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Chinese Journal of Polymer Science 2024年第3期42卷 333-343,I0007页

作者： Elizaveta v.Batishcheva nikolay n.smirnov.natalya v.bobrov. Maria P.Sokolova Michael A.smirnov Institute of Macromolecular Compounds Russian Academy of SciencesBolshoy pr.31Saint Petersburg 199004Russia

Green method for preparation of ion-conducting membranes(ICM) based on bacterial cellulose nanofibers(CnF) modified by a copolymer of sodium acrylate and 2-acrylamido-2-methylpropanesulfonic acid was elaborated. FTIR and nMR data confirmed grafting of polyacrylate onto cellulose surface. Formation of porous structure of the ICM was controlled by SEM and AFM. The maximal ionic conductivity of the membranes reaches 1.5 and 3.1 mS·cm^(-1)(60 ℃ and 98% relative humidity) when they are saturated with water or H_2SO_4(1 mol·L^(-1)) electrolyte,respectively. Prepared ICM was tested as a separator in a symmetrical supercapacitor with electrodes based on polyaniline hydrogel. The assembled cell demonstrate ability to operate at high current density up to 100 A·g^(-1) maintaining specific capacitance 165 F·g^(-1). Maximal specific capacitance of 289 F·g^(-1) was achieved at current density 1 A·g^(-1). Retaining of 90% of initial capacitance after 10000 of charge-discharge cycles proves high electrochemical stability of prepared ICM.

关键词： Bacterial cellulose Ion conductivity Porous membrane Supercapacitor

Self-healable and Robust Film Based on Electroactive Polymer Brush as Electrode for Flexible Supercapacitor

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Chinese Journal of Polymer Science 2024年第8期42卷 1049-1059页

作者： Maria P.Sokolova vitaly K.vorobiov nikolay n.smirnov Ivan S.Kuryndin natalya v.bobrov. Michael A.smirnov Institute of Macromolecular Compounds Russian Academy of SciencesBolshoy pr.31Saint Petersburg 199004Russia

The aim of this study was to develop self-healable and robust elect roconductive film based on polyaniline copolymer for application as electrode in flexible *** this purpose,the electroconductive polymer brushes(EPB)was *** synthesis of EPB is based on graft polymerizations of acrylamide(AAm)on poly(vinyl alcohol)(PvA)with formation of PvA-PAAm polymer brush and subsequent graft copolymerization of aniline and p-phenylenediamine on PvA-PAAm resulting in formation of EPB with electroconducting copoly(aniline-co-pphenylenediamine)(PAPh DA).It was found that the ratio between PvA and PAAm at the first stage greatly influence the electrochemical performance of the *** films were prepared by casting of EPB solution with subsequent *** of electrical current distribution through the film with AFM reveal more uniform distribution of PAPhDA in EPB in comparison with reference PvA-PAPhDA and PAAm-PAPhDA *** was demonstrated that mechanical cha racteristics and electrical conductivity values of films restore at large extent after curring and self-healing under optimal relative humidity level(58%).The flexile supercapacitor cell with EPB film electrodes demon strate specific capacitance 602 mF·cm^(-2)at the current density of 1 mA·cm^(-2)and retention 94%of initial capacitance after 5000 charge/discharge cycles.

关键词： Polymer brush Polyaniline Flexible supercapacitor Self-healing Electroconducting film

3,6-Bis-β-Dicarbonylsubstituted Carbazoles Bearing n-Spacers and Their Eu(III) Complexes as Immunofluorescent Labelling Agents

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International Journal of Organic Chemistry 2024年第1期14卷 20-31页

作者： Dmitry E. Pugachev Georgy v. Zatonsky Tatyana S. Kostryukova Anna G. Shubina nikolay v. vasiliev Department of Biological Microanalysis FGUP State Research Institute of Biological Engineering Moscow Russia Department of Theoretical and Applied Chemistry State University of Education Mytishchi Russia

new reagents for immunofluorescence analysis of carbazole series containing fluorinated β-dicarbonyl fragments and carboxylic substituent groups separated by spacers of different lengths from the light-gathering carbazole scaffold have been developed. The markers in complex with Eu3+ ions possess stability in the aqueous phase, intense and prolonged luminescence (τ 550 - 570 μs) with characteristic emission maxima in the region of 615 nm and excitation wavelengths in the region of 380 - 390 nm, which distinguishes them from most of the analogs used. In the study of marker conjugation with streptavidin, a reagent containing 4 - 5 europium labeling complexes based on spacer-containing carbazole tetraketone was obtained. The marker-doped silicate nanoparticles exhibit intense and long-lived luminescence in the characteristic region.

