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CO oxidation under lean and stoichiometric conditions over ceriazirconia with very low metal contents(Cu,Co,Ag and pt)

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Journal of Rare Earths 2024年第9期42卷 1669-1681,I0002页

作者： J.C.Martínez-Munuera M.p.Yeste A.García-García MCMA Group Department of Inorganic Chemistry and Institute of MaterialsUniversity of AlicanteCarretera de San Vicente del Raspeig s/n03690San Vicente del RaspeigAlicanteSpain Solid Chemistry and Catalysis Group Department of Materials ScienceMetallurgic Engineering and Inorganic ChemistryInstitute of Electronic Microscopy and Materials ResearchUniversity of CádizAp.40E-11510Puerto RealCádizSpain

In this work,several ceria-zirconia based catalysts with very lo w(and equimolar) metal contents were prepared,characterised and tested for the CO oxidatio n reaction(under lean and stoichiometric conditions),trying to emulate those conditions found in a diesel oxidation catalyst(DOC) system from a diesel engine and those encountered under gasoline exhaust(λ=1).The metals chosen are Cu,Co,Ag and pt(as a reliable benchmark).The results reveal enormous differences among reducibility and catalytic activity despite quite similar structural and textural properties of the catalysts,showing differences among dispersion(Ag-catalyst seems to present a low level of dispersion).This catalyst seems to be characterised,as well,by a strong electronic interaction between Ce and Ag centres which is suggested to yield an improved reducibility under H_(2)-TpR ***,the order in catalytic activity(Cu>Ag>Co≈pt>>support) seems not to follow the order found in reducibility and the Cu-catalyst seems to be the most active independently on the reaction conditions,yielding nearly overlapped CO oxidation catalytic *** restingly,a stro ng correlation between the catalytic activity under the two conditions tested and the OSC values of the Ce_(0.8)Zr_(0.2)O_(2)-supported metal catalysts is ***,OSC parameter measured at 150℃ can be used as a relevant descriptor to evaluate the CO oxidation activity at low and medium conversions for the investigated catalysts,much better than the H_(2)-TpR measurements.

关键词： CO oxidation Low metal content Ceria-zirconia Copper species OSC parameter Rare earths

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Effect of high temperature short time infrared roasting of peanuts

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Journal of Future Foods 2024年第2期4卷 173-178页

作者： Rahi Golani Chinglen Leishangthem Hongwei Xiao Qi Zhang p.p.Sutar Department of Food process Engineering National Institute of Technology RourkelaOdisha 769008India College of Engineering China Agricultural UniversityBeijing 100083China College of Mechanical Engineering Yangzhou UniversityYangzhou 225127China

Roasting is the most common processing method that enhances color,and *** this study,infrared roasting of peanuts was done using an infrared rotary *** was operated at 90%infrared power(630 W)with different rotating speed(1 and 2 r/min).The effect of roasting was studied at different moisture levels(7.66%,11.49%,and 13.72%db).From the study,the color parameter,L*value,was found to be significantly different(ppeed,and the∆E value varies from 2.32 to *** also showed that the antioxidant activity decreased with the reduction in rotating speed as lesser revolutions took longer roasting time,and the values decreased from 84.34%to 71.74%.Minimal changes in total phenolic content were found and varied from 3.62 to 2.10 mg/g GAE,an appropriate limit for good-quality roasted *** hardness of roasted peanuts ranged from 12.25 to 39.43 *** content 13.72%,and 1 r/min is the best possible treatment for infrared peanut roasting,significantly enhancing the quality of *** study concluded that high-power short-time infrared roasting could give good-quality roasted peanuts with optimum bioactive compounds.

关键词： Roasting Infrared Total phenolic content Antioxidant activity

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perianal Crohn’s disease:Still more questions than answers

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World Journal of Gastroenterology 2024年第39期30卷 4260-4266页

作者： Akhilesh Swaminathan Miles p Sparrow Department of Medicine University of OtagoChristchurch 8011CanterburyNew Zealand Department of Gastroenterology Alfred HealthMelbourne 3004VictoriaAustralia Department of Gastroenterology The Alfred HospitalMelbourne 3004VictoriaAustralia Department of Gastroenterology Alfred Health and School of Translational MedicineMonash UniversityMelbourne 3004VictoriaAustralia

In this editorial we comment on the article by pacheco et al published in a recent issue of the World Journal of *** focus specifically on the burden of illness associated with perianal fistulizing Crohn’s disease(pFCD)and the diagnostic and therapeutic challenges in the management of this ***-ving evidence has shifted the diagnostic framework for pFCD from anatomical classification systems,to one that is more nuanced and patient-focused to drive ongoing decision *** editorial aims to reflect on these aspects to help clinicians face the challenge of pFCD in day-to-day clinical practice.

