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Postnatal feeding with high-fat diet induces obesity and precocious puberty in C57BL/6J mouse pups： a novel model of obesity and puberty

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Frontiers of Medicine 2017年第2期11卷 266-276页

作者： Rahim Ullah Yan Su Yi Shen Chunlu Li Xiaoqin Xu Jianwei Zhang Ke Huang naveed rauf Yang He Jingjing Cheng Huaping Qin Yu-Dong Zhou Junfen Fu Department of Endocrinology Children's Hospital Zhejiang University School of Medicine Hangzhou 310051 China Department of Neurobiology Institute of Neuroscience and the Collaborative Innovation Center for Brain Science Key Laboratory of Medical Neurobiology of the Ministry of Health of China Zhejiang University School of Medicine Hangzhou 310058 China

Childhood obesity and obesity-related metabolic complications are induced by a high-fat postnatal diet. The lack of a suitable animal model, however, remains a considerable challenge in obesity studies. In the current study, we provided high-fat diet （HFD） to dams during lactation and to pups after weaning. We also developed a novel model of C57BL/6J mouse pups with HFD-induced postnatal obesity. Results showed that feeding with HFD induces fat deposition and obesity in pups. Furthermore, HFD more potently increased the body weight （BW） of male than female pups. HFD-fed female pups were obese, underwent precocious puberty, and showed increased kisspeptin expression in the hypothalamus. However, parental obesity and precocious puberty exerted no synergistic effects on the HFD-induced postnatal weight gain and puberty onset of the pups. Interestingly, some HFD-fed litters with normal BW also exhibited precocious puberty. This finding suggested that diet composition but not BW triggers puberty onset. Our model suggests good construction validity of obesity and precocious puberty. Furthermore, our model can also be used to explore the mutual interactions between diet-induced postnatal childhood obesity and puberty.

关键词： postnatal HFD feeding obesity kisspeptin HPG axis precocious puberty

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Alternative Strategy for Development of Dielectric Calcium Copper Titanate‑Based Electrolytes for Low‑Temperature Solid Oxide Fuel Cells

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Nano-Micro Letters 2025年第1期17卷 310-332页

作者： Sajid rauf Muhammad Bilal Hanif Zuhra Tayyab Matej Veis MAKYousaf Shah naveed Mushtaq Dmitry Medvedev Yibin Tian Chen Xia Martin Motola Bin Zhu College of Mechatronics and Control Engineering Shenzhen UniversityShenzhen 518060People’s Republic of China Department of Inorganic Chemistry Faculty of Natural SciencesComenius University BratislavaIlkovicova684215 BratislavaSlovakia Energy Storage Joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing 210096People’s Republic of China Hydrogen Energy Laboratory Ural Federal University620002 EkaterinburgRussia Laboratory of Electrochemical Devices Based on Solid Oxide Proton Electrolytes Institute of High Temperature Electrochemistry620066 EkaterinburgRussia School of Microelectronics Hubei UniversityWuhan 430062People’s Republic of China

The development of low-temperature solid oxide fuel cells(LT-SOFCs)is of significant importance for realizing the widespread application of *** has stimulated a substantial materials research effort in developing high oxide-ion conductivity in the electrolyte layer of *** this context,for the first time,a dielectric material,CaCu_(3)Ti_(4)O_(12)(CCTO)is designed for LT-SOFCs electrolyte application in this *** individual CCTO and its heterostructure materials with a p-type Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ)(NCAL)semiconductor are evaluated as alternative electrolytes in LT-SOFC at 450–550℃.The single cell with the individual CCTO electrolyte exhibits a power output of approximately 263 mW cm^(-2) and an open-circuit voltage(OCV)of 0.95 V at 550℃,while the cell with the CCTO–NCAL heterostructure electrolyte capably delivers an improved power output of approximately 605 mW cm^(-2) along with a higher OCV over 1.0 V,which indicates the introduction of high hole-conducting NCAL into the CCTO could enhance the cell performance rather than inducing any potential short-circuiting *** is found that these promising outcomes are due to the interplay of the dielectric material,its structure,and overall properties that led to improve electrochemical mechanism in CCTO–***,density functional theory calculations provide the detailed information about the electronic and structural properties of the CCTO and NCAL and their heterostructure CCTO–*** study thus provides a new approach for developing new advanced electrolytes for LT-SOFCs.

