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Re-Os age for molybdenite from the Gangdese porphyry copper belt on Tibetan plateau: Implication for geody- namic setting and duration of the Cu mineralization

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Science china Earth Sciences 2004年第3期47卷 221-231页

作者： HOU Zengqian1, QU Xiaoming1, WANG Shuxian2. DU Andao2. GAO Yongfeng3.& HUANG Wei4 1. Institute of mineral Resources, {3. Academy of {2. Sciences, Beijing 10003., china 2. national center of Geoanalysis, {3. Academy of {2. Sciences, Beijing 10003., china 3. Shijiazhuang College of Economy, Shijiazhuang 056000, china 4. Xizang Bureau of Geology and mineral Resources, Lhasa 850000, china chinese Acad Geol Sci Inst Mineral Resources Beijing 100037 Peoples R China chinese Acad Geol Sci Natl Ctr Geoanal Beijing 100037 Peoples R China Shijiazhuang Coll Econ Shijiazhuang 056000 Peoples R China Xizang Bur Geol & mineral Resources Lhasa 850000 Peoples R China

The Gangdese porphyry copper belt consists of one large and five middle-small deposits in addition to dozens of ore-bearing porphyry bodies. The belt trends 3.0 km long along the EW-striking Gangdese batholith, and locally occurs as a string of beads extending about 50 km within the SN-trending rifting zones (grabens) on the Tibetan plateau. Monzonitic granite- porphyry and quartz monzonitic porphyry, as dominant host rocks, are shoshonitic and potassic calc-alkaline. Available dating data indicate that the ages of the shallow-level emplacement for these porphyries vary from 10 Ma to 18 Ma, which are identical to that of associated potassic calc-alkaline volcanic rocks (10—15 Ma) and mafic dykes (13.18 Ma). The timing and duration of Cu {2.ization events are constrained by Re-Os ages for molybdenites from three porphyry copper deposits in the Gangdese porphyry copper belt. Five molybdenite samples from the Nanmu deposit yielded an 187Re-187Os isochron with a highly pre-cise age of (14.76?.2.) Ma; six molybdenites from the Chongjiang deposit gave an isochron age of (14.04?.16) Ma. Re-Os model ages for two molybdenite samples from Lakang抏 deposit vary from 13.5 Ma to 13.6 Ma, which are basically identical to isochron ages mentioned above. All the thirteen samples from these three deposits yielded a linear array in the isochron diagram with a higher correlation coefficient of 0.99719 and an isochron age of (14.3.?.2.) Ma (1s error), suggesting an coeval event of the Cu {2.ization and a shared source of ore materials for the Gangdese porphyry copper belt. Compared with the longer-lived felsic magmatic-hydrothermal system, the Cu {2.ization is a relatively short event with duration of about 0.5 Ma, and usu-ally occurs in the later-stage of the complicate magmatic system. The emplacement age of the Gangdese porphyries indicates that they intruded after the rapid rising of the Gangdese Mountains at 2.—2. Ma, and formed in a post-collision crustal ex-tension env

关键词： porphyry copper deposit, Re-Os age, Gangdese, Tibetan plateau.

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Re-Os(ICP-MS)dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

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Science china Earth Sciences 2005年第10期48卷 1672-1677页

作者： YANG Gang1,2. DU Andao1, LU Jiren3. QU Wenjun1 & CHEN Jiangfeng2.1. national Research {3. of Geo{2., Beijing 10003., china 2. Laboratory for Earth Material Cycling, School of Earth and Space Sciences, University of Science and Technology of china, Hefei 2.002., china 3. Institute of mineral Resource, {13. Academy of geological Sciences, Beijing 10003., china national Research center of Geo{2. Beijing{3. Laboratory for Earth Material Cycling School of Earth and Space Sciences University of Science and Technology of China Hefei China Institute of mineral Resource chinese Academy of {2. Sciences Beijing{3.

Massive sulfide ore from the Jinchuan Ni-Cu-PGE deposit was dated by Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measurement. An isochron giving an age of 83. ± 3. Ma, initial 187Os/188Os ratio of 0.2.9 ± 0.018 (MSWD = 1.7) and γOs = 13. ± 15 is obtained. The Re-Os age obtained agrees, within analytical uncertainties, with previous SHRIMP zircon U-Pb age of 82. ± 8 Ma (n=5, MSWD = 4.3.. The result suggests that the deposit was formed at Neoproterozoic and that the formation of the Jinchuan Ni-Cu-PGE sulfide deposit may be closely related to the plume activity, which were attributed to the breakup of the Rodinia supercontinent. The high γOs of the massive ores sug-gests that crustal material was involved in the formation of the Jinchuan deposit, however, the quantity of the added crustal material is less than 10%.

