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Highly defective dark Tio_(2) Modified with Pt: Effects of Precursor Nature and Preparation Method on Photocatalytic Properties

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Transactions of Tianjin University 2024年第2期30卷 198-209页

作者： E.d.Fakhrutdinova o.A.Reutova T.A.Bugrova I.Yu.ovsyuk L.S.Kibis o.A.Stonkus d.B.Vasilchenko o.V.Vodyankina V.A.Svetlychnyi National Research Tomsk State University TomskRussia 634050 Novosibirsk State University NovosibirskRussia 630090 Boreskov Institute of Catalysis NovosibirskRussia 630090 Nikolaev Institute of Inorganic Chemistry NovosibirskRussia 630090

The study focused on the modification with platinum of dark defective titania obtained via pulsed laser ablation. Both the method of Pt introduction and the nature of the Pt precursor were varied. All samples exhibited similar phase compositions, specific surface areas, and Pt contents. High-resolution transmission electron microscopy coupled with pulsed Co adsorption revealed increased dispersity when photoreduction and the hydroxonitrate complex (Me _(4) N) _(2) [Pt _(2) (oH) _(2) (No _(3) ) _(8) ] were used. The sample featured a high content of single-atom species and subnano-sized Pt clusters. The X-ray photoelectron spectroscopy results showed that the photoreduction method facilitated the appearance of a larger number of Pt ^(2+) states, which appeared owing to the strong metal-support interaction (SMSI) eff ect of the transfer of electron density from the electron-saturated defects on the Tio _(2) surface to Pt ^(4+) . In the hydrogen evolution reaction, samples with a significant fraction of the Pt ^(2+) ionic component, capable of generating short-lived Pt^(0) single-atom sites under irradiation due to the SMSI eff ect, exhibited the highest photocatalytic activity. The 0.5Pt(C)/Tio_(2) -Ph sample exhibited the highest hydrogen yield with a quantum efficiency of 0.53, retaining its activity even after 8 h of operation.

关键词： dark(black)Tio_(2) Pulsed laser ablation Platinum reduction method Precursor type Photocatalysis Hydrogen evolution reaction

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Fatty acids derived from oviposition systems guide female black soldier flies(Hermetia illucens)toward egg deposition sites

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Insect Science 2024年第4期31卷 1231-1248页

作者： Patrick Klüber Emna Arous Jeanny Jerschow Marco Fraatz daniel Bakonyi Martin Rühl Holger Zorn department Bioresources Fraunhofer Institute for Molecular Biology and Applied EcologyGiessenGermany Institute of Food Chemistry and Food Biotechnology Justus Liebig University GiessenGiessenGermany

The black soldier fly,Hermetia illucens,comes with big promises for industrial purposes since its larvae feed polyphagously on a broad spectrum of organic ***,research focusing on adult flies is scarce,which is inconsistent with their reproductive relevance within the rearing *** particular,directed oviposition is a challenge in artificial ***,decomposing organic matter is commonly used as oviposition substrate,which has extensive potential for improvement in view of the lack of standardization and the risk of microbial ***,we identified three fatty acids and one fatty acid methyl ester derived from the surface of old oviposition sites and targeted to elucidate their effect on preference behavior and oviposition site selection using Y-olfactometry and prepared oviposition sites,*** to tetradecanoic acid attracted gravid females and stimulated oviposition most strongly,while decanoic acid demonstrated a repulsive *** kept in mixed-sex populations were attracted by tetradecanoic acid,resulting in a higher egg mass found in the compound box(3.0–11.4 fold),a≥2.3 fold reduction of nonspecifically deposited eggs,and the highest total egg ***,decanoic and dodecanoic acid caused females to lay a greater proportion of eggs nonspecifically outside both *** data suggest that fatty acids,especially tetradecanoic acid,are important cues for oviposition site selection in black soldier *** order to achieve a directed oviposition behavior,the role of further short-and long-chain fatty acids as attractants should be examined.

