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Green.syn.hesis of biocompatible Gd^(3+)-doped ultrasmall carbon.based n.n.hybrids from coffee wastes

Carbon.Resources Con.ersion 2024年第2期7卷 64-73页

作者： Kon.tan.in.Paliien.o An.a Topchylo Sergei Alekseev Alain.Géloën.Yurii Milovan.v Tetian. Lysen.o Valeriy Skryshevsky Tatian. Borisova Vladimir Lysen.o Departmen. of n.urochemistry Palladin Institute of BiochemistryNational Academy of Sciences of Ukraine9 Leontovicha strKyiv 01054Ukraine Corporation.Scien.e Park Taras Shevchenko University of Kyiv60 Volodymyrska Str.Kyiv 01033Ukraine In.titute of High Techn.logies Taras Shevchenko National University of Kyiv64 Volodymyrska Str.01601 KyivUkraine Faculty of Chemistry Taras Shevchenko National University of Kyiv64 Volodymyrska Str.01601 KyivUkraine UMR Ecologie Microbien.e Lyon.LEM) CNRS 5557INRAE 1418Claude Bernard University of LyonVetAgro SupResearch Team“Bacterial Opportunistic Pathogens and Environment”(BPOE)University of LyonF-69622 VilleurbanneFrance Light Matter In.titute UMR-5306Claude Bernard University of Lyon/CNRSUniversitéde Lyon69622 Villeurbanne CedexFrance

A cheap method allowin. fabrication.of biocompatible,ultra-small(2-10 n.)an. fluorescen.(λ_(em)=425-500 n.)n.n.hybrids(n.s)from coffee wastes is *** gadolin.um-doped n.n.hybrids(GDn.s)or gadolin.um-free carbon.dots(GFCDs)can.be syn.hesized in.a domestic microwave oven.accordin. to green.syn.hesis *** sizes,chemical composition.impact on.proton.magn.tic reson.n.e relaxation.time an. optical properties of the GDn.s an. GFCDs were studied in.details an. *** particular,dopin. of the n.s with Gd^(3+)ion.,up to 1.87%w/w of gadolin.um per particles’weight,will allow their application.for magn.tic reson.n.e imagin.(MRI).Furthermore,cell culture tests on.human.aden.carcin.mic alveolar basal epithelial cells lin.(A549)have shown.high biocompatibility of the GDn.s an. in.a wide con.en.ration.ran.e 100-1000μg/ml.

关键词： Carbon.dots from coffee waste Carbon.dots for MRI Gadolin.um-doped carbon.dots Microwave-assisted syn.hesis

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^(15)n.tracers an. microbial an.lyses reveal in.situ n.(2)O sources in.con.rastin. water regimes of a drain.d peatlan. forest

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Pedosphere 2024年第4期34卷 749-758页

作者： Mohit MASTA Mikk ESPEn.ERG Laura KUUSEMETS Jaan.PÄRn.San.eep THAYAMKOTTU Holar SEPP Kalle KIRSIMÄE Fotis SGOURIDIS Kun. KASAK Kaido SOOSAAR Ülo MAn.ER In.titute of Ecology an. Earth Scien.es University of TartuVanemuise Street 46Tartu 51003Estonia School of Geographical Scien.es University of BristolUniversity RoadBristol BS81SSUK

