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Olefin polymerization Behavior of Titanium(IV) Complexes with Fluorinated and Non-fluorinated Aliphatic phenoxyimine Ligands

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Chinese Journal of polymer Science 2024年第1期42卷 52-62,I0007页

作者： Vladislav A.Tuskaev Kasim F.Magomedov Svetlana Ch.Gagieva Dmitry A.Kurmaev Yulia V.Nelyubina evgenii K.Golubev Maria D.evseeva Viktor G.Vasil'ev Galina G.Nikiforova Mikhail I.Buzin Vyacheslav S.Bogdanov Boris M.Bulychev Department of Chemistry M.V.Lomonosov Moscow State UniversityMoscow 119992Russian Federation A.N.Nesmeyanov Institute of Organoelement Compounds Russian Academy of SciencesMoscow119991Russian Federation Enikolopov Institute of Synthetic polymer Materials Russian Academy of SciencesMoscow 117393Russian Federation

A series of Ti(Ⅳ) dichloride and dialkoxide com plexes with phenoxyimine ligands containing fluorinated and nonfluorinated aliphatic imine fragments have been *** molecular structures of complexes 1 and 4 were established by single-crystal X-ray diffraction *** complexes adopt a distorted octahedral coordination structure around the titanium atom and two oxygen atoms are situated in trans position while two nitrogen atoms and two outgoing ligands(Cl or iprO) are situated in cis *** of activators(MMAO-12 and combinations Et_nAICl_(3-n)+Bu_(2)Mg) and outgoing ligand(Cl or iprO) nature on the catalytic activity and properties of the resulting polymers was *** Ti complexes,despite the nature of the outgoing ligands(Cl or iprO) in the presence of Al/Mg activators,was found to display a high ethylene polymerization activity in the range 1600-3830 kg_(polymer)·mol_(Ti)^(-1)·h^(-1)·atm^(-1) with a viscosity average molecular weight(M_v) value in the range 1.1×10~6-7.1×10~6 Dalton(Da).The resulting UHMWpE can be processed by a solventless method into high-strength and high-modulus oriented *** rheological characteristics of a polymer melt have been *** absence of a cross-over point did not allow to compare the values of the molecular weight distribution of polymers obtained on fluorinated and non-fluorinated pre-catalysts,however,the estimation of the entanglement density is in good agreement with the mechanical characteristics of oriented film *** activation with methylalumoxane,the activity of the com plexes decreased very significantly;however,a polymer with a molecular weight of about 12 million Da was *** the process of ethylene/octene-1 copolymerization,fluorine-containing precatalysts showed a clear advantage over non-fluorinated analogues both in activity and in comonomer content.

关键词： FI catalysts Titanium(IV) (Co)polymerization Al/Mg co-catalyst Ultra-high molecular weight polyethylene

Non-thermal atmospheric-pressure positive pulsating corona discharge in degradation of textile dye Reactive Blue 19 enhanced by Bi_(2)O_(3) catalyst

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plasma Science and Technology 2024年第2期26卷 104-113页

作者： Milica pETROVIC Dragan RADIVOJevIC Sasa RANCev Nena VELINOV Milos KOSTIC Danijela BOJIC Aleksandar BOJIC Department of Chemistry Faculty of Sciences and MathematicsUniversity of NisNis 18000Serbia Department of physics Faculty of Sciences and MathematicsUniversity of NisNis 18000Serbia

In this work,monoclinic Bi_(2)O_(3) was applied for the first time,to the best of our knowledge,as a catalyst in the process of dye degradation by a non-thermal atmospheric-pressure positive pulsating corona *** research focused on the interaction of the plasma-generated species and the catalyst,as well as the role of the catalyst in the degradation *** decomposition of the anthraquinone reactive dye Reactive Blue 19(RB 19) was performed in a selfmade reactor ***_(2)O_(3) was prepared by electrodeposition followed by thermal treatment,and characterized by x-ray diffraction,scanning electron microscopy and energy-dispersive xray *** was observed that the catalyst promoted decomposition of plasma-generated H_(2)O_(2) into ·OH radicals,the principal dye-degrading reagent,which further attacked the dye *** catalyst improved the decolorization rate by 2.5 times,the energy yield by 93.4%and total organic carbon removal by 7.1%.Excitation of the catalyst mostly occurred through strikes by plasma-generated reactive ions and radical species from the air,accelerated by the electric field,as well as by fast electrons with an energy of up to 15 ev generated by the streamers reaching the liquid *** strikes transferred the energy to the catalyst and created the electrons and holes,which further reacted with H_(2)O_(2) and water,producing ·OH *** was indentified as the primary role of the catalyst in this *** reactions followed pseudo first-order *** of H_(2)O_(2) and the dye degradation rate increased with increase in the input *** optimal catalyst dose was 500 mg·dm^(-3).The decolorization rate was a little lower in river water compared with that in deionized water due to the side reactions of ·OH radicals with organic matter and inorganic ions dissolved in the river water.

