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A passive sampler for synchronously measuring inorganic and organic pollutants in sediment porewater:Configuration and field application

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Journal of Environmental Sciences 2024年第2期136卷 201-212页

作者： Pei Lei Mingying Chen nan Rong Wenzhong Tang Hong Zhang School of Environment Nanjing Normal UniversityNanjing 210023China State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China South China Institute of Environmental Sciences Ministry of Ecology and EnvironmentGuangzhou 510530China State Environmental Protection Key Laboratory of Water Environmental Simulation and Pollution Control Guangzhou 510530China University of Chinese Academy of Sciences Beijing 100049China

In situ measurement of multiple pollutants coexisting in sediment porewater is an essential step in comprehensively assessing the bioavailability and risk of pollutants,but to date,this needs to be better *** this study,a passive sampler,consisting of an“I-shaped”supporting frame and inorganic/organic sampling units,incorporating equilibrium dialysis theory and kinetic/equilibrium sorption principle,was developed for the synchronous measurement of inorganic(e.g.,phosphorus and metal(loid)s)and organic pollutants(e.g.,parent and substituted PAHs).The equilibrium time and sampling rates were explored in laboratory tests to support in situ *** of pollutants in porewater within a vertical resolution of centimeters,i.e.,1 cm and 2 cm for inorganic and organic pollutants,respectively,were obtained by field deployment of the sampler for further estimation of diffusive fluxes across the sediment-water *** results suggested that the role of sediments for a specific pollutant may change(e.g.,from“sink”to“source”)during the sampling *** study demonstrated the feasibility of synchronous measurement of inorganic and organic pollutants in sediment porewater by the passive *** addition,it provided new insight for further investigation into the combined pollution effects of various pollutants in sediments.

关键词： Passive sampling Bioavailability Polycyclic aromatic hydrocarbons Combined pollution Diffusive flux

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Ultrasound-driven self-decomposition porphyrins as metal-free CO precursors for gas and sonodynamic synergistic therapy

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Science China Chemistry 2024年第5期67卷 1624-1635页

作者： Shuxin Liu Jinjuan Ma Xiang Xu Aiguo Wang nan Zheng School of Chemical Engineering Dalian University of TechnologyDalian 116024China Department of Comparative Medicine Laboratory Animal Center Dalian Medical UniversityDalian 116000China Cancer Hospital of Dalian University of Technology Shenyang 116000China

Carbon monoxide(CO) is an endogenous therapeutic gas with an anti-tumor effect. The precise delivery and controlled release of CO in tumor tissues play crucial roles in anti-cancer treatment. However, efficient in situ generation of CO from metal-free COreleasing molecules(CORMs) remains a formidable challenge. Herein, we develop ultrasound(US)-driven self-decomposition porphyrin as organic and metal-free US-CORMs, which can spatiotemporally control the CO release(347 mmol CO/mol porphyrin) efficiently under physiologically harmless US conditions(1.0 MHz, 1.5 W/cm^(2), 50% duty cycle, 50 min). Moreover,porphyrin as a sonosensitizer can also generate reactive oxygen species(ROS) under US treatment to achieve sonodynamic therapy(SDT). Advanced functions of such porphyrin-based CORMs in CO gas-sonodynamic synergistic treatment have been demonstrated by evaluating the in vitro and in vivo anti-tumor effects.

关键词： porphyrin sonodynamic therapy metal-free CO precursors ultrasound-driven gas therapy

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Kinetics and mechanism of propylene hydro-oxidation to acrolein on Au catalysts

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nano Research 2024年第1期17卷 354-363页

作者： Wei Du Zhihua Zhang nan Song Xuezhi Duan Xinggui Zhou State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China

Propylene epoxidation by H_(2)and O_(2)to propylene oxide(PO)over the Au-Ti bifunctional catalysts,as an ideal reaction for PO production,has attracted great *** the mechanism of acrolein formation is of great importance for understanding the mechanism of molecular oxygen activation and the formation of hydroperoxo species on the Au ***,we investigate the reaction mechanism of propylene oxidation to acrolein on the Au/uncalcined TS-1(Au/TS-1-B)catalyst through a combination of multiple characterization,H_(2)/D_(2)exchange,kinetics experiment,and *** Ti sites are found to be non-essential to acrolein ***,the acrolein formation on the Au/TS-1-B catalyst is confirmed to be promoted by H_(2)through hydroperoxo species formation,which includes two main steps:propylene dehydrogenation to*C_(3)H_(5)with the aid of*OOH species,and*C_(3)H_(5)oxidation by*OOH to *** latter step is determined to be the rate-determining step because the corresponding kinetics model gives the best description for experimental *** work not only provides kinetics insights for the propylene hydro-oxidation to acrolein on the Au-Ti bifunctional catalysts,but also facilitates the rational design of Au catalysts with high activity and selectivity in the direct propylene epoxidation with H_(2)and O_(2).