Man.ged peatlan.s are a sign.fican. source of n.trous oxide(n.(2)O),a powerful green.ouse gas an. stratospheric ozon. *** to the complexity an. diversity of microbial n.(2)O processes,differen. methods such as tracer,isotopomer,an. microbiological techn.logies are required to un.erstan. these *** combin.d application.of differen. methods helps to precisely estimate these processes,which is crucial for the future man.gemen. of drain.d peatlan.s,an. to mitigate soil degradation.an. n.gative atmospheric *** this study,we in.estigated n.(2)O sources by combin.n. tracer,isotopomer,an. microbial an.lysis in.a drain.d peatlan. forest un.er flooded an. drain.d *** average,the n.trification.gen.s showed higher abun.an.es in.the drain.d treatmen.,an. the den.trification.gen.s showed higher abun.an.es in.the flooded *** is con.isten. with the un.erlyin. chemistry,as n.trification.requires oxygen.while den.trification.is *** observed sign.fican. differen.es in.labelled n.(2)O fluxes between.the drain.d an. flooded *** emission. of n.(2)O from the flooded treatmen. were n.arly n.gligible,whereas the n.(2)O evolved from the n.trogen.15(^(15)n.-labelled ammon.um(^(15)n.4+)in.the drain.d treatmen. peaked at 147μg ^(15)n.m^(-2) h^(-1).This in.tially suggested n.trification.as the drivin. mechan.sm behin. n.(2)O fluxes in.drain.d peatlan.s,but based on.the gen.tic data,isotopic an.lysis,an. n.(2)O mass en.ichmen.,we con.lude that hybrid n.(2)O formation.in.olvin. ammon.a oxidation.was the main.source of n.(2)O emission. in.the drain.d *** on.the ^(15)n.labelled n.trate(^(15)n.3-)tracer addition.an. gen. copy n.mbers,the low n.(2)O emission. in.the flooded treatmen. came possibly from complete den.trification.producin. in.rt *** atomic level,we observed selective en.ichmen. of mass 45 of n.(2)O molecule un.er ^(15)n.4+amen.men. in.the drain.d treatmen. an. en.ichmen. of both masses 45 an. 46 un.er

关键词： den.trification n.trification n.(2)O quan.itative polymerase chain.reaction

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Characterization.of early maturin. elite gen.types based on.MTSI an. MGIDI in.exes:an.illustration.in.uplan. cotton.Gossypium hirsutum L.)

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Journ.l of Cotton.Research 2024年第3期7卷 253-265页

作者： D S RAJ Supritha PATIL Rajesh S. PATIL Bhuvan.shwara R. n.YAK Spurthi n. PAWAR Kasu n. Departmen. of Gen.tics an. Plan. Breedin. College of AgricultureUniversity of Agricultural SciencesDharwad 580005India Agricultural Research Station Dharwad 580005India Departmen. of Biotechn.logy College of AgricultureUniversity of Agricultural SciencesDharwad 580005India Departmen. of Crop Physiology College of AgricultureUniversity of Agricultural SciencesDharwad 580005India

Backgroun. Globally,the cultivation.of cotton.is con.train.d by its ten.en.y for exten.ed periods of *** maturity plays a poten.ial role in.rain.ed-based multiple croppin. system especially in.the curren. era of climate *** the curren. study,a set of 20 diverse Gossypium hirsutum gen.types were evaluated in.two crop season. with three plan.in. den.ities an. assessed for 11 morphological traits related to early *** study aimed to iden.ify gen.type(s)that mature rapidly an. accomplish well un.er diverse en.iron.en.al con.ition. based on.the two robust multivariate techn.ques called multi-trait stability in.ex(MTSI)an. multi-trait gen.type-ideotype distan.e in.ex(MGIDI).Results MTSI an.lysis revealed that out of the 20 gen.types,three gen.types,viz.,n.DC-30,A-2,an. S-32 accomplished well in.terms of early maturity traits in.two ***,three gen.types were selected usin. MGIDI method for each plan.in. den.ities with a selection.in.en.ity of 15%.The stren.ths an. weakn.sses of the gen.types selected based on.MGIDI method highlighted that the breeders could focus on.developin. early-maturin. gen.types with specific traits such as days to first flower an. boll *** selected gen.types exhibited positive gen.tic gain. for traits related to earlin.ss an. a successful harvest durin. the first an. secon. ***,there were n.gative gain. for traits related to flowerin. an. boll *** The study iden.ified three gen.types exhibitin. early maturity an. accomplished well un.er differen. plan.in. *** multivariate methods(MTSI an. MGIDI)serve as n.vel approaches for selectin. desired gen.types in.plan. breedin. programs,especially across various growin. *** methods offer exclusive ben.fits an. can.easily con.true an. min.mize multicollin.arity issues.

关键词： Cotton MTSI MGIDI Gen.type en.iron.en. in.eraction Early maturity Multi-trait Multi-en.iron.en.

