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Generating highly active oxide-phosphide heterostructure through interfacial engineering to break the energy scaling relation toward urea-assisted natural seawater electrolysis

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Journal of Energy Chemistry 2024年第10期97卷 687-699,I0014页

作者： ngoc Quang tran Nam Hoang vu Jianmin Yu Khanh Vy Pham Nguyen Thuy Tien Nguyen tran Thuy-Kieu Truong Lishan Peng Thi Anh Le Yoshiyuki Kawazoe Center for Innovative Materials and Architectures Ho Chi Minh City 700000Vietnam Vietnam National University Ho Chi Minh City 700000Vietnam Faculty of Materials Science and Technology University of ScienceHo Chi Minh City 700000Vietnam Department of Mechanical Engineering Hanbat National University(HBNU)Daejeon 34158Republic of Korea Key Laboratory of Rare Earths Ganjiang Innovation AcademyChinese Academy of SciencesGanzhou 341119JiangxiChina School of Chemical Engineering-Hanoi University of Science and Technology Hanoi 10000Vietnam New Industry Creation Hatchery Center Tohoku UniversitySendai 980-8579Japan

Urea-assisted natural seawater electrolysis is an emerging technology that is effective for grid-scale carbon-neutral hydrogen mass production yet *** scaling relations is an effective strategy to break through the bottleneck of natural seawater ***,by DFT calculation,we demonstrated that the interface boundaries between Ni_(2)P and MoO_(2) play an essential role in the selfrelaxation of the Ni-O interfacial bond,effectively modulating a coordination number of intermediates to control independently their adsorption-free energy,thus circumventing the adsorption-energy scaling *** this conceptual model,a well-defined 3D F-doped Ni_(2)P-MoO_(2) heterostructure microrod array was rationally designed via an interfacial engineering strategy toward urea-assisted natural seawater *** a result,the F-Ni_(2)P-MoO_(2) exhibits eminently active and durable bifunctional catalysts for both HER and OER in acid,alkaline,and alkaline sea water-based *** in-situ analysis,we found that a thin amorphous layer of NiOOH,which is evolved from the Ni_(2)P during anodic reaction,is real catalytic active sites for the OER and UOR ***,such electrode-assembled urea-assisted natural seawater electrolyzer requires low voltages of 1.29 and 1.75 V to drive 10 and600 mA cm^(-2)and demonstrates superior durability by operating continuously for 100 h at 100 mA cm^(-2),beyond commercial Pt/C||RuO_(2) and most previous reports.

关键词： Interfacial engineering Break scaling relationships Doping Natural seawater splitting Urea electrolysis

Photocatalytic degradation of antibiotic sulfamethizole by visible light activated perovskite LaZnO_(3)

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Journal of Environmental Sciences 2024年第10期144卷 212-224页

作者： Bui The Huy XCuong Nguyen vu Khac Hoang Bui Nguyen ngoc Tri Iqra Rabani Nhu Hoa Thi tran Quang Viet Ly Hai Bang Truong Major of Biomedical Engineering Division of Smart HealthcareCollege of Information Technology and ConvergencePukyong National UniversityBusan 48513Korea Center for Advanced Chemistry Institute of Research and DevelopmentDuy Tan UniversityDa Nang 550000Viet Nam Faculty of Environmental and Chemical Engineering Duy Tan UniversityDa Nang 550000Viet Nam Department of Environment and Energy Sejong UniversitySeoul 05006Korea Lab of Computational Chemistry and Modelling Department of ChemistryFaculty of Natural SciencesQuy Nhon UniversityQuy NhonViet Nam Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Korea Faculty of Materials Science and Technology University of ScienceHo Chi Minh City 700000Viet Nam Vietnam National University Ho Chi Minh City 700000Viet Nam Department of Environmental Engineering Seoul National University of Science and TechnologySeoul 01811Korea Optical Materials Research Group Science and Technology Advanced InstituteVan Lang UniversityHo Chi Minh CityViet Nam Faculty of Applied Technology School of TechnologyVan Lang UniversityHo Chi Minh CityViet Nam

In thiswork,the perovskite LaZnO_(3) was synthesized via sol-gel method and applied for photocatalytic treatment of sulfamethizole(SMZ)antibiotics under visible light *** was almost completely degraded(99.2%±0.3%)within 4 hr by photocatalyst LaZnO3 at the optimal dosage of 1.1 g/L,with amineralization proportion of 58.7%±0.4%.The efficient performance of LaZnO_(3) can be attributed to itswide-range light absorption and the appropriate energy band edge levels,which facilitate the formation of active agents such as·O_(2)^(−),h^(+),and·*** integration of RP-HPLC/Q-TOF-MS and DFT-based computational techniques revealed three degradation pathways of SMZ,which were initiated by the deamination reaction at the aniline ring,the breakdown of the sulfonamidemoieties,and a process known as Smile-type rearrangement and SO2 *** toxicity of SMZ and the intermediateswere analyzed by quantitative structure activity relationship(QSAR),indicating the effectiveness of LaZnO_(3)-based photocatalysis in preventing secondary pollution of the intermediates to the ecosystem during the degradation *** visible-light-activated photocatalyst LaZnO_(3) exhibited efficient performance in the occurrence of inorganic anions and maintained high durability across multiple recycling tests,making it a promising candidate for practical antibiotic treatment.

