检索结果-南通市图书馆

Heteroepitaxial growth of Au@Pd core–shell nanocrystals with intrinsic chiral surfaces for enantiomeric recognition

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第1期43卷 225-235页

作者： Feng-xia Wu Feng-Hua Li xia-Li Lv Qi-xian Zhang Guo-Bao Xu Wen-Xin niu State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China Shaoxing Institute of Technology Shanghai UniversityShaoxing 312000China University of Science and Technology of China Hefei 230026China School of Materials Science and Engineering Shanghai UniversityShanghai 200436China Zhejiang Institute of Advanced Materials Shanghai UniversityJiashan 314113China University of Chinese Academy of Sciences Beijing 100039China

Noble metal surfaces with intrinsic chirality serve as an ideal candidate for investigating enantioselective chemistry due to their superior chemical durability and high catalytic ***,significant advance has been made in synthesizing metal nanocrystals with intrinsic ***,the majority reports are limited to ***,through a heteroepitaxial growth strategy,the synthesis of metal nanocrystals with intrinsic chirality to palladium was extended for the first time and their application in enantioselective recognition was *** heteroepitaxial growth strategy allows for transferring the chirality of homochiral Au nanocrystals to Au@Pd core–shell *** employing the chiral Au@Pd nanocrystals as enantiomeric recognizing elements,a series of electrochemical sensors for chiral discrimination were *** optimal conditions,the peak potential between D-dihydroxyphenylalanine(D-DOPA)and L-dihydroxyphenylalanine(L-DOPA)is about 80 m V,and the peak current of D-DOPA is 2 times as much as that of L-DOPA,which enables the determination of the enantiomeric excess(EE,%)of ***,this report not only introduces a heteroepitaxial growth strategy to synthesize metal nanocrystals with intrinsic chirality,but also demonstrates the superior capability of integrating intrinsic chirality and catalytic properties into metal nanocrystals for chiral recognition.

关键词： Core–shell nanostructures Chirality transfer Electrochemical sensors Chiral recognition Chiroplasmonics

On traceable iterated line graph and hamiltonian path index

在线全文

学校读者我要写书评

暂无评论

Applied Mathematics(A Journal of Chinese Universities) 2024年第2期39卷 239-252页

作者： niu Zhao-hong XIONG Li-ming YANG Wei-hua School of Mathematical Sciences Shanxi UniversityTaiyuan 030006China School of Mathematics and Statistics Beijing Key Laboratory on MCAACIBeijing Institute of TechnologyBeijing 100081China Department of Mathematics Taiyuan University of TechnologyTaiyuan 030024China

Xiong and Liu[21]gave a characterization of the graphs G for which the n-iterated line graph L^(n)(G)is hamiltonian,for n≥*** this paper,we study the existence of a hamiltonian path in L^(n)(G),and give a characterization of G for which L^(n)(G)has a hamiltonian *** applications,we use this characterization to give several upper bounds on the hamiltonian path index of a graph.

关键词： iterated line graph traceable hamiltonian index hamiltonian path index

UAV-assisted cooperative offloading energy efficiency system for mobile edge computing

在线全文

学校读者我要写书评

暂无评论

Digital Communications and Networks 2024年第1期10卷 16-24页

作者： Xue-Yong Yu Wen-Jin niu Ye Zhu hong-Bo Zhu Jiangsu Key Laboratory of Wireless Communications Nanjing University of Posts and Telecommunications Nanjing210003China Engineering Research Centerof Health Service System Based on Ubiquitous Wireless Networks Ministry of EducationNanjng Universityof Posts and Telecommunications Nanjing210003China

