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Production of Spirulina platensis Using Inexpensive Local Resources in Palestine

Journal of Environmental Protection 2024年第3期15卷 357-377页

作者： Imad Al-Jabali Ahmad qutob Mahmoud Alkhatib mutaz qutob Department of Environment and Earth Studies Al-Quds University Jerusalem Palestine Department of Electrical Engineering Faculty of Engineering Al-Quds University Jerusalem Palestine Department of Chemistry and Chemical Technology Al-Quds University Jerusalem Palestine

Spirulina platensis is a special and unique cyanobacteria that is produced worldwide with a varied cost of cultivation media. In this study, five main experiments with different treatments were performed to evaluate the possibility of using cheap aquaculture water for Spirulina production, to test if solutions made by plant ash (PAS) could be used for Spirulina production, to determine if brackish water (BW) and mining water have a good impact on Spirulina production, to create a medium composed of cheap chemicals and fertilizers to be used for Spirulina cultivation, and to test if a mixture made from local components could be used to produce Spirulina. All experiments were performed via growth and dry weight measurements, including determination of chemical and physical characteristics of the samples with a comparison with Zarrouk medium (ZM) as a reference for each experiment, and all experiments were performed for 21 days to determine the best media type that lasts longer for commercial purposes. In all experiments, pH values were between 8 and 11, and EC was between 9.8 and 30 ms/cm, while temperature was at 30°C and 35°C, and light was at 1500 and 5000 Lux for 16 h light and 8 h dark. Spirulina can grow in (FW). It can also grow in FW diluted with BW. Also a 3% PAS can be used as a source to cultivate Spirulina at a very low price compared to ZM. The chemical fertilizer formula was one of the best types among all treatments with a good price. A mixture of these local resources could be a very good cheap alternative source. The main result that was obtained from all experiments in this study is the ability of Spirulina to grow within a wide range of chemical parameters at a lower price.

关键词： Spirulina platensis Tilapia Brackish Water Zarrouk Medium

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Production of Spirulina platensis Using Inexpensive Local Resources in Palestine

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Journal of Environmental Protection（环境保护） 2024年第3期 357页

作者： Imad Al-Jabali Ahmad qutob Mahmoud Alkhatib mutaz qutob

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Analysis of Different Rare Metals, Rare Earth Elements, and other Common Metals in Groundwater of South West Bank/Palestine by ICP/MS-Data and Health Aspects

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Journal of Environmental Protection 2013年第10期4卷 1157-1164页

作者： Fuad Al-Rimawi Khalid Kanan mutaz qutob 1Department of Earth and Environmental Studies Faculty of Science and Technology Al-Quds University East Jerusalem Palestine 2Aquatic and Aquaculture Research Laboratory Al-Quds University East Jerusalem Palestine. Faculty of Science and Technology Al-Quds University East Jerusalem Palestine

Ground water samples are collected from south West Bank/Palestine and analyzed for different rare elements (Rb, Zr, U, P, Ti, V), rare earth elements (La, Ce, and Nd), and other common trace metals (Li, Na, Mg, Ca, Sr, Ba, K, Bi) that most of them usually have no maximum acceptable limits as either they are considered not to be toxic to human health or there is no sufficient data about their toxicity to human health. This study was conducted to determine the water quality of ground water which is used for drinking in the study area. Water samples from ten groundwater wells were obtained in three different dates of the year (November 2012, March 2013, and April 2013). Three water samples were obtained from each well for each sampling date;so a total of 90 water samples were collected from the ten wells. The results obtained from this study suggest a possible risk to the population of the study area given the high concentration of some metals that have no maximum allowed concentration, and the fact that for many people in the study area, ground water is a main source of their water supply.