关键词： Perovskite Antibiotics Photocatalysis Density functional theory Toxicity

Tissue engineering using mesenchymal stem cells with periosteal wrap for bone defect repair in rabbits

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Plastic and Aesthetic Research 2015年第1期2卷 340-345页

作者： Trung-Hau LêThua Dang-Nhat Pham Khanh-Linh Lê Minh-Tuan Lê Quang-Ton-Quyen Nguyen Phan-Huy Nguyen ngoc-vu tran ngoc-Luong Nguyen Willy Boeckx Albert Demey Department of Plastic Reconstructive and Hand SurgeryCenter of Orthopaedic and Plastic SurgeryHue Central HospitalHue City 531120Vietnam Department of Hematology Hue Central HospitalHue City 531120Vietnam Department of Biology College of SciencesHue UniversityHue City 521120Vietnam Department of Plastic Surgery Brugmann University HospitalUniversitélibre de Bruxelles1020 BrusselsBelgium

Aim:Mesenchymal stem cells(MSCs)are an excellent potential source of cells for bone tissue engineering due to their excellent renewal ability and osteogenic differentiation *** study was designed to evaluate the bone formation properties of a demineralized cancellous bone scaffold seeded with MSCs,with or without periosteum,in a critical size bone defect model in ***:Rabbit culture-expanded bone marrow(BM)-MSCs were seeded onto a human demineralized cancellous bone(HDCB)*** defects measuring 15 mm in length were created in each radius.A total of 56 bone defects in 28 rabbits were randomly assigned to one of the 4 groups for scaffold implantation:Group 1:HDCB graft only;Group 2:periosteum-wrapped HDCB graft;Group 3:HDCB graft seeded with BM-MSCs and Group 4:periosteum-wrapped HDCB graft seeded with *** rabbits were sacrificed 12 weeks after surgery for gross observation,radiological assessment,histological analyses and biomechanical ***:New bone(NB)formation and bone healing were successfully achieved,both radiologically and histologically,on demineralized cancellous bone graft seeded with *** were improved when BM-MSCs were associated with ***:This study demonstrates that repair of bone defects in a rabbit model can be achieved through bone grafting using BM-MSCs,implanted on a demineralized cancellous bone *** formation of NB was optimized when combined with the preservation of periosteum at the site of injury.

关键词： Bone defects bone marrow bone tissue engineering mesenchymal stem cells periosteum

Prevalence and outcomes of neonates with severe COVID-19:An observational study at Children’s Hospital 1 in Ho Chi Minh City,Vietnam

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Asian Pacific Journal of Tropical Medicine 2024年第9期17卷 392-399,I0001页

作者： Phung Nguyen The Nguyen tran Thanh Thuc Nguyen Thanh Hung Ngo ngoc Quang Minh Dang Quoc Duy tran Minh Nhut Nguyen Hoang Dung tran Nguyen Ai Nuong Dinh Nguyen Cam Tu Department of Pediatrics University of Medicine and Pharmacy at Ho Chi Minh cityHo Chi Minh CityVietnam Children’s Hospital 1 Ho Chi Minh CityVietnam Pediatric Department School of MedicineVietnam National University Ho Chi Minh CityVietnam

Objective:To evaluate the impact of the severe COVID-19 pandemic on neonates and develop strategies to improve their ***:We conducted an observational cross-sectional study at Children's Hospital 1(CH1)from July 25,2021,to May 31,*** neonates who had fever or respiratory symptoms or were born from mothers with COVID-19 and had a positive RT-PCR SARS-CoV-2 result would be *** classified neonates with COVID-19 into 2 groups:mild/moderate and severe for *** between groups were analyzed using Fisher's exact test/Chi-square test for categorical variables and Student's t-test/Wilcoxon Rank Sum test for continuous ***:This study included 88 newborns who had positive RT-PCR SARS-CoV-2 *** severity COVID-19 rate among neonatal cases was found to be 13.6%(12/88),with a corresponding mortality rate of 1.1%(1/88).All severe cases showed lung abnormalities as evident on chest X-ray *** addition to respiratory symptoms,a higher incidence of gastrointestinal manifestations,such as vomiting and diarrhea,was observed in the severe group,indicating a compelling *** administration of anticoagulant and anti-inflammatory drugs in the study group resulted in a satisfactory outcome with no significant ***:The COVID-19 pandemic has had a substantial impact on the well-being of *** management of COVID-19 in this population presents significant challenges.

