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地壳深部压力状态与地质作用学术研讨会

作者： Lü Guxian, Chen Jing, Ding Tiping, Li Xiaobo, Wang Fangzheng and Liu Ruixun Institute of Geomechanics, beijing, 100081, china Electron Microscopy laboratory, Peking University, beijing, 100871, china open research laboratory of isotope geology, chinese academy of geological sciences, beijing 100037, china Institute of geological Information, beijing, 100037, china china University of Geosciences, Wuhan, Hubei, 430074, china Department of geology, Peking University, beijing, 100871, china

＜正＞ Plastic deformation of garnet in coesite-bearing eclogite, quartz eclogite and garnet amphibolite of the ultra-high pressure metamorphic（UHPM） complex in Yingshan County, Dabie Mountains, has been studied by transmission electron microscopy （TEM）. Garnets have undergone ductile deformation under eclogite and amphibolite facies conditions. Garnet microstructures vary greatly with the dislocation density of the garnet being lower in coesite-bearing eclogite is than that in garnel *** generated by strong tectonic movement were an important component of the total pressure causing the formation of eclogite in the Dabie UHPM zone. The three-dimensional tectonic principal stresses and additional tectonic stress-induced hydrostatic pressure [Ps=-（σ1+σ2+σ3）/3] are reconstructed according to the differential stress and strain ratio （a） of garnet in minor coesite-bearing eclogite of Yingshan county. Then the gravity-induced hydrostatic pressure （PG） is calculated through P minus PS, where P is estimated to be 2.8 GPa based on the quartz-coesite geobarmeter. Therefore, the thickness of the rock column overlying the coesite-bearing eclogite in Yingshan county is determined to be ≥2.09-32.11 km. this estimation is significantly different from the previous estimation of ≥100km obtained solely by considering the weight/specific weight ratio （W/SW）.It gives also a proper explanation to the puzzle that no tracer of addition of mantle-derived material has been found in the Dabie UHPM zone during the process of UHPM, although a number of researches claim that this process was taking place at depth of the mantle （≥100 km） . It is concluded that attention should be paid to the additional tectonic stress-induced hydrostatic pressure in the study of UHPM zones.

关键词： Dabie UHPM zone formation depth additional tectonic stress-induced hydrostatic pressure coesite-bearing eclogite tectonic physicochemistry plastic deformation garnet

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Experimental Observation of the Ore-Forming Fluid NaCl-H_2O System in the Earth Interior

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Acta Geologica Sinica(English Edition) 1999年第1期73卷 47-64页

作者： ZHANG Ronghua and HU Shumin open research laboratory of Geochemical Kinetics, chinese academy of geological sciences,26 Baiwanzhuang Road, beijing 100037, china open research laboratory of Geochemical Kinetics Chinese Academy of Geological Sciences 26 Baiwanzhuang Road Beijing 100037 China

The NaCl-H_2O binary system is a major component of solutions coexisting with ores. Observation ofsaturated solutions of NaCl-H_2O by using the method of hydrothermal diamond anvil cell (HDAC) is a new approach tothe study of ore-forming fluids. The salinities of NaCl-H_2O solutions in experimental observation are in a range of 32-55%. The observed temperature range is 25℃-850℃, and the pressure range 1 atm-10 kb. In this temperature-pressure range, the supercritical single phase, two phases (L,V) close to the critical state and two-phased (L+V) immis-cible region were observed. And for the salinity of 35% the two phase L+V immiscible region of NaCl-H_2O solutionwas observed in a range of 253-720℃. Another temperature range, 400-817℃, was observed for the immiscible two-phased region of 50% salinity solution. In the high-temperature part of the two-phased immiscible region, the phase na-ture is very unstable. A "critical phenomenon" was observed when the heating path was very close to the critical *** is possible to observe a 'critical phenomenon': an "explosion" occurred almost constantly at the interface between theliquid and vapour and the interface is rather obscure. A continuous transition between phases L and V could be foundin the immiscible L+V phase while heating continuously. Moreover, as the NaCl-H_2O solution was separated into liq-uid and vapour phases, static charges surrounding each vapour bubble could be seen, and these bubbles were attractedtogether by the static charges to form a special solution structure. Besides, critical states of different salinities of NaCl-H_2O were observed in order to study the properties of the fluids occurring in the rocks in the earth interior, the origin ofore-bearing fluids and the significance of supercritical fluid with respect to the ore formation. The comparison of the sa-linity data of the fluid inclusions in the minerals of ore deposits with observations of NaCl-H_2O under HDAC in theconditions of high temp