关键词： Rare Metals Rare Earth Elements WHO Limits ICP/MS Ground Water West Bank

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Determination of Different Trace Heavy Metals in Children’s Plastic Toys Imported to the West Bank/Palestine by ICP/MS-Environmental and Health Aspects

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Journal of Environmental Protection 2014年第12期5卷 1104-1110页

作者： mutaz Al-qutob Ahmad Asafra Tharwat Nashashibi Ahmad A. qutob Department of Earth and Environmental Studies Faculty of Science and Technology Al-Quds University Jerusalem Aquatic and Aquaculture Research Laboratory Al-Quds University Jerusalem Department of Electronic Engineering Faculty of Engineering Al-Quds University Jerusalem

The main aim of this study is to assess the quality of inexpensive plastic toys imported to Palestinian Markets. The content of heavy metals (Pb, Cd, Cr, Hg, As, Se, Ba, and Zn) was analyzed in 50 plastic toys purchased from local markets in Palestine and 17 plastic toys purchased from Israeli markets for comparison. After the digestion of samples with concentrated nitric acids and hydrogen peroxide using a microwave digester, the concentrations of the selected heavy metals were determined by ICP-MS Agilent 7500 in Al-Quds University. Results revealed that 40% of the Palestinian toy samples had high concentration (above international limits) of Pb, 30% of Cd, 34% of Cr, 6% of Hg, 42% of As, 32% of Se, 20% of Ba, and 40% of Zn. On the other hand, 95% of the Israeli samples were safe, and their concentrations were less than the maximum internationally allowable limits. In the same context, ten toy samples (2.5 gm each) had been crushed and dipped for 8 hours in a solution of artificial saliva. The solution was acidified and tested for heavy metal concentrations, but none of the migration concentrations exceeded the international maximum allowable limit. High levels of heavy metal concentrations, found in the plastic toys from the Palestinian markets could form a health hazard to children and put their lives at risk. It could be also an indirect source for environmental pollution.

关键词： Plastic Toys Heavy Metals Content Palestinian Markets Israeli Markets

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Heavy Metals Concentrations in Leafy Vegetables in Palestine, Case Study: Jenin and Bethlehem Districts

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Journal of Environmental Protection 2022年第1期13卷 97-111页

作者： Mahmoud AlKhatib Ahmad qutob Elizabeth Kattan Husam Malassa mutaz qutob Department of Chemistry and Chemical Technology Al-Quds University Jerusalem Palestine Department of Electrical Engineering Faculty of Engineering Al-Quds University Jerusalem Palestine Department of Environment and Earth Studies Al-Quds University Jerusalem Palestine

This study investigates the concentrations of metals in leafy vegetables in Bethlehem and Jenin districts in Palestine. The concentrations of Fe, Pb, Cr, Co, Cu, Mn, Cd, and Zn were measured. Vegetables including spinach, arugula, and parsley were collected from different farms from both regions, and analyzed by using ICP-MS. In Bethlehem region, Iron concentrations were ranged from 25 to 1046 mg/kg. Iron concentrations were higher than the WHO/FAO limits of 425 mg/kg in 33% of the samples. Lead concentrations were ranged from 0.04 to 1.77 mg/kg. Lead concentrations were higher than the WHO/FAO limits of 0.3 mg/kg in 40% of the samples. Chromium concentrations were ranged from 0.02 to 2.51 mg/kg. Chromium concentrations were higher than the WHO/FAO limits of 1.3 mg/kg in 13% of the samples. Zinc concentrations were ranged from 4 to 107 mg/kg. Zinc concentrations were higher than the WHO/FAO limits of 99.4 mg/kg in 6.6% of the samples. Cadmium concentrations were ranged from 0.01 to 1.4 mg/kg. Cadmium concentrations were higher than the WHO/FAO limits of 0.2 mg/kg in 13% of the samples. The concentration of Manganese, Cobalt and Cupper were all below the WHO/FAO limits of 500, 50 and 73 mg/kg respectively. In Jenin region, Iron concentrations were ranged from 42 to 543 mg/kg. Iron concentrations were higher than the WHO/FAO limits of 425 mg/kg in 20% of the samples. Lead concentrations were ranged from 0.05 to 0.67 mg/kg. Lead concentrations were higher than the WHO/FAO limits of 0.3 mg/kg in 20% of the samples. Copper concentrations were ranged from 0.62 to 278 mg/kg. Copper concentrations were higher than the WHO/FAO limits of 73 mg/kg in 6.66% of the samples. Cadmium concentrations were ranged from 0.02 to 1.62 mg/kg. Cadmium concentrations were higher than the WHO/FAO limits of 0.2 mg/kg in 6.66% of the samples. The concentration of Chromium, Manganese, Cobalt and Cupper were all below the WHO/FAO limits. It was concluded that the contamination found in some leaf

