Chinese Journal of Polymer Science 2024年第8期42卷 1111-1121页

作者： Zhi-Qing Ge Shuo Yan zu-xiong pan Shan Lei Xuan-Zhi Mao Chu Zhao Mo-Zhen Wang Xue-Wu Ge Key Laboratory of Precision and Intelligent Chemistry Department of Polymer Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Marshall Laboratory of Biomedical Engineering International Cancer CenterLaboratory of Evolutionary Theranostics(LET)School of Biomedical EngineeringShenzhen University Medical SchoolShenzhen UniversityShenzhen 518055China Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Sciences Beijing 100049China

The thermochromic mechanism and the structure-property regulation principle of reversible thermochromic polydiacetylene(PDA)materials have always been a challenging *** this work,a series of diacetylene monomers(m-PCDA)containing phenyl and amide or carboxyl groups were synthesized from 10,12-pentacosadiynoic acid(PCDA)through the esterification or amidation *** effects of the number and the distribution of the functional groups in m-PCDA molecules on their solid-state polymerization capability,and the thermochromic mechanism of their corresponding polymers(m-PDA)were investigated and discussed in *** results show that the m-PCDA monomers containing both benzene ring and groups that can form hydrogen bonding interactions have strong intermolecular interaction,and are easy to carry out the solid phase polymerization under 254-nm UV irradiation to obtain the corresponding new thermochromic m-PDA *** thermochromic behavior of m-PDA depends on its melting *** initial color-change temperature(blue to red)is determined by the onset melting tem perature,and the temperature range in which reversible color recovery can be achieved by repeat heating-cooling treatment is determined by its melting *** to the proposed thermochromic mechanism of PDA,various new PDA materials with precise thermochromic temperatu res and reversible thermochromic temperature ra nges can be designed and synthesized through the appropriate introduction of benzene ring and groups that can form hydrogen bonding interactions into the molecular structure of linear diacetylene *** work provides a perspective to the precise molecular structure design and the property regulation of the reversible thermochromic PDA materials.

关键词： Polydiacetylene Thermochromism Hydrogen bonding Chemical modification

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Cmtm4 deficiency exacerbates colitis by inducing gut dysbiosis and S100a8/9 expression

引用

Journal of Genetics and Genomics 2024年第8期51卷 811-823页

作者： Qiao Meng Jing Ning Jingjing Lu Jing Zhang Ming zu Jing Zhang Xiurui Han Huiling Zheng Yueqing Gong Xinyu Hao Ying xiong Fang Gu Wenling Han Weiwei Fu Jun Wang Shigang Ding Department of Gastroenterology Peking University Third HospitalBeijing 100191China Beijing Key Laboratory for Helicobacter Pylori Infection and Upper Gastrointestinal Diseases(BZ0371) Beijing 100191China CAS Key Laboratory of Pathogenic Microbiology and Immunology Institute of MicrobiologyChinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100101China Department of Immunology School of Basic Medical SciencesPeking University Health Science CenterNHC Key Laboratory of Medical Immunology(Peking University)Beijing 100191China Peking University Center for Human Disease Genomics Beijing 100191China

The dysfunction of innate immunity components is one of the major drivers for ulcerative colitis(UC),and increasing reports indicate that the gut microbiome serves as an intermediate between genetic mutations and UC ***,we find that the IL-17 receptor subunit,CMTM4,is reduced in UC patients and dextran sulfate sodium(DSS)-induced *** deletion of CMTM4(Cmtm4^(-/-))in mice leads to a higher susceptibility to DSS-induced colitis than in wild-type,and the gut microbiome significantly changes in *** causal role of the gut microbiome is confirmed with a cohousing *** further identify that S100a8/9 is significantly up-regulated in Cmtm4^(-/-)colitis,with the block of its receptor RAGE that reverses the phenotype associated with the CMTM4 ***4 deficiency rather suppresses S100a8/9 expression in vitro via the IL17 pathway,further supporting that the elevation of S100a8/9 in vivo is most likely a result of microbial *** together,the results suggest that CMTM4 is involved in the maintenance of intestinal homeostasis,suppression of S100a8/9,and prevention of colitis *** study further shows CMTM4 as a crucial innate immunity component,confirming its important role in UC development and providing insights into potential targets for the development of future therapies.