Reliable communication and intensive computing power cannot be provided effectively by temporary hot spots in disaster areas and complex terrain ground *** this has greatly developed the application and integration of UAV and Mobile Edge Computing(MEC)to the Internet of Things(loT).However,problems such as multi-user and huge data flow in large areas,which contradict the reality that a single UAV is constrained by limited computing power,still *** to allowing UAV collaboration to accomplish complex tasks,cooperative task offloading between multiple UAVs must meet the interdependence of tasks and realize parallel processing,which reduces the computing power consumption and endurance pressure of *** the computing requirements of the user terminal,delay constraint of a computing task,energy constraint,and safe distance of UAV,we constructed a UAV-Assisted cooperative offloading energy efficiency system for mobile edge computing to minimize user terminal energy ***,the resulting optimization problem is originally nonconvex and thus,difficult to solve *** tackle this problem,we developed an energy efficiency optimization algorithm using Block Coordinate Descent(BCD)that decomposes the problem into three convex ***,we jointly optimized the number of local computing tasks,number of computing offloaded tasks,trajectories of UAV,and offloading matching relationship between multi-UAVs and multiuser *** results show that the proposed approach is suitable for different channel conditions and significantly saves the user terminal energy consumption compared with other benchmark schemes.

关键词： Computation offloading Internet of things(IoT) Mobile edge computing(MEC) Block coordinate descent(BCD)

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

基于数据驱动的高速列车速度复合控制研究

交通运输系统工程与信息 2023年第3期23卷 145-152页

作者：侯涛唐丽牛宏侠兰州交通大学自动化与电气工程学院兰州730070

针对高速列车在外部干扰下的速度控制问题,本文提出基于Koopman算子的高速列车高维线性模型的建模方法,并设计一种结合扩张状态观测器(ESO)与基于Koopman算子的模型预测控制(K-MPC)的复合控制器(ESO-K-MPC)。利用扩展动态模式分解算法... 详细信息

针对高速列车在外部干扰下的速度控制问题,本文提出基于Koopman算子的高速列车高维线性模型的建模方法,并设计一种结合扩张状态观测器(ESO)与基于Koopman算子的模型预测控制(K-MPC)的复合控制器(ESO-K-MPC)。利用扩展动态模式分解算法来近似无限维线性Koopman算子,建立具有动态非线性特性的高速列车动力学高维线性模型;引入模型预测控制,设计扩张状态观测器,对系统总扰动进行估计与补偿,构建基于ESO-K-MPC的高速列车速度控制系统,再设计控制器与控制算法;结合CRH3列车参数和郑西高铁华山北站—西安北站实际线路数据,分别在没有扰动和白噪声干扰下对设计的控制方法与算法进行仿真研究。仿真结果表明:基于Koopman的高速列车建模对位移与速度的预测精度相比于线性状态空间模型分别提高了83.86%与87.40%;ESO-K-MPC可以准确估计与补偿高速列车运行中受到的干扰,控制输出曲线与期望曲线几乎重叠,实现了列车运行期望曲线的高精度跟踪。

关键词：铁路运输 Koopman算子模型预测控制高速列车扩张状态观测器速度控制

Enhancing cut selection through reinforcement learning

在线全文

学校读者我要写书评

暂无评论

Science China Mathematics 2024年第6期67卷 1377-1394页

作者： Shengchao Wang Liang Chen Lingfeng niu Yu-hong Dai Academy of Mathematics and Systems Science Chinese Academy of SciencesBeijing100190China Research Center on Fictitious Economy and Data Science Chinese Academy of SciencesBeijing100190China

With the rapid development of artificial intelligence in recent years,applying various learning techniques to solve mixed-integer linear programming(MILP)problems has emerged as a burgeoning research *** from constructing end-to-end models directly,integrating learning approaches with some modules in the traditional methods for solving MILPs is also a promising *** cutting plane method is one of the fundamental algorithms used in modern MILP solvers,and the selection of appropriate cuts from the candidate cuts subset is crucial for enhancing *** to the reliance on expert knowledge and problem-specific heuristics,classical cut selection methods are not always transferable and often limit the scalability and generalizability of the cutting plane *** provide a more efficient and generalizable strategy,we propose a reinforcement learning(RL)framework to enhance cut selection in the solving process of ***,we design feature vectors to incorporate the inherent properties of MILP and computational information from the solver and represent MILP instances as bipartite ***,we choose the weighted metrics to approximate the proximity of feasible solutions to the convex hull and utilize the learning method to determine the weights assigned to each ***,a graph convolutional neural network is adopted with a self-attention mechanism to predict the value of weighting ***,we transform the cut selection process into a Markov decision process and utilize RL method to train the *** experiments are conducted based on a leading open-source MILP solver *** on both general and specific datasets validate the effectiveness and efficiency of our proposed approach.