关键词： critical phenomenon solution structure of the two-phased immiscible region ore-forming hydrothermal solutions

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Development of Zr/ZrO_2 high temperature and high pressure sensors for in-situ measuring chemical parameters of deep-sea water

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Science china(Technological sciences) 2009年第8期52卷 2466-2473页

作者： ZHANG XueTong, ZHANG RongHua, HU ShuMin & WANG Yong open research laboratory of Geochemical Kinetics, Institute of Mineral Resources, chinese academy of geological sciences, beijing 100037, china open research laboratory of Geochemical Kinetics Institute of Mineral Resources Chinese Academy of Geological Sciences Beijing 100037 China

In order to in situ measure chemical parameters of deep-sea water and hydrothermal fluids at midocean ridge(MOR), it is necessary to use high temperature and high pressure chemical *** new sensors is essential to measure in-situ pH and other chemical parameters(dissolved H2, dissolved H2S) of deep-sea water and hydrothermal fluids in a wide temperature range(2℃―400℃) at MOR *** YSZ(Yttria Stabilized Zirconia, 9%Y2O3) ceramic-based(HgO/Hg) chemical sensors possess excellent electrochemical properties at high temperatures, which have been used to measure chemical parameters of hydrothermal fluids above 200℃.A novel Zr/ZrO2 oxidation/reduction electrode was constructed by oxidation of Zr wire in Na2CO3 *** Zr/ZrO2 electrode has good chemical stability while measuring pH of high-temperature aqueous solutions, combined with a Ag/AgCl reference *** of the Zr/ZrO2 sensor in association with a Ag/AgCl reference electrode vary linearly with pH over a wide pH range, as tested by various NaCl-HCl-H2O solutions(NaOH-NaCl-H2O for basic solutions), at temperatures in the range of 20℃―200℃.Thus, the Zr/ZrO2 sensors can be utilized in monitoring the fluids over the temperature range of 2℃―200℃.The Zr/ZrO2 electrode combined with Ag/AgCl, Ag/Ag2S, and Au electrodes has been used to measure pH and other chemical parameters(dissolved H2, dissolved H2S) of aqueous fluids from low to high temperatures and high pressures in the laboratory and to monitor those parameters of deep-sea water in South china Sea.

关键词： Zr/ZrO2 sensor melt oxidation method high temperature and high pressure chemical parameters investigation in the deep ocean

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SHRIMP zircon U-Pb geochronology of early Mesozoic felsic igneous rocks from the southern Lancangjiang and its tectonic implications

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Science china Earth sciences 2006年第10期49卷 1032-1042页

作者： PENG Touping1,2, WANG Yuejun1, FAN Weiming1, LIU Dunyi3, SHI Yuruo3 & MIAO Laicheng4 1. Key laboratory of isotope Geochronology and Geochemistry, Guangzhou Institute of Geochemistry, chinese academy of sciences, Guangzhou 510640, china 2. Graduate University of chinese academy of sciences, beijing 100039, china 3. SHRIMP isotope laboratory, chinese academy of geological sciences, beijing 100037, china 4. Institute of geology and Geophysics, chinese academy of sciences, beijing 100029, china Key laboratory of isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Graduate University of chinese academy of sciences Beijing China SHRIMP isotope laboratory Chinese Academy of Geological Sciences Beijing China Institute of geology and Geophysics Chinese Academy of Sciences Beijing China

The SHRIMP zircon U-Pb geochronology of three typical samples, including two monzo nitic granites from the Lincang batholith and a rhyolite from the Manghuai Formation are presented in the southern Lancangjiang, western Yunnan Province. The analyses of zircons for the biotite monzonitic granites from the northern (02DX-137) and southern (20JH-10) Lincang batholith show the single and tight clusters on the concordia, and yield the weighted mean 206Pb/238U ages of 229.4 ± 3.0 Ma and 230.4 ± 3.6 Ma, respectively, representing the crystallized ages of these granites. The zircons for the rhyolitic sample (02DX-95) from the Manghuai Formation give a weighted mean 206Pb/238U age of 231.0 ± 5.0 Ma. These data suggest that the igneous rocks from the Lincang granitic batholith and Manghuai Formation have a similar crystallized age. In combination with other data, it is inferred that both were generated at a narrow age span (~230 Ma) and were originated from the postcollisional tectonic regime. An early Proterozoic 206Pb/238U apparent age of 1977±44 Ma is additionally obtained from one zircon from the biotite monzonitic granite (southern Lincang batholith), indicative of devel- opment of the early Proterozoic Yangtze basement in the region. These precisely geochronological data provide important constraints on better understanding the Paleozoic tectonic evolution of the Tethys, western Yunnan Province.