关键词： corona RB 19 Bi_(2)O_(3) catalyst degradation

Flat-footed Females and Missing Males:A New Genus and Species of pleciofungivoridae(Diptera:Bibionomorpha)Represents the First Record of the Family from Mid-Cretaceous Kachin Amber

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 541-547页

作者： ZHANG Qingqing Wiesław KRZEMINSKI Jan SevCIK Vladimir BLAGODEROV Agnieszka SOSZYNSKA Kornelia SKIBINSKA Yunnan Key Laboratory for palaeobiology Institute of PalaeontologyYunnan UniversityKunming 650500China MEC International Joint Laboratory for palaeobiology and palaeoenvironment Yunnan UniversityKunming 650500China State Key Laboratory of palaeobiology and Stratigraphy Nanjing Institute of Geology and Palaeontology and Center for Excellence in Life and PaleoenvironmentChinese Academy of SciencesNanjing 210008China Institute of Systematics and evolution of Animals Polish Academy of Sciences52551 KrakówPoland University of Ostrava Faculty of ScienceDepartment of Biology and EcologyChittussiho 10CZ-71000 OstravaCzech Republic National Museums Scotland EdinburghUK Natural History Museum LondonUK University of Lodz Faculty of Biology and Environmental ProtectionDepartment of Invertebrate Zoology and HydrobiologyBanacha 12/1690-237ŁódźPoland

A new genus and species,Cretopleciofungivora simpsoni *** ***.,from the extinct family pleciofungivoridae(Diptera:Bibionomorpha),is discovered in mid-Cretaceous Kachin ***,this family was known only from imprints in sedimentary rocks of the Jurassic and the Lower *** of a representative of pleciofungivoridae in Kachin amber confirms the presence of the family in the Upper *** new species has a unique structure of fore tarsus,with lobed and extended tarsal segments Ⅱ to Ⅳ,a feature hitherto known only in a few species of extant *** not particularly rare,the new species is currently known only from female *** reasons for this phenomenon,very unusual in Sciaroidea,are briefly discussed,including parthenogenesis as a potentially plausible hypothesis.

关键词： fungus gnats Sciaroidea Upper Cretaceous Burmese amber swollen tarsomeres

On Finite Non-Solvable Groups Whose Gruenberg-Kegel Graphs are Isomorphic to the paw

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Communications in Mathematics and Statistics 2022年第4期10卷 653-667页

作者： A.S.Kondrat’ev N.A.Minigulov N.N.Krasovskii Institute of Mathematics and Mechanics of the Ural Branch of the Russian Academy of Sciences 16 S.Kovalevskaya StrYekaterinburg 620108Russia

The Gruenberg-Kegel graph(or the prime graph)Γ(G)of a finite group G is a graph,in which the vertex set is the set of all prime divisors of the order of G and two different vertices p and q are adjacent if and only if there exists an element of order pq in *** paw is a graph on four vertices whose degrees are 1,2,2,*** consider the problem of describing finite groups whose Gruenberg-Kegel graphs are isomorphic as abstract graphs to the *** example,the Gruenberg-Kegel graph of the alternating group A_(10)of degree 10 is isomorphic as abstract graph to the *** this paper,we describe finite non-solvable groups G whose Gruenberg-Kegel graphs are isomorphic as abstract graphs to the paw in the case when G has no elements of order 6 or the vertex of degree 1 ofΓ(G)divides the order of the solvable radical of G.