关键词： Fluorescence Immunoassay Fluorinated β-Diketones Carbazole Europium Complexes Streptavidin nanodispersions

On the Path to High-Temperature Josephson Multi-Junction Devices

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Electromagnetic Science 2024年第3期2卷 71-78页

作者： Xu Wang Fucong Chen Zefeng Lin Shibing Tian Chunguang Li victor Kornev nikolay Kolotinskiy Institute of Physics Chinese Academy of SciencesBeijing 100190China Faculty of Physics Lomonosov Moscow State UniversityMoscow 119991Russia

We report our progress in the high-temperature superconductor(HTS)Josephson junction fabrication process founded on utilizing a focused helium ion beam damaging technique and discuss the expected device performance attainable with the HTS multi-junction device *** the achievable high value of characteristic voltage v_(C)=I_(C)R_(n)of Josephson junctions and the ability to design a large number of arbitrary located Josephson junctions allow narrowing the existing gap in design abilities for lowtemperature superconductor(LTS)and HTS circuits even with using a single YBa_(2)Cu_(3)O_(7-x) film layer.A one-layer topology of active electrically small antenna is suggested and its voltage response characteristics are considered.

关键词： Josephson junctions High-temperature superconductors YBa_(2)Cu_(3)O_(7-x)(YBCO) Focused helium ion beam fabrication technique Josephson multi-junction devices Superconducting quantum interference device Active electrically small antenna

A new insight into the nature of seasonal variations in coordinate time series of GPS sites located near active faults

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Frontiers of Earth Science 2016年第3期10卷 560-569页

作者： Sergey v. TROFIMEnKO victor G. BYKOv nikolay v. SHESTAKOv nikolay n. GRIB Hiroaki TAKAHASHI Institute of Tectonics and Geophysics Far Eastern Branch Russian Academy of Sciences Khabarovsk 680000 Russia north-Eastern Federal University Neryungri 678960 the Republic of Sakha (Yakutia) Russia Institute for Applied Mathematics Far Eastern Branch Russian Academy of Sciences Vladivostok 690041 Russia Far Eastern Federal University Vladivostok 690041 Russia Institute of Seismology and volcanology Graduate School of Science Hokkaido University Sapporo 060-0810 Japan

This study provides new insights into the nature of seasonal variations in coordinate time series of GPS sites located near active faults and methods of their modeling. Monthly averaged coordinate time series were analyzed for several pairs of collocated GPS sites situated near the active fault intersection area, in close proximity to the central part of the northern boundary of the Amurian plate and the vicinity of the San Andreas Fault zone. It is concluded that the observed seasonal variations are best described by a breather function which is one of the solutions of the well-known sine-Gordon equation. The obtained results suggest that, in this case, the source of seasonal variations may be caused by the appearance of solitary strain waves in the fault intersection system, which may be qualitatively treated as standing waves of compression-extension of the geological medium. Based on statistical testing, the limits of applicability of the suggested model have been established.

关键词： space geodetic surveys oscillatory move-ments of crustal blocks seasonal variations Amurianmicroplate

The Fifth Edition of the General Catalogue of variable Stars:experiences in the constellation Centaurus

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Research in Astronomy and Astrophysics 2018年第7期18卷 93-100页

作者： nikolay n.Samus Elena n.Pastukhova Olga v.Durlevich Elena v.Kazarovets Institute of Astronomy Russian Academy of Sciences Sternberg Astronomical Institute Lomonosov Moscow University

We have recently announced that the General Catalogue of variable Stars enters the stage of its fifth, purely electronic edition （GCvS 5.1）. We have included 1408 variable stars in the constellation Centaurus in this new version, GCvS 5.1. Working on this revision, we applied current possibilities from data mining, suggested new variability types for many variable stars and found new light elements for a large number of periodic variables. This paper describes the work completed during the preparation of GCvS 5.1 for Centaurus and discusses in detail a number of the most astrophysically significant cases.