关键词： LT-SOFCs Dielectric CaCu_(3)Ti_(4)O_(12) Semiconductor Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ) Ionic conductivity Heterostructure electrolyte

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Antioxidant and lipoxygenase inhibitory properties of a novel flavonoid from Pistacia chinensis Bunge and its molecular docking analysis

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Traditional Medicine Research 2025年第2期10卷 30-36页

作者： Abdur rauf Zuneera Akram naveed Muhammad Najla AlMasoud Taghrid Saad Alomar Saima Naz Abdul Wadood Chandni Hayat Marcello Iriti Department of Chemistry University of SwabiAmbar 23561Pakistan Department of Pharmacology Faculty of Pharmaceutical SciencesBaqai Medical UniversityKarachi 74600Pakistan Department of Pharmacy Abdul Wali Khan University MardanMardan 23200Pakistan Department of Chemistry College of SciencePrincess Nourah bint Abdulrahman UniversityRiyadh 11671Saudi Arabia Department of Biotechnology BKUC-Bacha Khan University CharsaddaCharsadda 24620Pakistan Department of Biochemistry Abdul Wali Khan University MardanMardan 23200Pakistan Department of Biomedical Surgical and Dental SciencesUniversity of MilanMilan 20129Italy National Interuniversity Consortium of Materials Science and Technology(INSTM) Firenze 50121Italy

Background:Pistacia chinensis Bunge has been traditionally used to manage various conditions,including asthma,pain,inflammation,hepatoprotection,and *** study was conducted to investigate the antioxidant and anti-lipoxygenase(LOX)properties of the isolated compound 2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4H-chromen-4-one from Pistacia ***:LOX assay and antioxidant activity using 2,2-diphenyl-1-picrylhydrazyl(DPPH)assay were *** docking studies were conducted using a molecular operating ***:The LOX assay revealed significant inhibitory effects at 0.2µM concentration,with an IC50 value of 37.80µ*** antioxidant effect demonstrated dose-dependency across 5 to 100µg/mL concentrations,reaching 93.09%at 100µg/mL,comparable to ascorbic acid’s 95.43%*** docking studies highlighted strong interactions with the lipoxygenase enzyme,presenting an excellent docking score of-10.98 kcal/***:These findings provide valuable insights into Pistacia chinensis’chemical components and biological effects,reinforcing its traditional medicinal applications.

关键词： Pistacia chinensis Bunge antioxidant DPPH assay antilipoxygenase docking analysis

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Proton transport controlled at surface layer of CeO_(2) by gradient-doping with a built-in-field effect

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Journal of Rare Earths 2023年第12期41卷 2025-2032,I0008页

作者： Yuzheng Lu naveed Mushtaq M.A.K Yousaf Shah Sajid rauf Chen Xia Bin Zhu School of Electronic Engineering Nanjing Xiaozhuang UniversityNanjing21171China School of Physics Electronics and Intelligent ManufacturingHuaihua UniversityHuaihua418008China Jiangsu Provincial Key Laboratory of Solar Energy Science and Technology/Energy Storage Joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing210096China College of Electronics and Information Engineering Shenzhen UniversityShenzhen58000China Faculty of Physics and Electronic Science Hubei UniversityWuhan430062China

Ceramic fuel cells hold an important position for the sustainable energy future using renewable energy sources with high *** design and synthesis of active materials,interface engineering and having capability of low operating temperature is considered as an important factor to further increase the power output and stability of ceramic fuel cell devices.A novel methodology has vital importance to develop new functionalities of existing materials by introducing new different *** built-in electric field(BIEF) is one of the most recently used approaches to improve charge transfer and ionic conductivity of solid oxide ***,we demonstrate gradient doping strategy in CeO_(2)-δstructure to produce BIEF effect and to modulate the proton transport effectively at the surface layer rather than bulk *** inclusions of La and Sr metal ions at the surface and Co-metal ions into bulk-layer of CeO_(2)form the gradiently doped *** gradient doping into CeO_(2)highly improves the proton transport properties through the surface layer by modifying the energy ***,unbalanced charge distribution due to gradient doping produces built-in electric-field to provide extra driving force for protons transport through surface *** acquired gradiently doped fluorite structure exhibits remarkable proton conductivity of>0.2 S/cm,as a result ceramic fuel cell shows power output of>1000 mW/cm2while operating at 500℃.This unique work highlights the critical role of gradiently doped electrolyte in electrochemical conversion energy devices and offers new understanding and practices for sustainable energy future.