关键词： black soldier fly Hermetia illucens fatty acids insects as food and feed oviposition oviposition site selection tetradecanoic acid

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development and testing of a high-power S-band klystron at BINP SB RAS

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Nuclear Science and Techniques 2024年第7期35卷 58-67页

作者： A.Levichev A.Barnyakov S.Samoylov d.Nikiforov V.Ivanov M.Arsentyeva d.Chekmenev o.Pavlov I.Pivovarov Budker Institute of Nuclear Physics Lavrentyeva Av.11NovosibirskRussia630090 Novosibirsk State University Pirogova Str.2NovosibirskRussia630090

This paper details the development and testing of the first working prototype of the S-band high-power klystron,accomplished at the Budker Institute of Nuclear Physics,Siberian Branch,Russian Academy of Sciences(BINP SB RAS).Upon testing,the klystron demonstrated the following parameters:an operating frequency of 2856 MHz and a peak power output of 50 *** paper presents the klystron's design,its constituent units,and pertinent processing procedures,along with discussions on the measurement of its parameters.

关键词： Klystron Linear accelerator Electron beam

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Sustainable Biocomposites Materials for Automotive Brake Pad Application:An overview

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Journal of Renewable Materials 2024年第3期12卷 485-511页

作者： Joseph o.dirisu Imhade P.okokpujie olufunmilayo o.Joseph Sunday o.oyedepo oluwasegun Falodun Lagouge K.Tartibu Firdaussi d.Shehu department of Mechanical Engineering Covenant UniversityOtaOgunNigeria department of Mechanical and Mechatronics Engineering AFE Babalola UniversityAdoEkitiNigeria department of Mechanical and Industrial Engineering Technology University of JohannesburgJohannesburg2028South Africa School of Chemical and Metallurgical Engineering University of the WitwatersrandJohannesburgSouth Africa

Research into converting waste into viable eco-friendly products has gained global *** natural fibres and pulverized metallic waste becomes necessary to reduce noxious environmental emissions due to indiscriminately occupying the *** study reviews the literature in the broad area of green composites in search of materials that can be used in automotive brake *** made by biocomposite,rather than fossil fuels,will be favoured.A database containing the tribo-mechanical performance of numerous potential components for the future green composite was established using the technical details of bio-polymers and natural *** development of materials with diverse compositions and varying proportions is now conceivable,and these materials can be permanently connected in fully regulated *** explanation demonstrates that all of these variables affect friction coefficient,resistance to wear from friction and high temperatures,and the operating life of brake pads to varying *** this study,renewable materials for the matrix and reinforcement are screened to determine which have sufficient strength,coefficient of friction,wear resistance properties,and reasonable costs,making them a feasible option for a green *** most significant,intriguing,and unusual materials used in manufacturing brake pads are gathered in this review,which also analyzes how they affect the tribological characteristics of the pads.

关键词： Asbestos brake pad biocomposites green composite mechanical properties natural reinforcement waste

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detailed seismic zoning of the East Kazakhstan region in the Republic of Kazakhstan

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Geodesy and Geodynamics 2024年第2期15卷 156-165页

作者： Natalya V.Silacheva N.P.Stepanenko o.K.Kurilova A.d.Kudabayeva A.T.danabayeva Institute of Seismology Ministry of Emergency SituationsAlmaty 050060Kazakhstan

Kazakhstan is currently drafting new construction regulations that comply with the major provisions of the *** regulations are created on the basis of seismic zoning maps of various degrees of detail,developed by our Institute of Seismology using a new methodological approach for *** article is about creating the first normative map of the detailed Seismic Zoning on a probabilistic foundation for the Republic of Kazakhstan’s East Kazakhstan *** carried out the probabilistic assessment of seismic hazard using a methodology consistent with the main provisions of Eurocode 8and updated compared with that used in developing maps of Kazakhstan’s General Seismic Zoning and seismic microzoning of *** most thorough and current data accessible for the area under consideration were combined with contemporary analytical *** have been done to not only the databases being used but also the way seismic sources were shown,including active faults *** a scale of 1:1000000,precise seismic zoning maps of the East Kazakhstan region were created for two probabilities of exceedance:10%and 2%in 50 years in terms of peak ground accelerations and macroseismic *** obtained seismic hazard distribution is generally consistent with the General Seismic Zoning of Kazakhstan’s previous ***,because active faults were included and a thoroughly revised catalog was used,there are more pronounced zones of increased danger along the fault in the western part of the *** the west of the territory,acceleration values also increased due to a more accurate consideration of seismotectonic *** maps are the basis for developing new state building regulations of the Republic of Kazakhstan.