关键词： SHRIMP zircon U-Pb dating, Middle Triassic, Lincang granitic batholith, Manghuai Formation rhyolite, southern Lancangjiang.

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Mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating

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Science china Earth sciences 2005年第2期48卷 192-198页

作者： WANG Denghong, QU Wenjun, LI Zhiwei, YIN Hanlong4 & CHEN Yuchuan Institute of Mineral Resources, chinese academy of geological sciences, beijing 100037, china National Center of Rock and Mineral Analysis, chinese academy of geological sciences, beijing 100037, china Resource Assessment Center of Yunnan, Kunming 650011, china Institute of geology and Geophysics, chinese academy of sciences, beijing 100101, china chinese academy of geological sciences, beijing 100037, china 1. Institute of Mineral Resources Chinese Academy of Geological Sciences 100037 Beijing China 2. National Center of Rock and Mineral Analysis Chinese Academy of Geological Sciences 100037 Beijing China 3. Resource Assessment Center of Yunnan 650011 Kunming China 4. Institute of geology and Geophysics Chinese Academy of Sciences 100101 Beijing China 5. chinese academy of geological sciences 100037 Beijing China

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 33.9±1.1 Ma for the Machangqing deposit and 34.4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (35.4 Ma, 35.9 Ma, 36.2 Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.

关键词： Re-Os isotopic dating, porphyry Cu deposits, Cenozoic, mineralization episode.

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Carbon and Oxygen Stable isotope Values and Microfossils at 41.4-4.5ka BP in Tai Co,Tibet,china,and Their Paleoclimatic Significance

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Acta Geologica Sinica(English Edition) 2011年第5期85卷 1036-1050+1052-1056+1051页

作者： ZHENG Mianping~(1,2,*),LIU Junying~(1,3),MA Zhibang~(1,4),WANG Hailei~(1,2) and MA Nina~(1,2) 1 MLR Key laboratory of Saline Lake Resources and Environment,Institute of Mineral Resources,CAGS, beijing 100037,china 2 research and Development Center for Saline Lakes and Epithermal Deposits,chinese academy of geological sciences,beijing 100037,china 3 Institute of geology,chinese academy of geological sciences,beijing 100037,china 4 Key laboratory of Cenozoic geology and Environment,chinese academy of sciences,beijing 100029, china MLR Key laboratory of Saline Lake Resources and Environment Institute of Mineral Resources CAGS Beijing 100037 China research and Development Center for Saline Lakes and Epithermal Deposits Chinese Academy of Geological Sciences Beijing 100037 China Institute of geology Chinese Academy of Geological Sciences Beijing 100037 China Key laboratory of Cenozoic geology and Environment Chinese Academy of Sciences Beijing 100029 China *Correspondence: Mianping ZHENG *Correspondence: Corresponding author. E-mail: zhengmp2010@***

Two sedimentary sections were measured at Tai Co(Co means lake in Tibetan) in western Tibet,*** two sections are almost all composed of clay carbonate beds except in their lower parts where there are carbonized plants at>10 cm depths and dark-colored carbonate clay and clay at 50-70 cm depths,yielding abundant gastropods,ostracods,and *** carbon and oxygen stable isotope values of carbonate,ostracods,and charophytes and ecological features of microfossil communities indicate the following climatic change in the area from 41.4 to 4.5 ka BP:at 41.4-26.2 ka BP,the climate was relatively wet;at 26.2-25.5 ka BP,it was slightly warm-dry;at 25.5-22.5 ka BP,it was warm-wet;at 22.5-21.0 ka BP,it was slightly cold-wet;at 20.5-17.5 ka BP,it became cold abruptly and slightly wet,implying the climate of the last glacial maximum;at 17.5-16.0 ka BP,it was slightly cold-dry;at 16.0-11.8 ka BP,it was slightly warm-wet;at 11.8-10.4 ka BP,it was relatively cold-dry, roughly equivalent to the climate of the Younger Dryas,and at 10.4 ka BP,the temperatures began to rise again;at 10.4-9.4 ka BP,it was slightly warm-wet;at 9.4-8.5 ka BP,there occurred short warm-wet oscillations;at 8.5-7.9 ka BP,it was slightly dry-cold,representing a strong temperature-lowering and drying event in the postglacial stage;at 7.8-6.3 ka BP,it was slightly warm-wet;at 6.3-4.5 ka BP,the climate tended to be cold-dry.4.5 ka BP recorded the maximum aridity since the late part of the late Pleistocene.

