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Chinese Journal of Chemistry 2023年第6期41卷 741-741页

作者： Linzi Chen Zhenqi Jiang Lifei Yang Ye Fang Shuwei Lu ozioma u.akakuru Shuaishuai Huang Juan Li Suya Ma Aiguo Wu 不详

Multiple valence states of Fe boosting SERS activity of Fe_(3)O_(4) nanoparticles and enabling effective SERS-MRI bimodal cancer imaging

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Fundamental Research 2024年第4期4卷 858-867页

作者： Jie Lin Xuehua Ma Anran Li ozioma udochukwu.akakuru Chunshu Pan Meng He Chenyang Yao Wenzhi Ren Yanying Li Dinghu Zhang Yi Cao Tianxiang Chen Aiguo Wu Cixi Institute of Biomedical Engineering International Cooperation Base of Biomedical Materials Technology and ApplicationChinese Academy of Science Key Laboratory of Magnetic Materials and DevicesZhejiang Engineering Research Center for Biomedical MaterialsNingbo Institute of Materials Technology and EngineeringCASNingbo315201China School of Engineering Medicine Key Laboratory of Big Data-Based Precision Medicine(Beihang University)Ministry of Industry and Information TechnologyBeihang UniversityBeijing100191China Advanced Energy Science and Technology Guangdong Laboratory Huizhou 516000China university of Chinese Academy of Sciences Bejing 100049China

Developing novel nanoparticle-based bioprobes utilized in clinical settings with imaging resolutions ranging from cell to tissue levels is a major challenge for tumor diagnosis and ***,an optimized strategy for designing a Fe_(3)O_(4)-based bioprobe for dual-modal cancer imaging based on surface-enhanced Raman scattering(SERS)and magnetic resonance imaging(MRI)is *** SERS activity of ultrasmall Fe_(3)O_(4) nanoparticles(NPs)was discovered,and a 5×10^(-9)M limit of detection for crystal violet molecules was successfully *** high-efficiency interfacial photon-induced charge transfer in Fe_(3)O_(4) NPs was promoted by multiple electronic energy levels ascribed to the multiple valence states of Fe,which was observed using ultraviolet-visible diffuse reflectance *** functional theory calculations were utilized to reveal that the narrow band gap and high electron density of states of ultrasmall Fe_(3)O_(4) NPs significantly boosted the vibronic coupling resonances in the SERS system upon *** subtypes of cancer cells were accurately recognized via high-resolution SERS imaging in vitro using the prepared Feg Og-based bioprobe with high sensitivity and good ***,Fe_(3)O_(4)-based bioprobes simultaneously exhibited T,-weighted MRI contrast enhancement with an active targeting capability for tumors in *** the best of our knowledge,this is the first report on the use of pure semiconductor-based SERS-MRI dual-modal nanoprobes in tumor imaging in vivo and in vitro,which has been previously realized only using semiconductor-metal complex *** non-metallic materials with SERS-MRI dual-modal imaging established in this report are a promising cancer diagnostic platform,which not only showed excellent performance in early tumor diagnosis but also possesses great potential for image-guided tumor treatment.

关键词： Fe_(3)O_(4)NPs SERS-MRI dual-modal nanoprobes PICT Multiple valence states Cancer diagnosis

Research progress and mechanism of nanomaterials-mediated in-situ remediation of cadmium-contaminated soil:A critical review

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Journal of Environmental Sciences 2021年第6期33卷 351-364页

作者： Yuenan Zhang Yujie Zhang ozioma udochukwu.akakuru Xiawei Xu Aiguo Wu Cixi Institute of Biomedical Engineering Chinese Academy of Science(CAS)Key Laboratory of Magnetic Materials and Devices&Zhejiang Engineering Research Center for Biomedical MaterialsNingbo Institute of Materials Technology and EngineeringCAS NingboNingbo 315201China university of Chinese Academy of Sciences Beijing 100049China

Cadmium contamination of soil is a global issue and in-situ remediation technology as a promising mitigation strategy has attracted more and more *** nanomaterials have been applied for the in-situ remediation of cadmium-contaminated soil due to their excellent properties of the nano-scale size *** this work,recent research progress of various nanomaterials,including carbon nanomaterials,metal-based nanomaterials and nano mineral materials,in the removal of cadmium and in-situ remediation of cadmiumcontaminated soil were systematically *** emphases were particularly laid on both laboratory and field restoration ***,the factors which can affect the stability of cadmium,main interaction mechanisms between nanomaterials and cadmium in the soil,and potential future research direction were also ***,it is believed that this work will ultimately contribute to the myriad of environmental cleanup advances,and further improve human health and sustainable development.

