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Synthesis of Ag and cd nanoparticles by nanosecond-pulsed discharge in liquid nitrogen

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Frontiers of chemical Science and Engineering 2019年第2期13卷 360-368页

作者： Mahmoud Trad Alexandre Nominé Natalie Tarasenka Jaafar Ghanbaja cédric noel Malek Tabbal Thierry Belmonte Universite de Lorraine CNRSIJLF-54000 NancyFrance B.I. Stepanov Institute of Physics National Academy of Sciences of BelarusMinskBelarus Department of Physics American University of BeirutBeirutLebanon

The synthesis of cdO, Ag2O (5nm) and Ag (~20~30 nm) nano-objects is achieved simultaneously by nanosecond-pulsed discharges in liquid nitrogen between one cadmium electrode and one silver electrode. Oxidation occurs when liquid nitrogen is fully evaporated and nanoparticles are in contact with the air. No alloy is formed, whatever the conditions, even though both elements are present simultaneously, as showed by timeresolved optical emission spectroscopy. This lack of reactivity between elements is attributed to the high pressure within the discharge that keeps each metallic vapor around the electrode it comes from. Each element exhibits a specific behavior. cubic cd particles, formed at 4 kV, get elongated with filamentary tips when the applied voltage reaches 7 and 10 kV. cd wires are formed by assembly in liquid nitrogen of cd nanoparticles driven by dipole assembly, and not by dielectrophoresis. On the contrary, silver spherical particles get assembled into 2D dendritic structures. The anisotropic growth of these structures is assumed to be due to the existence of pressure gradients.

关键词： spark discharges submerged discharges timeresolved optical emission spectroscopy liquid nitrogen

A quantum cascade laser infrared spectrometer for cO_2 stable isotope analysis：Field implementation at a hydrocarbon contaminated site under bio-remediation

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Journal of Environmental Sciences 2016年第2期28卷 60-74页

作者： christophe Guimbaud cécile noel Michel chartier Valéry catoire Michaela Blessing Jean christophe Gourry claude Robert Laboratoire de Physique et de chimie de l'Environnement et de l'Espace (LPc2E) CNRS et Universite d'Orleans (UMR 7328)45071 Orleans cedex 2 France Bureau de Recherches Geologiques et Minieres (BRGM) 45060 Orleans cedex 2 France

Real-time methods to monitor stable isotope ratios of cO_2 are needed to identify biogeochemical origins of cO_2 emissions from the soil–air interface. An isotope ratio infra-red spectrometer（IRIS） has been developed to measure cO_2 mixing ratio with δ~13c isotopic signature, in addition to mixing ratios of other greenhouse gases（cH_4, N2_O）. The original aspects of the instrument as well as its precision and accuracy for the determination of the isotopic signature δ~13c of cO_2 are discussed. A first application to biodegradation of hydrocarbons is presented, tested on a hydrocarbon contaminated site under aerobic bio-treatment. cO_2 flux measurements using closed chamber method is combined with the determination of the isotopic signature δ~13c of the cO_2 emission to propose a non-intrusive method to monitor in situ biodegradation of hydrocarbons. In the contaminated area, high cO_2 emissions have been measured with an isotopic signature δ~13c suggesting that cO_2 comes from petroleum hydrocarbon *** first field implementation shows that rapid and accurate measurement of isotopic signature of cO_2 emissions is particularly useful in assessing the contribution of contaminant degradation to the measured cO_2 efflux and is promising as a monitoring tool for aerobic bio-treatment.

关键词： Isotope ratio infrared spectrometry Isotopic signature δ^(13)c of cO_2 Biodegradation monitoring Hydrocarbons BTEX

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长江中下游成矿带成矿规律和成矿模式

岩石学报 2017年第11期33卷 3353-3372页

作者：周涛发范裕王世伟 noel c WHITE 合肥工业大学资源与环境工程学院合肥230009 合肥工业大学矿床成因与勘查技术研究中心合肥230009

长江中下游成矿带作为中国东部重要的成矿带之一,成矿地质条件、成矿规律和成矿模式的相关研究已经十分深入,形成了一系列公认的理论研究成果,本文重点论述了成矿带成矿地质条件和成矿规律方面研究的新进展,并在此基础上构筑了成矿带的... 详细信息