关键词： Heavy Metals Vegetables Pesticides

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Evaluation of Heavy Metal Concentrations in Soil and Edible Vegetables Grown in Compost from Unknown Sources in Al-Jiftlik, Palestine

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Journal of Environmental Protection 2022年第1期13卷 112-125页

作者： Mohammed Bawwab Ahmad qutob Mahmoud Al Khatib Husam Malassa Ayman Shawahna mutaz qutob Department of Materials Engineering Faculty of Engineering Al-Quds University Jerusalem Palestine Department of Electrical Engineering Faculty of Engineering Al-Quds University Jerusalem Palestine Department of Chemistry and Chemical Technology Al-Quds University Jerusalem Palestine Environment Quality Authority Al-Bireh Palestine

The use of compost as a fertilizer has been widely used in many countries. However, compost that contains heavy metals can transfer these metals to soils and plants (vegetables). This study investigates the concentrations of metals in soil and edible vegetables that were fertilized by polluted unknown compost in Al-Jiftlik region (Palestine). The source of the compost is the autocratic dumping sites of the Israeli settlements. The compost is distributed free of charge to the Palestinian farmers. The concentrations of Ba, Cu, Pb, Th, Se, Mn, Co and As in the contaminated farms were measured. Vegetables include: Eggplant, Corn, Bell Pepper, Cucumber and Marrow. Metals availability as well as the pH, was also examined in the soil samples. Normal farms that did not use this unknown compost were used as a reference. The concentrations of Ba, Cu, Pb, Th, Se, Mn, Co and As in soil and vegetables in the polluted farms were above the WHO limits. Barium concentrations in the vegetables were ranged from 1.00 mg/kg to 0.453 mg/kg. It is high when compared to WHO limit of 0.3 mg/kg. Copper concentrations in the vegetables were ranged from 63.84 mg/kg to 50.53 mg/kg. It is high when compared to WHO limit of 40 mg/kg. Lead concentrations in the vegetables were ranged from 1.00 mg/kg to 0.453 mg/kg. Lead concentration is high when compared to WHO limit of 0.3 mg/kg. Thallium concentrations in the vegetables were ranged from 2.99 mg/kg to 1.22 mg/kg. Thallium concentration is high when compared to WHO limit of 0.3 mg/kg. Selenium concentrations in the vegetables were ranged from 0.550 mg/kg to 0.348 mg/kg. It is high when compared to WHO limit of 0.3 mg/kg. Manganese concentrations in the vegetables were ranged from 825.3 mg/kg to 446.2 mg/kg. It is almost high when compared to WHO limit of 500 mg/kg. Cobalt concentrations in the vegetables were ranged from 1.119 mg/kg to 0.522 mg/kg. Cobalt concentration is high when compared to WHO limit of 0.1 mg/kg. A

关键词： Compost Heavy Metals Vegetables Autocratic Dumping

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Determination of Different Trace Heavy Metals in Ground Water of South West Bank/Palestine by ICP/MS

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Journal of Environmental Protection 2013年第8期4卷 818-827页

作者： Husam Malassa mutaz Al-qutob Mahmoud Al-Khatib Fuad Al-Rimawi 1Department of Earth and Environmental Studies Faculty of Science and Technology Al-Quds University East Jerusalem Palestinian Authority 2Aquatic and Aquaculture Research Laboratory Al-Quds University East Jerusalem Palestinian Authority. Faculty of Science and Technology Al-Quds University East Jerusalem Palestinian Authority