关键词： Jinchuan Ni-Cu-PGE deposit, Re-Os dating, ICP-MS.

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Isotopic compositions of small shelly fossil Anabarites from Lower Cambrian in Yangtze Platform of South china: Implications for palaeocean temperature

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Progress in Natural Science:Materials International 2007年第10期17卷 1185-1191页

作者： Chen Yongquan1,2. Jiang Shaoyong1, Ling Hongfei1, Yang Jinghong1 and Wan Defan3.1. State Key Laboatory for mineral Deposits Research and center for Marine Geochemistry Research, Department of Earth Sciences, Nanjing University, Nanjing 2.0093.{2. 2. Tarim Oilfield Company Exploration & Development Research Institute, Ku’erle 841000,{2. 3. Institute of mineral Resources, chinese Academy of geological Sciences, Beijing 10003.,{2.) State Key Laboatory for mineral Deposits Research and center for Marine Geochemistry Research Department of Earth Sciences Nanjing University Nanjing 210093 China arim Oilfield Company Exploration & Development Research Institute Ku’erle 841000 China Institute of mineral Resources Chinese Academy of Geological Sciences Beijing 100037 China

Anabarites belong to small shelly fossils (SSF), which occur widely in the Lower Cambrian strata of Yangtze Platform in South china. They are phosphate shell in composition and represent the earliest stage of the Cambrian bioradiation of Bilateria, the so-called "Cambrian Explosion". In this study, we attempted to separate Anabarites fossils from Lower Cambrian dolostones, and we obtained samples of both the fossils (SSF) and the granular phosphates (GP). Isotopic analyses were performed on samples of SSF, GP, and matrix dolostone (DH-2.). The results showed that the δ3.Si values of the quartz filling in fossils celoms, and the siliceous materials in granular phosphates are -0.6‰ and -0.7‰, which is different from normal sedimentary siliceous rocks from the Lower Cambrian strata (0—0.7‰) as reported by Li et al., but is consistent with the data for siliceous rocks and cherts of submarine hydrothermal origin. It is likely that a later hydrothermal replacement could have taken place in the SSF-bearing sedimentary rocks. The oxygen isotope values of the phosphate of SSF and GP are 16.8‰ and 17.0‰, respectively. These are significantly higher than the Neoproterozoic phosphate ores (10.9‰—13.9‰) as reported by Ling et al., hence, late diagenesis and hydrothermal replacement may not have caused a significant change in the oxygen isotope compositions of the small shelly fossils, and the calculated temperatures (2..4—2..3.) for palaeo-seawater using a SSF phosphate oxygen isotope thermometer are therefore considered here as the upper limit of seawater temperature in the Early Cambrian ocean of the Yangtze Platform.

关键词： Anabarites oxygen isotope silicon isotope paleo-temperature.

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Aoyitake plagiogranite in western Tarim Block, NW china: Age, geochemistry, petrogenesis and its tectonic implications

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Science china Earth Sciences 2006年第11期49卷 1121-1134页

作者： ZHANG Chuanlin1,2. YU Haifeng3. YE Haimin2. ZHAO Yu2.& ZHANG Dongsheng4 1. Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou Institute of Geochemistry, {3. Academy of Sciences, Guangzhou 510640, china 2. Nanjing Institute of Geology and {2. Resources, Nanjing 2.0016, china 3. Tianjin Institute of Geology and {2. Resources, Tianjin 3.0170, china 4. The 2.d Regional geological Investigation Party, Xinjiang Bureau of Geology and {2. Resources, Changji 83.100, china 1. Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China 2. Nanjing Institute of Geology and mineral Resources Nanjing 210016 China 3. Tianjin Institute of Geology and mineral Resources Tianjin 300170 China 4. The 2.d Regional geological Investigation Party Xinjiang Bureau of Geology and Mineral Resources Changji 831100 China