长江中下游成矿带作为中国东部重要的成矿带之一,成矿地质条件、成矿规律和成矿模式的相关研究已经十分深入,形成了一系列公认的理论研究成果,本文重点论述了成矿带成矿地质条件和成矿规律方面研究的新进展,并在此基础上构筑了成矿带的成矿模式。本文主要开展了以下总结工作:(1)将成矿带的构造要素突破以往按构造单元分解的做法,确立跨构造单元的"复合构造系统",结合成矿带成岩成矿作用特点,重新确定了长江中下游成矿带的范围,并对成矿亚带进行了重新划分;(2)收集汇总了长江中下游成矿带近年来国内外学者最新的成岩成矿年龄数据,总结了矿床时空分布规律;(3)从地质,地球物理和地球化学等方面,总结归纳了沿基底结合带复活的网状断裂系统,阐明了成矿带的控矿构造格架,分析了长江中下游成矿带的成因规律;(4)补充和完善了断隆区和断凹区的成矿模式,并初步构筑了长江中下游成矿带综合成矿模式。提出长江中下游成矿带内主体成岩成矿作用总体上分为走滑挤压阶段(146~135Ma)、走滑引张阶段(135~126Ma)和拉张伸展阶段(126~123Ma)等三个阶段,古太平洋板块作用导致的壳幔过程,引发含元古代弧岩浆岩源区活化和中生代的构造活化("双活化")是长江中下游成矿带形成的主要机制。

关键词：长江中下游成矿带成矿规律成矿模式成矿背景

Genesis of Mafic Microgranular Enclaves in the Shaocunwu Granodiorite,Southern china,and their Implications:Evidence from Zircon and Whole-rock Geochemistry

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Acta Geologica Sinica(English Edition) 2021年第3期95卷 761-779页

作者： JIANG Hua ZHANG Dayu WANG Shiwei FU Xiang YE Longxiang noel c.WHITE ZHOU Taofa School of Resources and Environmental Engineering Hefei University of TechnologyHefei 230009China Ore Deposit and Exploration centre Hefei University of TechnologyHefei 230009China Anhui Province Engineering Research center for Mineral Resources and Mine Environments Hefei 230009China

Magmatic microgranular enclaves(MMEs)are widely developed in the Shaocunwu granodiorite at the northeast margin of the eastern Jiangnan orogenic *** geology showed that the MMEs occur as irregular ellipsoids near the edge of the intrusion,and consist of diorite,dominantly composed of amphibole,biotite,and plagioclase grains,with minor acicular *** U-Pb dating showed the ages of the host granodiorites and MMEs are 145.9±1.1 Ma and 145.6±2.5 Ma,respectively,indicating both originated during coeval late Jurassic ***-rock geochemical results show that the host granodiorite and MMEs have similar rare earth and trace element partition curves in spider grams,and similar 87Sr/86Sr,and 147Nd/144Nd isotope ratios,and their zircon 177Hf/176Hf isotopic ratios are *** studies indicate that both the host granodiorite and MMEs formed by mixing of coeval *** Ti thermometers and oxygen fugacity of the host granodiorite and the MMEs show high oxygen fugacity,similar to that of W-cu(Mo)mineralized granitoids in the eastern Jiangnan orogenic belt.A similar magma mixing process was probably one of the mechanisms that generated the W-cu(Mo)fertile melts.

关键词： MME zircon U-Pb dating Sr-Nd-Hf isotope magma mixing Shaocunwu granodiorite South Anhui

Overview on signal transduction cascades regulation roles of garlic and its bioactive constituents

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Food Science and Human Wellness 2024年第5期13卷 2353-2362页

作者： Ammad Ahmad Farooqi Iqra Mobeen Rukset Attar Khalida I.noel Baojun Xu William c.cho Institute of Biomedical and Genetic Engineering(IBGE) Islamabad 44000Pakistan Khursheed Rasheed Hospital Lahore Lahore 53720Pakistan Department of Obstetrics and Gynecology Yeditepe UniversityAtaşehir 34755Turkey Human Anatomy Department College of MedicineAl-Mustansiriyah UniversityBaghdad 10036Iraq Food Science and Technology Program Department of Life SciencesBNU-HKBU United International CollegeZhuhai 519087China Department of clinical Oncology Queen Elizabeth HospitalHong Kong G514TFChina

