检索结果-南通市图书馆

Enhanced degradation of refractory organics in ORR-EO system with a blue TiO_(2)nanotube array modified Ti-based Ni-Sb co-doped SnO_(2)anode

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第8期35卷 391-395页

作者： Yifen he Chao Qu na Ren Dawei Liang Department of Materials Chemistry School of Materials Science&EngineeringBeihang UniversityBeijing 102206China Department of Environmental Science Faculty of Environment&LifeBeijing University of TechnologyBeijing 100124China

Recently,a novel 2-electron oxygen reduction reaction(ORR)based electro-oxidation(EO)system was developed,which utilizes a h_(2)O_(2)generation cathode instead of h_(2)evolution cathode.A Ti-based Ni-Sb co-doped SnO_(2)(Ti/naTO)anode was selected for efficient degradation of refractory organics and O_(3)*** synergistic reaction of O3/h_(2)O_(2)further accelerated the generation of hydroxyl radicals(·Oh)in the ORR-EO ***,the catalytic activity and long-term effectiveness of the Ti/naTO anode limited the large-scale application of the ORR-EO *** this study,a blue TiO_(2)nanotube array(blue-TiO_(2)-NTA)inter-layer was introduced into the fabrication process between the Ti substrate and naTO catalyst *** to the Ti/naTO anode,the Ti/blue-TiO_(2)-NTA/naTO anode achieved higher efficiency of organic removal and O_(3)***,the accelerated lifetime of the Ti/blue-TiO_(2)-NTA/naTO anode was increased by 7 times compared to the Ti/naTO *** combined with CNTs-C/PTFE air cathode in ORR-EO system,all anodic oxidation and O_(3)/h_(2)O_(2)processes achieved higher•Oh *** 92%of TOC in leachate bio-effluent was effectively eliminated with a relatively low energy cost of 45 kWh/t.

关键词： Electro-oxidation Blue TiO_(2)nanotube array O_(3)/h_(2)O_(2)process Refractory organics Leachate bio-effluent

Boosted sustained-release with iron-based MOF-derived mesoporouscarbon-spheres as a nitroimidazole drugs carrier

在线全文

学校读者我要写书评

暂无评论

Particuology 2024年第3期86卷 269-280页

作者： Danping Wu Jiaying Zou Junyi Chen Yan Li na Ma Wei Dai College of Chemistry and Materials Science Zhejiang Normal UniversityJinhua321004China College of Life Sciences Zhejiang Normal UniversityJinhua321004China College of Geography and Environmental Sciences Zhejiang Normal UniversityJinhua321004China

Metal-organic framework(MoF)with a buildable internal structure has aroused great interest focus as self-sacrificing precursors of porous carbon(PC).however,as a drug carrier,the MOF-derived PC developed thus far are generally composed of irregular powder shape due to their crystalline nature,which consequently causing the cerebral infarction,cerebral thrombosis,and other blood *** this article,we propose a novel approach to constructing amorphous carbon microspheres(AcMs)by dis-torting the topological network through hydrothermal treatment precursors of MIL-101(Fe).Then,a distinctive MIL-101(Fe)-derived spherical porous carbons(MSPC)is achieved through high temperature calcination toward *** of the glucose initial concentration and hydrothermal treatment time on the sphericity of the as-prepared mesoporous MsPC were investigated in *** the loading capacities and sustained-release performances of nitroimidazole drugs over MsPC through simulation internal environment of human body at different ph values was systematically *** nitro-imidazole drugs loading rate and release time of MsPC are 10% and 17 h under preferred ***,the MSPC exhibited very low toxicity on hela cells and 293T cells at the concentrations tested(10-800μg mL^(-1)).This study,therefore,supports the potential of the mesoporous carbon spheres as a carrierfor nitroimidazole drug delivery.