关键词： Finite group Non-solvable group Gruenberg-Kegel graph The paw

High-yield and rapid isolation of extracellular vesicles by flocculation via orbital acoustic trapping:FLOAT

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Microsystems & Nanoengineering 2024年第1期10卷 313-323页

作者： Joseph Rufo peiran Zhang Zeyu Wang Yuyang Gu Kaichun Yang Joseph Rich Chuyi Chen Ruoyu Zhong Ke Jin Ye He Jianping Xia Ke Li Jiarong Wu Yingshi Ouyang Yoel Sadovsky Luke p.Lee Tony Jun Huang Department of Mechanical Engineering and Materials Science Duke UniversityDurhamNCUSA Department of Biomedical Engineering Duke UniversityDurhamNCUSA Department of Obstetrics Gynecologyand Reproductive SciencesMagee-Womens Research InstituteUniversity of PittsburghPittsburghPAUSA Department of Microbiology and Molecular Genetics School of MedicineUniversity of PittsburghPittsburghPAUSA Renal Division and Division of Engineering in Medicine Department of MedicineBrigham and Women’s HospitalHarvard Medical SchoolBostonMAUSA Department of Bioengineering Department of Electrical Engineering and Computer ScienceUniversity of CaliforniaBerkeleyBerkeleyCAUSA Department of Biophysics Institute of Quantum BiophysicsSungkyunkwan UniversitySuwonKorea

Extracellular vesicles(evs)have been identified as promising biomarkers for the noninvasive diagnosis of various ***,challenges in separating evs from soluble proteins have resulted in variable ev recovery rates and low ***,we report a high-yield(>90%)and rapid(ev isolation method called FLocculation via Orbital Acoustic Trapping(FLOAT).The FLOAT approach utilizes an acoustofluidic droplet centrifuge to rotate and controllably heat liquid *** adding a thermoresponsive polymer flocculant,nanoparticles as small as 20 nm can be rapidly and selectively concentrated at the center of the *** demonstrate the ability of FLOAT to separate urinary evs from the highly abundant Tamm-Horsfall protein,addressing a significant obstacle in the development of ev-based liquid *** to its high-yield nature,FLOAT reduces biofluid starting volume requirements by a factor of 100(from 20 mL to 200µL),demonstrating its promising potential in point-of-care diagnostics.

关键词： trapping utilize separating

Excellent photoluminescence and electrochemical properties of Sm^(3+) doped Ca_(2)MgSi_(2)O_(7) nanophosphor:Display and electrochemical sensor applications

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Journal of Rare Earths 2024年第6期42卷 1046-1055,I0002页

作者： R.B.Basavaraj K.Sureshkumar D.p.Aarti M.B.Madhusudana Reddy G.Nagaraju T.Ramakrishnappa G.R.Navyashree K.R.Venkatesha Babu K.S.Hemalatha Department of physics BMS Institute of Technology and ManagementBangalore560064India Department of Chemistry BMS Institute of Technology and ManagementBangalore560064India Department of Chemistry School of Applied SciencesREVA UniversityBangalore560064India Energy Materials ResearchLaboratory Department of ChemistrySiddaganga Institute of TechnologyTumakuru57203KarnatakaIndia School of physical Sciences REVA UniversityBangalore560057Indi Department of physics Govt.Science CollegeBengaluru560001India Department of physics Maharani Science College for WomenMaharani Cluster UniversityBengaluru560001India

A series of orange-red light emitting Ca_(2)MgSi_(2)O_(7):Sm^(3+)nanopowders were fabricated via low-cost ecofriendly green combustion technique using Aloe vera gel as *** phase purity of the samples were confirmed by the powder X-ray diffraction(pXRD)*** single-phase tetragonal structure is observed from the pXRD results with no additional impurity *** band gap energy of the fabricated powders was estimated by diffuse reflectance spectra(DRS)and is found to be in the range of 4.01-5.98 ev.A high resolution scanning electron microscope(SEM)was used to study the morphological behaviour of the ***-like structures are observed from the SEM *** particle size was evaluated by transmission electron microscopy(TEM)and is found to be~50 *** interplanar distance is found to be 0.53 *** properties were systematically studied in *** phosphors are successfully excited at 403 nm NUV light,producing reddish-orange characteristic *** emission peaks are centered at 558(^(4)G_(5/2)→^(6)H_(5/2)),607(^(4)G_(5/2)→^(6)H_(7/2))and 645 nm(^(4)G_(5/2)→^(6)H_(9/2)),*** the observed peaks the red emanation(^(4)G_(5/2)→^(6)H_(7/2))is stronger than the orange emission(^(4)G_(5/2)→^(6)H_(5/2))in the current *** photoluminescent concentration quenching is noticed above 5 mol%Sm^(3+)ion doping *** dipole-dipole interaction resulting in cross relaxation is found to be the principal cause of concentration quenching *** color features such as Commission Internationale de I’Eclairage(CIE)and correlated color temperature(CCT)were studied in *** optimized chromaticity coordinates were estimated to be(0.6363,0.3632),which fall in the reddish-orange *** average CCT value obtained is 3362 *** average color purity is found to be~82%.Sm^(3+)incorporated Ca_(2)MgSi_(2)O_(7) samples are possible contender for single white light generation commercial candidates owing to

