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Selective sorptive removal of Methyl Red from individual and binary component solutions by mesoporous organosilicas of MCM-41 type

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Journal of Environmental Sciences 2021年第1期33卷 59-71页

作者： nadiia v.roik Lyudmila A.Belyakova Marina O.Dziazko Chuiko Institute of Surface Chemistry of NAS of Ukraine 17 General Naumov Str.Kyiv 03164Ukraine

Organosilicas with chemically immobilized 3-aminopropyl and Methyl Red-containing surface groups were prepared by sol-gel condensation of tetraethyl orthosilicate and(3-aminopropyl)triethoxysilane in the presence of dye as part of the mixed micelles or dyecontaining silane as silica *** hexagonally arranged mesoporous structure of synthesized materials was confirmed by low-temperature nitrogen adsorption-desorption,xray diffraction,and TEM *** composition of MCM-41-type organosilicas was established by FT-IR spectroscopy and chemical analysis of surface *** of Methyl Red by organosilicas was studied from diluted phosphate buffer solutions in dependence of medium p H,duration of contact,and equilibrium concentration of *** was found that effective removal of Methyl Red takes place at p H values within a range of *** curves of Methyl Red sorption on organosilicas were analyzed by the Lagergren,Ho-McKey,and Weber-Morris kinetic *** was found that the pseudo-second-order model fits the kinetics of Methyl Red sorption on all synthesized materials and the intraparticle diffusion is not the only one mechanism controlling the rate of Methyl Red sorptive *** parameters of equilibrium sorption of Methyl Red on organosilicas of MCM-41 type were calculated using Langmuir,Freundlich,Redlich-Peterson,and Brunauer-Emmett-Teller *** of acid dyes with geometry similar or substantially different from Methyl Red on mesoporous silicas was studied from single and binary component mixtures in aqueous solutions with p H 4.8 and *** was found that selective sorption process is highly dependent on the structural characteristics and protolytic state of silica surface as well as acid dye.

关键词： MCM-41 Sol-gel synthesis Methyl Red Chemical modification Selective sorption

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Plasma-Enhanced Atomic Layer Deposition of Amorphous Ga_(2)O_(3) for Solar-Blind Photodetection

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Journal of Electronic Science and Technology 2022年第4期20卷 331-344页

作者： Ze-Yu Fan Min-Ji Yang Bo-Yu Fan Andraz Mavric nadiia Pastukhova Matjaz valant Bo-Lin Li Kuang Feng Dong-Liang Liu Guang-Wei Deng Qiang Zhou Yan-Bo Li Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054 Materials Research Laboratory University of Nova GoricaNova Gorica SI-5000 Yangtza Delta Region Institute(Huzhou) University of Electronic Science and Technology of ChinaHuzhou 313001

Wide-bandgap gallium oxide(Ga_(2)O_(3))is one of the most promising semiconductor materials for solar-blind(200 nm to 280 nm)*** its amorphous form,amorphous gallium oxide(a-Ga_(2)O_(3))maintains its intrinsic optoelectronic properties while can be prepared at a low growth temperature,thus it is compatible with Si integrated circuits(ICs)***,the a-Ga_(2)O_(3) film is directly deposited on pre-fabricated Au interdigital electrodes by plasma enhanced atomic layer deposition(PE-ALD)at a growth temperature of 250°*** stoichiometric a-Ga_(2)O_(3) thin film with a low defect density is achieved owing to the mild PE-ALD *** a result,the fabricated Au/a-Ga_(2)O_(3)/Au photodetector shows a fast time response,high responsivity,and excellent wavelength selectivity for solar-blind ***,an ultra-thin MgO layer is deposited by PE-ALD to passivate the Au/a-Ga_(2)O_(3)/Au interface,resulting in the responsivity of 788 A/W(under 254 nm at 10 v),a 250-nm-to-400-nm rejection ratio of 9.2×10^(3),and the rise time and the decay time of 32 ms and 6 ms,*** results demonstrate that the a-Ga_(2)O_(3) film grown by PE-ALD is a promising candidate for high-performance solar-blind photodetection and potentially can be integrated with Si ICs for commercial production.

关键词： Amorphous gallium oxide(a-Ga_(2)O_(3)) passivation layer plasma enhanced atomic layer deposition(PE-ALD) responsivity solar-blind photodetector

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Preparation,Characterization and Catalytic Activity of Palladium Nanoparticles Embedded in the Mesoporous Silica Matrices

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World Journal of Nano Science and Engineering 2012年第3期2卷 117-125页

作者： nadiia A.Ivashchenko Wojciech Gac valentyn A.Tertykh viktor v.Yanishpolskii Sergei A.Khainakov Alla v.Dikhtiarenko Sylwia Pasieczna-Patkowska Witold Zawadzki Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine KyivUkraine Faculty of Chemistry Maria Curie-Skłodowska UniversityLublinPoland Department of Organic and Inorganic Chemistry Faculty of ChemistryUniversity of OviedoOviedoSpain

Novel in-situ reduction approach was applied for the synthesis of palladium nanoparticles in the pores of mesoporous silica materials with grafted siliconhydride groups. Matrices possessing different structural properties (MCM-41, SBA-15 and Silochrom) were used. Samples were studied by nitrogen adsorption-desorption method, low-angle X-ray diffraction, transmission electron microscopy (TEM) and FT-IR/PAS spectroscopy. The temperature-programmed oxidation (TPO) and reduction (TPR) methods were applied to examine reducibility of palladium species. Palladium containing catalysts were tested in methane oxidation reaction. It was demonstrated that relatively large pores in SBA-15 type silica facilitated formation of well-dispersed palladium nanoparticles confined in the pores channels. In the case of MCM-41 support, metallic palladium nanoparticles were formed on the external surface. The obtained materials showed high catalytic activity. Lower activity of the samples containing small crystallites located in the pore volume at high temperatures was related to worse accessibility of active sites to the reation mixture.

关键词： Palladium Nanoparticles Siliconhydride Groups Mesoporous Ordered Silica MCM-41 SBA-15 Palladium-Containing Nanocomposites Methane Oxidation

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