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Ionic Conductivity in Gelatin-Based Hybrid Solid Electrolytes:The Non-trivial Role of Nanoclay

Journal of Materials Science & Technology 2014年第11期30卷 1096-1102页

作者： Ali Ghadami nader taheri qazvini Nasser Nikfarjam Polymer Division School of ChemistryCollege of ScienceUniversity of Tehran Biomaterials Research Center (BRC) University of Tehran

In this study, the ionic conductivity behavior in hybrid gelatin-based transparent electrolytes including various types of nanoclays with different size, shape and surface properties was characterized. The effects of nanoclay type and nanoclay concentration as well as different experimental conditions, e.g., pH, temperature and crosslinking were also investigated. In general, the impedance spectroscopy results suggested a non- trivial role for nanoclay. Regardless of the nanoclay type, the ionic conductivity slightly increased first and then decreased by increasing the nanoclay concentration. Furthermore, among sodium montmorillonite （Na＋MMT）, lithium montmorillonite （Li＋MMT）, laponite and hydrotalcite, the hybrid electrolytes prepared by Li＋MMT showed higher ionic conductivity. The results also showed that the chemical crosslinking along with sample preparation at optimum pH, where the gelatin chains might be efficiently adsorbed on exfoliated, negatively charged clay nanosheets, plays an important role. In comparison with the ionic conductivity of the neat sample at room temperature （～10-7 S cm-1）, a ten-fold increase was observed for the crosslinked sample containing 2 wt% of Li^＋MMT prepared at optimum pH 3.5. The conductivity behavior as a function of temperature revealed the obedience with the VogeI-Fulcher-Tammann （VFT） model for all samples, suggesting the important role of segmental motions in the ionic conductivity. Finally, a qualitative explanation was presented for the mechanism of the ionic conduction in gelatin-nanoclay hybrid electrolytes.

关键词： Gelatin Solid-state electrolytes Ionic conductivity Montmorillonitc Laponite Impedance spectroscopy

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Engineering Nano/Microscale Chiral Self‑Assembly in 3D Printed Constructs

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Nano-Micro Letters 2024年第3期16卷 313-332页

作者： Mohsen Esmaeili Ehsan Akbari Kyle George Gelareh Rezvan nader taheri‑qazvini Monirosadat Sadati Department of Chemical Engineering University of South CarolinaColumbiaSC 29208USA TA Instruments Waters LLCNew CastleDE 19720USA Biomedical Engineering Program University of South CarolinaColumbiaSC 29208USA

Helical hierarchy found in biomolecules like cellulose,chitin,and collagen underpins the remarkable mechanical strength and vibrant colors observed in living *** study advances the integration of helical/chiral assembly and 3D printing technology,providing precise spatial control over chiral nano/microstructures of rod-shaped colloidal nanoparticles in intricate *** designed reactive chiral inks based on cellulose nanocrystal(CNC)suspensions and acrylamide monomers,enabling the chiral assembly at nano/microscale,beyond the resolution seen in printed *** employed a range of complementary techniques including Orthogonal Superposition rheometry and in situ rheo-optic measurements under steady shear rate *** techniques help us to understand the nature of the nonlinear flow behavior of the chiral inks,and directly probe the flow-induced microstructural dynamics and phase transitions at constant shear rates,as well as their post-flow ***,we analyzed the photo-curing process to identify key parameters affecting gelation kinetics and structural integrity of the printed object within the supporting *** insights into the interplay between the chiral inks self-assembly dynamics,3D printing flow kinematics and photopolymerization kinetics provide a roadmap to direct the out-of-equilibrium arrangement of CNC particles in the 3D printed filaments,ranging from uniform nematic to 3D concentric chiral structures with controlled pitch length,as well as random orientation of chiral *** biomimetic approach can pave the way for the creation of materials with superior mechanical properties or programable photonic responses that arise from 3D nano/microstructure and can be translated into larger scale 3D printed designs.

关键词： Directed chiral self-assembly Cellulose nanocrystals Bioinspired nanocomposite 3D printing Rheology

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Study of Physical, Chemical and Morphological Alterations of Smectite Clay upon Activation and Functionalization via the Acid Treatment

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World Journal of Nano Science and Engineering 2013年第4期3卷 161-168页

作者： Mahmood Torabi Angaji Amir Zamani Zinali nader taheri qazvini School of Chemical Engineering College of Engineering University of Tehran Tehran Iran School of Chemistry College of Science University of Tehran Tehran Iran

The present study was carried out on the effect of acid leaching on the modification and structure alteration of montmorillonite. A nanostructured, activated material was prepared by selective leaching of pure smectite clay with different concentrations of sulfuric acid (1 - 10 N/L) at 85°C for 120 min using a solid/liquid ratio of 1:20 and a reflux system. The Fourier transform infrared (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-Ray diffraction (XRD) techniques were used for the characterization and study of the acid-treated montmorillonite clay. Chemical structure of specimens was distinguished by FTIR. The results showed that the formation of Si-OH bonds and leaching of Al3+ ions increased progressively with severity of the acid treatment. As the FTIR studies indicated, acid treatment led to the removal of the octahedral Al3+ cations and an increase in the Si-OH bonds. The morphological alteration of the untreated and treated montmorillonite was investigated by using TEM and SEM. X-ray fluorescence (XRF) analysis revealed a considerable decrease in the relative content of Al by increasing the acid strength. Moreover, the XRD results showed that the treatment using highly concentrated acid resulted in the formation of an amorphous silica phase.

关键词： Montmorillonite Acid Treatment Chemical Activation Morphology Nanomaterial Clay

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On Zero Dynamics and Controllable Cyber-Attacks in Cyber-Physical Systems and Dynamic Coding Schemes as Their Countermeasures

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IEEE/CAA Journal of Automatica Sinica 2024年第11期11卷 2191-2203页

作者： Mahdi taheri Khashayar Khorasani nader Meskin the Department of Electrical and Computer Engineering Concordia University the Department of Electrical Engineering Qatar University

In this paper, we study stealthy cyber-attacks on actuators of cyber-physical systems(CPS), namely zero dynamics and controllable attacks. In particular, under certain assumptions, we investigate and propose conditions under which one can execute zero dynamics and controllable attacks in the CPS. The above conditions are derived based on the Markov parameters of the CPS and elements of the system observability matrix. Consequently, in addition to outlining the number of required actuators to be attacked, these conditions provide one with the minimum system knowledge needed to perform zero dynamics and controllable cyber-attacks. As a countermeasure against the above stealthy cyber-attacks, we develop a dynamic coding scheme that increases the minimum number of the CPS required actuators to carry out zero dynamics and controllable cyber-attacks to its maximum possible value. It is shown that if at least one secure input channel exists, the proposed dynamic coding scheme can prevent adversaries from executing the zero dynamics and controllable attacks even if they have complete knowledge of the coding system. Finally, two illustrative numerical case studies are provided to demonstrate the effectiveness and capabilities of our derived conditions and proposed methodologies.

关键词： Controllable attacks cyber-physical systems(CPS) dynamic coding zero dynamics attacks stealthy cyber-attacks

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