关键词： Green combustion photoluminescence Orange-red emission Color purity Sensors Rare earths

Hole-doping induced ferromagnetism in 2D materials

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npj Computational Materials 2022年第1期8卷 2180-2189页

作者： Ruishen Meng Lino da Costa pereira Jean-pierre Locquet Valeri Afanas’ev Geoffrey pourtois Michel Houssa Department of physics and Astronomy KU LeuvenCelestijnenlaan 200DLeuvenB-3001Belgium imec Kapeldreef 75B-3001LeuvenBelgium

Two-dimensional(2D)ferromagnetic materials are considered as promising candidates for the future generations of spintronic ***,2D materials with intrinsic ferromagnetism are ***,high-throughput first-principles simulations are performed to screen 2D materials that present a non-magnetic to a ferromagnetic transition upon hole doping.A global evolutionary search is subsequently performed to identify alternative possible atomic structures of the eligible candidates,and 122 materials exhibiting a hole-doping induced ferromagnetism are *** energetic and dynamic stability,as well as magnetic properties under hole doping are investigated *** of these 2D materials are metal halides,followed by chalcogenides,oxides,and nitrides,some of them having predicted Curie temperatures above 300 *** exchange interactions responsible for the ferromagnetic order are also *** work not only provides theoretical insights into hole-doped 2D ferromagnetic materials,but also enriches the family of 2D magnetic materials for possible spintronic applications.

关键词： ferromagnetic doping materials

Finite Groups Isospectral to Simple Groups

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Communications in Mathematics and Statistics 2023年第2期11卷 169-194页

作者： Maria A.Grechkoseeva Victor D.Mazurov Wujie Shi Andrey V.Vasil’ev Nanying Yang Sobolev Institute of Mathematics Koptyuga 4NovosibirskRussia 630090 Department of Mathematics Chongqing University of Arts and SciencesChongqing 402160People’s Republic of China School of Mathematics Suzhou UniversitySuzhou 215006People’s Republic of China School of Science Hainan UniversityHaikou 570228HainanPeople’s Republic of China School of Science Jiangnan UniversityWuxi 214122People’s Republic of China

The spectrum of a finite group is the set of element orders of this *** main goal of this paper is to survey results concerning recognition of finite simple groups by spectrum,in particular,to list all finite simple g... 详细信息

关键词： Finite group Simple group Element order Spectrum Recognition by spectrum

Fatal bleeding due to an aorto-esophageal fistula: A case report and literature review

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World Journal of Clinical Cases 2022年第31期10卷 11493-11499页

作者： Davorin Ćeranić Sara Nikolić Jernej Lučev Aleš Slanič Tatjana Bujas Andreja Ocepek pavel Skok Department of Gastroenterology Internal Medicine ClinicUniversity Medical Centre MariborMaribor 2000Slovenia Department of Radiology University Medical Centre MariborMaribor 2000Slovenia Department of pathology University Medical Centre MariborMaribor 2000Slovenia

BACKGROUND Aorto-esophageal fistula is an extremely rare cause of acute upper gastrointestinal bleeding(UGIB).CASE SUMMARY We present a case of an 80-year-old woman with esophageal cancer who was admitted to our department with hemorrhagic shock due to *** the diagnostic procedure,emergency computed tomography angiography was performed and confirmed aorto-esophageal *** radiologists inserted a stent graft into the aorta,successfully closing the ***,the patient later died of heart failure following irreversible hemorrhagic *** confirmed the aorto-esophageal fistula,which formed 1 cm below the distal edge of the stent previously inserted into the esophagus for a malignant *** There are very rare causes of *** clinical decisions are made during the diagnostic workup of these patients,we must be aware of the limitations of various therapeutic options,even the most contemporary.

关键词： Aorto-esophageal fistula Upper gastrointestinal bleeding Interventional radiology Stent graft Case report