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mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating

Science china Earth sciences 2005年第2期48卷 192-198页

作者： WANG Denghong, QU Wenjun, LI Zhiwei, YIN Hanlong4 & CHEN Yuchuan Institute of mineral Resources, chinese Academy of geological {3., beijing 10003., china national center of rock and mineral analysis, chinese Academy of geological {3., beijing 10003., china Resource Assessment center of Yunnan, Kunming 650011, china Institute of Geology and Geophysics, chinese Academy of {3., beijing 100101, china chinese Academy of geological {3., beijing 10003., china Institute of mineral Resources Chinese Academy of Geological Sciences Beijing China national center of rock and mineral analysis Chinese Academy of Geological Sciences Beijing China Resource Assessment center of Yunnan Kunming China Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China chinese Academy of geological sciences Beijing China

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 3..9±1.1 Ma for the Machangqing deposit and 3..4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (3..4 Ma, 3..9 Ma, 3..2 Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.

关键词： Re-Os isotopic dating, porphyry Cu deposits, Cenozoic, mineralization episode.

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Re-Os age for molybdenite from the Gangdese porphyry copper belt on Tibetan plateau: Implication for geody- namic setting and duration of the Cu mineralization

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Science china Earth sciences 2004年第3期47卷 221-231页

作者： HOU Zengqian1, QU Xiaoming1, WANG Shuxian2, DU Andao2, GAO Yongfeng3.& HUANG Wei4 1. Institute of mineral Resources, chinese Academy of geological {3., beijing 10003., china 2. national center of Geoanalysis, chinese Academy of geological {3., beijing 10003., china 3. Shijiazhuang College of Economy, Shijiazhuang 056000, china 4. Xizang Bureau of Geology and mineral Resources, Lhasa 850000, china Institute of mineral Resources Chinese Academy of Geological Sci. Beijing 100037 China national center of Geoanalysis Chinese Academy of Geological Sci. Beijing 100037 China Shijiazhuang College of Economy Shijiazhuang 056000 China Xizang Bureau of Geol./mineral Rsrc. Lhasa 850000 China

The Gangdese porphyry copper belt consists of one large and five middle-small deposits in addition to dozens of ore-bearing porphyry bodies. The belt trends 3.0 km long along the EW-striking Gangdese batholith, and locally occurs as a string of beads extending about 50 km within the SN-trending rifting zones (grabens) on the Tibetan plateau. Monzonitic granite- porphyry and quartz monzonitic porphyry, as dominant host rocks, are shoshonitic and potassic calc-alkaline. Available dating data indicate that the ages of the shallow-level emplacement for these porphyries vary from 10 Ma to 18 Ma, which are identical to that of associated potassic calc-alkaline volcanic rocks (10—15 Ma) and mafic dykes (13.18 Ma). The timing and duration of Cu mineralization events are constrained by Re-Os ages for molybdenites from three porphyry copper deposits in the Gangdese porphyry copper belt. Five molybdenite samples from the Nanmu deposit yielded an 187Re-187Os isochron with a highly pre-cise age of (14.76?.22) Ma; six molybdenites from the Chongjiang deposit gave an isochron age of (14.04?.16) Ma. Re-Os model ages for two molybdenite samples from Lakang抏 deposit vary from 13.5 Ma to 13.6 Ma, which are basically identical to isochron ages mentioned above. All the thirteen samples from these three deposits yielded a linear array in the isochron diagram with a higher correlation coefficient of 0.99719 and an isochron age of (14.3.?.22) Ma (1s error), suggesting an coeval event of the Cu mineralization and a shared source of ore materials for the Gangdese porphyry copper belt. Compared with the longer-lived felsic magmatic-hydrothermal system, the Cu mineralization is a relatively short event with duration of about 0.5 Ma, and usu-ally occurs in the later-stage of the complicate magmatic system. The emplacement age of the Gangdese porphyries indicates that they intruded after the rapid rising of the Gangdese Mountains at 21—23.Ma, and formed in a post-collision crustal ex-tension env

关键词： porphyry copper deposit, Re-Os age, Gangdese, Tibetan plateau.