关键词： perianal Crohn’s disease Crohn’s disease classification Disease severity Crohn’s disease treatment Anorectal malignancy

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New guidelines for screening,evaluation and management of hepatobiliary disease in cystic fibrosis

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Hepatobiliary Surgery and Nutrition 2024年第5期13卷 875-878页

作者： p.Aiden McCormick Emer Fitzpatrick Liver Unit St Vincent’s University HospitalDublinIreland Department of Medicine UCD School of MedicineUniversity College DublinDublinIreland Gastroenterology and Liver Department Children’s Health IrelandCrumlinDublinIreland

The recently published guidelines on screening,monitoring and treatment update previous guidelines published 25 years ago(1,2).This update is timely as much has happened in the *** fibrosis(CF)modulator therapy has dramatically improved prognosis for patients with CF,although it is not yet clear whether liver disease is *** understanding of the pathophysiology of CF liver disease has also changed with the recognition of the importance of non-cirrhotic portal hypertension(3,4).Non-invasive tests for fibrosis and elastography have changed the practice of hepatology and reduced the need for liver *** guideline committee was made up of experts from North America and Europe and included adult and paediatric hepatologists and pulmonologists together with allied health practitioners and representatives of the CF community.A systematic literature search was performed and a vote of 80%was required to adopt a *** guidelines contain 7 recommendations for screening,13 for disease monitoring and 14 for treatment.

关键词： Cirrhosis oesophageal varices non-cirrhotic portal hypertension porto-sinusoidal vascular disease hepatobiliary

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Enantioselective iridium-catalyzed allylic substitution with a Reformatsky reagent: direct construction of β-stereogenic homoallylic esters

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Science China Chemistry 2024年第11期67卷 3791-3797页

作者： Debasis pal Kirana D.Veeranna Yuk Fai Wong p.Andrew Evans Department of Chemistry Queen's University Xiangya School of pharmaceutical Sciences Central South University

The Reformatsky reagent derived from ethyl bromoacetate circumvents the challenge associated with the direct regio-and enantioselective iridium-catalyzed allylic alkylation with an unstabilized aliphatic ester enolate. Notably, this work represents the first example of using a Reformatsky reagent in a metal-allyl reaction, which permits the direct construction of enantioenriched β-stereogenic homoallylic esters without preactivation of the pronucleophile or post-reaction modification of the product(e.g., thermal decarboxylation of a 1,3-dicarbonyl). Moreover, the process allows the coupling of a broad range of sterically and electronically diverse electrophiles bearing aryl, heteroaryl and alkenyl derivatives, including the significantly more challenging alkyl-substituted allylic carbonates. The versatility of the ester product is exemplified by a series of functional group manipulations and the development of a concise and efficient enantioselective total synthesis of the natural product,(+)-descurainolide A. Finally, mechanistic studies indicate that the zinc enolate behaves as a soft nucleophile that undergoes outer-sphere alkylation.

关键词： allylic substitution asymmetric catalysis mechanistic studies natural product synthesis Reformatsky reagent

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The Value of Traditional Medicine Should not be Underestimated-Traditional Chinese Medicine in Treatment of Autoimmune Diseases

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Chinese Medicine and Culture 2024年第2期7卷 167-173页

作者： Yurii O Novikov Anait p Akopyan Bashkir State Medical University Republic of BashkortostanRussia 450008

Autoimmune diseases of the nervous system(ADNS)are characterized by the formation of a pronounced neurologic deficit and often lead to *** attention of doctors and researchers is increasingly attracted by complementary medicine as adjuvant or preventive therapy for various diseases,including autoimmune *** Chinese medicine(TCM)is a combination of treatment methods that include acupuncture,herbal medicine,dietetics,physical exercises,and other methods that are often used in conjunction with recognized approaches of official medical *** article describes the application of TCM techniques in autoimmune diseases of the nervous system,and demonstrates clinical experience in the use of acupuncture,herbal medicine,diets and physical *** and complementary medicine is an important and often underestimated healthcare resource,especially in the prevention and treatment of autoimmune diseases of the nervous system.

关键词： Autoimmune diseases Traditional Chinese medicine Nervous diseases

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performance of unique and secure routing protocol(USRp)in flying Adhoc Networks for healthcare applications

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High-Confidence Computing 2024年第1期4卷 24-31页

作者： J.Vijitha Ananthi p.Subha Hency Jose Department of Biomedical Engineering Karunya Institute of Technology and SciencesCoimbatoreIndia

Nowadays,Flying Adhoc Networks play a vital role due to its high efficiency in fast *** aerial vehicles transmit data much faster than other networks and are useful in all aspects of *** healthcare applications,wireless body area network transmits the data,whereas the security,which is the most important concern to be focused in a flying adhoc network is not *** intruders tamper the network,degrading the overall network *** avoid security issues,a unique and secure routing protocol that provides a single solution for five different types of attacks such as,black hole attacks,grey hole attacks,yoyo attacks,conjoint attack and jamming attacks,is *** simulation results analyses the network performance by using the proposed routing *** comparison to the other solutions rendered to resolve the affected network,this proposed routing protocol has a higher throughput,higher delivery rate,and lower *** Unique and Secure Routing protocol(USRp)provides an integrated solution for an efficient and secure communication in a flying adhoc network.