关键词： COVID-19 Neonate Anti-inflammatory Anticoagulant

EP Aquarii:A New Picture of the Circumstellar Envelope

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Research in Astronomy and Astrophysics 2024年第3期24卷 83-105页

作者： Pham T.Nhung Do T.Hoai Pierre Darriulat Pham Tuan-Anh Pham N.Diep Nguyen B.ngoc tran T.Thai Department of Astrophysics Vietnam National Space CenterVietnam Academy of Science and Technology18Hoang Quoc VietNghia DoCau GiayHa Noivietnam

New analyses of earlier ALMA observations of oxygen-rich AGB star EP Aquarii are presented,which complete a previously published analysis and offer a different interpretation of the morpho-kinematics of the circumstellar *** birth of the equatorial density enhancement(EDE)is shown to occur very close to the star where evidence for rotation has been *** to the star and where outflows have been observed:their interaction with the gas of the nascent EDE is seen to play an important role in the development of the wind and the evolution of its radial velocity from 8 to 10 km s^(-1) on the polar symmetry axis to~2 km s^(-1) at the *** implies complex morpho-kinematics:making reliable interpretations with reasonable confidence is *** particular,it questions an earlier interpretation implying the presence of a white dwarf companion orbiting the star at an angular distance of -0″4 from its *** proposes instead an interpretation in terms of a standard mass ejection associated with a shock wave leaving a void of emission in its *** Doppler velocity wings are seen to consist of two components,the upper velocity end of the global wind,reaching above±12 km s^(-1),and an effective line broadening,confined within 200 mas from the center of the star,reaching above±20 km s^(-1) and interpreted as caused by the pattern of shock waves resulting from the interaction between stellar pulsation and convective cell partition.

关键词： stars AGB and post-AGB-(stars) circumstellar matter-radio lines stars

Exploring the Interplay between Job Stress,Work Performance,and Attitudes toward Professional Psychological Help among Employees

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International Journal of Mental Health Promotion 2024年第7期26卷 531-545页

作者： Cong Minh Le Son Van Huynh Ky Luu Quynh-Nhi ngoc Ho Van Thi Le Nguyen Vinh-Long tran-Chi Center for Mental Health Research and Support University of Social Sciences and HumanitiesVietnam National University Ho Chi Minh CityHo Chi Minh City700000Vietnam Faculty of Psychology Ho Chi Minh City University of EducationHo Chi Minh City700000Vietnam Faculty of Tourism College of BusinessUniversity of Economics Ho Chi Minh CityHo Chi Minh City700000Vietnam Scientific Management Department Dong A UniversityDa Nang500000Vietnam

Objective:This study explores the interplay between job stress,job-related factors,work performance,and attitudes toward seeking professional psychological help among Vietnamese ***:A total of 374 employees in Vietnam were surveyed using random sampling and an online questionnaire from November 07 to November 28,*** data and self-reported from three scales:The New Job Stress Scale(NJSS),Work Performance(WP),and Attitudes Toward Seeking Professional Psychological Help(ATSPPH_SF)were ***:Significant variations were found across several variables,including forms of work,operating hours,education levels,monthly income,numbers of daily working hours,and the presence of a psychological counseling department within the *** analysis has highlighted direct relationships between key latent *** who were more open to seeking professional help tended to report higher levels of job *** negative relationship was found between job stress and attitudes toward seeking professional ***,work effort was positively associated with work *** analyses revealed the influence of co-worker support on role expectation conflict and work effort,role expectation conflict and work-life balance,as well as interactions between role expectation conflict and attitudes needed toward seeking professional *** analyses showed that work effort mediated relationships between openness to seeking professional help,co-worker support,work-life balance,role expectation conflict,and work *** toward seeking professional help also mediated relationships between work-life balance,job stress,and work ***:The study highlights the complex dynamics surrounding job stress,job-related factors,work performance,and attitudes toward seeking professional psychological help among Vietnamese *** highlights the importance of addressing help-seeking barriers,promoting work engagement

关键词： Stress co-worker support work-life balance role expectation conﬂict professional psychological help-seeking

Complex Network Analysis of the Robustness of the Hanoi, Vietnam Bus Network

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Journal of Systems Science & Complexity 2019年第5期32卷 1251-1263页

作者： tran vu Hieu CHEONG Siew Ann BUI ngoc Dung Faculty of Information Technology University of Transport and CommunicationsHanoiVietnam Division of Physics and Applied Physics School of Physical and Mathematical SciencesNanyang Technological University21 Nanyang Link637371Singapore Faculty of Information Technology University of Transport and CommunicationsHanoiVietnam.