High-throughput technologies in combination with modern exciting advancements in mass spectrometry-based proteomics and data analysis pipelines have empowered comprehensive characterization of disease phenotypes and their mechanistic regulation by dietary agents and bioactive molecules at unprecedented dimensionality and ***-ordinary breakthroughs in the field of nutrigenomics have leveraged our understanding altogether to a new level of *** researchers have extensively analyzed health promoting and pharmacologically significant properties of garlic(Allium sativum).Importantly,garlic and its biologically active chemicals targeted oncogenic signaling *** this mini-review we have attempted to summarize how garlic and its bioactive constituents regulated signal transduction cascades in cell culture studies and tumor-bearing mice.

关键词： cancer Nutrigenomics Signaling Apoptosis Allium sativum

福建紫金山矿田悦洋银多金属矿床银的赋存状态和沉淀机制

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岩石学报 2024年第3期40卷 987-1002页

作者：刘兰海陈静周涛发孙艺 WHITE noel c 合肥工业大学资源与环境工程学院合肥工业大学矿床成因与勘查技术研究中心(ODEC)合肥230009 安徽省矿产资源与矿山环境工程技术研究中心合肥230009 centre of Excellence in Ore Deposits(cODES) University of TasmaniaHobart 7001

浅成低温热液矿床是世界上银矿的重要矿床类型,伴生有金铜铅锌等多种金属。银的赋存状态研究可以为矿床资源禀赋、选冶成本以及经济价值的综合评价提供重要的依据。近年来,矿物自动定量分析系统越来越多地应用到贵金属的赋存状态研究中... 详细信息

浅成低温热液矿床是世界上银矿的重要矿床类型,伴生有金铜铅锌等多种金属。银的赋存状态研究可以为矿床资源禀赋、选冶成本以及经济价值的综合评价提供重要的依据。近年来,矿物自动定量分析系统越来越多地应用到贵金属的赋存状态研究中,相比传统方法而言其能提供精确定量的矿物学信息。悦洋银多金属矿床位于福建省紫金山矿田,是典型的浅成低温热液矿床,是研究银赋存状态的理想选区。通过野外地质调查研究发现,矿体主要受控于岩性边界和断裂构造,主要矿石类型为热液角砾岩型和石英脉型。成矿作用可以分为石英-黄铁矿、石英-黄铁矿-黄铜矿、石英-银多金属、石英-碳酸盐等四个阶段,其中银在石英-银多金属阶段沉淀,可以进一步划分为石英伊利石硫化物亚阶段和石英冰长石硫化物亚阶段。本文在野外地质调查的基础上,针对不同的矿石类型使用TIMA(TEScAN Integrated Mineral Analyzer)自动矿物分析系统,结合显微镜下观察、扫描电镜和电子探针分析手段,对银的赋存形式和分布情况进行了定量化研究,根据矿物共生组合对银沉淀机制及成矿过程进行了探讨。研究结果显示,悦洋矿床中的银90%以上以独立矿物的形式存在,主要是硫化银和自然银,且粒径大多在10~50μm之间;少部分银以次显微包裹体形式存在于黄铜矿中,或以显微包裹体和类质同相形式存在于黄铁矿和闪锌矿中。成矿热液中银主要以硫氢络合物形式运移,主成矿期大量的冰长石与银矿物共生表明沸腾作用是主要的沉淀机制。

关键词：银的赋存状态矿物定量分析银的沉淀机制浅成低温热液矿床紫金山矿田

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Nano cuO/g-c_3N_4 sheets-based ultrafiltration membrane with enhanced interfacial affinity,antifouling and protein separation performances for water treatment application

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Journal of Environmental Sciences 2019年第8期31卷 57-69页

作者： Thanigaivelan Arumugham Reshika Gnanamoorthi Amimodu noel Jacob Kaleekkal Dipak Rana Department of chemistry School of Advanced Sciences Vellore Institute of Technology (VIT) Department of Integrative Biology School of Bioscience and Technology Vellore Institute of Technology (VIT) Department of chemical Engineering National Institute of Technology Calicut Department of chemical and Biological Engineering Industrial Membrane Research Institute University of Ottawa