关键词： Ulcerative colitis CMTM4 Gut microbiota IL-17 receptor C(IL-17RC) S100a8/9

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

与有限热浴耦合的布朗粒子的演化行为研究

引用

四川大学学报（自然科学版） 2024年第4期61卷 244-250页

作者：卢宏张红熊祖洪贵州工程应用技术学院理学院毕节551700 四川大学物理学院成都610065 西南大学物理科学与技术学院重庆400715

本文重点考查与有限热浴耦合的布朗粒子的非各态历经和非平衡性.在广义朗之万方程框架下,基于拉普拉斯变换理论推导得出粒子演化的精确解,并进一步探究粒子的渐进行为.研究发现即使在非线性势束缚作用下,粒子的稳态行为依赖于初始坐标,... 详细信息

本文重点考查与有限热浴耦合的布朗粒子的非各态历经和非平衡性.在广义朗之万方程框架下,基于拉普拉斯变换理论推导得出粒子演化的精确解,并进一步探究粒子的渐进行为.研究发现即使在非线性势束缚作用下,粒子的稳态行为依赖于初始坐标,而与初始速度无关,呈现非各态历经性.数值模拟结果表明,只初始坐标分布取Gibbs-Boltzmann分布时,粒子才有可能达到平衡态.

关键词：布朗运动非各态历经非线性势

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

基础环式风机基础周期荷载损伤特征分析

引用

科学技术与工程 2024年第6期24卷 2489-2494页

作者：桂鑫保叶祖洋熊宇轩武汉科技大学资源与环境工程学院武汉430081 冶金矿产资源高效利用与造块湖北省重点实验室武汉430081

基础环式风机基础的损伤累积破坏影响风力机系统的安全运行。针对基础环式风机运行过程中基础混凝土损伤问题,以内蒙古某49.5MW风电场为例,利用ABAQUS有限元软件建立风机基础混凝土损伤模型,对比分析了静力荷载工况与周期性荷载工况下... 详细信息

基础环式风机基础的损伤累积破坏影响风力机系统的安全运行。针对基础环式风机运行过程中基础混凝土损伤问题,以内蒙古某49.5MW风电场为例,利用ABAQUS有限元软件建立风机基础混凝土损伤模型,对比分析了静力荷载工况与周期性荷载工况下基础混凝土损伤变化规律。结果表明:静力荷载工况下,基础主要产生拉伸损伤,受压性能稳定,钢筋骨架未达到极限状态;相较于静力荷载,在周期性荷载作用下,拉伸损伤区域增大3倍,竖向扩展增加3倍,压缩损伤面积扩展2倍,位移量增加1.6倍,钢筋应力增大0.5倍,有助于解释周期性荷载作用下基础的损伤行为。

关键词：风机基础周期性荷载损伤 ABAQUS

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

基于LSTM和先验知识的高速公路路面温度预报

引用

应用气象学报 2024年第1期35卷 68-79页

作者：熊国玉祖繁包云轩王可心南京信息工程大学气象灾害预报预警和评估协同创新中心南京210044 中国气象局交通气象重点开放实验室/南京气象科技创新研究院南京210009 无锡学院江苏省物联网设备超融合应用与安全工程研究中心无锡214105

为了精准预报高速公路路面温度,为车辆安全行驶提供气象保障,采用2019—2022年南京市绕城高速公路上9个交通气象站及ERA5-land再分析数据,通过构建时间序列特征工程、引入物理机制相关数据两类方法结合先验知识,运用长短期记忆神经网络... 详细信息

为了精准预报高速公路路面温度,为车辆安全行驶提供气象保障,采用2019—2022年南京市绕城高速公路上9个交通气象站及ERA5-land再分析数据,通过构建时间序列特征工程、引入物理机制相关数据两类方法结合先验知识,运用长短期记忆神经网络模型建立研究区域内4个交通气象站未来3 h逐10 min路面温度多步预报模型并进行验证;在此基础上,将已建立的模型应用于其他交通气象站,探究模型的适用性。结果表明:结合先验知识后,模型预报性能明显提高,准确率在85%以上,且随着预报时效的延长,性能提升更为明显,准确率最高提升36%;模型能较为准确地预报路面极端低温发生的时间和极值,且在预报时效较短时对路面极端高温的预报也具有一定参考价值;利用已建立的模型对其他交通气象站的路面温度进行预报时,准确率在62%以上,在预报时效较短时效果较好,准确率在80%以上,且交通气象站所处的下垫面背景类型对模型的选择起关键作用。