关键词： Ornidazole Metronidazole Carbon spheres Sustained-release performance Biocompatibility

Electrolytes additives for Zn metal anodes:regulation mechanism and current perspectives

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Rare Metals 2024年第9期43卷 4162-4197页

作者： Yu-Zhe Zhang huai-Sheng Ao Qi Dong Shao-Jie Zhang Zhi-Guo hou na-na Wang Xue-Song Xie Jian Rong Zhong-Yu Li School of Environmental Science and Engineering Changzhou UniversityChangzhou 213164China School of Petrochemical Engineering Changzhou UniversityChangzhou 213164China hefei national Laboratory for Physical Science at Microscale School of Chemistry and Materials ScienceUniversity of Science and Technology of ChinaHefei 230026China Institute for Superconducting and Electronic Materials Australian Institute for Innovative MaterialsInnovation CampusUniversity of WollongongNorth WollongongNSW 2500Australia Department of Chemical and Materials Engineering University of AlbertaEdmonton AB T6G 1H9Canada

With distinct advantages such as high gravimetric and volumetric capacity(5855 mAh·cm^(-3)and 820mAh·g^(-1)),low redox potential(-0.762 V *** hydrogen electrode(ShE)),high abundance,low toxicity and intrinsic safety of Zn metal anode,Zn-ion batteries have become a potential alternative to Li-ion ***,several challenges still need to be addressed prior to the practical applications of Zn-ion batteries,such as dendrite growth during Zn plating/stripping and interfacial side reactions on the Zn *** issues can be addressed by introducing additives to regulate the components and structures of the *** this review,we systematically discussed the core issues of metallic Zn anodes and comprehensively summarized a novel perspective of the regulation mechanism of inhibiting dendrite growth or interfacial side reactions in Zn anodes by introducing additives into aqueous ***,some discussions and prospects for aqueous Zn ion batteries(AZIBs)are presented for future research.

关键词： Electrolyte additives Zn metal anode Regulation mechanism Current perspectives AZIBs

A Scalable Pillar Layered Metal-Organic Framework for natural Gas Purification

在线全文

学校读者我要写书评

暂无评论

Chemical Research in Chinese Universities 2024年第4期40卷 675-681页

作者： LU nan LAN Lan GAO Qiang LI na BU Xian-he School of Materials Science and Engineering Nankai UniversityTianjin300350P.R.China State Key Laboratory of Elemento-Organic Chemistry College of ChemistryNankai UniversityTianjin300071P.R.China School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang212003P.R.China

One-step harvest of high-purity methane(Ch_(4))from ternary propane/ethane/methane(C_(3)h_(8)/C_(2)h_(6)/Ch_(4))mixtures remains a desirable yet challenging goal for natural gas ***,adsorbents either suffer from high capacity and selectivity,or are caught in a dilemma of scalable ***,we demonstrate a scalable pillar layered metal-organic framework Ni-MOF for highly efficient one-step Ch_(4)***-MOF exhibits high C_(2)h_(6)and C_(3)h_(8)uptakes of 83.3 and 86.1 cm^(3)/g at 298 K and 100 kPa and remarkable C_(2)h_(6)/Ch_(4)(50/50,volume ratio,21.5)and C_(3)h_(8)/Ch_(4)(50/50,volume ratio,212.0)***,high C_(2)h_(6)(42.2 cm^(3)/g at 10 kPa)and C_(3)h_(8)(64.7 cm^(3)/g at 5 kPa)capacities in the low-pressure region at 298 K were realized on Ni-MOF,suggesting the strong affinities of Ni-MOF towards C_(2)h_(6)and C_(3)h_(8).Furthermore,the dynamic breakthrough experiments revealed that purifying Ch_(4)from natural gas in one-step can be achieved in Ni-MOF with high-purity(>99.8%)and productivity(346.0 cm^(3)/g).Most significantly,the production of Ni-MOF can be scalably synthesized at room temperature,rendering it promising potential for industrial *** combined advantages of exceptional separation performance,scalability,and cycle stability of Ni-MOF pave the way for one-step Ch_(4)purification from natural gas.

关键词： Metal-organic framework Adsorption and separation natural gas purification Scale-up synthesis

Ginsenoside Rd Induces Differentiation of Myeloid Leukemia Cells via Regulating ERK/GSK-3βSignaling Pathway

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Integrative Medicine 2024年第7期30卷 588-599页

作者： JIANG Yu-xia ZhAO Yan-na YU Xiao-ling YIN Li-ming Department of hematology Tongde Hospital of Zhejiang ProvinceHangzhou310012China Institute of hematology Research the First Affiliated Hospital of Zhejiang Chinese Medical University(Zhejiang Provincial Hospital of Chinese Medicine)Hangzhou310006China

