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Single atom Cu-N-C catalysts for the electro-reduction of CO_(2) to CO assessed by rotating ring-disc electrode

Journal of Energy Chemistry 2024年第1期88卷 169-182,I0004页

作者： S.Pérez-Rodríguez M.Gutiérrez-Roa C.Giménez-Rubio D.Ríos-Ruiz P.arévalo-Cid M.V.Martínez-Huerta A.Zitolo M.J.Lázaro D.Sebastián Instituto de Carboquímica(CSIC) Miguel Luesma Castán 450018 ZaragozaSpain Instituto de Catálisis y Petroleoquímica(CSIC) Marie Curie 228049 MadridSpain Synchrotron SOLEIL L’Orme des MerisiersDépartementale 12891190France

The electrochemical CO_(2) reduction reaction(CO_(2)RR) to controllable chemicals is considered as a promising pathway to store intermittent renewable energy. Herein, a set of catalysts based on copper-nitrogendoped carbon xerogel(Cu-N-C) are successfully developed varying the copper amount and the nature of the copper precursor, for the efficient CO_(2)RR. The electrocatalytic performance of Cu-N-C materials is assessed by a rotating ring-disc electrode(RRDE), technique still rarely explored for CO_(2)RR. For comparison, products are also characterized by online gas chromatography in a H-cell. The as-synthesized Cu-NC catalysts are found to be active and highly CO selective at low overpotentials(from -0.6 to -0.8 V ***) in 0.1 M KHCO_(3), while H_(2) from the competitive water reduction appears at larger overpotentials(-0.9 V vs. RHE). The optimum copper acetate-derived catalyst containing Cu-N_(4) moieties exhibits a CO_(2)-to-CO turnover frequency of 997 h^(-1) at -0.9 V vs. RHE with a H_(2)/CO ratio of 1.8. These results demonstrate that RRDE configuration can be used as a feasible approach for identifying electrolysis products from CO_(2)RR.

关键词： Cu-N-C Carbon xerogel Rotating ring disc electrode Carbon dioxide reduction reaction Carbon monoxide

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Equivalent circuit for the characterization of the resonance mode in piezoelectric systems

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Journal of Advanced Dielectrics 2015年第4期5卷 37-41页

作者： Y.Fernández-Afonso O.García-Zaldívar F.Calderón-Piñar Centrode Estudios Avanzadosde Cuba Kilómetro 1y 1/2 Carreter a San Antonio de los Baños Valle Grande La LisaHabanaCuba Facultadde Física-Instituto de Cienciay Tecnología de Materiales Universidad de La Habana.San LázaroyL Vedado.La Habana 10400 Cuba CINVESTAV-Unidad Querétaro Libramiento Norponiente No.2000 Realde Juriquilla QuerétaroQro.76230México

The impedance properties in polarized piezoelectric can be described by electric equivalent *** classic circuit used in the literature to describe real systems is formed by one resistor(R),one inductance(L)and one capacitance C connected in series and one capacity(C_(0))connected in parallel with the ***,the equation that describe the resonance and anti-resonance frequencies depends on a complex manner of R,L,C and C_(0).In this work is proposed a simpler model formed by one inductance(L)and one capacity(C)in series;one capacity(C_(0))in parallel;one resistor(R_(p))in parallel and one resistor(Rs)in series with other *** the traditional circuit,the equivalent circuit elements in the proposed model can be simply determined by knowing the experimental values of the resonance frequency fr,anti-resonance frequency fa,impedance module at resonance frequency|Z|,impedance module at anti-resonance frequency|Za|and low frequency capacitance C_(0),without ftting the im-pedance experimental data to the obtained equation.

关键词： Piezoelectric equivalent circuit electromechanic

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Low phase angle is associated with the development of hepatic encephalopathy in patients with cirrhosis

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World Journal of Gastroenterology 2016年第45期22卷 10064-10070页

作者： Astrid Ruiz-Margáin Ricardo Ulises Macías-Rodríguez Javier Ampuero Francisco Javier Cubero Luis Chi-Cervera Silvia L Ríos-Torres Andrés Duarte-Rojo Ángeles Espinosa-Cuevas Manuel Romero-Gómez Aldo Torre Department of Gastroenterology Instituto Nacional de Ciencias Médicas y Nutrición Salvador Zubirán14080 México City México Department of Internal Medicine Ⅲ University Hospital RWTH Aachen52074 Aachen Germany Unit for the Clinical Management of Digestive Diseases Virgen del Rocio-Virgen Macarena University Hospital41009 Sevilla Spain Department of Immunology Complutense University School of Medicine28040 Madrid Spain University of arkansas for Medical Sciences Little Rock AR 72205 United States Department of Nephrology and Mineral Merabolism Instituto Nacional de Ciencias Médicas y Nutrición Salvador Zubirán México City 14080 México

AIM Evaluate the association between phase angle and the development of hepatic encephalopathy in the longterm follow-up of cirrhotic *** This was a prospective cohort study. Clinical, nutritional and biochemical evaluations were performed. MannWhitney's U and χ2 tests were used as appropriate. Kaplan-Meier curves and Cox proportional Hazards analysis were used to evaluate the prediction and incidence of hepatic *** Two hundred and twenty were included; the most frequent etiology of cirrhosis was hepatitis C infection, 52% of the patients developed hepatic encephalopathy(18.6% covert and 33.3% overt); the main precipitating factors were infections and variceal bleeding. KaplanMeier curves showed a higher proportion of HE in the group with low phase angle(39%) compared to the normal phase angle group(13%)(P = 0.012). Furthermore, creatinine and phase angle remained independently associated to hepatic encephalopathy in the Cox regression multivariate analysis [hazard ratio = 1.80(1.07-3.03)]. CONCLUSION In our cohort of patients low phase angle was associated with an increased incidence of hepatic encephalopathy. Phase angle is a useful nutritional marker that evaluates cachexia and could be used as a part of the integral assessment in patients with cirrhosis.

关键词： Malnutrition Hepatic encephalopathy Phase angle Cachexia Prognosis

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卒中患者运动力量的感知与其所受刺激的大小相关

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世界核心医学期刊文摘（神经病学分册） 2006年第9期2卷 30-30页

作者： Taylor-Cooke P.A. Ricci R. Baos J.H M.S. Mennemeier 史利利 510 Jack Stephens Drive Slot 826 Little Rock AR 72205 United States Dr.

The authors examined whether perception of contralateral limb strength is altered and whether perception of strength correlates with perception of stimulus intensity (magnitude) in a prospective sample of patients with unilateral right (RHL: n = 13) and left (LHL: n = 6) hemisphere lesions due to stroke. Patients with RHL tended to overestimate strength and patients with LHL tended to underestimate strength; both patterns were highly correlated with altered perception of stimulus magnitude.

关键词：卒中患者动力量感知大脑半球刺激强度前瞻性研究侧肢体损伤

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