关键词： sedimentary environment index paleoclimatic changes late Pleistocene-Holocene(41.4-4.5 ka BP) Tai Co Tibet

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Ages and Compositions of the Precambrian High-grade Basement of the Qilian Terrane and Its Adjacent Areas

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Acta Geologica Sinica(English Edition) 2001年第4期75卷 375-384页

作者： WAN Yusheng, XU Zhiqin, YANG Jingsui and ZHANG Jianxin Institute of geology, chinese academy of geological sciences, beijing 100037 Institute of geology Chinese Academy of Geological Sciences Beijing 100037 [?]2Wan Yusheng Born in 1958 graduated from china University of Geosciences in 1981 received the Ph.D. degree in 1993 now senior geologist at the Institute of geology Chinese Academy of Geological Sciences engaged in the study of geochemistry. Tel: 010–68328411 e-mail: wanysh@***

Based on geological, chronological, geochemical and Nd isotopic studies of the high-grade basement of the Qilian terrane, the authors have drawn the following main conclusions: (1) the high-grade basement of the Qilian terrane consists mainly of meta-argillo-arenaceous rocks and granites and its bulk part was formed in the period of 0.8–1.0 Ga (the Jinningian period); (2) most of the meta-argillo-arenaceous rocks and granitic rocks have strong negative Eu and Ba anomalies (Eu/Eu*= 0.47–0.71 and Ba/Ba*=0.16–0.64), with fDM and ENd (1.0 Ga) ranging from 1.87 to 2.26 Ga and from ?8.54 to ?4.06 respectively, showing relatively high maturity; and (3) the Jinningian granitic rocks are a typical product of continent-continent collision, being probably related to the formation of the supercontinent Rodinia. These studies, combined with the study of high-grade basement rocks near the Qilian terrane, suggest that before the Jinningian period, the Qilian-Qaidam northern-margin terrane and Dunhuang-Alxa terrane were separated from each other, belonging to different plate systems of the North china craton and Yangtze platform respectively. The Qilian orogenic belt was the same as or similar to the Qiling orogenic belt in terms of the geological evolution history at least before the Jinningian period.

关键词： Qilian terrane chronology Nd isotope geochemistry Precambrian basement

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Malanite——A New Cupric Platinum (Pt^(3+)) and Iridium (Ir^(3+)) Sulphide

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Acta Geologica Sinica(English Edition) 1997年第2期71卷 152-157,233页

作者： Yu Zuxiang Institute of geology, chinese academy of geological sciences, beijing, 100037 Institute of geology Chinese Academy of Geological Sciences Beijing 100037 [?]Yu Zhuxiang Born in Nov. 1930 graduated from the Specialty of Petrology and Mineralogy of the Department of geology Beijing College of Geology in 1953. He has long engaged in the study of mineralogy as Research Professor at the Institute of Geology Chinese Academy of Geological Sciences.

Malanite was first found in veinlets of disseminated copper-nickel ores inZunhua County, Hebei Province, and then in platinum-bearing chromite ores in ShuangfengVillage, Yanshan. In the former case, malanite appears as octahedrons or dodecahedrons asso-ciated with pyrrhotite, pentlandite, sperrylite and cooperite; while in the latter case, it is massiveor present in anhedral glomerocrysts, filling in cracks of iridisite and associated with osmiride,ferrian platinum and iridisite. Malanite is steel-grey in colour, opaque with metallic lustre andblack streaks and brittle with no magnetism. H_M=5.0, VHN_(20)=417kg/mm^2, cleavage {111}sometimes observed. The calculated density is 7.57g/cm^3. The reflective colour is white with alight green tint. Internal reflections are not observed. This mineral is isotropic, showing nobireflection or reflection pleochroism in air. By means of electron microprobe analysis, the em-pirical formula (based on 7 atoms) is expressed as (Cu_(0.93)Fe_(0.06))_(∑0.99)(Pt_(1.03)Ir_(0.66)Rh_(0.04)Pd_(0.03)Co_(0.20)Ni_(0.03))_(1.99)S_(4.03) or (Cu_(0.95)Fe_(0.07))_(∑1.02)(Pt_(1.37)Ir_(0.45)Co_(0.11)Rh_(0.08))_(∑2.01)S_(3.97). Five strongestlines (hkl, d, I) of X-ray powder diffraction data of malanite are 311,2.98(6); 400,2.48(5);333, 1.90(7); 440, 1.75(10); 731, 1.29(5). It was known on the basis of X-ray powder diffractiondata that malanite is cubic, and the space group is Fd3m with α=0.9940nm, V=0.9821(3)nm^3 and Z=4. The type material of malanite is deposited at the geological Museum of china(GMC)s