Objective To investigate the role of ginsenoside Rd(GRd)in acute myeloid leukemia(AML)cell *** AML cells were treated with GRd(25,50,100 and 200µg/mL),retinoic acid(RA,0.1g/L)and PD98059(20 mg/mL)for 72 h,cell survival was detected by methylthiazolyldiphenyl-tetrazolium bromide and colony formation assays,and cell cycle was detected by flow *** morphology and differentiation were observed by Wright-Giemsa staining,peroxidase chemical staining and cellular immunochemistry assay,*** protein expression levels of GATA binding protein 1(GATA-1),purine rich Box-1(PU.1),phosphorylated-extracellular signal-related kinase(p-ERK),ERK,phosphorylated-glycogen synthase kinase-3β(p-GSK3β),GSK3βand signal transducer and activator of transcription 1(STAT1)were detected by Western ***-six mice were randomly divided into 3 groups using a random number table:model control group(non-treated),GRd group[treated with 200 mg/(kg·d)GRd]and homoharringtonine(hTT)group[treated with 1 mg/(kg·d)hTT].A tumor-bearing nude mouse model was established,and tumor weight and volume were *** of subcutaneous tumor tissue were observed after hematoxylin and eosin ***1 and GATA-1 expressions were detected by immunohistochemical *** The cell survival was inhibited by GRd in a dose-dependent manner and GRd caused G0/G1 cell arrest(phowing increased expressions of peroxidase and specific proteins concerning erythrogenic or granulocytic differentiation(phe effects of PD98059 on inhibiting the expressions of peroxidase,GATA-1 and PU.1(Pht and volume of mice were decreased,and tumor cells underwent massive apoptosis and necrosis(P<0.05).WT1 level was decreased,and GATA-1 level was significantly increased in subcutaneous tumor ti

关键词： ginsenoside Rd myeloid leukemia survival differentiation extracellular signal-related kinase signaling pathway

Efficient and selective upcycling of waste polylactic acid into acetate using nickel selenide

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第10期97卷 575-584,I0012页

作者： Bing Lan Yinfang Chen nantian Xiao na Liu Chao Juan Chuan Xia Fan Zhang national Engineering Laboratory of Eco-Friendly Polymeric Materials College of ChemistrySichuan UniversityChengdu 610064SichuanChina School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina

The conversion of waste polylactic acid(PLA)plastics into high-value-added chemicals through electrochemical methods is a promising and sustainable ***,developing efficient and highly selective catalysts for lactic acid oxidation reaction(LAOR)and understanding the reaction process are ***,we report the electrooxidation of waste PLA to acetate at a high current density of 100 mA cm-2 with high Faraday efficiency(~95%)and excellent stability(>100 h)over a nickel selenide nanosheet *** addition,a total Faraday efficiency of up to 190%was achieved for carboxylic acids,including acetic acid and formic acid,by coupling with the cathodic CO_(2) reduction *** situ experimental results and theoretical simulations revealed that the catalytic activity center of LAOR was dynamically formed NiOOh species,and the surface-adsorbed SeO_(x) species accelerated the formation of Ni~(3+)species,thus promoting catalytic *** mechanism of lactic acid electrooxidation was further *** acid was dehydrogenated to produce pyruvate first and then formed Ch_3CO due to preferential C-C bond cleavage,resulting in the presence of *** work demonstrated a sustainable method for recycling waste PLA and CO_(2) into high-value-added products.

关键词： Waste plastic upcycling Poly(lactic acid) Lactic acid electro-oxidation Acetic acid

The guest Ch_(3)CN molecule triggers solid-state photochromism in a Cu_(2)I_(2)-based MOF for advanced time-dependent encryption and inkless erasable printing

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第3期35卷 532-537页

作者： Meng-Juan Wang Bo Li Yong-Li Wei Shu-na Zhao Shuang-Quan Zang henan Key Laboratory of Crystalline Molecular Functional Materials Henan International Joint Laboratory of Tumor Theranostical Cluster MaterialsGreen Catalysis Centerand College of ChemistryZhengzhou UniversityZhengzhou 450001China College of Chemistry and Pharmaceutical Engineering Nanyang Normal UniversityNanyang 473061China

