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Low-cost high entropy alloy(HEA)for high-efficiency oxygen evolution reaction(OER)

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Nano Research 2022年第6期15卷 4799-4806页

作者： Lalita Sharma nirmal kumar katiyar Arko Parui Rakesh Das Ritesh kumar Chandra Sekhar Tiwary Abhisek K.Singh Aditi Halder Krishanu Biswas School of Basic Sciences Advanced Materials Research Centre(AMRC)Indian Institute of Technology Mandi(H.P)KamandMandi 175005India Department of Materials Science and Engineering Indian Institute of Technology KanpurKanpur 208016India School of Engineering London South Bank UniversityLondonSE10 AAUK Materials Research Centre Indian Institute of ScienceBangalore 560012India Metallurgical and Materials Engineering Indian Institute of Technology KharagpurKharagpur 382355India

Oxygen evolution reaction(OER)is the key step involved both in water splitting devices and rechargeable metal-air batteries,and hence,there is an urgent need for a stable and low-cost material for efficient *** the present investigation,Co-Fe-Ga-NiZn(CFGNZ)high entropy alloy(HEA)has been utilized as a low-cost electrocatalyst for ***,after cyclic voltammetry activation,CFGNZ-nanoparticles(NPs)are covered with oxidized surface and form high entropy(oxy)hydroxides(HEOs),exhibiting a low overpotential of 370 mV to achieve a current density of 10 mA/cm^(2)with a small Tafel slope of 71 mV/*** alloy has higher electrochemical stability in comparison to state-of-the art RuO2 electrocatalyst as no degradation has been observed up to 10 h of *** electron microscopy(TEM)studies after 10 h of long-term chronoamperometry test showed no change in the crystal structure,which confirmed the high stability of *** density functional theory(DFT)based calculations show that the closeness of d(p)-band centers to the Fermi level(EF)plays a major role in determining active *** work highlights the tremendous potential of CFGNZ HEA for OER,which is the primary reaction involved in water splitting.

关键词： high entropy alloy cyclic voltammetry activation oxygen evolution reaction electrocatalyst nanocrystalline catalyst

Multilocular thymic cysts-a diagnostic challenge on computed tomography

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World Journal of Clinical Cases 2025年第3期13卷 61-65页

作者： nirmal kumar Reddy Onteddu Naga Sai Rasagna Mareddy Sai Swarupa R Vulasala Jayabharath Onteddu Mayur Virarkar Department of Internal Medicine University of Florida College of MedicineJacksonvilleFL 32209United States Department of Diagnostic Radiology University of AlabamaBirminghamAL 35294United States Department of Diagnostic Radiology University of Florida College of MedicineJacksonvilleFL 32209United States Department of Public Health Sciences University of FloridaGainesvilleFL 32611United States

A recent case report provided a patient scenario,wherein,a 39-year-old male patient presented with occasional palpitations,headache,and *** of tumor markers did not show any abnormal ***,a computed tomography(CT)scan was undertaken,and its findings were affirmative of thymic ***,the postoperative histopathological assessment of the mass,after its resection,confirmed it as an anterior mediastinal multilocular thymic cyst(MTC),with concurrent acute upper respiratory tract infection and acute ***,this case report advocates the need for a preoperative histopathological examination with CT imaging to minimize the risk of confusing an MTC with a malignant thymic tumor.

关键词： Imaging findings Multilocular thymic cyst Histopathology Thymic cancer Mediastinal mass

Influence of alumina/MWCNT hybrid nanoparticle additives on tribological properties of lubricants in turning operations

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Friction 2019年第2期7卷 153-168页

作者： Anuj kumar SHARMA Jitendra kumar katiyar Shubrajit BHAUMIK Sandipan ROY Tribology and Surface Interaction Research Lab Department of Mechanical EngineeringSRM Institute of Science and Technology Kattankulathur

A hybrid lubricant with improved thermal and tribological properties was developed by blending multiwalled carbon nanotubes(MWCNTs) with alumina-based nanoparticles into cutting fluid at fixed volumetric proportions(10:90). The hybrid cutting fluid was prepared in different volumetric concentrations(0.25, 0.75, and 1.25 vol%), and the tribological properties and contact angles were measured using pin-on-disc tribometry and goniometry, respectively. The study showed a reduction in wear and friction coefficient with increasing nanoparticle concentration. The cutting fluid performance was investigated using minimum quantity lubrication(MQL) in the turning of AISI 304 stainless steel. Regression models were developed for measuring the temperature and tool flank wear in terms of cutting speed, feed, depth of the cut, and nanoparticle concentration using response surface methodology. The developed hybrid nanolubricants significantly reduced the tool flank wear and nodal temperature by 11% and 27.36%, respectively, as compared to alumina-based lubricants.