关键词： Probabilistic seismic hazard assessment detailed seismic zoning Peak ground acceleration Microseismical intensity

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Progress of Lyman-alpha-based beam emission spectroscopy(Ly BES)diagnostic on the hl-2A tokamak

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Plasma Science and Technology 2024年第3期26卷 118-125页

作者：周艺轩余羿许敏柯锐聂林徐皓赵光义刘灏袁子豪肖晨雨李继全肖池阶 the hl-2A Team Southwestern Institute of Physics Chengdu 610041People's Republic of China Sino-French Institute of Nuclear Engineering and Technology Sun Yat-sen UniversityZhuhai 519082People's Republic of China State Key Laboratory of Nuclear Physics and Technology School of PhysicsPeking UniversityBeijing 100871People's Republic of China

An edge Lyman-alpha-based beam emission spectroscopy(LyBES)diagnostic,using a heating NBI(neutral beam injection)system,is currently under development on the hl-2A *** 20-channel edge LyBES,which is intended to measure the density fluctuation in plasma edge(from R=1960 mm to R=2026 mm)with an improved spatial resolution of 3.3 mm,is a complement to the existing conventional beam emission spectroscopy(BES)*** this article,we introduce the progress of LyBES diagnostic,including the collection optics,the monochromator,and the detector *** reflectance of the collection mirrors is measured to be~82%at 122 nm,and the aberration geometrical radius of the collection optics is tested to be~150μm in the aimed *** linear dispersion of the LyBES monochromator is designed to be~0.09 nm mm^(-1).The bandwidth of the detector system with the 5×10^(7)V A^(-1)preamplifier gain is measured to be~280 kHz,and the peak-to-peak noise of the detector system is tested to be~16 *** finalized design,components development and testing of the LyBES diagnostic have been completed at present,and an overall performance of the LyBES diagnostic is to be confirmed in the next hl-2A campaign.

关键词： density fluctuation Ly BES BES vacuum ultraviolet

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China’s hl-3 tokamak achieves H-mode operation with 1 MA plasma current

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The Innovation 2024年第1期5卷 5-6页

作者： Wulyu Zhong hl-team Southwestern Institute of Physics Chengdu 610225China

In a remarkable achievement,China’s new-generation magnetic confinement fusion device,the hl-3 tokamak(formerly known as hl-2M),achieved highconfinement mode(H-mode)operation with a plasma current of 1 mega amperes(MA)for the first time on August 25th,*** breakthrough signifies a noteworthy milestone in China’s controlled nuclear fusion research,bringing us one step closer to the burning plasma phase.

关键词： tokamak mode bringing

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Stability analysis of a time-delayed Van der Pol–Helmholtz–duffing oscillator in fractal space with a non-perturbative approach

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Communications in Theoretical Physics 2024年第4期76卷 22-31页

作者： Yusry o El-dib department of Mathematics Faculty of EducationAin Shams UniversityRoxyCairoEgypt

The time-delayed fractal Van der Pol–Helmholtz–duffing(VPHd)oscillator is the subject of this paper,which explores its mechanisms and highlights its stability *** time-delayed technologies are currently garnering significant attention,the focus of this research remains crucially relevant.A non-perturbative approach is employed to refine and set the stage for the system under *** innovative methodologies introduced yield an equivalent linear differential equation,mirroring the inherent nonlinearities of the ***,the incorporation of quadratic nonlinearity into the frequency formula represents a cutting-edge *** analytical solution's validity is corroborated using a numerical *** conditions are ascertained through the residual Galerkin ***,it is observed that the delay parameter,in the context of the fractal system,reverses its stabilizing influence,impacting both the amplitude of delayed velocity and the *** analytical solution's precision is underscored by its close alignment with numerical ***,the study reveals that fractal characteristics emulate damping *** its applicability across diverse nonlinear dynamical systems,this non-perturbative approach emerges as a promising avenue for future research.