Heavy metal contamination of the groundwater of south West Bank in Palestine was assessed. The groundwater samples were analyzed for different trace heavy metals (Tl, Pb, Bi, Cr, Mn, Co, Ni, Cu, Zn, Mo, Ag, and Cd), and Al content by ICP/MS. This study was conducted to determine the water quality of ground water which is used for drinking in the study area. Water samples from ten groundwater wells were obtained in four different dates of the year (October 2012, November 2012, March 2013, and April 2013). Three water samples were obtained from each well for each sampling date. A total of 120 water samples were collected from the ten wells. The samples were analyzed for their pH, electrical conductivity, total dissolved solids, and different trace metals content. The pH, electrical conductivity, and total dissolved solids of all water samples were found to be within the US Environmental protection Agency limits. Results showed that Pb, Al, Cr, Co, Ni, Cu, Zn, and Mo were detected in all water samples analyzed in this study, while Tl, Bi, Mn, Ag, and Cd were detected in 80%, 88%, 90%, 75%, and 95% of the water samples analyzed in this study, respectively. In general, 93% of all samples analyzed contained one or more of the 13 metals studied each in varying concentration. Furthermore, results showed that the concentration of Cr, Mn, Ni, Cu, Zn, and Mo is within the allowed WHO limits in drinking water. However the concentration of Pb Cd, and Al are found to be higher than the allowed WHO limits in 40%, 8%, and 33% of the water samples analyzed in this study, respectively. Statistical analyses showed that concentrations of the metals studied in this study vary significantly between the ten ground water wells, indicating that the wells analyzed in this study is different from each other in terms of heavy metal content. Additionally, from the statistical results obtained, it was found that there is a significant difference in the concentration of the metals in each well fo

关键词： Heavy Metals WHO Limits ICP/MS Ground Water West Bank

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Assessment of Groundwater Pollution with Heavy Metals in North West Bank/Palestine by ICP-MS

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Journal of Environmental Protection 2014年第1期5卷 54-59页

作者： Husam Malassa Mohamad Hadidoun Mahmoud Al-Khatib Fuad Al-Rimawi mutaz Al-qutob 1Department of Earth and Environmental studies Faculty of Science and Technology Al-Quds University East Jerusalem Palestine 2Aquatic and Aquaculture Research Laboratory Al-Quds University East Jerusalem Palestine Faculty of Science and Technology Al-Quds University East Jerusalem Palestine Palestinian Water Authority Ramallah Palestine

Groundwater of North West Bank in Palestine was assessed for pollution with trace metals by ICP/MS. The samples were analysed for their pH, electrical conductivity, total dissolved solids, and different trace metals content. The pH, electrical conductivity, and total dissolved solids of all water samples were found to be within the US Environmental protection Agency limits. Results showed that the concentration of nine trace metals (Cr, Mn, Ni, Cu, Zn, Mo, Pb, Cd, and Al) is within the WHO limits in drinking water (50, 500, 20, 2000, 3000, 70, 10, 3, and 200 ug/L, respectively), however six metals of them (Cr, Mn, Ni, Cu, Mo, and Al) were detected in 100% of the samples, while Pb, Cd, and Zn were detected in 80%, 60%, and 20% of the samples, respectively. On the other hand, Tl which is a very toxic heavy metal with allowed WHO limits of 0.01 - 1 ug/L is detected in 100% of the water samples analysed with a range of 0.02 - 0.12 ug/L. It indicates that such concentration levels of Tl would be harmful to the human being drinking the water. In general, 82% of all samples analysed contained one or more of the 12 metals studied each in varying concentration. Results of this study suggest a possible risk to the people of the study area given the toxicity of heavy metals, and the fact that for many people in the study area, groundwater is a main source of their water supply.