To improve the interfacial affinity and antifouling properties of polyphenylsulfone(PPSU)membrane, nano cuO/g-c3 N4(g-cN) sheets were synthesized via facile calcination route as one pot synthesis method. The uniformly assembled nanohybrid fillers, cuO on g-cN sheets were confirmed by using XRD, TEM, EDX and FTIR analysis. The non-solvent induced phase inversion technique was used to fabricate the nanohybrid ultrafiltration(UF)membranes by doping different concentration(0.5–1 wt.%) of nano cuO/g-c_3 N_4(g-cN)sheets within the PPSU matrix. The results of contact angle, atomic force microscopy,energy-dispersive X-ray spectroscopy reveal that surface structure and physico-chemical properties of nanohybrid membrane plays lead role in solute interaction and rejection compared to bare membrane, M0. Furthermore, the interfacial affinity of membrane was explored in detail via surface free energy, spreading coefficient, wetting tension and reversible work of adhesion analysis. Nanohybrid UF membrane, with 0.5% of the filler(M1)displayed remarkable permeation flux of 202, 131 L/m2/hr for pure water and protein solution, respectively while maintaining a high protein rejection(96%). Moreover, the exceptional dispersion of the nanosheets in the polymer matrix enhanced FRR(79%) and decreased the overall resistance of M1 compared to the pristine membrane(M0). Overall results suggest that the incorporation of nano sheets is a facile modification technique which improves the comprehensive membrane performance and holds a great potential to be further explored for water treatment.

关键词： Ultrafiltration membrane copper oxide Graphitic carbon nitride Interfacial affinity Antifouling Protein removal

安徽庐枞盆地酸性蚀变岩帽地质地球化学特征研究

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岩石学报 2017年第11期33卷 3545-3558页

作者：李旋旋张乐骏高昌生谢杰 noel c WHITE 合肥工业大学资源与环境工程学院合肥230009 合肥工业大学矿床成因与勘查技术研究中心合肥230009 centre for Ore Deposits and Exploration Science University of Tasmania 安徽省地质矿产勘查局327地质队合肥230011

酸性蚀变岩帽是浅成低温热液系统演化的产物,形成于酸性高氧化性流体的化学条件下;在高硫化型浅成低温热液金矿床中广泛发育,是该类矿床的显著识别特征。通过对酸性蚀变岩帽的野外地质特征、矿物共生组合和地球化学特征研究,能较好阐明... 详细信息

酸性蚀变岩帽是浅成低温热液系统演化的产物,形成于酸性高氧化性流体的化学条件下;在高硫化型浅成低温热液金矿床中广泛发育,是该类矿床的显著识别特征。通过对酸性蚀变岩帽的野外地质特征、矿物共生组合和地球化学特征研究,能较好阐明浅成低温成矿热液系统的特征、性质、发生和发展演化及成矿作用过程。庐枞矿集区是长江中下游成矿带重要的矿集区之一,盆地内广泛发育以明矾石为特征蚀变矿物的酸性蚀变岩帽,面积超过30km^2,指示盆地内高硫化浅成低温热液系统的存在。目前为止,前期工作主要针对明矾石矿床地质特征和明矾石资源储量进行,该酸性蚀变岩帽的地质地球化学特征研究尚未开展。本次工作通过对酸性蚀变岩帽系统的野外采样、全岩地球化学分析和短波红外光谱测试分析技术(PNIRS测试)分析,确定其主要赋存在砖桥组火山岩中,组成矿物为石英、明矾石、高岭石、地开石,此外有少量绢云母、伊利石、珍珠陶土、叶蜡石、褐铁矿,极少数的叶腊石和黄钾铁矾等,在钻孔深部存在浸染状和半自形粒状黄铁矿。由于受到地表风化剥蚀和不同热热中心的影响,水平方向从矾山明矾石矿床向外围发育石英+明矾石带、石英+高岭石/地开石+明矾石带、石英+高岭石/地开石带、硅化带以及最外围的泥质带即高岭石±绢云母±伊利石带。根据酸性蚀变岩帽的矿物组合和主量元素特征,可将其分为三类:硅质蚀变岩、明矾石蚀变岩和粘土蚀变岩。硅质蚀变岩中SiO_2含量发生明显的富集作用,其余主量元素(K_2O、Na_2O、Al_2O_3、Fe_2O_3、P_2O5)含量显著降低;明矾石蚀变岩和粘土蚀变岩具有相似的地球化学特征,SiO_2、Al_2O_3、Fe_2O_3、P_2O_5元素含量范围变大,K_2O和Na_2O含量降低,且Na_2O降低更加明显;而钛为不活泼元素,在岩石发生蚀变过程中TiO_2含量变化很小。矾山地区的酸性蚀变岩帽的产状、蚀变类型、地球化学特征受构造和地层的双重控制。