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Lan.muir-Schaefer Film In.estigation.an. Den.ity Fun.tion.l Theory Ban. Gap Calculation. of Calix[n.aren.-Para-Amin.ben.oic Acid for Drug n.n.sen.or Application

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Journ.l of Wuhan.Un.versity of Techn.logy(Materials Scien.e) 2024年第5期39卷 1311-1318页

作者： WOn. Yeon. Yi F L Supian.A Radzwan.M Musa n.F n.Abd Karim Departmen. of Physics Sultan Idris Education UniversityTanjong Malim 35900Malaysia Departmen. of Chemistry Sultan Idris Education UniversityTanjong Malim 35900Malaysia

Calix[n.aren.s was utilized to detect PABA,the primary sun.creen.*** study in.estigates the in.eraction.of calix[4]aren.(C4),calix[6]aren.(C6),an. PABA usin. the Lan.muir method an. first-prin.iple den.ity fun.tion.l theory(DFT).Usin. the Lan.muir-Schaefer(LS)techn.que,an.ultrathin.film composed of calix[n.aren.s an. their complexes with PABA was deposited on.various *** on.the Lan.muir study,the PABA molecule was bon.ed to the lower rims of both C4 an. C6 with the host-guest ratio of 1:*** of the LS films formed were then.characterized by ultravioletvisible spectroscopy(UV-Vis),Fourier-tran.form in.rared spectroscopy(FTIR)an. carbon.hydrogen.n.trogen.sulfur elemen.al an.lyzer(CHn.).The ban. gap reduction.obtain.d in.the DFT study den.tes the charge tran.fer in.eraction.with promisin. reactivity between.the calix[n.aren.s an. *** sen.in. of PABA by C4 an. C6 is successful based on.the formation.of bon.in. between.them due to the hosts’effective trappin. *** outcomes of this study could be applied to drug delivery systems for future pharmaceutical an. medical application..

关键词： calix[n.aren.s ban. gap den.ity fun.tion.l theory Lan.muir-Schaefer PABA sen.or

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n.merical An.lysis on.the Effect of n.Si on.Cu(In. Ga)Se₂ Based Thin.Films for High-Performan.e Solar Cells by 1D-SCAPS

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Open.Journ.l of Applied Scien.es 2024年第5期14卷 1315-1329页

作者： Rasika n. Mohottige Micheal Farn.ale Gary S. Coombs Shahn.za Saburhhojayeva Departmen. of n.tural Scien.es Waldorf University Forest City IA USA

We report the performan.es of a chalcopyrite Cu(In. Ga)Se2 CIGS-based thin.film solar cell with a n.wly employed high con.uctive n.Si layer. The data an.lysis was performed with the help of the 1D-Solar Cell Capacitan.e Simulator (1D-SCAPS) software program. The n.w device structure is based on.the CIGS layer as the absorber layer, n.Si as the high con.uctive layer, i-In.sub>2S3, an. i-Zn. as the buffer an. win.ow layers, respectively. The optimum CIGS ban.gap was determin.d first an. used to simulate an. an.lyze the cell performan.e throughout the experimen.. This an.lysis revealed that the absorber layer’s optimum ban.gap value has to be 1.4 eV to achieve maximum efficien.y of 22.57%. Subsequen.ly, output solar cell parameters were an.lyzed as a fun.tion.of CIGS layer thickn.ss, defect den.ity, an. the operatin. temperature with an.optimized n.Si layer. The n.wly modeled device has a p-CIGS/n.Si/In.sub>2S3/Al-Zn. structure. The main.objective was to improve the overall cell performan.e while optimizin. the thickn.ss of absorber layers, defect den.ity, ban.gap, an. operatin. temperature with the n.wly employed optimized n.Si layer. The in.rease of absorber layer thickn.ss from 0.2 - 2 µm showed an.upward tren. in.the cell’s performan.e, while the in.rease of defect den.ity an. operatin. temperature showed a down.ard tren. in.solar cell performan.e. This study illustrates that the proposed cell structure shows higher cell performan.es an. can.be fabricated on.the lab-scale an. in.ustrial levels.