关键词： Cadmium pollution Contaminated soil In-situ remediation Mechanism Nanomaterials

Bubble coalescence in interacting system of DNA molecules

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International Journal of Biomathematics 2024年第4期17卷 195-216页

作者： u.A.Rozikov V.I.Romanouskiy Institute of Mathematics 9 Universitet Street100174 Tashkent uzbekistan AKFA university National Park StreetBarkamol MFY Mirzo-Ulugbek District111221 Tashkent uzbekistan National university of uzbekistan 4Universitet Street 100174 TashkentUzbekistan

We consider two models of interacting DNA molecules:First is(four parametric)bubble coalescence model in interacting DNAs(shortly:BCI-DNA).Second is(three parametric)bubble coalescence model in a condensed DNA molecules(shortly BCC-DNA).To study bubble coalescence thermodynamics of BCI-DNA and BCC-DNA models we use methods of statistical ***,we define Hamiltonian of each model and give their translation-invariant Gibbs measures(TIGMs).For the first model,we find parameters such that corresponding Hamiltonian has up to three TIGMs(three phases of system)biologically meaning existence of three states:“No bubble coalescence”,“Dominated soft zone”,“Bubble coalescence”.For the second model,we show that for any(admissible)parameters,this model has unique *** is a state where“No bubble coalescence”phasedominates.

关键词： DNA bubble configuration Cayley tree Gibbs measure Potts model

Variational data encoding and correlations in quantum-enhanced machine learning

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Chinese Physics B 2024年第9期33卷 298-306页

作者： Ming-Hao Wang Hua L¨u School of Physics Hubei UniversityWuhan 430062China School of Science Hubei University of TechnologyWuhan 430068China

Leveraging the extraordinary phenomena of quantum superposition and quantum correlation,quantum computing offers unprecedented potential for addressing challenges beyond the reach of classical *** paper tackles two pivotal challenges in the realm of quantum computing:firstly,the development of an effective encoding protocol for translating classical data into quantum states,a critical step for any quantum *** encoding strategies can significantly influence quantum computer ***,we address the need to counteract the inevitable noise that can hinder quantum *** primary contribution is the introduction of a novel variational data encoding method,grounded in quantum regression algorithm *** adapting the learning concept from machine learning,we render data encoding a learnable *** allowed us to study the role of quantum correlation in data *** numerical simulations of various regression tasks,we demonstrate the efficacy of our variational data encoding,particularly post-learning from instructional ***,we delve into the role of quantum correlation in enhancing task performance,especially in noisy *** findings underscore the critical role of quantum correlation in not only bolstering performance but also in mitigating noise interference,thus advancing the frontier of quantum computing.

关键词： quantum machine learning variational data encoding quantum correlation

ICG and Sunitinib-loaded NH_(2)-MOFs for Folate-mediated Hepatocellular Carcinoma Dual-modal Therapy

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Chemical Research in Chinese universities 2021年第4期37卷 967-974页

作者： ZHANG Zhoujing LIu Chuang ozioma akakuru Xu Wenjing Wu Aiguo ZHANG Yewei School of Medicine Southeast UniversityNanjing210009P.R.China Cixi Institute of BioMedical Engineering CNITECHChinese Academy of SciencesNingbo315201P.R.China

This research investigated a novel folic acid(FA)-modified zirconium core metal-organic framework(MOF)uio-66 as a nanocarrier to deliver indocyanine green(ICG)and Sunitinib to cancer cells for combination ***-loaded uio-66 nanoparticles(Pu)were synthesized via a one-pot method,followed by the modification with FA on their *** afforded FPu that enabled subsequent loading of ICG and Sunitinib to achieve dual-modal cancer *** loading/release test and singlet oxygen detection were also conducted in vitro,and the nanoparticles showed considerable drug loading efficiency for both ICG and Sunitinib,coupled with a high singlet oxygen generation ***,drug loading and encapsulation efficiency of Sunitinib were 2.30%and 72.67%,while those for ICG were 2.87%and 90.28%,***,cytotoxicity test on HepG2 human hepatocellular carcinoma cancer cell line revealed that the fully functional nanoparticles possess excellent biocompatibility and as such could be further investigated as a potential drug delivery system for effectual carcinoma cancer treatment.