关键词：明矾石酸性蚀变岩帽明矾石1480hm吸收峰地球化学特征矿物组合分带庐枞盆地

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蚀变岩帽的特征、成因以及在华南的分布探讨

岩石学报 2020年第11期36卷 3380-3396页

作者：陈静周涛发张乐骏孙艺 WHITE noel c 李旋旋合肥工业大学资源与环境工程学院合肥工业大学矿床成因与勘查技术研究中心合肥230009 centre for Ore Deposit and Earth Sciences University of TasmaniaHobart 7001 安徽省矿产资源与矿山环境工程技术研究中心合肥230009

Sillitoe (1995)蚀变岩帽(Lithocap)的定义为大范围富黄铁矿的硅化、高级泥化和泥化蚀变,在地质环境上位于古地表和浅成中-酸性岩浆侵入体之间。蚀变岩帽往往显示为突出的正地形,有助于寻找隐伏的斑岩矿化体。但蚀变岩帽在地表的范围往... 详细信息

Sillitoe (1995)蚀变岩帽(Lithocap)的定义为大范围富黄铁矿的硅化、高级泥化和泥化蚀变,在地质环境上位于古地表和浅成中-酸性岩浆侵入体之间。蚀变岩帽往往显示为突出的正地形,有助于寻找隐伏的斑岩矿化体。但蚀变岩帽在地表的范围往往多达几十个平方千米,又常常掩盖下覆斑岩矿床的蚀变矿化特征及其地球化学印记,因此大型的蚀变岩帽又给勘探工作带来一定的挑战。蚀变岩帽相关矿床的勘探需以地质填图为基础,结合近红外光谱分析(SWIR)进行蚀变填图,以及全岩地球化学以及矿物地球化学表现的元素或元素组合异常,来帮助定位热源或深部斑岩体。遥感和地球物理中的激电响应,也可以辅助定位岩体。华南地区的蚀变岩帽主要分布于长江中下游成矿带和东南沿海火山岩带。前人对安徽庐枞盆地中的矾山蚀变岩帽进行了系统研究,确定了矾山蚀变岩帽形成于白垩纪,与围岩砖桥组火山岩年龄一致。同位素和流体包裹体工作证明了形成矾山蚀变岩帽的流体主要为深部岩浆热液中的酸性气体与浅部大气降水的混合,在浅部高渗透率的火山岩及其岩性界面反应,广泛发育了一套硅化和高级泥化蚀变,指示与矾山相关可能存在斑岩和高硫型浅成低温热液铜金矿床。福建紫金山地区有中国最大的高硫型浅成低温热液矿床,主要赋存于紫金山蚀变岩帽中。紫金山蚀变岩帽的地质特征和蚀变分带已经研究的较为详细,但目前深部的侵入体还没有发现。浙江的蚀变岩帽是中国非金属矿产的重要来源,包括明矾石矿、地开石矿和红柱石矿等,这些蚀变岩帽与金属矿化的关系尚未有相关研究。根据目前的资料总结,有较多的蚀变岩帽分布在中国华南,这些蚀变岩帽特征典型,但目前的研究程度尚浅。现有的研究结果表明,华南的蚀变岩帽的成矿潜力巨大,可能存在一条巨型的斑岩-浅成低温矿床成矿带,具有广阔的找矿勘查前景,建议加强蚀变岩帽及相关矿床的找矿与研究工作。

关键词：蚀变岩帽华南明矾石地球化学特征高级泥化蚀变