SHRIMPP U-Pb zircon age and geochemical and Nd isotopic data are reported for the Aoyitake plagiogranite in western Tarim Block, NW china. The plagiogranite intruded the Middle Pro- terozoic and Lower Carboniferous with an exposure area of ca. 60 km2.and crystallized at 3.0.7±4.8 Ma. rock types mainly include tonalite, trondhjemite and minor amounts of diorite and quartz-diorite. Feldspars in the rocks are dominated by oligoclase-andesine, and minor perthite observed locally. The granites are sodic with Na/K ratios (molar) between 4 and 87. Total REE (50-2.0 ppm) show a clear positive correlation with SiO2. There is no LRRE/HREE fractionation (LaN/YbN=0.5-1.5), me- dium negative Eu anomalies (δ Eu=0.3.0.6), high Y content and low Sr/Y ratio (~1.0). These granites exhibit relatively juvenile Nd T2.M model ages of 470 to 580 Ma and positive εNd(3.1 Ma) values of 6.2. to 7.65. The aforementioned characteristics are similar to those of ocean island or ocean ridge plagiogranites. However, the regional geology, especially its scale, precludes that the plagiogranite pluton was derived directly from fractionational crystallization of mantle-derived basaltic magma. We interpreted that the primary magma of the pluton might be tonalitic in composition generated by ca. 50% partial melting of the juvenile basaltic crust. The primary magma experienced intensive frac- tionational crystallization, and intruded into the middle to upper crusts to form the granite pluton. In combination with the previous regional geological data, it is concluded that the plagiogranite pluton was emplaced within the Tarim Block in respond to the Carboniferous continental rifting along the Tianshan orogenic belt.

关键词： western Tarim, Aoyitake plagiogranite, age, geochemistry, tectonic implications.

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Petrogenesis of Songshugou dunite body in the Qinling orogenic belt, Central china: Constraints from geochemistry and melt inclusions

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Science china Earth Sciences 2005年第8期48卷 1146-1157页

作者： SU Li1,2. SONG Shuguang3.& ZHOU Dingwu1 1. Key Laboratory of Continental Dynamics of the Ministry of Education, Department of Geology, Northwestern University, Xi’an 710069, china 2. The {3. Lab {2., china University of Geosciences (Beijing), Beijing 100083. china 3. Key Laboratory of Orogenic Belts of the Ministry of Education, Department of Geology, Peking University, Beijing 100871, china 1. Key Laboratory of Continental Dynamics of the Ministry of Education Department of Geology Northwestern University 710069 Xi’an China 2. The geological Lab center China University of Geosciences 100083 (Beijing)Beijing China 3. Key Laboratory of Orogenic Belts of the Ministry of Education Department of Geology Peking University 100871 Beijing China

The Songshugou dunite body, which occupies an area of about 2. km2. is the largest ultramafic massif in the eastern Qinling orogenic belt, Central china. The major compo-nent of this body is dunitic {3.s including mylonitic dunite and coarse-grained dunite; they oc-cupy about 95 vol% of the total body. Petrography, {2. composition, major and trace ele-ments and primitive melt inclusions have been investigated in this paper; all revealed that this dunite body is the product of melt-{3. interaction by porous percolation flow. In comparison with dunite sills or veins in harzburgite from the basal part of Oman ophiolite, this dunite body is characterized by lower contents of Al2.3. CaO and HREE but higher content of highly incom-patible elements and Zr and Hf. The LREE enriched patterns and primitive mantle normalized spidergrams of trace elements are also different from the Oman dunite. Combining with melt in-clusions observed in olivines, we conclude that this dunite body is the product of large- scale porous percolation flow of high-MgO melts within depleted mantle peridotites. The high-MgO magma, in essence, was most probably produced at the hot head of an upwelling mantle plume. The occurrence of the Songshugou dunite body is closely associated with the activity of mantle super-plume in Neo-Proterozoic era in the Yangtze Craton.

关键词： Songshugou dunite body, geochemistry, melt inclusion, mantle plume, Qinling orogenic belt.

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mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating

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Science china Earth Sciences 2005年第2期48卷 192-198页

作者： WANG Denghong, QU Wenjun, LI Zhiwei, YIN Hanlong4 & CHEN Yuchuan Institute of mineral Resources, chinese Academy of {2. Sciences, Beijing {3., china national center of rock and mineral analysis, chinese Academy of {2. Sciences, Beijing {3., china Resource Assessment center of Yunnan, Kunming 650011, china Institute of Geology and Geophysics, chinese Academy of Sciences, Beijing 100101, china chinese Academy of {2. Sciences, Beijing {3., china 1. Institute of mineral Resources Chinese Academy of Geological Sciences 100037 Beijing China 2. national center of rock and mineral analysis Chinese Academy of Geological Sciences 100037 Beijing China 3. Resource Assessment center of Yunnan 650011 Kunming China 4. Institute of Geology and Geophysics Chinese Academy of Sciences 100101 Beijing China 5. chinese Academy of geological Sciences 100037 Beijing China

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 3..9±1.1 Ma for the Machangqing deposit and 3..4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (3..4 Ma, 3..9 Ma, 3..2.Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.

关键词： Re-Os isotopic dating, porphyry Cu deposits, Cenozoic, mineralization episode.