关键词： reinforcement learning mixed-integer linear programming cutting plane method cut selection

同方期刊数据库

Immobilizing Triphenylamine with Photoredox Inert Sr^(2+)Forming Sr-MOF with Controlled Electron Migration for Photocatalytic Oxidation of Thiols to Disulfides

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Chemistry 2024年第10期42卷 1093-1099页

作者： Ying-xia Wang Fang Zheng Dong-xia Song Bao-Yue niu Lu-Qian Deng xian-Ming Zhang Key Laboratory of Magnetic Molecules and Magnetic Information Materials(Ministry of Education) Schoolof Chemistry and Materials ScienceShanxi Normal UniversityTaiyuanShanxi 030006China Key Laboratory of Interface Science and Engineering in Advanced Material(Ministry of Education) College of ChemistryTaiyuan University of TechnologyTaiyuanShanxi 030024China

The photocatalytic oxidative coupling of thiols is one of the most popular methods to synthesize the *** and its derivatives(TPAs)are promising for the above reaction,but suffer from the easy polymerization and difficult *** overcome these obstacles while controlling the photogenerated electrons transfer directly to target substrates,herein,we constructed one TPA-based metal-organic framework(MOF),(Me_(2)NH_(2))[Sr(TCBPA)]·DMA·3H_(2)O(1),by direct self-assembly of tris(4′-carboxybiphenyl)amine(H_(3)TCBPA)and photoredox inert strontium ion(Sr^(2+)).DFT calculations revealed that the valence band maximum(VBM)and the conduction band minimum(CBM)are mainly located on TCBPA^(3-),successfully inhibiting the undesirable electron migration to metal *** results indicated that 1 displays superior performance than homogeneous H_(3)TCBPA,which may result from the abundant π…π and C—H…π interactions between the well-arranged TCBPA^(3-)and the build-in electric field between the anionic framework and the Me_(2)NH^(2+).This work highlights that immobilizing TPAs into MOFs is one promising approach to designing heterogeneous photocatalysts for the synthesis of disulfides by oxidative coupling of thiols.

关键词： Triphenylamine Metal-organic frameworks Strontium Photooxidation Thiols Disulfides

Efficient and robust CNN-LSTM prediction of flame temperature aided light field online tomography

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China(Technological Sciences) 2024年第1期67卷 271-284页

作者： niu ZhiTian QI hong SUN AnTai REN YaTao HE MingJian GAO BaoHai School of Energy Science and Engineering Harbin Institute of TechnologyHarbin 150001China Key Laboratory of Aerospace Thermophysics Ministry of Industry and Information TechnologyHarbin 150001China

Light field tomography,an optical combustion diagnostic technology,has recently attracted extensive attention due to its easy implementation and ***,the conventional iterative methods are high data throughput,low efficiency and time-consuming,and the existing machine learning models use the radiation spectrum information of the flame to realize the parameter field measurement at the current *** is still an offline measurement and cannot realize the online prediction of the instantaneous structure of the actual turbulent combustion *** this work,a novel online prediction model of flame temperature instantaneous structure based on deep convolutional neural network and long short-term memory(CNN-LSTM)is *** method uses the characteristics of local perception,shared weight,and pooling of CNN to extract the threedimensional(3D)features of flame temperature and outgoing radiation ***,the LSTM is used to comprehensively utilize the ten historical time series information of high dynamic combustion flame to accurately predict 3D temperature at three future moments.A chaotic time-series dataset based on the flame radiation forward model is built to train and validate the performance of the proposed CNN-LSTM *** is proven that the CNN-LSTM prediction model can successfully learn the evolution pattern of combustion flame and make accurate predictions.

