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Methane Steam Reforming on Supported Nickel Based Catalysts. Effect of Oxide ZrO2, La2O3and Nickel Composition

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Open Journal of Physical Chemistry 2013年第2期3卷 89-96页

作者： Akila Belhadi Mohamed Trari Chérifa Rabia ouiza cherifi Laboratory of Chemistry of Natural Gas Faculty of Chemistry (USTHB) Algiers Algeria

The catalytic properties of Ni (4 and 10 wt%) supported on both La2O3 and ZrO2 were investigated for the methane steam reforming reaction between 475℃ and 700℃ at atmospheric pressure. The catalysts were prepared by the impregnation method and characterized by several techniques (atomic absorption, BET method, X-ray diffraction and TG-TPO). The catalytic activity of Ni/support systems strongly depends on both of the nature and physico-chemical properties of the support. No deactivation was observed in catalytic systems, whatever the reaction temperature indicating high stability of the catalyst.

关键词： Methane Steam Reforming Nickel Coke Supported Catalysts

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Methane Steam Reforming on Supported Nickel, Effect of Nickel Content for Product Hydrogen

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Open Journal of Physical Chemistry 2016年第2期6卷 34-41页

作者： Akila Belhadi Souhila Boumaza Amar Djadoun Mohamed Trari ouiza cherifi Laboratory of Chemistry of Natural Gas Faculty of Chemistry USTHB Algiers Algeria Department of Géologie FSTGAT USTHB Algiers Algeria Laboratory of Storage and Valorization of Renewable Energies Faculty of Chemistry (USTHB) Algiers Algeria

The steam reforming of methane over NiO/ZnO mixed oxides with different nickel contents was studied. Solids to x% Ni/ZnO (x = 4 and 10%) were deposited on ZnO by impregnation from nickel nitrate solution;after vaporization the solid is calcined at 500°C for 6 h. The catalysts were characterized by X-ray diffraction (XRD) and BET method, scanning electron microscopy (SEM) and temperature programmed reduction (TPR). The XRD patterns revealed the NiO phase for all calcined catalysts. The chemical analysis confirmed the theoretical values of nickel. The catalysts were pre-treated under hydrogen at 500°C in situ, overnight before testing for the steam reforming of methane reaction (CH4/H2O/Ar = 10/10/80) in the temperature range (475°C - 650°C) under atmospheric pressure. The activities of both catalysts were investigated in a fixed-bed reactor for the Methane Steam Reforming (MSR) reaction. Globally, it was shown that the catalyst 10% nickel content has an important effect on the catalytic performances of solids i.e. the better results of hydrogen production were obtained with 10% wt. Ni/ZnO (28 ′ 10-3 mol/g catalyst).

关键词： Nickel Catalysts ZnO Methane Steam Reforming Hydrogen

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