关键词： Van der Pol-Helmholtz-duffing oscillator fractal space time-delay non-perturbative approach stability analysis El-dib's frequency formula

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Localized-states quantum confinement induced by roughness in CdMnTe/CdTe heterostructures grown on Si(111) substrates

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Journal of Semiconductors 2024年第9期45卷 28-35页

作者： Leonarde N.Rodrigues Wesley F.Inoch Marcos L.F.Gomes odilon d.d.Couto Jr. Bráulio S.Archanjo Sukarno o.Ferreira Physics department Federal University of ViçosaViçosa36570-900Minas GeraisBrazil Instituto de Física Gleb Wataghin Universidade Estadual de CampinasCampinas13083-859São PauloBrazil National Institute of Metrology Quality and Technology(Inmetro) Materials Metrology Division(DIMAT)Xerém2525-020Rio de JaneiroBrazil

This work shows that despite a lattice mismatch of almost 20%, CdMnTe/CdTe/CdMnTe heterostructures grown directly on Si(111) have surprisingly good optical emission properties. The investigated structures were grown by molecular beam epitaxy and characterized by scanning transmission electron microscopy, macro-and micro-photoluminescence. Low temperature macro-photoluminescence experiments indicate three emission bands which depend on the CdTe layer thickness and have different confinement characteristics. Temperature measurements reveal that the lower energy emission band (at 1.48 eV)is associated to defects and bound exciton states, while the main emission at 1.61 eV has a weak 2d character and the higher energy one at 1.71 eV has a well-defined (zero-dimensional, 0d) 0d nature. Micro-photoluminescence measurements show the existence of sharp and strongly circularly polarized (up to 40%) emission lines which can be related to the presence of Mn in the heterostructure. This result opens the possibility of producing photon sources with the typical spin control of the diluted magnetic semiconductors using the low-cost silicon technology.

关键词： CdMnTe/CdTe/CdMnTe heterostructure CdTe/CdMnTe quantum emitters quantum dot-like emission silicon(111)substrate

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hl-3装置欧姆等离子体中高频磁流体不稳定性的实验观测

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核聚变与等离子体物理 2024年

作者：杨秋磊陈伟张洁程时葵梁绍勇张轶泼 hl-3 实验团队核工业西南物理研究院

在hl-3装置1MA电流等离子体欧姆放电实验期间，米尔诺夫(Mirnov)探针测量到两种高频磁流体(MHd)不稳定性。在等离子体启动阶段，电流爬升受到抑制，碘化钠探测器测量到逃逸电子增加。同时Mirnov探针测量到多分支频率f为20～400k Hz的高... 详细信息

在hl-3装置1MA电流等离子体欧姆放电实验期间，米尔诺夫(Mirnov)探针测量到两种高频磁流体(MHd)不稳定性。在等离子体启动阶段，电流爬升受到抑制，碘化钠探测器测量到逃逸电子增加。同时Mirnov探针测量到多分支频率f为20～400k Hz的高频MHd不稳定性。结果表明，这种不稳定性的出现与逃逸电子增加密切相关，并抑制了等离子体电流的爬升，损失了大约7%伏秒数。等离子密度较高时，Mirnov探针测量到频率f为110～160k Hz的高频MHd不稳定性。这种不稳定性频率与芯部阿尔芬频率成正比，处于环向阿尔芬本征模频率范围。随着这种不稳定性的演化，等离子体发生了破裂。这些高频MHd不稳定性的研究对于hl-3后续放电及未来ITER的初始放电有重要的参考意义。

关键词：等离子体磁流体不稳定性逃逸电子破裂

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