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SHRIMP U-Pb dating and Hf isotopic analyses of Middle Ordovician meta-cumulate gabbro in central Qiangtang, northern Tibetan Plateau

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Science china Earth sciences 2010年第5期53卷 657-664页

作者： ZHAI QingGuo1 WANG Jun1, LI Cai2 & SU Li3.1 Institute of Geology, chinese Academy of geological sciences,{3., china 2 College of Earth sciences, Jilin University, Changchun 13.061, china 3.The geological Laboratory center and State Key Laboratory of geological Processes and mineral Resources, china University of Geo- sciences, {13. 100083. china Institute of Geology Chinese Academy of Geological Sciences Beijing China College of Earth sciences Jilin University Changchun China The geological Laboratory center and State Key Laboratory of geological Processes and {3. Resources China University of Geosciences Beijing China

Metabasites consisting of metamorphic ultra-mafic rocks, cumulate gabbro, gabbro (diabase), basalt, and plagiogranite are exposed at the Taoxinghu area in central Qiangtang, northern Tibetan Plateau. Zircon SHRIMP U-Pb dating for the cumulate gabbro yields a weighted mean age of 467±4 Ma, which is the oldest and most reliable magmatic age in this area. Zircon 176Hf/177Hf ratios range from 0.282615 to 0.282657, with εHf(t) values of 5.02±0.28, indicating that the cumulate gabbro was mainly derived from the depleted mantle. In addition, geochemical data of metabasites suggest that they have similar characteristics to those in the mid-ocean ridge basalts (MORB). The Taoxinghu metabasites may represent the fragment of Early Paleozoic ophiolite in the "Central Uplift" of the Qiangtang, northern Tibetan Plateau.

关键词： Qiangtang cumulate gabbro SHRIMP dating Hf isotope

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Re-Os(ICP-MS)dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

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Science china Earth sciences 2005年第10期48卷 1672-1677页

作者： YANG Gang1,2, DU Andao1, LU Jiren3. QU Wenjun1 & CHEN Jiangfeng2 1. national Research center of Geoanalysis,{3., china 2. Laboratory for Earth Material Cycling, School of Earth and Space sciences, University of Science and Technology of china, Hefei 23.026, china 3. Institute of mineral Resource, chinese Academy of geological sciences,{3., china national Research center of Geoanalysis University of Science and Technology of china chinese Academy of geological sciences

Massive sulfide ore from the Jinchuan Ni-Cu-PGE deposit was dated by Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measurement. An isochron giving an age of 83. ± 3. Ma, initial 187Os/188Os ratio of 0.279 ± 0.018 (MSWD = 1.7) and γOs = 13. ± 15 is obtained. The Re-Os age obtained agrees, within analytical uncertainties, with previous SHRIMP zircon U-Pb age of 827 ± 8 Ma (n=5, MSWD = 4.3.. The result suggests that the deposit was formed at Neoproterozoic and that the formation of the Jinchuan Ni-Cu-PGE sulfide deposit may be closely related to the plume activity, which were attributed to the breakup of the Rodinia supercontinent. The high γOs of the massive ores sug-gests that crustal material was involved in the formation of the Jinchuan deposit, however, the quantity of the added crustal material is less than 10%.

关键词： Jinchuan Ni-Cu-PGE deposit, Re-Os dating, ICP-MS.

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Petrogenesis and dating of the Kangding complex,Sichuan Province

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Science china Earth sciences 2005年第5期48卷 622-634页

作者： CHEN Yuelong 1 , LUO Zhaohua 1 , ZHAO Junxiang, LI Zhihong, ZHANG Hongfei & SONG Biao 3.1. Faculty of Earth sciences and Natural Resources, china University of Geosciences, {3. 100083. china 2. Faculty of Earth sciences, china University of Geosciences, Wuhan 43.074, china 3. {3. SHRIMP center, Institute of Geology, chinese Academy of geological sciences, beijing 10003., china Faculty of Earth sciences and Natural Resources China University of Geosciences Beijing China Faculty of Earth sciences China University of Geosciences Wuhan China beijing SHRIMP center Institute of Geology Chinese Academy of Geological Sciences Beijing China