关键词： new mineral malanite chrome ore

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Kinematics and dynamics of the Mesozoic orogeny and late-orogenic extensional collapse in the Sino-Mongolian border areas

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Science china Earth sciences 2005年第7期48卷 849-862页

作者： ZHENG Yadong 1 & WANG Tao2 1. Key laboratory of Orogenic Belts and Crustal Evolution (Peking University), Ministry of Education, beijing 100871, china 2. Institute of geology, chinese academy of geological sciences, beijing 100037, china Key laboratory of Orogenic Belts and Crustal Evolution (Peking University) Ministry of Education Beijing 100871 China Institute of geology Chinese Academy of Geological Sciences Beijinq 100037 China

The Sino-Mongolian border areas underwent two important tectonic events during Mesozoic time after late Paleozoic orogeny: a late Triassic to earlier Jurassic contractional event that resulted in a large-scale south-vergent thrust during the orogeny and a late Jurassic-earlier Cretaceous extensional event in a north-south direction that formed a metamorphic core complex. The kinematic and dynamic analyses show that the thrust sheet moved southwards with a kinematic vorticity number of ca. -0.10 and sub-horizontal maximum compressive stress axis that belongs to a contraction-thickening shear. The upper plate of the late-orogenic detachment relatively moved in a 165°direction. The average kinematic vorticity in its earlier stage was 0.74 that belongs to simple shear dominated shearing and related to the maximum compressive stress axes dipping at ～66°, while the later average kinematic vorticity was ～0.55°that belongs to pure shear dominated shearing with sub-vertical maximum compressive stress axes. This suggests that the thrusting led to the crust thickened and the lower plate rocks that were originally located in the upper crust depressed through a brittle-ductile transition zone into the lower crust and became warmer. The heated rocks trended to uplift since their increasing volume and decreasing density while the loading of the upper-plate rocks increased due to the structural thickening. Under the combined effect of the loading and the thermal-uplifting, the ductile shear zone in between increased in its component of vertical pure shear. Once its pure-shear component exceeded its simple-shear one the ductile shear zone became an extension-thinned shear zone. This progressive transitional process reflects internal and essential temporal and spatial relationships: the extensional factor nucleated during the crust thickening by thrusting and increase of the extensional factor finally led to late-orogenic collapse.

关键词： Mesozoic thrusting,late-orogenic collapse,kinematic vorticity number,stress state.

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Kinetics of ore-forming fluids in epithermal systems

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chinese Science Bulletin 1999年第S2期44卷 5-6页

作者： ZHANG Ronghua, ZHANG Xuetong and HU Shumin open research laboratory of Geochemical Kinetics, Institute of Mineral Deposits, chinese academy of geological sciences, beijing 100037, china open research laboratory of Geochemical Kinetics Institute of Mineral Deposits Chinese Academy of Geological Sciences Beijing 100037 China

As verified by the data of fluid inclusions in minerals in some paleo-hydrothermal systems, a lowering intemperature of the ore-forming fluids and a decrease in salinity occurred simultaneously from the centralzone （deep part） of the deposit profile to its outer zone （shallow part）. The usual situation shown byexperimental data is that solubility rises with an increase in temperature, as shown by quartz and manyore minerals. However, the solubility of some minerals increases as the temperature decreases within acertain temperature range. Therefore, continuous deposition cannot be achieved as the temperature of thesystem decreases, as in the cases of calcite, fluorite, and anhydrite. In water and NaCl-H2O systems,the solubility of calcite （or anhydrite） decreases with a rise in temperature at < 300℃ (or < 450℃

关键词： kinetics ore-forming fluids epithermal systems.

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