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Petrogenesis and dating of the Kangding complex,Sichuan Province

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Science china Earth Sciences 2005年第5期48卷 622-634页

作者： CHEN Yuelong 1 , LUO Zhaohua 1 , ZHAO Junxiang, LI Zhihong, ZHANG Hongfei & SONG Biao 3.1. Faculty of Earth Sciences and Natural Resources, china University of Geosciences, Beijing 100083. china 2. Faculty of Earth Sciences, china University of Geosciences, Wuhan 43.074, china 3. Beijing SHRIMP center, Institute of Geology, chinese Academy of geological Sciences, Beijing 10003., china 1. Faculty of Earth Sciences and Natural Resources China University of Geosciences 100083 Beijing China 2. Faculty of Earth Sciences China University of Geosciences 430074 Wuhan China 3. Beijing SHRIMP center Institute of Geology Chinese Academy of Geological Sciences 100037 Beijing China

An analysis of major and trace element geochemistry and SHRIMP U-Pb zircon dating of mafic, intermediate, and felsic rocks from the Mianning metamorphic complex of Si- chuan Province was conducted. One of our conclusions is that a majority of the zircons crystal- lized between 72. and 773.Ma in a magmatic regime. The complexes contain early to late Pa- leo-proterozoic relict zircons from ancient continental crust. The oldest age, 2.68 Ma, may rep- resent the basement of the Yangtze block. Overgrowth zircon rims and palingenetic zircons have been observed and dated, and are believed to have formed after crystallization, during Paleozoic and Mesozoic metamorphic-anatexis. We also conclude that depletion of Nb, Ta, HREE, in a spider-diagram normalized to primitive mantle and calc-alkaline association, implies that they formed in island-arc or under-plating settings.

关键词： Kangding complex, zircons, SHRIMP, tectonic setting.

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U-Pb dating of zircon from the bed parallel anatectic granitic intrusion in the Baoban group in Hainan Island and the tectonic implication

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Science china Earth Sciences 2005年第12期48卷 2092-2103页

作者： DING Shijiang1, HU Jianmin2. SONG Biao3.4, CHEN Mulun1, XIE Shengzhou1 & FAN Yuan1 1. geological Surveying Institute of Hainan, Haikou 5702.6,{3. 2. Institute of Geomechanics, {2. Academy of geological Sciences, Beijing 100081,{3. 3. Beijing center of SHRIMP, Beijing 10003.,{3. 4. Institute of Geology, {2. Academy of geological Sciences, Beijing 10003.,{3. 1. geological Surveying Institute of Hainan 570206 Haikou China 2. Institute of Geomechanics Chinese Academy of Geological Sciences 100081 Beijing China 3. Beijing center of SHRIMP 100037 Beijing China 4. Institute of Geology Chinese Academy of Geological Sciences 100037 Beijing China

The petrological and geochemical features of the bed parallel granitic intrusion in the Pre-Cambrian Baoban group in Hainan Island attest to the anatexis origin of the granites. U-Pb dating analyses of zircons from the anatectic granite and the biotite two-feldspar gneiss in the Baoban group, using SHRIMP II in the Beijing Ion-probe center, acquire 2.6Pb/2.8U ages of 3.8±3.5 Ma (of granite, 95% confidence level, MSDW=1.2.) and 3.2.9±6.1 Ma (of gneiss, 95% confidence level, MSDW = 2.04) respectively. The two late Devonian ages indicate consistently a tectonic- thermal event experienced in Hainan Island, and are the first discovered record of the Devonian geological process in the district. This event possibly resulted from the deep ther-mal-dynamic process when the Gondwana continent began to break up in the Devonian period.

关键词： Hainan Island, Devonian period, anatectic granite, zircon SHRIMP U-Pb dating.

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Lithosphere types in North china:Evidence from geology and geophysics

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Science china Earth Sciences 2005年第11期48卷 1809-1827页

作者： QIU Ruizhao1,2. DENG Jinfu3. ZHOU Su3. LI Jinfa4, XIAO Qinghui1,5, WU Zongxu6 & LIU Cui3.1. Institute of Geology, chinese Academy of geological Sciences, Beijing {2., china 2. Development and Research center, china geological Survey, Beijing {2., china 3. china University of Geosciences, Beijing 100083. china 4. china University of Geosciences, Wuhan 43.074, china 5. Information center of Ministry of Land and Resources, Beijing 100812. china 6. Institute of Geology, State Seismological Bureau, Beijing 10002., china 1. Institute of Geology Chinese Academy of Geological Sciences 100037 Beijing China 2. Development and Research center China Geological Survey 100037 Beijing China 3. china University of Geosciences 100083 Beijing China 4. china University of Geosciences 430074 Wuhan China 5. Information center of Ministry of Land and Resources 100812 Beijing China 6. Institute of Geology State Seismological Bureau 100029 Beijing China