An analysis of major and trace element geochemistry and SHRIMP U-Pb zircon dating of mafic, intermediate, and felsic rocks from the Mianning metamorphic complex of Si- chuan Province was conducted. One of our conclusions is that a majority of the zircons crystal- lized between 721 and 773.Ma in a magmatic regime. The complexes contain early to late Pa- leo-proterozoic relict zircons from ancient continental crust. The oldest age, 2468 Ma, may rep- resent the basement of the Yangtze block. Overgrowth zircon rims and palingenetic zircons have been observed and dated, and are believed to have formed after crystallization, during Paleozoic and Mesozoic metamorphic-anatexis. We also conclude that depletion of Nb, Ta, HREE, in a spider-diagram normalized to primitive mantle and calc-alkaline association, implies that they formed in island-arc or under-plating settings.

关键词： Kangding complex, zircons, SHRIMP, tectonic setting.

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Isotopic compositions of small shelly fossil Anabarites from Lower Cambrian in Yangtze Platform of South china: Implications for palaeocean temperature

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Progress in Natural Science:Materials International 2007年第10期17卷 1185-1191页

作者： Chen Yongquan1,2, Jiang Shaoyong1, Ling Hongfei1, Yang Jinghong1 and Wan Defan3.1. State Key Laboatory for mineral Deposits Research and center for Marine Geochemistry Research, Department of Earth sciences, Nanjing University, Nanjing 210093.{3. 2. Tarim Oilfield Company Exploration & Development Research Institute, Ku’erle 841000,{3. 3. Institute of mineral Resources, chinese Academy of geological sciences, beijing 10003.,{3.) State Key Laboratory for mineral Deposits Research Department of Earth Sciences Nanjing University Nanjing 210093 China Exploration and Development Research Institute Tarim Oilfield Company Ku'erle 841000 China Institute of mineral Resources Chinese Academy of Geological Sciences Beijing 100037 China

Anabarites belong to small shelly fossils (SSF), which occur widely in the Lower Cambrian strata of Yangtze Platform in South china. They are phosphate shell in composition and represent the earliest stage of the Cambrian bioradiation of Bilateria, the so-called "Cambrian Explosion". In this study, we attempted to separate Anabarites fossils from Lower Cambrian dolostones, and we obtained samples of both the fossils (SSF) and the granular phosphates (GP). Isotopic analyses were performed on samples of SSF, GP, and matrix dolostone (DH-23.. The results showed that the δ3.Si values of the quartz filling in fossils celoms, and the siliceous materials in granular phosphates are -0.6‰ and -0.7‰, which is different from normal sedimentary siliceous rocks from the Lower Cambrian strata (0—0.7‰) as reported by Li et al., but is consistent with the data for siliceous rocks and cherts of submarine hydrothermal origin. It is likely that a later hydrothermal replacement could have taken place in the SSF-bearing sedimentary rocks. The oxygen isotope values of the phosphate of SSF and GP are 16.8‰ and 17.0‰, respectively. These are significantly higher than the Neoproterozoic phosphate ores (10.9‰—13.9‰) as reported by Ling et al., hence, late diagenesis and hydrothermal replacement may not have caused a significant change in the oxygen isotope compositions of the small shelly fossils, and the calculated temperatures (25.4—26.3.) for palaeo-seawater using a SSF phosphate oxygen isotope thermometer are therefore considered here as the upper limit of seawater temperature in the Early Cambrian ocean of the Yangtze Platform.

关键词： Anabarites oxygen isotope silicon isotope paleo-temperature.

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U-Pb dating of zircon from the bed parallel anatectic granitic intrusion in the Baoban group in Hainan Island and the tectonic implication

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Science china Earth sciences 2005年第12期48卷 2092-2103页

作者： DING Shijiang1, HU Jianmin2, SONG Biao3.4, CHEN Mulun1, XIE Shengzhou1 & FAN Yuan1 1. geological Surveying Institute of Hainan, Haikou 570206, china 2. Institute of Geomechanics, chinese Academy of geological sciences, beijing 100081, china 3. beijing center of SHRIMP, beijing 10003., china 4. Institute of Geology, chinese Academy of geological sciences, beijing 10003., china geological Surveying Institute of Hainan Haikou China Institute of Geomechanics Chinese Academy of Geological Sciences Beijing China beijing center of SHRIMP Beijing China Institute of Geology Chinese Academy of Geological Sciences Beijing China

