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Binuclear and Hexanuclear Ti(Ⅳ) Complexes Supported by [OOOO]^(4–)-type Ligand for Preparing Disentangled UHMWPE

Chinese Journal of Polymer Science 2019年第5期37卷 471-477页

作者： Vladislav A.Tuskaev Svetlana Ch.Gagieva Dmitry A.Kurmaev Viktor G.Vasil'ev Nikolay A.Kolosov Sergey V.Zubkevich Elena S.Mikhaylik Evgenii K.Golubev Galina G.Nikiforova Pavel A.Zhizhko olga a.serenko Boris M.Bulychev Department of Chemistry M.V.Lomonosov Moscow State University A.N.Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences Enikolopov Institute of Synthetic Polymer Materials Russian Academy of Sciences

Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]^(4–)-type ligand were active in ethylene polymerization in the presence of Et2 AlCl/Bu2 Mg binary co-catalyst, giving high molecular weight polyethylene. The binuclear complex showed significantly higher catalytic activity and thermal stability in comparison to mononuclear analogue. Ultra high molecular weight polyethylene(UHMWPE) samples were processed by a solid-state uniaxial deformation into high-strength(up to 2.5 GPa) and highmodulus(over 100 GPa) oriented film tapes, which indirectly indicates a low degree of entanglements between the macromolecular chains.

关键词： Binuclear catalysts Titanium Ethylene Ziegler-Natta polymerization UHMWPE

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Effect of the Morphology of Leather Surface on the Hydrophobic-Hydrophilic Properties

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Advances in Materials Physics and Chemistry 2014年第2期4卷 13-19页

作者： Olga.serenko Zarina Nizamova Mikhail Kalinin Yuri Ostrovsky Ludmila Polukhina Aziz Muzafarov 1Enikolopov Institute of Synthetic Polymeric Materials Foundation of the Russian Academy of Sciences Moscow Russia Enikolopov Institute of Synthetic Polymeric Materials Foundation of the Russian Academy of Sciences Moscow Russia Moscow State University of Design and Technology Moscow Russia

Natural leathers (split, velour split, nubuck) ware investigated. Solution of fluorine silane in ethanol was applied as the hydrophobic agent. It is shown that the microstructure of the leather surface, provided its structural elements possess hydrophilic properties, determines the wetting regime and duration of the induction period of changeover from heterogeneous to homogeneous wetting. The heterogeneous regime of wetting is distinguished by low rates of spreading and absorbing. The homogeneous wetting is characterized by high rates of spreading and absorbing of a water drop. A necessary condition of the stable heterogeneous wetting regime and achieving hydrophobicity of leather with structurally inhomogeneous face layer is to preserve the microstructure features of their surface at hydrophobic treatment. The morphological peculiarities of split and ground leather ensure stable hydrophobic properties after application of efficient hydrophobizators.

关键词： Leather Surface Modification Water Contact Angle Wetting Hydrophobic Effect

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