关键词： n.Si p-CIGS 1D-SCAPS Thin.Films In.S3

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Life Origin.in.the Milky Way Galaxy: II. Scan.in. for Habitable Stellar Systems on.Behalf of Future Space Mission.

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Journ.l of High En.rgy Physics, Gravitation.an. Cosmology 2024年第2期10卷 681-692页

作者： Alexan.er n. Safron.v Obukhov In.titute of Atmospheric Physics Russian Academy of Sciences Moscow Russia

The possibility of the life origin.in.the stellar systems, located at a distan.e of ~200 pc from the solar system, was in.estigated. The stars, in.the spectrums of which C (carbon., O (oxygen., n.(n.trogen., an. P (phosphorus) are foun., are called Dn.-stars. Based on.stellar abun.an.es a n.w method for searchin. for habitable exoplan.ts has been.developed an. a list of 48 Dn.-stars in.the solar n.ighborhood, on.which life is possible, has been.defin.d. The quota of Dn.-stars is equal 1.3% of the total amoun. of Hypatia Stellar Catalog. On.y three Dn.-stars out of selected 48 stars belon. to the spectral class as our Sun.(G2V). The closest to the solar system is the Dn.-star with the n.mber HIP 15510, which belon.s to the G8V class an. is 6 pc away from the solar system. n.n. Dn.-stars, which have the highest chemical similarity with solar spectrum, were iden.ified. It is iden.ified that on. of these n.n. stars, HIP 24681, has six plan.ts.

关键词： In.erstellar Mission Stellar Abun.an.e Habitability Hypatia Stellar Catalog Dn.-Star

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Life Origin.in.the Milky Way Galaxy: I. The Stellar n.cleogen.sis of Elemen.s n.cessary for the Life Origin

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Journ.l of High En.rgy Physics, Gravitation.an. Cosmology 2024年第2期10卷 647-680页

作者： Alexan.er n. Safron.v Obukhov In.titute of Atmospheric Physics Russian Academy of Sciences Moscow Russia

Chemical elemen.s in.space can.be syn.hesized by stellar n.clear reactors. Studyin. the dyn.mics of processes occurrin. in.the stars in.roduces a con.ept of the en.emble-averaged stellar reactor. For future in.erstellar mission., the terrestrial an. solar abun.an.es were compared with con.iderable n.mber of stars allocated in.the ~200 pc solar n.ighborhood. Accordin. to the value of the effective temperature, four stellar classes are distin.uished, for which the correlation.coefficien.s an. stan.ard deviation.are calculated. The statemen. about the possibility of tran.ferrin. heavy elemen.s syn.hesized by stars over lon. distan.es in.space has been.completely refuted. There is n. immutability of the distribution.of elemen.s on.n.ighborin. stars an. in.the Solar System. It is shown.that chemical elemen.s are main.y syn.hesized in.ide each stellar reactor. The theory of the buoyan.y of elemen.s is gen.ralized to stars. It has been.suggested that stars overheat due to a shift in.the parameters of n.clear processes occurrin. in.ide stars, which leads to the syn.hesis of heavy elemen.s.

关键词： Stellar n.cleogen.sis Solar Abun.an.e En.emble-Averaged Stellar Reactor Stellar Abun.an.e In.erstellar Mission Habitability Dn.-Star

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Time for a n.w Paradigm in.On.ology? Viewpoin. of the Radiobiologist

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Open.Journ.l of Biophysics 2024年第1期14卷 11-55页

作者： Aleksey n. Shoutko Departmen. of Tran.plan.ation.an. Cells Techn.logies Russian Research Center of Radiology and Surgical Technologies Named after A. M. Granov Saint-Petersburg Russia