关键词： kinetics mechanism gold acrolein hydro-oxidation

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Pyrolysis Empirical Modeling of Polyester Glass Fiber Reinforced Plastics Using Sestak-Berggren Model Method

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Journal of Thermal Science 2024年第2期33卷 725-738页

作者： nan Wei JI Wenhui YUAN Yanping YUAN Zhongyuan SUN Yong School of Mechanical Engineering Southwest Jiaotong UniversityChengdu610031China CRRC Changchun Railway Vehicles Co. LtdChangchun130062China

Polyester Glass Fiber Reinforced Plastic(Polyester GFRP),a thermosetting plastic comprised of glass fiber and polyester polymer compounds,is extensively utilized in high-speed *** its pyrolysis mechanism is crucial as it significantly influences the combustion characteristics and fire safety ***,kinetic research on polyester GFRP primarily focuses on employing the Coats-Redfern method to derive a theoretical kinetic ***,the pyrolysis process of polyester GFRP is complex and the aforementioned theoretical model fails to accurately describe the pyrolysis ***,this study seeks to utilize the Sestak and Berggren(SB) model as a methodological approach to reveal the complex reaction mechanism during the pyrolysis *** on thermogravimetric analysis,the entire pyrolysis process of polyester GFRP is divided into two primary ***,model-free methods are employed to ascertain the activation energy and pre-exponential *** results show that the fitted empirical models of the two main pyrolysis stages are f(α)=(1-α)^(1.47)[-ln(1-α)]^(1.50) and f(α)=(1-α)^(1.77)[-ln(1-α)]^(1.72),*** predicted results are in good agreement with experimental data under different heating rates,which indicates that the empirical model can sufficiently describe the pyrolysis process of polyester GFRP.

关键词： polyester GFRP model-fitting methods empirical models pyrolysis

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A bifunctional POM-based Cu-viologen complex with mixed octamolybdate clusters for rapid oxidation desulfurization and effective photogeneration of hydrogen

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Rare Metals 2024年第1期43卷 236-246页

作者： Lin Yang Zhong Zhang Chao-nan Zhang Xiu-Li Wang College of Chemistry and Materials Engineering Bohai UniversityJinzhou 121013China Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell Bohai UniversityJinzhou 121013China

The design and synthesis of catalysts for the oxidation desulfurization and production of hydrogen are extremely important for solving environmental pollution and energy ***,a novel bifunctional [α-Mo_(8)O_(26)]^(4-)/[β-Mo_(8)O_(26)]^(4-)-based Cu-viologen complex H_(4)[Cu_(2)~ⅠCl_(2)(Hbcbpy)_(4)] [α-Mo_(8)O_(26)] [β-Mo8O_(26)]·H_(2)O(BHU-2,Hbcbpy=1-(4-carboxybenzyl)-4,4'-bipyridinium) was synthesized and characterized by single-crystal X-ray diffraction(XRD),infrared radiation spectra,powder X-ray diffraction(PXRD) and X-ray photoelectron spectroscopy(XPS) *** structural characteristic of BHU-2 is the presence of two types of octamolybdate clusters [α-Mo_(8)O_(26)]^(4-)/[β-Mo_(8)O_(26)]^(4-)and a new binuclear Cu~Ⅰ-Hbcbpy complex linked by Cl-bridges[Cu_(2)ⅠCl_(2)(Hbcbpy)_(4)]^(4+).BHU-2 as a heterogeneous catalyst exhibits excellent activities to the oxidation desulfurization and photocatalytic hydrogen *** room temperature,BHU-2 can catalyze 96% conversion of methyl phenyl sulfide with 98% selectivity,and the process obeys the pseudo-first-order reaction kinetic with the half-life of9.6 *** notorious 2-chloroethyl ethyl sulfide can achieve 99% conversion with 98% selectivity within only1 min at the presence of BHU-2,and the turnover frequency(TOF) is up to 7400 h^(-1).BHU-2 also exhibits high catalytic activity for the oxidation of other aromatic and aliphatic thioethers within short time at room ***,BHU-2 shows a high catalytic activity for visible-light-driven hydrogen evolution with an H_(2) evolution rate of 1677.85 μmol·g^(-1)·h^(-1) within 10 ***,the catalytic activities do not decrease evidently after three cycles,revealing the prominent structural stability and recyclability.