Many complex networks exist to facilitate the transport of material or information. In this capacity, the authors are often concerned with the continued flow of material or information when a fraction of the links in the complex network is disrupted. In other words, the authors are interested in the robustness of the complex network. In this paper, the authors survey measures of robustness like the average path length, the average clustering coefficient, the global efficiency, the size of largest cluster and use these to analyze the robustness of the bus network in Hanoi, Vietnam. The authors find that the bus network is robust against random failure but sensitive to targeted attack, in agreement with its scale-free character. By examining sharp drops in the average path length within the largest cluster of the Hanoi bus network under successive targeted attack, the authors identify five nodes whose loss lead to the fragmentation of the network into five or six disconnected clusters. These isolated clusters represent geographically the Central, Western, Southern, and Northwestern districts of Hanoi. Special considerations must therefore be given to these five nodes when planners wish to expand the bus network, or make it more robust.

关键词： Complex network hanoi bus network random failure robustness targeted attack

Building the ARIMA Model for Forecasting the Production of Vietnam’s Coffee Export

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Journal of Applied Mathematics and Physics 2024年第4期12卷 1237-1246页

作者： Duy Quang Phung Quoc Thang Trinh Quang Truong Do Ngan Giang Nguyen Van Ha Nguyen Gia Khiem Ngo Thi Minh ngoc tran Faculty of Technology and Data Science Foreign Trade University Hanoi Vietnam School of Economics and International Business Foreign Trade University Hanoi Vietnam

Coffee is a significant industry, accounting for 3% of Vietnam’s GDP, with annual export turnover consistently exceeding USD 3 billion. Despite global economic challenges affecting purchasing power at various times, Vietnam’s coffee exports in December 2023 continued to surge, reaching the highest level in the past 9 months at 190,000 tons, a 59.3% increase compared to November 2023, but still a slight 3.5% decrease from the same period last year. The export turnover reached USD 538 million, a 51% increase from November 2023 and a 26.4% increase from the same period last year. Therefore, forecasting the coffee export volume holds significant importance for coffee producers nationwide. This research employs the Box-Jenkins method to construct an ARIMA model for forecasting Vietnam’s coffee export volume based on annual data published by the General Statistics Office. Results indicate that among the models considered, the ARIMA(1, 1, 2) model is the most suitable. The study also provides short-term forecasts for Vietnam’s coffee export volume. However, the current model is limited to forecasting and is not yet optimized, as the assumed linearity in the model is a simplification.

关键词： ARIMA Forecasting Coffee Export Volume Data Science

Kriging-based reliability analysis of the long-term stability of a deep driftconstructed in the Callovo-Oxfordian claystone

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Journal of Rock Mechanics and Geotechnical Engineering 2021年第5期13卷 1033-1046页

作者： ngoc-Tuyen tran Duc-Phi Do Dashnor Hoxha Minh-ngoc vu Gilles Armand Univ.Orléans Univ.ToursINSA CVLLaméEA 7494France Andra R&D Division92298Chatenay-MalabryFrance

Callovo-Oxfordian(COx)claystone has been considered as a potential host rock for geological radioactive waste disposal in France(Cigéo project).During the exploitation phase(100 years),the stability of drifts(***/alveoli)within the disposal is assured by the liner,which includes two layers:concrete arch segment and compressible *** latter exhibits a significant deformation capacity(about 50%)under low stress(<3 MPa).Although the response of these underground structures can be governed by complex thermo-hydro-mechanical coupling,the creep behavior of COx claystone has been considered as the main factor controlling the increase of stress state in the concrete liner and hence the long-term stability of ***,by focusing only on the purely mechanical behavior,this study aims at investigating the uncertainty effect of the COx claystone time-dependent properties on the stability of an alveolus of Cigéo during the exploitation *** describe the creep behavior of COx claystone,we use Lemaitre’s viscoplastic model with three parameters whose uncertainties are identified from laboratory creep *** the reliability analysis,an extension of a well-known Kriging metamodeling technique is proposed to assess the exceedance probability of acceptable stress in the concrete liner of the *** open-source code Code_Aster is chosen for the direct numerical evaluations of the performance *** Kriging-based reliability analysis elucidates the effect of the uncertainty of COx claystone on the long-term stability of the concrete ***,the role of the compressible material layer between the concrete liner and the host rock is also highlighted.

关键词： Reliability analysis Kriging metamodeling Time-dependent behavior Compressible material Callovo-Oxfordian(COx)claystone Long-term stability