关键词： temperature prediction convolutional neural network long short-term memory light field imaging online tomography

Dynamical nonlinear excitations induced by interaction quench in a two-dimensional box-trapped Bose-Einstein condensate

在线全文

学校读者我要写书评

暂无评论

Chinese Physics B 2024年第2期33卷 209-215页

作者：牛真霞高超 Department of Physics Zhejiang Normal UniversityJinhua 321004China Key Laboratory of Optical Information Detection and Display Technology of Zhejiang Zhejiang Normal UniversityJinhua 321004China

Manipulating nonlinear excitations,including solitons and vortices,is an essential topic in quantum many-body physics.A new progress in this direction is a protocol proposed in[***.2043256(2020)]to produce dark solitons in a one-dimensional atomic Bose–Einstein condensate(BEC)by quenching inter-atomic *** by this work,we generalize the protocol to a two-dimensional BEC and investigate the generic scenario of its post-quench *** an isotropic disk trap with a hard-wall boundary,we find that successive inward-moving ring dark solitons(RDSs)can be induced from the edge,and the number of RDSs can be controlled by tuning the ratio of the after-and before-quench interaction strength across different critical *** role of the quench played on the profiles of the density,phase,and sound velocity is also *** to the snake instability,the RDSs then become vortex–antivortex pairs with peculiar dynamics managed by the initial density and the after-quench *** tuning the geometry of the box traps,demonstrated as polygonal ones,more subtle dynamics of solitons and vortices are *** proposed protocol and the discovered rich dynamical effects on nonlinear excitations can be realized in near future cold-atom experiments.

关键词： Bose-Einstein condensate quench interaction soliton vortex

Atomistic study of inverse size effect induced by interfacial plasticity in pearlitic multi-principal element alloy

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第7期43卷 3341-3355页

作者： Chen Yang Qiao-Sheng xia Cun-hong Yin Dong-Peng Hua College of Mechanical Engineering Guizhou University Key Laboratory of Advanced Manufacturing Technology Ministry of EducationGuizhou University State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsNorthwestern Polytechnical University

Owing to the fine nano-laminated structure,the pearlitic multi-principal element alloy（PMPEA） exhibits excellent mechanical and tribological ***,the incomplete understanding of the size effect of its lamella thickness and the unclear understanding of the plasticity-interface interaction mechanism limit further optimization of *** this study,the FeCoNi/Ni3Ti interface-mediated plastic deformation behavior in PMPEA and the variation of mechanical and tribological properties with lamella thickness within the nanoscale range using molecular dynamics（MD） simulation were *** results indicate that the mechanical and tribological properties of the PMPEA with lamella thicknesses below 10 nm have a significant inverse size effect,i.e.,the smaller the lamella thickness,the weaker the *** is because the plastic carrier-interface interaction mechanism changes from a strengthening mechanism that hinders dislocations to a weakening mechanism that promotes dislocations with the decreases in the lamella thickness,and the weakening effect becomes more pronounced as the lamella thickness decreases and the number of interfaces *** particular,the deformation behavior of Ni3Ti lamellae changes from crystal-like to amorphous-like with decreasing ***,in the sample with larger lamella thickness,the occurrence of hierarchical slips in the body-centered cubic（BCC） phase due to the multiprincipal elements effect can better alleviate the stress concentration caused by the dislocation accumulation at the interface,so that the phase interface exhibits outstanding load-bearing *** the dislocation pattern in BCC phase shows a firm high-density cell,which makes the substrate exhibit a stable tribological response.

关键词： Multi-principal element alloy Nano-laminated structure Molecular dynamics simulation Nanoindentation and nanoscratch