关键词： hybrids nanolubricants MQL MWCNT tool wear friction coefficient

Infrared Spectra of PH3 and NF_(3): An Algebraic Approach

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Chinese Physics Letters 2013年第7期30卷 9-12页

作者： Joydeep Choudhury nirmal kumar Sarkar Ramendu Bhattacharjee Department of Physics Assam UniversitySilchar-788011India Department of Physics Karimganj CollegeKarimganj-788710India

Molecular spectroscopy is a branch of physics which deals with the interaction of electromagnetic radiation with *** the new theoretical approach,i.e.,Lie algebraic approach,we calculate the infrared spectra of phosphine in the range from 3000 cm^(-1) to 9500 cm^(-1) and nitrogen trifluoride in the range from 900 cm^(-1) to 4500 cm^(-1).The model Hamiltonian constructed seems to describe the P–H and N–F stretching modes accurately with only four numbers of *** present calculation not only predicts the higher overtones but also shows good agreement with the few observed data.

关键词： parameters. Infrared stretching

Tree Age Affects Postharvest Attributes and Mineral Content in Amrapali Mango(Mangifera indica) Fruits

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Horticultural Plant Journal 2018年第2期4卷 55-61页

作者： MEENA nirmal kumar ASREY Ram Division of Food Science and Postharvest Technology ICAR-Indian Agriculture Research Institute

The study was carried out to investigate the effect of tree age on postharvest attributes and mineral content of Amrapali mango fruits. Effect of 3 different tree ages(6, 18 and 30 years) on functional components, including the antioxidant activity(AOX), total phenols, total carotenoids,ascorbic acid and minerals like Ca, K, Mg, Fe, Zn, Cu, Mn and B along with total sugars, total soluble solids(TSS) and titratable acidity(TA),respiration rate, polygalacturonase(PG) and pectin methylesterase(PME) activities in Amrapali cultivar were studied. With tree ageing total phenols, ascorbic acid and antioxidant activity decreased whereas total carotenoids increased. Ca diminished and K elevated with the tree age progression while, B, Fe, Cu, Zn, and Mn showed an indefinite pattern. Total soluble solids and total sugars were recorded higher in 18 year old tree fruits. Fruit respiration rate, polygalacturonase and pectin methylesterase activities showed an upward trend with tree ageing. The study indicates that fruit produced from middle age group mango orchard(18 year old) suits to the requirement of consumers as well as industry.

关键词： mango(Mangifera indica) tree age functional parameter mineral

Mechanical, tribological and anti-corrosive properties of polyaniline/graphene coated Mg-9Li-7Al-1Sn and Mg-9Li-5Al-3Sn-1Zn alloys

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Journal of Materials Science & Technology 2019年第8期35卷 1767-1778页

作者： Rita Maurya Abdul Rahim Siddiqui Prvan kumar katiyar Kantesh Balani Materials Science and Engineering Indian Institute of Technology Kanpur Kanpur 208016 India Centre for Material Science & Engineering National Institute of Technology Hamirpur Hamirpur 177005 India China-Canada Institute for Advanced Surface & Interface Science and Engineering Jiangsu University of Technology Changzhou 213001 China