关键词： Metal organic framework uio-66 Indocyanine green Sunitinib Hepatocellular carcinoma

Fuzzy and IRLNC-based routing approach to improve data storage and system reliability in IoT

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Intelligent and Converged Networks 2024年第1期5卷 68-80页

作者： u.Indumathi A.R.Arunachalam the Department of Computer Science and Engineering Dr.M.G.R.Educational and Research InstituteChennai 600095India

Internet of Things(IoT)based sensor network is largely utilized in various field for transmitting huge amount of data due to their ease and cheaper *** performing this entire process,there is a high possibility for data corruption in the mid of *** the other hand,the network performance is also affected due to various *** address these issues,an efficient algorithm that jointly offers improved data storage and reliable routing is ***,after the deployment of sensor nodes,the election of the storage node is achieved based on a fuzzy expert *** Random Linear Network Coding(IRLNC)is used to create an encoded *** encoded packet from the source and neighboring nodes is transmitted to the storage ***,to transmit the encoded packet from the storage node to the destination shortest path is found using the Destination Sequenced Distance Vector(DSDV)*** analysis of the proposed work is carried out by evaluating some of the statistical *** residual energy,packet delivery ratio,compression ratio and storage time achieved for the proposed work are 8.8%,0.92%,0.82%,and 69 *** on this analysis,it is revealed that better data storage system and system reliability is attained using this proposed work.

关键词： Internet of Things(IoT) data storage management fuzzy system improved random linear network coding energy utilization system reliability

Lump and travelling wave solutions of a(3+1)-dimensional nonlinear evolution equation

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Journal of Ocean Engineering and Science 2024年第2期9卷 164-172页

作者： Kalim u.Tariq Raja Nadir Tufail Department of Mathematics Mirpur University of Science and TechnologyMirpurAJK 10250Pakistan

In this paper,the(3+1)-dimensional nonlinear evolution equation is studied *** bilinear form of given model is achieved by using the Hirota bilinear *** a result,the lump waves and col-lisions between lumps and periodic waves,the collision among lump wave and single,double-kink soliton solutions as well as the collision between lump,periodic,and single,double-kink soliton solutions for the given model are ***,some new traveling wave solutions are developed by applying the exp(−φ(ξ))expansion *** 3D,2D and contours plots are drawn to demonstrate the nature of the nonlinear model for setting appropriate set of *** a result,a collection of bright,dark,periodic,rational function and elliptic function solutions are *** applied strategies appear to be more powerful and efficient approaches to construct some new traveling wave structures for various contemporary models of recent era.

关键词： The Hirota bilinear method Lump wave solution Travelling wave solution Exp(−φ(ξ))expansion technique

Latest Carboniferous-Early Permian Rifting of the Northern Gondwanan Margin and the Opening of the Northern Neotethys: New Evidence from the Carboniferous and Permian Foraminiferal Assemblages from the Beyşehir-Hoyran Nappes, Central Taurides(Southern Turkey)

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Journal of Earth Science 2024年第2期35卷 394-415页

作者： Cengiz Okuyucu u.Kagan Tekin Cagri Guzgun Kaan Sayit Department of Geological Engineering Konya Technical UniversityKonya42250Turkey Department of Geological Engineering Hacettepe UniversityAnkara06800Turkey Department of Geological Engineering Middle East Technical UniversityAnkara06800Turkey

The Beyşehir-Hoyran Nappes,one of the tectonostratigraphic units of the Taurides,are thought to be originated from the Izmir-Ankara Ocean(northern branch of Neotethys).In this study,Late Paleozoic rock units from the blocks of Beyşehir-Hoyran Nappes were studied in detail using foraminiferal assemblages in two different locations from the southwest of Karaman City(southern Turkey).In both places,blocks/slices and pebbles of various origins are embedded within a highly sheared matrix of Late Cretaceous Age,and the whole unit can be regarded as a sedimentary mé*** ages of the blocks from the southwest of Karaman City range from the Late Serpukhovian(Late Mississippian)to Late Capitanian(Middle Permian)with some depositional breaks(e.g.,Bashkirian,Kasimovian).Combined with the previous data from the Mersin Mélange,which also include the remnants of the Beyşehir-Hoyran Nappes,our new findings suggest that a shallowing-upward sequence,characterized by a shallow water environment with foraminifera-bearing limestones,was deposited over the Tournaisian pelagic sequence in the Beyşehir-Hoyran Nappes till the Early Moscovian(Early Middle Pennsylvanian).This shallowing-upward sequence in the Beyşehir-Hoyran Nappes could be related to the Late Paleozoic Glaciation on the Gondwana supercontinent(Glacial Ⅱ),which resulted in a sea-level drop and deposition of platform carbonates during the Viséan–Early Moscovian(Middle Mississippian to Early Middle Pennsylvanian)time *** absence of the main part of the Middle-upper Pennsylvanian deposits(continental phase during the Middle Moscovian–Middle Gzhelian)in the Beyşehir-Hoyran Nappes can be mainly attributed to the occurrence of a mantle plume and partially to the effect of Late Paleozoic Gondwanan Glaciation(Glacial Ⅲ).Progressive uplifting by the buoyant mantle plume material has resulted in rifting at the center of the basin where the Beyşehir-Hoyran Nappes have *** rifting process led to tectonic destabiliz

关键词： foraminifera Carboniferous and Permian Beyşehir-Hoyran Nappes plume rifting Neotethys paleontology