The petrological and geochemical features of the bed parallel granitic intrusion in the Pre-Cambrian Baoban group in Hainan Island attest to the anatexis origin of the granites. U-Pb dating analyses of zircons from the anatectic granite and the biotite two-feldspar gneiss in the Baoban group, using SHRIMP II in the beijing Ion-probe center, acquire 206Pb/23.U ages of 3.8±3.5 Ma (of granite, 95% confidence level, MSDW=1.23. and 3.2.9±6.1 Ma (of gneiss, 95% confidence level, MSDW = 2.04) respectively. The two late Devonian ages indicate consistently a tectonic- thermal event experienced in Hainan Island, and are the first discovered record of the Devonian geological process in the district. This event possibly resulted from the deep ther-mal-dynamic process when the Gondwana continent began to break up in the Devonian period.

关键词： Hainan Island, Devonian period, anatectic granite, zircon SHRIMP U-Pb dating.

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Carbon and Oxygen Stable Isotope Values and Microfossils at 41.4-4.5ka BP in Tai Co,Tibet,china,and Their Paleoclimatic Significance

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Acta Geologica Sinica(English Edition) 2011年第5期85卷 1036-1050+1052-1056+1051页

作者： ZHENG Mianping~(1,2,*),LIU Junying~(1,3.,MA Zhibang~(1,4),WANG Hailei~(1,2) and MA Nina~(1,2) 1 MLR Key Laboratory of Saline Lake Resources and Environment,Institute of mineral Resources,CAGS, beijing 10003.,china 2 Research and Development {3. for Saline Lakes and Epithermal Deposits,chinese Academy of geological sciences,beijing 10003.,china 3.Institute of Geology,chinese Academy of geological sciences,beijing 10003.,china 4 Key Laboratory of Cenozoic Geology and Environment,chinese Academy of sciences,beijing 100029, china MLR Key Laboratory of Saline Lake Resources and Environment Institute of Mineral Resources CAGS Beijing 100037 China Research and Development center for Saline Lakes and Epithermal Deposits Chinese Academy of Geological Sciences Beijing 100037 China Institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China Key Laboratory of Cenozoic Geology and Environment Chinese Academy of Sciences Beijing 100029 China

Two sedimentary sections were measured at Tai Co(Co means lake in Tibetan) in western Tibet,*** two sections are almost all composed of clay carbonate beds except in their lower parts where there are carbonized plants at>10 cm depths and dark-colored carbonate clay and clay at 50-70 cm depths,yielding abundant gastropods,ostracods,and *** carbon and oxygen stable isotope values of carbonate,ostracods,and charophytes and ecological features of microfossil communities indicate the following climatic change in the area from 41.4 to 4.5 ka BP:at 41.4-26.2 ka BP,the climate was relatively wet;at 26.2-25.5 ka BP,it was slightly warm-dry;at 25.5-22.5 ka BP,it was warm-wet;at 22.5-21.0 ka BP,it was slightly cold-wet;at 20.5-17.5 ka BP,it became cold abruptly and slightly wet,implying the climate of the last glacial maximum;at 17.5-16.0 ka BP,it was slightly cold-dry;at 16.0-11.8 ka BP,it was slightly warm-wet;at 11.8-10.4 ka BP,it was relatively cold-dry, roughly equivalent to the climate of the Younger Dryas,and at 10.4 ka BP,the temperatures began to rise again;at 10.4-9.4 ka BP,it was slightly warm-wet;at 9.4-8.5 ka BP,there occurred short warm-wet oscillations;at 8.5-7.9 ka BP,it was slightly dry-cold,representing a strong temperature-lowering and drying event in the postglacial stage;at 7.8-6.3.ka BP,it was slightly warm-wet;at 6.3.4.5 ka BP,the climate tended to be cold-dry.4.5 ka BP recorded the maximum aridity since the late part of the late Pleistocene.