关键词： La_(0.20)Sr_(0.05)Ce_(0.65)Co_(0.1)0_(2-δ)(LSCC) Gradient doping Fast protonic transport High grain boundary conduction Built-in electric field Rare earths

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Novel LaFe_(2)O_(4)spinel structure with a large oxygen reduction response towards protonic ceramic fuel cell cathode

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Journal of Rare Earths 2023年第3期41卷 413-421,I0004页

作者： Jinping Wang Yuzheng Lu naveed Mushtaq M.A.K Yousaf Shah Sajid rauf Peter D.Lund Muhammad Imran Asghar School of Energy and Power Engineering Nanjing Institute of TechnologyNanjing 211167China School of Electronic Engineering Nanjing Xiao Zhuang UniversityNanjing 211171China Jiangsu Provincial Key Laboratory of Solar Energy Science and Technology/Energy Storage Joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing 210096China College of Electronics and Information Engineering Shenzhen UniversityShenzhen 518000China New Energy Technologies Group Department of Applied PhysicsAalto University School of ScienceP.O.Box.15100FI00076AaltoEspooFinland Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials Faculty of Physics and Electronic ScienceHubei UniversityWuhan 430062China

Highly active and stable electrocatalysts are mandatory for developing high-performance and longlasting fuel *** current study demonstrates a high oxygen reduction reaction(ORR)electrocatalytic activity of a novel spinel-structured LaFe_(2)O_(4)via a self-doping *** LaFe_(2)O_(4)demonstrates excellent ORR activity in a protonic ceramic fuel cell(PCFC)at temperature range of 350-500℃.The high ORR activity of LaFe_(2)O_(4)is mainly attributed to the facile release of oxide and proton ions,and improved synergistic incorporation abilities associated with interplay of multivalent Fe^(3+)/Fe^(2+)and La^(3+)*** LaFe_(2)O_(4)as cathode over proton conducting BaZr_(0.4)Ce_(0.4)Y_(0.2)O_(3)(BZCY)electrolyte,the fuel cell has delivered a high-power density of 806 mW/cm^(2)operating at 500℃.Different spectroscopic and calculations methods such as UV-visible,Raman,X-ray photoelectron spectroscopy and density functional theory(DFT)calculations were performed to screen the potential application of LaFe_(2)O_(4)as *** study would help in developing functional cobalt-free ORR electrocatalysts for low temperature-PCFCs(LT-PCFCs)and solid oxide fuel cells(SOFCs)applications.

关键词： LaFe_(2)O_(4)cathode Facile Fe^(3+/2+)ions resale Oxygen reductionreaction(ORR) Excellent electrocatalyst Protonic ceramicfuel cell(PCFC) Rare earths

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Highly Active Interfacial Sites in SFT-SnO_(2) Heterojunction Electrolyte for Enhanced Fuel Cell Performance via Engineered Energy Bands:Envisioned Theoretically and Experimentally

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Energy & Environmental Materials 2024年第3期7卷 384-397页

作者： Sajid rauf Muhammad Bilal Hanif Faiz Wali Zuhra Tayyab Bin Zhu naveed Mushtaq Yatao Yang Kashif Khan Peter D.Lund Martin Motola Wei Xu College of Electronic and Information Engineering and State Key Laboratory of Radio frequency Heterogeneous Integration Shenzhen UniversityShenzhen 518000China Department of Inorganic Chemistry Faculty of Natural SciencesComenius University in BratislavaIlkovicova 684215BratislavaSlovakia College of Physics and Optoelectronic Engineering Shenzhen UniversityShenzhen 518060China School of Energy and Environment Southeast UniversityNo.2 Si Pai LouNanjing 210096China School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731China New Energy Technologies Group Department of Applied PhysicsAalto University School of ScienceP.O.Box 15100Fl-00076AaltoEspoo Finland