关键词： catalogs - techniques photometric - stars variables general - binaries eclipsing

Fluctuating fine-scale spatial genetic structure in the common shrews (Eulipotyphla, Mammalia)

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Integrative Zoology 2023年第3期18卷 469-492页

作者： nikolay A.SHCHIPAnOv Artem v.ARTAMOnOv Sergey v.TITOv Svetlana v.PAvLOvA A.n.Severtsov Institute of Ecology and Evolution Russian Academy of SciencesMoscowRussia Department of Zoology and Ecology Penza State UniversityPenzaRussia

The spatial genetic structure is a topical issue in the studies of various aspects of ecology and *** the multilocus autocorrelation method with hypervariable microsatellite genetic markers,we investigated aﬁne-scale pattern of genetic structure in 5 local populations of the common shrew Sorex araneus separated by distances of 300–1000 m(the Moscow chromosomal race).Spatial genetic autocorrelation analysis based on 5 microsatellite loci(expected heterozygosity>0.79)with 90 alleles revealed a consistent pattern of signiﬁcant positive genetic *** testing the autocorrelation at multiple scales from 25 to 500 m,we found that positive spatial genetic structure is detectable in distance classes ofnetic structure positively correlated with a higher ratio of nonresident individuals to residents’activity(number of captures).In contrast to nonresident animals,the residents demonstrated prominent genetic *** difference(FST)between the populations was signiﬁcant(0.016–0.051)and comparable with that between populations of different races analyzed previously(0.016–0.038).FST was not associated with geographic *** demographic patterns allowed us to propose a scheme of genetic-structure dynamics involving periodic appearance of more related local groups and renewal of allelic proﬁles fromаcommon pool where the alleles are *** scheme predictsﬂuctuating genetic structure and random similar differences among local populations.

关键词： demographic pattern geneﬂow microsatellite spatial autocorrelation

GSC 4560–02157: a new long-period eclipsing cataclysmic variable star

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Research in Astronomy and Astrophysics 2015年第7期15卷 1005-1011页

作者： Anton v.Khruslov Anatoly v.Kusakin Elena A.Barsukova vitaly P.Goranskij Azamat F.valeev nikolay n.Samus Institute of Astronomy Russian Academy of Sciences Fesenkov Astrophysical Institute Special Astrophysical Observatory Russian Academy of Sciences Sternberg Astronomical Institute Lomonosov Moscow State University

We study the newly discovered variable star GSC 4560-02157. CCD photometry was performed in 2013-2014 at the Tien Shan Astronomical Observatory,and a spectrum was obtained with the 6-m telescope of the Special Astrophysical Observatory in June, 2014. GSC 4560-02157 is demonstrated to be an eclipsing variable star（P = 0.265359d）. All its flat-bottom primary minima are approximately at the same brightness level, but the star＇s out-of-eclipse brightness and brightness at secondary minima vary considerably（by up to 0.6m） from cycle to cycle. Moreover,there are short-term（time scale of 0.03-0.04 days） small-amplitude brightness variations out of eclipse. This behavior suggests a cataclysmic nature for the star, which is confirmed with a spectrum taken on 2014 June 5. The spectrum shows numerous emissions of the hydrogen Balmer series, He Ⅰ and He Ⅱ.

关键词： stars: dwarf novae -- binaries: eclipsing -- stars: individual: GSC 4560-02157

Alien species of mammals and their impact on natural ecosystems in the biosphere reserves of Russia

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Integrative Zoology 2008年第2期3卷 83-94页

作者： valery M.nEROnOv Ludmila A.KHLYAP vladimir v.bobrov.Andrey A.WARSHAvSKY A.n.Severtsov Institute of Ecology and Evolution Russian Academy of SciencesMoscowRussia

The paper analyses the results of a survey of 37 Russian biosphere reserves using questionnaires concerning thepresence of alien species of mammals, their pathways of penetration, and their impacts on protected *** penetration of alien mammals into terrestrial ecosystems of Russia is extensive, both in places with maximumhuman environmental impact (inhabited areas and agricultural lands) and in biosphere reserves with minimal humanimpact. There are 62 mammal species registered as alien in Russian ecosystems and they account for 22% of theterrestrial mammal fauna of Russia. The percentage of alien species in biosphere reserves is 32.6% at most. In mostregions, Castor fiber, Ondatra zibethicus, nyctereutes procyonoides, Canis familiaris, neovison vison and Susscrofa are very dangerous, and both Castor fiber and Sus scrofa can have environment-forming impacts.

关键词： alien species biosphere reserves invasions mammals(Mammalia) Russia.

The Methodological Way to Diagnostic of Efficiency Active Leaching Materials

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Materials Sciences and Applications 2012年第2期3卷 116-119页

作者： nikolay n. Petrov Roman v. Gorokhov Tatyana n. Musorina Tatyana B. Kasatkina natalya A. Shkabara nikolay n. Bukov 不详

It was demonstrated possibility of express diagnostic of characters and prediction efficiency of leaching materials on the bases comparison release rate of active substance and accelerated field tests. It makes on the... 详细信息

关键词： Barrier Diffusion Moderator Release Rate Antifouling Diagnostic of Efficiency