关键词： Polyoxometalate Metal-organic complex Viologen Oxidation desulfurization Photocatalytic hydrogen production

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Dynamic Hypergraph Modeling and Robustness Analysis for SIoT

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Computer Modeling in Engineering & Sciences 2024年第9期140卷 3017-3034页

作者： Yue Wan nan Jiang Ziyu Liu School of Information Engineering East China Jiaotong UniversityNanchang330013China

The Social Internet of Things(SIoT)integrates the Internet of Things(IoT)and social networks,taking into account the social attributes of objects and diversifying the relationship between humans and objects,which overcomes the limitations of the IoT’s focus on associations between *** Intelligence(AI)technology is rapidly *** is critical to build trustworthy and transparent systems,especially with system security issues coming to the *** paper emphasizes the social attributes of objects and uses hypergraphs to model the diverse entities and relationships in SIoT,aiming to build an SIoT hypergraph generation model to explore the complex interactions between entities in the context of intelligent *** hypergraph generation models impose too many constraints and fail to capture more details of real *** contrast,this paper proposes a hypergraph generation model that evolves dynamically over time,where only the number of nodes is *** combines node wandering with a forest fire model and uses two different methods to control the size of the *** new nodes are added,the model can promptly reflect changes in entities and relationships within *** results exhibit that our model can effectively replicate the topological structure of real-world *** also evaluate the vulnerability of the hypergraph under different attack strategies,which provides theoretical support for building a more robust intelligent SIoT hypergraph model and lays the foundation for building safer and more reliable systems in the future.

关键词： Large-scale artificial intelligence Social Internet of Things hypernetwork robustness analysis

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Research on the Stability Analysis Method of DC Microgrid Based on Bifurcation and Strobe Theory

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Energy Engineering 2024年第4期121卷 987-1005页

作者： Wei Chen nan Qiu Xusheng Yang School of Electrical Engineering and Information Engineering Lanzhou University of TechnologyLanzhou730050China

During the operation of a DC microgrid,the nonlinearity and low damping characteristics of the DC bus make it prone to oscillatory *** this paper,we first establish a discrete nonlinear system dynamic model of a DC microgrid,study the effects of the converter sag coefficient,input voltage,and load resistance on the microgrid stability,and reveal the oscillation mechanism of a DC microgrid caused by a single ***,a DC microgrid stability analysis method based on the combination of bifurcation and strobe is used to analyze how the aforementioned parameters influence the oscillation characteristics of the ***,the stability region of the system is obtained by the Jacobi matrix eigenvalue *** simulation verifies the feasibility and effectiveness of the proposed method.

关键词： DC microgrid bifurcation nonlinear dynamics stability analysis oscillation characteristics

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切削用量遗传优化中的约束条件处理

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机械设计与研究 2008年第4期24卷 93-97页

作者：黄宗南何岚岚舒洲上海大学机械电子工程及自动化学院上海200072

针对应用遗传算法进行切削用量优化,提出了三种约束条件的处理方法,并进行了性能测试,比较其在进化趋势、合格个体数和寻优能力方面的性能,结果显示:采用交叉变异操作产生合格个体的种群进入下一次进化的搜索空间限定法效果较好。

关键词：切削用量遗传算法约束条件优化

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Photoinduced bismuth vanadate-catalyzed C(sp^(2))-H functionalization

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Chinese Chemical Letters 2024年第3期35卷 1-2页

作者： Rong-nan Yi Wei-Min He Key Laboratory of Food&Environment&Drug Monitoring and Testing of Universities in Hunan Province Hunan Police AcademyChangsha 410138China School of Chemistry and Chemical Engineering University of South ChinaHengyang 421001China

Visible light-induced organic reactions have gained much attention in recent years due to their mild conditions and high efficiency[1,2].In this context,many efficient photocatalysts including transition metal complex... 详细信息

关键词： bismuth catalyzed gained

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信息扩散和径向基神经网络的注塑模型建立

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机械设计与研究 2010年第3期26卷 112-114页

作者：黄宗南王祺刘文豪上海大学机电工程与自动化学院上海200072

在使用径向基神经网络建立注塑工艺模型时,虽然能够得到较好的模型,但是建模时训练样本数量将会对模型的质量产生较大的影响。本研究对建模所需的原始样本数据首先进行信息扩散处理,然后再使用径向基神经网络建立注塑工艺参数与塑件沉... 详细信息

在使用径向基神经网络建立注塑工艺模型时,虽然能够得到较好的模型,但是建模时训练样本数量将会对模型的质量产生较大的影响。本研究对建模所需的原始样本数据首先进行信息扩散处理,然后再使用径向基神经网络建立注塑工艺参数与塑件沉降斑指数之间的模型。从结果上看,在注塑训练样本数量相同的情况下,运用该方法均可以得到优于仅使用普通径向基网络构建的模型。

关键词：信息扩散径向基神经网络注塑模型

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