The mechanical,tribological and corrosion protection offered to Mg-9Li-7Al-1Sn and Mg-9Li-5Al-3Sn-1Zn alloys by the epoxy coating containing polyaniline/graphene(PANI/Gr)pigments is undertaken in the current ***/Gr containing coatings were observed to be strongly adherent with a higher scratch hardness(Hs)and plowing hardness(Hp),*** 0.43 GPa,and Hpof 0.61 GPa,respectively when compared to that of neat epoxy coating(Hsof 0.17 GPa,and Hpof 0.40 GPa,respectively).Due to their higher Hsand Hpvalues,PANI/Gr based coatings displayed an enhanced wear resistance(Wear volume,Wv=4.53×10^-3 m^3)than that of neat epoxy coating(Wv=5.15×10^-3 m^3).The corrosion protection efficiency in corrosive environment of 3.5 wt%NaCl solution was obtained to be>99% for PANI/Gr containing coatings when compared to that of neat epoxy *** charge-transfer resistance(R(ct))of the PANI/Gr containing coatings were estimated to be>10^6 cm^2,which indicates their highly protective nature when compared to that of neat epoxy coating(R(ct)10^5 Ω cm^2).Hence,PANI/Gr containing coatings can be potentially used for wear resistance and corrosion protection applications in marine environments.

关键词： Mg-Li alloys Scratch hardness Plowing hardness Wear resistance Corrosion protection efficiency Charge transfer resistance

Vibrational Spectroscopy of Stretching and Bending Modes of Nickel Tetraphenyl Porphyrin： an Algebraic Approach

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Chinese Physics Letters 2009年第9期26卷 122-125页

作者： Srinivasa Rao KARUMURI Joydeep CHOUDHURY nirmal kumar SARKAR Ramendu BHATTACHARJEE Department of Physics P.B. Siddhartha College of Arts and Sciences Vijayawada-520010 India Department of Physics Assam (a central) University Silchar- 788011 India Department of Physics Karimganj College Karimganj-788710 India

We calculate the vibrational frequencies of nickel tetraphenyl porphyrin for 36 vibrational bands by using the U（2） algebraic approach. The algebraic parameters in the calculations are accurate with the experimental... 详细信息

关键词： sea surface nonliear interaction numerical method

Vibrational Spectroscopy of CH/CD Stretches in Propadiene： An Algebraic Approach

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Chinese Physics Letters 2009年第2期26卷 36-38页

作者： Joydeep Choudhury nirmal kumar Sarkar Srinivasa Rao Karumuri Ramendu Bhattacharjee Department of Physics Assam University Silchar- 788011 India Department of Physics Karimganj College Karimganj-788710 India

Using Hamiltonian based on Lie algebraic method, the stretching vibrational modes of C3H4 and C3D4 molecules are calculated up to higher overtones. The model appears to describe C-H and C-D stretching modes with less number of parameters. The locality parameter ξ confirms the highly local behaviour of the stretching modes of these molecules.

关键词： No English Keywords

Microalgal bioinoculants for sustainable agriculture and their interactions with soil biotic and abiotic components:A review

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Pedosphere 2024年第2期34卷 297-314页

作者： Shisy JOSE nirmal RENUKA Sachitra kumar RATHA Sheena kumarI Faizal BUX Institute for Water and Wastewater Technology Durban University of TechnologyP.O.Box 1334Durban 4000South Africa Algal Biotechnology Laboratory Department of BotanyCentral University of PunjabBathinda 151401India Phycology Laboratory Council of Scientific and Industrial Research-National Botanical Research InstituteLucknowUttar Pradesh 226001India

Modern agricultural practices have posed a detrimental impact on the environment due to their intensive use to meet the food demands of an ever-increasing *** this context,microalgal bioinoculants,specifically cyanobacteria and green microalgae,have emerged as sustainable options for agricultural practices to improve soil organic carbon,nutrient availability,microbial quality,and plant *** overview of current and future perspectives on the use of microalgal bioinoculants in agriculture practices is presented in this review,along with a discussion of their interactions with soil biotic and abiotic factors that affect soil fertility,plant health,and crop *** benefits of microalgal bioinoculants include releasing agronomically important metabolites(exopolymers and phytohormones)as well as solubilizing soil ***,they function as biocontrol agents against soil-borne pathogens and facilitate the establishment of rhizosphere communities of agricultural *** far,very few studies have explored the basic mechanisms by which microalgal bioinoculants interact with soil biotic and abiotic *** recent years,advanced molecular techniques have contributed to a better understanding of these interactions.

关键词： biocontrol agent biofertilizer cyanobacteria microalgae microbial community molecular technique plant growth soil fertility