Extending the ionic conductivity is the pre-requisite of electrolytes in fuel cell technology for high-electrochemical *** this regard,the introduction of semiconductor-oxide materials and the approach of heterostructure formation by modulating energy bands to enhance ionic conduction acting as an electrolyte in fuel ***(n-type;SnO_(2))plays a key role by introducing into p-type SrFe_(0.2)Ti_(0.8)O_(3-δ)(SFT)semiconductor perovskite materials to construct p-n heterojunction for high ionic ***,two different composites of SFT and SnO_(2)are constructed by gluing p-and n-type SFT-SnO_(2),where the optimal composition of SFT-SnO_(2)(6∶4)heterostructure electrolyte-based fuel cell achieved excellent ionic conductivity 0.24 S cm^(-1)with power-output of 1004 mW cm^(-2)and high OCV 1.12 V at a low operational temperature of 500℃.The high power-output and significant ionic conductivity with durable operation of 54 h are accredited to SFT-SnO_(2)heterojunction formation including interfacial conduction assisted by a built-in electric field in fuel cell ***,the fuel conversion efficiency and considerable Faradaic efficiency reveal the compatibility of SFT-SnO_(2)heterostructure electrolyte and ruled-out short-circuiting ***,the first principle calculation provides sufficient information on structure optimization and energy-band structure modulation of SFT-SnO_(2).This strategy will provide new insight into semiconductor-based fuel cell technology to design novel electrolytes.

关键词： high ionic conductivity interfacial conduction modulated energy band structure p-n heterojunction semiconductors

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In vitro biological screening of the stem of Desmodium elegans

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Asian Pacific Journal of Tropical Biomedicine 2013年第9期3卷 711-715页

作者： Arshad Khan Rabia Usman Ming-Liang Wang Abdur rauf naveed Muhammad Akhatar Aman Taha Hussein Musa Tahir School of Chemistry and Chemical Engineering Southeast University Institute of Chemical Sciences University of Peshawar Department of Pharmacy Hazara University School of Public Health Southeast University Nanjing

Objective:To explore the medicinal importance of the stem of Desmodium elegans,methanolic extract,and its different solvent fractions were evaluated for brine shrimp lethality,insecticidal and phytotoxicity,antifungal,and antibacterial ***:The methanolic extract and its solvent fractions were tested for cytotoxic,phytotoxic,insecticidal,antifungal,and antibacterial effects using our previous published ***:The methanolic,DCM,ethyl acetate and n-butanol fractions exhibited insecticidal effect against Callosobruchus analis and Rhyzopertha *** methanolic extract,n-hexane,DCM ethyl acetate and n-butanol showed 75,85,85,65 and 5%phytotoxicity at the tested concentration of 500μg/*** solvent fractions(DCM and ethyl acetate)were effective against ***(10%and 20%,inhibition respectively).All the tested samples were devoid of cytotoxic and antibacterial ***:It was concluded diat diis plant can be practiced for control of weeds and insects.

关键词： Leguminosae Desmodium elegans Brine shrimp cytotoxicity Phytotoxic Insectioidal and antimicrobial activities

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Effect of Plant Derived Smoke on Germination and Post Germination Expression of Wheat (Triticum aestivum L.)

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American Journal of Plant Sciences 2016年第6期7卷 806-813页

作者： Muhammad Iqbal Saira Asif Noshin Ilyas naveed Iqbal Raja Mubashir Hussain Sumera Shabir Muhammad Nasim Ashraf Faz Abdul rauf Department of Botany PMAS-Arid Agriculture University Rawalpindi Pakistan Department of Botany Government College University Faisalabad Pakistan Department of Biology AIOU Islamabad Pakistan

Smoke produced from burning of plant material elicits a striking increase in seed germination in various plant species. In present work, effect of plant derived smoke exposure on wheat (Triticum aestivum L.) seeds germination and post germination response has been studied in laboratory. Plant derived smoke was generated by burning of plant material (leaf, straws etc.) in a special designed furnace. Non-imbibed and imbibed seeds of wheat were exposed to plant derived smoke for 1 hr time duration. Best results were observed in non-imbibed seeds treated with plant derived smoke while imbibed seeds showed poor response to germination percentage, germination index, seedling vigor index and root shoot length. It has been proved from present study that plant derived smoke has stimulatory effect on germination & post germination response of non-imbibed seeds while it may cause inhibitory effect in imbibed seeds of wheat.

关键词： Plant Derived Smoke Wheat Seed Germination Seedling Vigor Root Shoot Length

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