On the basis of the characteristics of geology and geophysics in North china, three types of lithosphere, namely, the cratonic, the orogenic and the rift lithospheres can be classified. In terms of petrological method (based on the information from Precambrian rock assemblages, igneous activities, deep-seated enclaves, etc.) and the relationship between seismic velocity and rock compositions, the crust-mantle petrological and chemical structure models can be set up. Researching results indicate that the geology and geophysics of North china platform bears the similar characteristics in comparison with those of the global typical cratons. The Eerduosi(Ordos) block located in the west of the North china Platform is a remnant of cratonic lithosphere after the North china platform had undergone “activation” in Mesozoic and “reconstruction” in Cenozoic times. The continental crust consists mainly of TTG rock assemblage while the subcontinental lithosphere mantle mainly consists of strongly depleted harzburgite. The craton was finally formed in late Archaean and early Proterozoic, and has been kept in stability up to present; its crustal-mantle petrological structures of lithosphere can be set up as a reference for the study of North china craton and even Sino-Korean craton. In the Mesozoic period, the middle and east areas of North china platform were activated in the Yanshanian orogenic process, the continental crust was reformed by material and heat-transfer of convective mantle and the original crustal TTG component was reconstructed to be granitic crust, and the subcontinental lithosphere man- tle was replaced by the Yanshanian harzburgite-lherzolite. The Yanshan-Taihang Mountains were the remnants of orogenic lithosphere after the rifting in eastern North china in Cenozoic. The present thickness of continental crust and lithosphere in the Yanshan-Taihang Mountains is not equal to their thickness during the Yanshanian orogenic movement because they had undergone the

关键词： lithospheric types,evidence of geology and geophysics,crust-mantle petrological structure,deep process

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Southeastern extension of the Red River fault zone (RRFZ) and its tectonic evolution significance in western South china Sea

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Science china Earth Sciences 2006年第8期49卷 839-850页

作者： LIU Baoming1,2.3. XIA Bin1, LI Xuxuan1,3. ZHANG Minqiang1,3. NIU Binhua2. ZHONG Lifeng1, JIN Qinghuan1,4 & JI Shaocheng1,5 1. Key Laboratory of Marginal Sea Geology and Resources, chinese Academy of Sciences,Guangzhou 510640,{3. 2.{3. University of Geosciences (Beijing), Beijing 100083.{3. 3. Research center of Science & Technology Department, CNOOC, Beijing 10002.,{3. 4. Guangzhou Marine geological Survey, Ministry of Land & Resources, Guangzhou 510075,{3. 5. Ecole Polytechnique Montreal, H3.3.7, Canada 1. Key Laboratory of Marginal Sea Geology and Resources Chinese Academy of Sciences Guangzhou 510640 China 2. china University of Geosciences (Beijing) Beijing 100083 China 3. Research center of Science & Technology Department CNOOC Beijing 100027 China 4. Guangzhou Marine geological Survey Ministry of Land & Resources Guangzhou 510075 China 5. Ecole Polytechnique Montreal H3C3A7 Canada

Recent geophysical surveys and basin modeling suggest that the No.1 fault in the Ying- gehai basin (YGHB) is the seaward elongation of the Red River fault zone (RRFZ) in the South china Sea (SCS). The RRFZ, which separates the South china and Indo{2. block, extends first along the Yuedong fault, offshore of Vietnam, and then continues southward and breaks off into two branches: the Lupar fault and the Tinjia fault. The southern extension of the Lupar fault dies out beneath the NW Borneo while the Tinjia fault extends southeast and reaches the Brunei-Sabah area. According to the gravity and geomagnetic data, and the tectonic evolution of the basins, there are different evolution histories between the Wan’an basin (WAB) and the basins in the Nansha block. The Tinjia fault may be the boundary between the Balingian block and the Nansha block. Hence, the line linking the Yue- dong fault and the Tinjia fault, which both are continental margin faults and strike-slip ones in the {3. evolution histories, constitute the boundary between the Indo{2. and Nansha block. The Lupar fault, in contrast, is an intraplate fault within the Indo{2. block. The results provide new hints for reconstructing the tectonic evolution history of the RRFZ and the opening of the SCS, and also a framework for hydrocarbon prospecting in the region.

关键词： Red River fault zone, tectonic evolution, fault, extension, western South china Sea.

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