关键词：高速公路路面温度长短期记忆神经网络先验知识多步预报模型

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

有机固废资源化制氢研究进展

引用

现代化工 2024年第9期44卷 55-58,63页

作者：黄家俊石明岩熊祖鸿鲁敏广州大学土木工程学院广东广州510006 中国科学院广州能源研究所广东广州510640

重点介绍了当前有机固废资源化制氢的研究现状和技术原理,包括生物处理和热化学处理2种主要技术途径;总结了各种技术的优缺点以及在实际工程中面临的挑战,并展望了未来的研究方向,为有机固废资源化制氢研究提供重要参考。

关键词：有机固废资源化利用生物处理热化学处理制氢

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation

引用

Chinese Chemical Letters 2024年第9期35卷 514-520页

作者： Lili Wang Ya Yan Rulin Li Xujie Han Jiahui Li Ting Ran Jialu Li Baichuan xiong Xiaorong Song Zhaohui Yin Hong Wang Qingjun Zhu Bowen Cheng Zhen Yin State Key Laboratory of Separation Membranes and Membrane Processes School of ChemistryTiangong UniversityTianjin 300387China School of Chemical Engineering and Technology Tiangong UniversityTianjin 300387China College of Chemical Engineering and Materials Science Tianjin University of Science and TechnologyTianjin 300457China State Key Laboratory of Biobased Fiber Manufacturing Technology Tianjin University of Science and TechnologyTianjin 300457China School of Materials Science and Engineering Tiangong UniversityTianjin 300387China Deutsches Elektronen-Synchrotron DESY Platanenallee 6Zeuthen 15738Germany Department of Chemistry and The Center for the Science of Materials Berlin Humboldt-Universitäzu BerlinBerlin 12489Germany

The electrochemical oxidation of 5-hydroxymethylfurfural(HMF)to valuable chemicals is an efficient way to upgrade biomass molecules and replace traditional catalytic *** is crucial to develop efficient and low-cost earth-abundant electrocatalysts to enhance catalytic performance of HMF ***,a new type of two-dimensional(2D)hybrid arrays consisting of Ni Fe layered double hydroxides(LDH)nanosheets and bimetallic sulfide(Ni Fe S)is constructed via interface engineering for efficient electrocatalytic oxidation of HMF to 2,5-furandicarboxylic acid(FDCA).The preparation process of 2D Ni Fe LDH/NiFeS with ultrathin heterostructure involves in anchoring a Co-based metal-organic framework(Co MOF)as template onto the carbon cloth(CC)via in-situ growth,formation of NiFe LDH on the surface of Co MOF and subsequent partial *** electrocatalyst of Ni Fe LDH/Ni Fe S exhibits outstanding performance towards HMF oxidation,about 98.5%yield for FDCA and 97.2%Faraday efficiency(FE)in the alkaline electrolyte with 10 mmol/L HMF,as well as excellent stability retaining 90.1%FE for FDCA after six cycles ***,even at an HMF concentration of 100 mmol/L,the yield and FE for FDCA remain high at 83.6%and 93.6%,*** findings highlight that 2D heterostructure containing abundant interfaces between Ni Fe LDH nanosheets and Ni Fe S can enhance the intrinsic activity of LDH and thus promote the oxidation reaction ***,the synergistic effect of the bimetallic Ni Fe compounds also improved the selectivity of HMF conversion to *** present work demonstrates that constructing 2D ultrathin heterostructure of Ni Fe LDH/Ni Fe S is a facile strategy via interface engineering to enhance the intrinsic activity of LDH electrocatalysts,which would open new avenues toward low-cost and advanced 2D nanocatalysts for sustainable energy conversion and electrochemical valorization of biomass derivatives.

关键词： Electrocatalytic oxidation Interface engineering 2D ultrathin heterostructure Layered double hydroxides 5-Hydroxymethylfurfural

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Arsenite oxidation by three types of manganese oxides

引用

Journal of Environmental Sciences 2006年第2期18卷 292-298页

作者： FENG xiong-han zu Yan-qun TAN Wen-feng LIU Fan College of Resources and Environment Huazhong Agricultural University Wuhan 430070 China College of Resources and Environment Yunnan Agricultural University Kunming 650201 China