关键词： Secure routing protocol Flying Adhoc Networks Unmanned aerial vehicles Mobile Adhoc network Attackers Denial of service attacks

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Niche differentiation among facultative filter feeders: Insights from invasive ponto-Caspian mysids

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Current Zoology 2024年第4期70卷 513-521页

作者： péter Borza Varsha Rani Csaba F.Vada Institute of Aquatic Ecology Centre for Ecological ResearchKarolina ut 29.1113 BudapestHungary Doctoral School of Biology Institute of BiologyEotvos Lorand UniversityPazmany Péter sétany 1/C1117 BudapestHungary

The degree of dietary specialization has a fundamental impact on the ecological function and interactions of suspension *** niche differentiation by food particle size is common among obligate suspension feeders,its role is not evident in facultative *** this study,we aimed at providing new insights on the matter by focusing on sympatric mysid *** mysids use different mechanisms for raptorial and filter-feeding,they represent a more adequate model system than for example,the more extensively studied *** made morpholog-ical measurements on the 4 coexisting invasive ponto-Caspian mysid species to determine the areas and mesh sizes of their *** also quantified their clearance rates on the microalga Cryptomonas *** a laboratory experiment to reveal how morphological differences manifest in their overall filtering *** found relatively small but consistent differences in the primary filter area among the species,indicating that morphological constraints due to the enclosed position of the setae might limit the possibility for *** primary filter mesh sizes were small in all 4 species(0.69-2.73μm)with moderate but consistent intraspecific differences,suggesting that the benefit of being able to capture small particles might outweigh the pressure for *** observed clearance rates were in accordance with the morphological characteristics of the species,highlighting that auxiliary filters(present in one of the species,Limnomysis benedeni)are needed to increase filtering capacity *** study confirmed that food particle size can contribute to the niche differentiation of facultative filter feeders,but also indicated that they can tolerate a higher overlap than obligate *** observed differences were related to the habitat preferences and predatory potentials of the species,suggesting that complementarity among the different niche axes might further facilitate theircoexistence.

关键词： clearance rate coexistence filter area filtermesh size.

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Technological achievements in the fabrication of tubular-designed protonic ceramic electrochemical cells

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Materials Futures 2024年第4期3卷 71-106页

作者： Maria A Gordeeva Artem p Tarutin Nikolai A Danilov Dmitry A Medvedev Laboratory of Electrochemical Devices Based on Solid Oxide proton Electrolytes Institute of High-Temperature Electrochemistry620066 EkaterinburgRussia Hydrogen Energy Laboratory Ural Federal University620002 EkaterinburgRussia

protonic ceramic electrochemical cells provide an excellent basis for the advancement of high-temperature solid oxide devices,offering potential solutions to a range of challenges in the hydrogen energy and carbon capture *** facilitated ionic transport in proton-conducting electrolytes enables these cells to operate at temperatures 100◦C–500◦C lower than those of conventional solid oxide cells with known zirconia *** a result,promising performances have been reported for various types of proton ceramic electrochemical ***,these advancements have been demonstrated only at the laboratory scale,whereas their ZrO2-based counterparts have already been *** review presents an overview of the fundamental and applied aspects related to the fabrication of tubular protonic ceramic electrochemical cells and their subsequent characterization as hydrogen permeation membranes,hydrogen pumps,hydrogen sensors,fuel cells,electrolysis cells,and electrochemical reactors.A specific focus is placed on the technological aspects of the tube preparations derived from the original powder sources as well as the dimensional characteristics of the tubes,which serve as an indicator of ***,this review serves as a starting point for the development and scaling of protonic ceramic electrochemical cells,with the potential for large-scale production.

关键词： electrochemistry energy conversion hydrogen proton transport perovskite solid oxide cells scaling

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Bile acid signaling in the regulation of whole body metabolic and immunological homeostasis

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Science China(Life Sciences) 2024年第5期67卷 865-878页

作者： Wei Jia Yitao Li Kenneth C.p.Cheung Xiaojiao Zheng School of Chinese Medicine Hong Kong Baptist UniversityHong KongChina Center for Translational Medicine and Shanghai Key Laboratory of Diabetes Mellitus Shanghai Sixth People's Hospital Affiliated to Shanghai JiaoTong University School of MedicineShanghai 200233China

Bile acids(BAs)play a crucial role in nutrient absorption and act as key regulators of lipid and glucose metabolism and immune *** the enterohepatic circulation,BAs are synthesized,metabolized,and reabsorbed,with a portion entering the vascular circulation and distributing *** allows BAs to interact with receptors in all major organs,leading to organ-organ interactions that regulate both local and global metabolic processes,as well as the immune *** review focuses on the whole-body effects of BA-mediated metabolic and immunological regulation,including in the brain,heart,liver,intestine,eyes,skin,adipose tissue,and *** BA synthesis and receptor signaling is a promising strategy for the development of novel therapies for various diseases throughout the body.

关键词： bile acid whole body metabolism immunity

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