关键词： Heavy Metals Ground Water Palestine Pollution ICP-MS

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Hexavalent Chromium Removal and Reduction to Cr (III) by Polystyrene Tris(2-aminoethyl)amine

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American Journal of Analytical Chemistry 2015年第1期6卷 26-37页

作者： Lina Odeh Imad Odeh Mustafa Khamis Mahmoud Khatib Mohannad Qurie Ziad Shakhsher mutaz qutob Department of Chemistry and Chemical Technology Al-Quds University Jerusalem Palestine Center for Chemical and Biological Analysis Al-Quds University Jerusalem Palestine Department of Earth and Environmental Studies Al-Quds University Jerusalem Palestine

A commercially available chelating polymer, polystyrene tris(2-aminoethyl)amine, was used for the removal of chromium from aqueous solution. The influence of pH, contact time, adsorbent dosage and initial Cr (VI) concentration on adsorption was studied. The optimum pH for the removal of Cr (VI) was at pH 5, while optimum contact time and adsorbent dosage were 120 minutes and 10 g/L, respectively. Total chromium and Cr (VI) concentrations were analyzed by ICP-MS and UV-Visible. Adsorption isotherms using Langmuir and Freundlich isotherm models revealed that the data fitted Langmuir isotherm model better than Freundlich with a maximum adsorption capacity of 312.27 mg/g. FTIR spectroscopy, Scanning electron microscopy (SEM) and Energy Dispersive Spectrometry (EDS) analyses were performed on the adsorbent before and after binding Cr (VI). All analyses confirmed the complexation of Cr (VI) to the adsorbent. Desorption experiments using KCl solution indicated 89.3% release of chromium, rendering this method of high potential for adsorbent regeneration.

关键词： Adsorption of Cr (VI) Polystyrene Tris(2-aminoethyl)amine ICP-MS SEM EDS

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Failure characterization of fully grouted rock bolts under triaxial testing

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第3期16卷 778-789页

作者： Hadi Nourizadeh Ali Mirzaghorbanali Mehdi Serati Elamin mutaz Kevin McDougall Naj Aziz Centre for Future Materials(CFM) School of EngineeringUniversity of Southern QueenslandToowoombaQLD4350Australia School of Engineering University of Southern QueenslandSpringfield CentralQLD4300Australia School of Civil Engineering University of QueenslandSt LuciaQLD4072Australia School of Surveying and Build Environment University of Southern QueenslandToowoombaQLD4350Australia School of Civil Mining&Environmental EngineeringUniversity of WollongongWollongongNSW2500Australia

Confining stresses serve as a pivotal determinant in shaping the behavior of grouted rock ***,prior investigations have oversimplified the three-dimensional stress state,primarily assuming hydrostatic stress *** these conditions,it is assumed that the intermediate principal stress(σ_(2))equals the minimum principal stress(σ_(3)).This assumption overlooks the potential variations in magnitudes of in situ stress conditions along all three directions near an underground opening where a rock bolt is *** this study,a series of push tests was meticulously conducted under triaxial *** tests involved applying non-uniform confining stresses(σ_(2)≠σ_(3))to cubic specimens,aiming to unveil the previously overlooked influence of intermediate principal stresses on the strength properties of rock *** results show that as the confining stresses increase from zero to higher levels,the pre-failure behavior changes from linear to nonlinear forms,resulting in an increase in initial stiffness from 2.08 kN/mm to 32.51 kN/*** load-displacement curves further illuminate distinct post-failure behavior at elevated levels of confining stresses,characterized by enhanced ***,the peak load capacity ranged from 27.9 kN to 46.5 kN as confining stresses advanced from σ_(2)=σ_(3)=0 to σ_(2)=20 MPa and σ_(3)=10 ***,the outcomes highlight an influence of confining stress on the lateral deformation of *** levels of confinement prompt overall dilation in lateral deformation,while higher confinements maintain a state of ***,diverse failure modes have been identified,intricately tied to the arrangement of confining *** confinements tend to induce a splitting mode of failure,whereas higher loads bring about a shift towards a pure interfacial shear-off and shear-crushed failure mechanism.

关键词： Rock bolts Bolt-grout interface Bond strength Push test Triaxial tests

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