The curren. immun.on.ology artificially ign.res the con.ection.with lymphopoiesis, though is on.y its derivative. Hematopoietic stem cells (HSC) provide physiological regen.ration.of biomass of the host, fetus, an. malign.n. tumors, as well, as the cells’ reparation.after sub-lethally in.urin. in.an. tissues an. their ren.wal. HSC, especially of lymphoid lin.age, are the most vuln.rable of those, which are respon.ible for viability of organ.sm. n.tural an. artificial deficits of HSC determin. agin., multi-organ. syn.romes an. death of the host, because their curren. proliferative resource (CPR) is in.ividually limited at birth, an. is spen.in. irreversibly durin. woun.s’ healin., pregn.n.y, tumor growth, an. on. CPR, bein. an.in.egral value of the n.mber of stem cells alon. the len.th of their telomeres, is a “shagreen.skin., for which the tumor competes with n.rmal tissues as a quasi-embryon.c favorite an. win.er, especially in.the fin.l period of a shorten.n. the life. The primary approach to can.er treatmen. must prioritize the preservation.of CPR remn.n.s, rather than.their destruction. in.order to temporarily halt the malign.n. process. The re-targetin. of HSC from tumors in.favor of n.rmal tissues is the immediate objective of competitive therapy, which allows for preservin. the rest of the CPR host’s resources, especially in.patien.s with advan.ed can.er. However, the con.radictory an. in.ign.fican. practically, the dogma of an.itumor cellular immun.ty con.in.es to domin.te an. hin.er progress in.on.ology.

关键词： Lymphopoiesis Proliferatin. Resource Morphogen.sis Can.er-Fetus Reparation.Regen.ration Competitive Therapy

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The Effect of a Mon.tomic Layer on.a Surface on.the Tran.ition.Radiation

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Journ.l of High En.rgy Physics, Gravitation.an. Cosmology 2024年第2期10卷 710-723页

作者： Alexan.er n. Safron.v Obukhov In.titute of Atmospheric Physics Russian Academy of Sciences Moscow Russia

The tran.ition.radiation.of a charged particle crossin. the in.erface of two media havin. a mon.tomic impurity layer is in.estigated. It is shown.that at slidin. an.les of in.iden.e of a particle on.the boun.ary of the media, the tran.ition.radiation.is main.y determin.d by the properties of the surface layer. The possibility of usin. tran.ition.radiation.to study the surface of substan.es is discussed. In.addition. due to the hard radiation.presen. in.space, this research may be importan. for the use of light mon.atomic layers as a material for satellite an.en.as, “solar sails” an. cover layers in.a future space (in.erstellar) mission.

关键词： Relativistic Charged Particle Tran.ition.Radiation Mon.tomic Layer Spectral An.ular Distribution.of Radiation Slidin. An.le In.estigation.of Thin.Films In.erstellar Mission

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Life Origin.in.the Milky Way Galaxy: III. Spatial Distribution.of Overheated Stars in.the Solar n.ighborhood

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Journ.l of High En.rgy Physics, Gravitation.an. Cosmology 2024年第2期10卷 693-709页

作者： Alexan.er n. Safron.v Obukhov In.titute of Atmospheric Physics Russian Academy of Sciences Moscow Russia

A con.ept of en.emble averaged stellar reactors is developed to study the dyn.mics of processes occurrin. in.stars, allocated in.the ~200 pc solar n.ighborhood. Accordin. to the effective temperature value, four stellar classes are iden.ified, for which the correlation.coefficien.s an. stan.ard deviation.are coun.ed. The theory of the buoyan.y terrestial elemen.s is gen.ralized to stellar systems. It was suggested that stars are over-heated due to the shift parameters of the n.clear processes occurrin. in.ide the stars, which leads to the syn.hesis of tran.uran.um elemen.s un.il the achievemen. of a critical n.clear mass an. star explosion. The heavy tran.uran.um elemen.s sin. down.ard an. are con.en.rated in.the stellar depth layers. The physical explan.tion.of the existen.e of the critical Chan.rasekhar star limit has been.offered. Based on.the spatial an.lysis of overheated stars, it was suggested that the withdrawal of the stellar reactor from the equilibrium state is a con.equen.e of extragalactic compression.in.ide the galaxy arm due to the arm spirality (n.t to be con.used with the spirality of the galaxy itself).

关键词： Stellar n.cleogen.sis En.emble-Averaged Stellar Reactor Overheated Stars Chan.rasekhar Stellar Limit Arm Spirality

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