It remains a big challenge to develop solid-state stimuli-responsive materials for time-dependent information encryption and inkless erasable printing with long retention ***,a 2D Cu_(2)I_(2)-based MOF with photoresponsive spiropyran(SP)groups orderly installed on its skeleton is *** structural isomerization from SP to colored merocyanine(MC)form can be triggered by removing the Ch_(3)CN ***,the degree of structural isomerization and the retention time can be adjusted by controlling the amount of Ch_(3)CN guests,exhibiting dynamic photochromic behavior with multicolor states and tunable retention *** on these advantages,time-dependent information encryption is successfully ***,the long retention time(>72 h)of the MC form under daylight conditions in the Ch_(3)CN-removed Cu_(2)I_(2)-based MOF and good repeatability make it promising in various applications,such as temporary calendars,price-cards,billboards,and reusable identity *** work provides a novel design strategy to fabricate multi-functional MOF-based smart materials for challenging applications of time-dependent information encryption and inkless erasable printing.

关键词： Stimuli-responsive materials Spiropyran Solid-state photochromism Time-dependent encryption Inkless erasable printing

Effect of Maternal DEhP Exposure on Lipid Metabolism in Adult Male Rats and the Antagonistic Effect of Genistein

在线全文

学校读者我要写书评

暂无评论

Biomedical and Environmental Sciences 2024年第3期37卷 315-319页

作者： ZhANG Yun Bo LI Jiang Li TIAN Jie na Xiao Lin Department of Environmental hygiene Public Health CollegeHarbin Medical UniversityHarbin 150081HeilongjiangChina

Lipid metabolism refers to the biochemical processes involved in synthesising,storing,utilising,and breaking down lipids in living *** are essential for various physiological functions,including energy storage,insulation,protection of organs,and the formation of cell *** in lipid metabolism can lead to a number of health issues,such as atherosclerosis,obesity,and type 2 diabetes,etc.[1].Environmental factors,genetics,and lifestyle factors are some of the factors that can contribute to the development of ***,there is a growing academic interest in the impact of environmental factors.

关键词： Lipid metabolism organs

Brain protective effect of dexmedetomidine vs propofol for sedation during prolonged mechanical ventilation in non-brain injured patients

在线全文

学校读者我要写书评

暂无评论

World Journal of Psychiatry 2024年第3期14卷 370-379页

作者： hong-Xun Yuan Li-na Zhang Gang Li Li Qiao Intensive Care Unit Peking University International HospitalBeijing 102206China Central Operating Room The Affiliated Beijing Chaoyang Hospital of Capital Medical UniversityBeijing 100020China

BACKGROUND Dexmedetomidine and propofol are two sedatives used for long-term *** remains unclear whether dexmedetomidine provides superior cerebral protection for patients undergoing long-term mechanical *** To compare the neuroprotective effects of dexmedetomidine and propofol for sedation during prolonged mechanical ventilation in patients without brain *** Patients who underwent mechanical ventilation for>72 h were randomly assigned to receive sedation with dexmedetomidine or *** Richmond Agitation and Sedation Scale(RASS)was used to evaluate sedation effects,with a target range of-3 to *** primary outcomes were serum levels of S100-βand neuron-specific enolase(NSE)every 24 *** secondary outcomes were remifentanil dosage,the proportion of patients requiring rescue sedation,and the time and frequency of RASS scores within the target *** A total of 52 and 63 patients were allocated to the dexmedetomidine group and propofol group,*** data were comparable between *** significant differences were identified between groups within the median duration of study drug infusion[52.0(IQR:36.0-73.5)h vs 53.0(IQR:37.0-72.0)h,P=0.958],the median dose of remifentanil[4.5(IQR:4.0-5.0)μg/kg/h vs 4.6(IQR:4.0-5.0)μg/kg/h,P=0.395],the median percentage of time in the target RASS range without rescue sedation[85.6%(IQR:65.8%-96.6%)vs 86.7%(IQR:72.3%-95.3),P=0.592],and the median frequency within the target RASS range without rescue sedation[72.2%(60.8%-91.7%)vs 73.3%(60.0%-100.0%),P=0.880].The proportion of patients in the dexmedetomidine group who required rescue sedation was higher than in the propofol group with statistical significance(69.2%vs 50.8%,P=0.045).Serum S100-βand NSE levels in the propofol group were higher than in the dexmedetomidine group with statistical significance during the first six and five days of mechanical ventilation,respectively(all P<0.05).CONCLUSION Dexmedetomidine demonstrated

关键词： Dexmedetomidine Propofol Sedation Prolonged mechanical ventilation Brain protective