Oxidation of As（Ⅲ） by three types of manganese oxides and the effects ofpH, ion strength and tartaric acid on the oxidation were investigated by means of chemical analysis, equilibrium redox, X-ray diffraction （XRD） and transmission electron microscopy （TEM）. Three synthesized Mn oxide minerals, bimessite, cryptomelane, and hausmannite, which widely occur in soil and sediments, could actively oxidize As（Ⅲ） to As（Ⅴ）. However, their ability in As（Ⅲ）-oxidation varied greatly depending on their structure, composition and surface properties. Tunnel structured cryptomelane exhibited the highest ability of As （Ⅲ） oxidation, followed by the layer structured birnessite and the lower oxide hausmannite. The maximum amount of As （Ⅴ） produced by the oxidation was in the order （mmol/kg） of cryptomelane （824.2）〉 bimessite （480.4）〉 hausmannite （117.9）, As pH increased from the very low value（pH 2.5）, the amount of As（Ⅲ） oxidized by the tested Mn oxides was firstly decreased, then negatively peaked in pH 3.0 6.5, and eventually increased remarkably. Oxidation of As（Ⅲ） by the Mn oxides had a buffering effects on the pH variation in the solution. It is proposed that the oxidative reaction processes between As （Ⅲ） and biruessite（or cryptomelane） are as follows：（1） at lower pH condition：（MnO2）x＋ H3AsO3 ＋ 0.5H^＋=0.5H2AsO4^- ＋ 0.5HAsO4^2- ＋Mn〉^2＋（MnO2）x-1 ＋ H2O; （2） at higher pH condition：（MnO2）x ＋ H3AsO3 = 0.5H2AsO4^- ＋ 0.5HAsO4^2- ＋ 1.5H^＋＋（MnO2）x-1. MnO. With increase of ion strength, the As（Ⅲ） oxidized by bimessite and cryptomelane decreased and was negatively correlated with ion strength. However, ion strength had little influence on As （Ⅲ） oxidation by the hausmarmite. The presence of tartaric acid promoted oxidation of As（Ⅲ） by birnessite. As for cryptomelane and hansmannite, the same effect was observed when the concentration of tartaric acid was below 4 mmol/L, otherwise the oxidized As（Ⅲ） decreased. These findings are of great significance in improving our understanding

关键词： oxidation of As(Ⅲ) As(Ⅴ) Mn oxides pH ion strength tartaric acid

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Interference-Limited Device-to-Device Multi-User Cooperation Scheme for Optimization of Edge Networking

引用

Journal of Computer Science & Technology 2016年第6期31卷 1096-1109页

作者： Hong-Cheng Huang Jie Zhang zu-Fan Zhang Zhong-Yang xiong College of Computer Science Chongqing University Chongqing 400044 China School of Communication and Information Engineering Chongqing University of Posts and Telecommunications Chongqing 400065 China

Device-to-device （D2D） communication is an emerging technology for improving cellular networks, which plays an important role in realizing Internet of Things （IoT）. The spectrum efficiency, energy efficiency and throughput of network can be enhanced by the cooperation among multiple D2D users in a self-organized method. In order to limit the interference of D2D users and load off the energy consumption of D2D users without decreasing communication quality, an interference- limited multi-user cooperation scheme is proposed for multiple D2D users to solve the energy problem and the interference problem in this paper. Multiple D2D users use non-orthogonal spectrums to form clusters by self-organized method. Multiple D2D users are divided into different cooperative units. There is no interference among different cooperative units so as to limit the interference of each D2D user in cooperative units. When the link capacity cannot meet the requirements of the user rate, it will produce an interrupt event. In order to evaluate the communication quality, the outrage probability of D2D link is derived by considering link delay threshold, data rate and interference. Besides the energy availability and signal-to-noise ratio （SNR） of each D2D user, the distance between D2D users is considered when selecting the relaying D2D users so as to enhance the signal-to-interference-plus-noise ratio （SINR） of D2D receiving users. Combining the derived outrage probability, the relationships among the average link delay threshold, the efficiency of energy and the efficiency of capacity are studied. The simulation results show that the interference-limited multiple D2D users cooperation scheme can not only help to offioad energy consumption and limit the interference of D2D users, but also enhance the efficiency of energy and the efficiency of capacity.

关键词： device-to-device (D2D) user cooperation relay selection efficiency of energy efficiency of capacity Internetof Things (IoT)

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Intrinsic Decoherence on Two-Qubit Heisenberg XX Chain

引用

Communications in Theoretical Physics 2007年第5期47卷 811-815页

作者： HE Zheng-Hong xiong zu-Hong HU Dong-Mei School of Physics Southwest University Chongqing 400715 China

Quantum teleportation is investigated by using the entangled states of two-qubit Heisenberg XX chain in an external uniform magnetic field as resources in the model of Milburn＇s intrinsic decoherence. Though intrinsic decoherence on quantum entanglement and quantum teleportation exerts different effects in different initial systems, proper magnetic fields and probabilities of different eigenstates in the initial states can weaken the effects.

关键词： Heisenberg chain fidelity intrinsic decoherence entanglement

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：