关键词： sedimentary environment index paleoclimatic changes late Pleistocene-Holocene(41.4-4.5 ka BP) Tai Co Tibet

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Lithosphere types in North china:Evidence from geology and geophysics

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Science china Earth sciences 2005年第11期48卷 1809-1827页

作者： QIU Ruizhao1,2, DENG Jinfu3. ZHOU Su3. LI Jinfa4, XIAO Qinghui1,5, WU Zongxu6 & LIU Cui3.1. Institute of Geology, chinese Academy of geological sciences,{3., china 2. Development and Research center, china geological Survey,{3., china 3. china University of Geosciences, beijing 100083. china 4. china University of Geosciences, Wuhan 43.074, china 5. Information center of Ministry of Land and Resources, beijing 100812, china 6. Institute of Geology, State Seismological Bureau, beijing 100029, china Institute of Geology Chinese Academy of Geological Sciences Beijing China Development and Research center China Geological Survey Beijing China china University of Geosciences Beijing China china University of Geosciences Wuhan China Information center of Ministry of Land and Resources Beijing China Institute of Geology State Seismological Bureau Beijing China

On the basis of the characteristics of geology and geophysics in North china, three types of lithosphere, namely, the cratonic, the orogenic and the rift lithospheres can be classified. In terms of petrological method (based on the information from Precambrian rock assemblages, igneous activities, deep-seated enclaves, etc.) and the relationship between seismic velocity and rock compositions, the crust-mantle petrological and chemical structure models can be set up. Researching results indicate that the geology and geophysics of North china platform bears the similar characteristics in comparison with those of the global typical cratons. The Eerduosi(Ordos) block located in the west of the North china Platform is a remnant of cratonic lithosphere after the North china platform had undergone “activation” in Mesozoic and “reconstruction” in Cenozoic times. The continental crust consists mainly of TTG rock assemblage while the subcontinental lithosphere mantle mainly consists of strongly depleted harzburgite. The craton was finally formed in late Archaean and early Proterozoic, and has been kept in stability up to present; its crustal-mantle petrological structures of lithosphere can be set up as a reference for the study of North china craton and even Sino-Korean craton. In the Mesozoic period, the middle and east areas of North china platform were activated in the Yanshanian orogenic process, the continental crust was reformed by material and heat-transfer of convective mantle and the original crustal TTG component was reconstructed to be granitic crust, and the subcontinental lithosphere man- tle was replaced by the Yanshanian harzburgite-lherzolite. The Yanshan-Taihang Mountains were the remnants of orogenic lithosphere after the rifting in eastern North china in Cenozoic. The present thickness of continental crust and lithosphere in the Yanshan-Taihang Mountains is not equal to their thickness during the Yanshanian orogenic movement because they had undergone the

关键词： lithospheric types,evidence of geology and geophysics,crust-mantle petrological structure,deep process

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A special intermediate-low temperature PGE-As-Co mineralization

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chinese Science Bulletin 1999年第S2期44卷 42-44页

作者： WANG Jingbin, WANG Yuwang and WANG Lijuan beijing Institute of Geology for mineral Resources, china {3. Nonferrous Metal Industry Corporation, beijing 100012 china Research center of mineral Resources Exploration, chinese Academy of sciences, beijing 100101, china

THIS paper introduces a new type of platinum-group elements (PGE) mineralization formed under a special condition of intermediate to low temperature, i. e. Huanggang PGE-As-Co deposit related to cryptoex-plosive hornblendite, Inner Mongolia, of which the proven reserves of arsenic reached small size. 1 Geology of mineral district Huanggang PGE-As-Co deposit, located at the margin of Huanggang Mesozoic volcanic basin in thesouthern part of Da Hinggan Range, was controlled by both Huanggang-Ganzhuermiao deep fracture andvolcanic apparatus. The volcanic apparatus in a protruding cupola land-form is about 0.25 km^2. It wasfilled with rhyolitic volcanic breccia, brecciated tuff, subvolcanic dacite porphyry and brecciated lava ofvolcanic neck facies. The host hornblendite, of which Rb-Sr isochron age (bulk rock) is (90.66 ±14.44) Ma, intruded into the apparatus in the form of irregular dike (figure 1).

关键词： intermediate-low temperature PGE-As-Co mineralization Inner Mongolia.

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